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51.
This study uses three acoustic instruments (different in their operating frequencies, 13, 3.5, and 6–10 kHz, and deployment type, hull-mounted, surface-towed and deep-towed) to investigate and characterize the acoustic response of seafloor NE of Oman in a frequency-independent manner. High-resolution control was achieved by having selected areas of our acoustic transects ground-truthed by sampling and/or sea-floor photography. On the regional scale, the greatest degree of change in backscatter amplitude was correlated with major changes of seabed morphology and lithology. However, small-scale roughness had the biggest effect on amplitude on the local scale, i.e. within each area of specific seafloor type. The study also shows that seafloor reflection amplitude changes are far more easily detected by deep-towed instrument than by surface-towed or hull-mounted systems. Whilst there are significant changes in bioturbation types and density along the transects, the suite of instruments deployed was not able to pick up the effect of the bioturbation on acoustic signals.  相似文献   
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The dissolution rate of natural barite, BaSO4, was measured in solutions of DTPA (diethylene triamine penta-acetic acid) to investigate the mechanism of ligand-promoted dissolution using a strong chelating agent. Experiments were carried out over a range of DTPA concentrations 0.5–0.0001 M solutions, at room temperature (22 °C), as well as a range of temperatures, 22–80 °C at 1 atm. The dissolution rate is inversely related to the DTPA concentration in solution. A more dilute DTPA solution is shown to be more efficient as a solvent in terms of the approach to the equilibrium saturation value for the dissolution of Ba2+. An analysis of the temperature dependence of the dissolution rate at high pH by the determination of activation energies indicates that the reaction is probably controlled by the pre-exponential term in the rate constant. This indicates that reaction frequency mostly controls differences in reactivity and suggests an explanation for the results in terms of stearic hindrance due to adsorbed DTPA molecules at the barite surface. The effect of DTPA on the solvation of the Ba2+ ion may also influence the dissolution rate.  相似文献   
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The Paleogene and Neogene evolution of Austroalpine basement units east of the Tauern Window is characterised by the formation of two major sets of faults: (1) ESE–WNW- to E–W-trending faults, associated with ENE- and NNW-trending conjugate structures and (2) N–S to NNE-SSW striking structures, mainly acting as high-angle normal faults, often associated with E-dipping low-angle normal faults along the western margin of the Styrian Basin.Together with the stratigraphic evolution of the Styrian and Lavanttal Basins and the related subsidence histories a tectonic evolution may be reconstructed for this part of the Eastern Alps. In the southern part of the Koralm Massif, WNW-trending fractures were activated as dextral strike-slip faults, associated with the evolution of WNW-trending troughs filled up with coarse block debris. W- to WNW-trending fractures were reactivated as normal faults, indicating N–S extension. It is assumed that these phases resulted in subsidence and block debris sedimentation in Karpatian and Badenian times (ca. 17–13 Ma).In the Western Styrian Basin no Sarmatian (13–11.5 Ma) sediments are observed; Pannonian (11.5 to 7.1 Ma) sediments are restricted to the Eastern Styrian Basin. This indicates, that the Koralm basement and the Western Styrian Basin were affected by post-Sarmatian uplift, coinciding with a re-activation of N-trending normal faults along the eastern margin of the Koralm Massif. Therefore, we suggest that the final uplift of the Koralm Complex, partly together with the Western Styrian Basin, occurred during the early Pannonian (at approximately 10 Ma). The elevation of clastic deposits indicates that the Koralm Complex was elevated by approximately 800 m during this phase, associated with an additional phase of E–W-directed extension accommodated by N–S striking normal faults.  相似文献   
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The Baqueró Group holds a rich fossil flora including macrofloristic and palynological remains that characterize the Early Cretaceous vegetation of Argentina. The age of the upper part of the Group, known as Punta del Barco Formation, has been a topic of several discussions in the past. The type locality of this stratigraphic unit exposes fossiliferous tuffs together with muddy tuffs and tuffaceous sandstones beds. However, there have been no reliable age constraints for the fossil assemblages. 206Pb/238U analyses of zircon crystals yielded an age of 114.67 ± 0.18 Ma. This age control makes possible an improved analysis and comparison of the floras in the southern region.  相似文献   
