New experimental determination of Li and B partition coefficients during upper mantle partial melting   总被引：1，自引：1，他引：0  

Luisa Ottolini  Didier Laporte  Nicola Raffone  Jean-Luc Devidal  Brieuc Le Fèvre 《Contributions to Mineralogy and Petrology》2009,157(3):313-325

Despite the growing interest for Li and B as geochemical tracers, especially for material transfer from subducting slabs to overlying peridotites, little is known about the behaviour of these two elements during partial melting of mantle sources. In particular, mineral/melt partition coefficients for B and to a lesser extent Li are still a matter of debate. In this work, we re-equilibrated a synthetic basalt doped with ~10 ppm B and ~6 ppm Li with an olivine powder from a spinel lherzolite xenolith at 1 GPa–1,330°C, and we analyzed Li and B in the run products by secondary ion mass spectrometry (SIMS). In our experiment, B behaved as a highly incompatible element with mineral/melt partition coefficients of the order of 10⁻² (D ^ol/melt = 0.008 (0.004–0.013); D ^opx/melt = 0.024 (0.015–0.033); D ^cpx/melt = 0.041 (0.021–0.061)), and Li as a moderately incompatible element (D ^ol/melt = 0.427 (0.418–0.436); D ^opx/melt = 0.211 (0.167–0.256); D ^cpx/melt = 0.246 (0.229–0.264)). Our partition coefficients for Li are in good agreement with previous determinations. In the case of B, our partition coefficients are equal within error to those reported by Brenan et al. (1998) for all the mineral phases analyzed, but are lower than other coefficients from literature for some of the phases (up to 5 times for cpx). Our measurements complement the data set of Ds for modelling partial melting of the upper mantle and basalt generation, and confirm that, in this context, B is more incompatible than previously anticipated.  相似文献   

Plagioclase and other mineral equilibria in a contact metamorphic aureole     

María Luisa Crawford 《Contributions to Mineralogy and Petrology》1972,36(4):293-314

Plagioclase, microcline, amphibole, clinozoisite, clinopyroxene and biotite from alternating pelitic and calcareous hornfelses of the Wyman Formation, Blanco Mountain Quadrangle, California, were analyzed using an electron microprobe. The metamorphic aureole formed at temperatures of 300–600° C, total pressure 2–3 Kb, and low but variable partial pressure of CO₂. The minerals show some compositional changes with metamorphic grade as well as differences from one assemblage to another. The plagioclases developed in the aureole do not form a continuous series. Rather, coexisting grains of plagioclase in individual rock layers form at certain distinct compositions: An 1–3, 15–17, 28–32, 38–45, 51–55, 59–65, 75 and 80. There is no evidence of disequilibrium in the rocks, although diffusion was limited; the volume for chemical equilibrium for most samples was less than 1 mm. Inspection of the changes in mineral assemblages with increasing degree of metamorphism and with changes in fluid composition suggests a number of reactions between the phases. Neither these reactions nor the compositions of coexisting minerals provide an obvious explanation for the observed gaps in the plagioclase series. Therefore it is postulated that the compositional clustering is structurally controlled.  相似文献   

Melt migration in the upper mantle along the Romanche Fracture Zone (Equatorial Atlantic)   总被引：1，自引：0，他引：1  

Paola Tartarotti  Sara Susini  Paolo Nimis  Luisa Ottolini 《Lithos》2002,63(3-4):125-149

Textural and petrological data of mantle peridotites sampled in the central and western parts of the Romanche Fracture Zone (Equatorial Atlantic) during the oceanographic expedition PRIMAR-96 (Russian R/V Gelendzhik) are presented. The studied rocks are mantle peridotites carrying patches, pockets and veins/dikes of magmatic origin, interpreted to be the product of various extents of magma impregnation on mantle partial melting residues. Estimated partial melting degrees based on clinopyroxene Ti/Zr ratios are in the ranges 5–13% and 18–20%. In highly impregnated samples, refertilization of residual peridotite minerals precludes a correct evaluation of the degree of melting. Magmatic products occur as pl±cpx±opx±ol±sp aggregates with various textural features. Interstitial pl-rich patches and gabbroic pockets are interpreted to derive from magma migration through the upper mantle by diffusive porous flow in the ductile part of the lithosphere and melt–rock reactions. Metasomatism of the host peridotites is testified by Ti and Cr increase in spinel and Ti, Sr, Zr, Y and LREE increase in clinopyroxene. Veins and dikes reflect channeled magma migration focused by brittle failures at shallower lithospheric levels. Minor or no chemical changes occurred in peridotites impregnated along fractures. The compositions of magmatic minerals in impregnated peridotites are consistent with derivation from variably fractionated melts of probably MORB type. Barometric estimates suggest that the Romanche peridotites were impregnated at minimum depths of ca. 9–12 km. Thermometric estimates for the peridotite hosts are in the range 750–1050 °C. The spread in temperature values is partly ascribed to localized heating by migrating melts of relatively cold peridotites. Our data and the occurrence of both fertile and depleted peridotites in a neighbouring area along the western Romanche FZ are in accord with the hypothesis of small-scale (<100 km) mantle heterogeneity along this fracture zone.  相似文献   

Pliocene marine deposits at Punta Maldonado, Guerrero state, Mexico     

Edgar Jurez-Arriaga  Ana Luisa Carreo  Jos Luis Snchez Zavala 《Journal of South American Earth Sciences》2005,19(4):537-546

Diverse and abundant Foraminifera and Ostracoda assemblages were recovered from a measured stratigraphic section at Punta Maldonado, Guerrero state, Mexico. The planktonic species indicate an early Pliocene age, between 5.3 and 3.6 Ma; an early late Pliocene (around 2.4 Ma) planktonic assemblage also was recorded from isolated deposits. These ages contradict the Cretaceous–Paleogene age previously assigned to the sedimentary succession at Punta Maldonado. All indicators—benthic assemblages, ichnofacies, lithology, grain size, primary structures, mineralogy, body rock geometry, and facies—suggest deposition in the foreshore and offshore transition zones of a storm-dominated shallow siliciclastic shelf. The Ostracoda and Foraminifera indicate deposition around the outer neritic/upper bathyal boundary, which suggests an uplift of 320–400 m in the area during the Pliocene. This study represents the first report of Pliocene marine rocks in the southwestern coast of Mexico; the data presented contribute to regional geotectonic models.  相似文献   

Daily patterns of CO2 in the lower atmosphere of a rural site     

Isidro A. Pérez  M. Luisa Sánchez  M. Ángeles García  Nuria Pardo 《Theoretical and Applied Climatology》2015,122(1-2):195-205

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The thin and medium filters of the EPIC camera on-board XMM-Newton: measured performance after more than 15 years of operation     

Marco Barbera  Fabio Gastaldello  Luisa Sciortino  Simonpietro Agnello  Gianpiero Buscarino  Alfonso Collura  Nicola La Palombara  Ugo Lo Cicero  Nicola Sartore  Andrea Tiengo  Salvatore Varisco  Anna Maria Venezia 《Experimental Astronomy》2016,42(2):179-197

After more than 15 years of operation of the EPIC camera on board the XMM-Newton X-ray observatory, we have reviewed the status of its Thin and Medium filters. We have selected a set of Thin and Medium back-up filters among those still available in the EPIC consortium and have started a program to investigate their status by different laboratory measurements including: UV/VIS transmission, Raman scattering, X-Ray Photoelectron Spectroscopy, and Atomic Force Microscopy. Furthermore, we have investigated the status of the EPIC flight filters by performing an analysis of the optical loading in the PN offset maps to gauge variations in the optical and UV transmission. We both investigated repeated observations of single optically bright targets and performed a statistical analysis of the extent of loading versus visual magnitude at different epochs. We report the results of the measurements conducted up to now. Most notably, we find no evidence for change in the UV/VIS transmission of the back-up filters in ground tests spanning a 2 year period and we find no evidence for change in the optical transmission of the thin filter of the EPIC-pn camera from 2002 to 2012. We point out some lessons learned for the development and calibration programs of filters for X-ray detectors in future Astronomy missions.  相似文献   

Stochastic analysis of the linear equivalent response of bridge piers with aseismic devices     

Luisa Carlotta Pagnini  Giovanni Solari 《地震工程与结构动力学》1999,28(5):543-560

The dynamic response of bridge piers with aseismic devices to earthquake excitation is evaluated by the stochastic equivalent linearization technique. The seismic acceleration is schematized through a Gaussian stationary random process. The pier is considered linear elastic, the span is idealized as a rigid mass, the restoring force of the device is represented through a non-linear differential model. The study of the complex modes of the linearized system gives an interpretation of the mechanical behaviour, leads to a formally elementary solution and highlights some phenomena which are typical of the hysteretic systems, particularly of those marked by weak hardening. Even though the solution is limited to the stationary field, it brings out several noteworthy considerations about the effective non stationary behaviour of the structure. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Industrial pollution at Bagnoli (Naples, Italy): benthic foraminifera as a tool in integrated programs of environmental characterisation   总被引：1，自引：1，他引：0  

Romano E  Bergamin L  Finoia MG  Carboni MG  Ausili A  Gabellini M 《Marine pollution bulletin》2008,56(3):439-457