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<正>A new genus Microelectrona gen.nov.and species Microelectrona cladara sp.nov.of the extinct tribe Protodikraneurini of the leafhoppers(Cicadeilidae:Typhlocybinae) from the Eocene Baltic amber is described. The piece of amber containing leafhopper inclusion is broken,unveiling some of the morphological structures,and enabling their studies using scanning electron microscopy.  相似文献   
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Despite its potential economic and environmental importance, the study of trace metals in supergene (secondary) Cu-sulfides has been seriously overlooked in the past decades. In this study, the concentration and mineralogical form of “invisible” precious metals (Ag, Au) and metalloids (As, Sb, Se, Te) in supergene digenite (Cu1.8S) from various Cu deposits in the Atacama Desert of northern Chile, the world’s premier Cu province, were determined in detail using a combination of microanalytical techniques. Secondary ion mass spectrometry (SIMS) and electron microprobe analyzer (EMPA) measurements reveal that, apart from hosting up to ∼11,000 ppm Ag, supergene digenite can incorporate up to part-per-million contents of Au (∼6 ppm) and associated metalloids such as As (∼300 ppm), Sb (∼60 ppm), Se (∼96 ppm) and Te (∼18 ppm). SIMS analyses of trace metals show that Ag and Au concentrations strongly correlate with As in supergene digenite, defining wedge-shaped zones in Ag-As and Au-As log-log spaces. SIMS depth profiling and high-resolution transmission electron microscopy (HRTEM) observations reveal that samples with anomalously high Ag/As (>∼30) and Au/As (>∼0.03) ratios plot above the wedge zones and contain nanoparticles of metallic Ag and Au, while samples with lower ratios contain Ag and Au that is structurally bound to the Cu-sulfide matrix. The Ag-Au-As relations reported in this study strongly suggest that the incorporation of precious metals in Cu-sulfides formed under supergene, low-temperature conditions respond to the incorporation of a minor component, in this case As. Therefore, As might play a significant role by increasing the solubility of Ag and Au in supergene digenite and controlling the formation and occurrence of Ag and Au nanoparticles. Considering the fact that processes of supergene enrichment in Cu deposits can be active from tens of millions of years (e.g. Atacama Desert), we conclude that supergene digenite may play a previously unforeseen role in scavenging precious metals from undersaturated (or locally slightly supersaturated) solutions in near-surface environments.  相似文献   
59.
Fe(II)-Fe(III) redox behavior has been studied in the presence of catechol under different pH, ionic media, and organic compound concentrations. Catechol undergoes oxidation in oxic conditions producing semiquinone and quinone and reduces Fe(III) in natural solutions including seawater (SW). It is a pH-dependent process. Under darkness, the amount of Fe(II) generated is smaller and is related to less oxidation of catechol. The Fe(II) regeneration is higher at lower pH values both in SW with log k = 1.86 (M−1 s−1) at pH 7.3 and 0.26 (M−1 s−1) at pH 8.0, and in NaCl solutions with log k of 1.54 (M−1 s−1) at pH 7.3 and 0.57 (M−1 s−1) at pH 8.0. At higher pH values, rate constants are higher in NaCl solutions than in SW. This is due to the complexation of Mg(II) present in the media with the semiquinone that inhibits the formation of a second Fe(II) through the reaction of this intermediate with other center Fe(Cat)+.  相似文献   
60.
The Viking Orbiters imaged early morning, long, linear wave clouds along the flanks of the Tharsis volcanoes during late northern spring and early summer. These clouds are believed to be a product of either an atmospheric bore wave or a hydraulic jump generated by nightly katabatic winds. The Mars Regional Atmospheric Modeling System was used to study the interaction of the katabatic flows with the surrounding atmosphere to determine what mechanism is responsible for the clouds. Simulations at Ls=90°, 100°, 142°, 180°, 270°, and 358° were conducted focusing on the eastern flank of Olympus Mons. Model results compare well with Viking observations and closely approximate theoretical treatments of atmospheric bores. Strong downslope flows are simulated during the night, with a bore wave forming on and behind a well-defined katabatic front. The observed seasonality of the clouds was reproduced in the simulations; the bore was deeper and faster during northern summer and weakest during the winter. When the bore was strong, it was undular in form, and generated vertically propagating gravity waves in the atmosphere above. During the winter, the atmospheric structure was such that any gravity waves generated damped with height. Less atmospheric water vapor abundance during northern winter, as compared to the summer, is also a factor in the seasonality of the wave clouds. This study concludes that bore waves are the most likely mechanism for the generation of the observed linear wave clouds.  相似文献   
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