In the 20th century an important industrial plant operated on the coastal area of Bagnoli. After its closing, an integrated study of environmental characterisation aimed at restoration started. The survey conducted was based on chemical and sedimentological analyses integrated with benthic foraminifera analyses. Statistical analysis of the data shows sectors with a distinct type and degree of pollution. Particularly, pollution linked to the silty sediment fraction, mainly due to Pb and Zn, was recognised in front of the southern sector of the plant. The study of benthic foraminifera provides evidence for a pollution-tolerant character in some species like Haynesina germanica and Quinqueloculina parvula. In addition, two species among the 113 recognised show high percentages of abnormal specimens. These percentages show a statistical correlation with some pollutants (PAHs, Mn, Pb and Zn). In addition, Energy Dispersive Spectrometry shows small amounts of Fe ions included in deformed tests of Miliolinella subrotunda. Because the number of these deformations is positively correlated to the concentration of PAHs, Mn and Zn, the inability of some specimens to exclude the foreign elements from the crystalline reticulum of the test could be attributed to the potential toxic effect of these pollutants.  相似文献   

The fractal properties of topography as controlled by the interactions of tectonic,lithological, and geomorphological processes          下载免费PDF全文

Luisa Liucci  Laura Melelli 《地球表面变化过程与地形》2017,42(15):2585-2598

Landscape topography widely exhibits fractal structure. Because of the complexity of relief geometry this structure is not homogeneous in space, and the study of its spatial characteristics represents a powerful method for investigating the interrelationships between landforms and underlying processes. We explore these interrelationships using the digital elevation model (DEM) of an area located in central Italy, where landscape topography is strongly linked to its geological evolution, being characterized by alternating intermountain basins and mountain ranges trending NW–SE. A modified version of the method based on the standard deviation of relief elevations is used to evaluate the fractal parameters of relief after tiling the DEM in spatial units characterized by homogeneous fractal geometry, and statistical methods in conjunction with spatial analysis techniques are applied to the resulting terrain datasets. Both the lowest and (to a lesser extent) the highest values of fractal dimension are found to follow the ridge‐and‐valley trend. Low fractal dimension is observed in the mountain ranges characterized by massive strata of limestone, and along the fault scarps defining the contact between the intermountain basins and the surrounding slopes, where sediment deposition prevails. High fractal dimension is observed in regions characterized by highly erodible terrigenous lithology, and in areas where tectonic activity favors erosional processes mainly by rivers. The analysis of the (fractal) power law parameters also suggests that each major lithological complex has its own characteristic fractal signature. These results provide new insights into the link between the fractal properties of topography and the tectonic, lithological, and geomorphological features of the area, and show that the analysis approach proposed is useful to depict key aspects about the geomorphological and geological setting of an area, using only a DEM. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

The changing Patagonian landscape: Erosion and westward sediment transfer paths in northern Patagonia during the Middle and Late Pleistocene     

Tania Villaseñor  Daniel Tentori  Kathleen M. Marsaglia  Luisa Pinto 《Basin Research》2020,32(5):1035-1053

Pleistocene glaciations have promoted important landscape transformations as a result of high rates of erosion and rapid sediment evacuation to adjacent marine basins. In the Patagonian Andes the role of the Patagonian Ice Sheet on landscape evolution, in particular the spatial patterns of glacial erosion and its influence on sediment fluxes, is poorly documented. Here, we investigate the Middle and Late Pleistocene sedimentary record of the continental slope from Ocean Drilling Program (ODP) Site 861, offshore Patagonia (46°S), to evaluate the link between glaciations, mountain range erosion and continental margin strata formation. Petrographic analysis of the sand-size fraction (0.063–2 mm) and ɛNd and ⁸⁷Sr/⁸⁶Sr measurements in the silt-size fraction (10–63 µm) indicate that glacial erosion over the last 350,000 years has focused within the Patagonian Batholith, with a minor influence of a proximal source to the drilling site, the Chonos Metamorphic Complex. This shows that erosion has focused in the core of the northern Patagonian Andes, coinciding roughly with the location of the Liquiñe-Ofqui Fault Zone and the zone of concentrated precipitation during glaciations, suggesting a combined climatic and structural control on glacial erosion. Temporal variation in the provenance signal is contemporaneous with a marked change in the stratigraphy of ODP Site 861 that occurred after the glaciation of MIS 8 (~240 kyr ago). Before MIS 8, a restricted provenance signal and coarse lithofacies accumulated on the continental slope indicates spatially restricted erosion and efficient transfer of sediment towards the ocean. In contrast, very high provenance variability and finer continental slope lithofacies accumulation after MIS 8 suggest a disorganized expansion of the areas under erosion and a more distal influence of ice sediment discharge to this site. We argue that this change may have been related to a re-organization of the drainage patterns of the Patagonian Ice Sheet and flow of outlet glaciers to the continental margin during the last two glaciations.  相似文献