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31.
A new approach to improve the representation of surface processes in the Global Environmental Multiscale (GEM) atmospheric model associated with the exchanges between the urban canopy and the atmosphere is presented. Effects of the urban canopy on the evolution of surface-layer wind, temperature, moisture, and turbulence are directly parametrized in order to allow realistic interactions between the canopy elements (i.e., roofs, roads, and walls) and the atmosphere at GEM’s multiple vertical levels that are positioned inside the canopy. Surface energy budgets as implemented in the Town Energy Balance (TEB) scheme have been used to determine temperatures of the urban canopy elements for the proposed multilayer scheme. Performance of the multilayer scheme is compared against standard implementations of the TEB scheme for one nighttime intensive observation period of the Joint Urban 2003 experiment held in Oklahoma City, USA. Although the new approach is found to have a negligible impact on urban surface-layer wind profiles, it improves the prediction of near-neutral nocturnal profiles of potential temperature close to the surface. The urban heat island effect is simulated with a better accuracy by the multilayer approach. The horizontal temperature gradient across the central business district of the city along the direction of flow is also reasonably well captured by the proposed scheme.  相似文献   
32.
Large sunspot areas correspond to dips in the total solar irradiance (TSI), a phenomenon associated with the local suppression of convective energy transport in the spot region. This results in a strong correlation between sunspot area and TSI. During the growth phase of a sunspot other physics may affect this correlation; if the physical growth of the sunspot resulted in surface flows affecting the temperature, for example, we might expect to see an anomalous variation in TSI. In this paper we study NOAA active region 8179, in which large sunspots suddenly appeared near disk center, at a time (March 1998) when few competing sunspots or plage regions were present on the visible hemisphere. We find that the area/TSI correlation does not significantly differ from the expected pattern of correlation, a result consistent with a large thermal conductivity in solar convection zone. In addition we have searched for a smaller-scale effect by analyzing white-light images from MDI (the Michelson Doppler Imager) on SOHO. A representative upper-limit energy consistent with the images is on the order of 3×1031 ergs, assuming the time scale of the actual spot area growth. This is of the same order of magnitude as the buoyant energy of the spot emergence even if it is shallow. We suggest that detailed image analyses of sunspot growth may therefore show `transient bright rings' at a detectable level.  相似文献   
33.
Size distribution of PM10 mass aerosols and its ionic characteristics were studied for 2 years from January 2006 to December 2007 at central Delhi by employing an 8-stage Andersen Cascade Impactor sampler. The mass of fine (PM2.5) and coarse (PM10?2.5) mode particles were integrated from particle mass determined in different stages. Average concentrations of mass PM10 and PM2.5 were observed to be 306 ± 182 and 136 ± 84 μg m?3, respectively, which are far in excess of annual averages stipulated by the Indian National Ambient Air Quality Standards (PM10: 60 μg m?3 and PM2.5: 40 μg m?3). The highest concentrations of PM10?2.5 (coarse) and PM2.5 (fine) were observed 505 ± 44 and 368 ± 61 μg m?3, respectively, during summer (June 2006) period, whereas the lower concentrations of PM10?2.5 (35 ± 9 μg m?3) and PM2.5 (29 ± 13 μg m?3) were observed during monsoon (September 2007). In summer, because of frequent dust storms, coarse particles are more dominant than fine particles during study period. However, during winter, the PM2.5 contribution became more pronounced as compared to summer probably due to enhanced emissions from anthropogenic activities, burning of biofuels/biomass and other human activities. A high ratio (0.58) of PM2.5/PM10 was observed during winter and low (0.24) during monsoon. A strong correlation between PM10 and PM2.5 (r 2 = 0.93) was observed, indicating that variation in PM10 mass is governed by the variation in PM2.5. Major cations (NH4 +, Na+, K+, Ca2+ and Mg2+) and anions (F?, Cl?, SO4 2? and NO3 ?) were analyzed along with pH. Average concentrations of SO4 2? and NO3 ? were observed to be 12.93 ± 0.98 and 10.33 ± 1.10 μg m?3, respectively. Significant correlation between SO4 2? and NO3 ? in PM1.0 was observed indicating the major sources of secondary aerosol which may be from thermal power plants located in the southeast and incomplete combustion by vehicular exhaust. A good correlation among secondary species (NH+, NO3 ? and SO4 2?) suggests that most of NH4 + is in the form of ammonium sulfate and ammonium nitrate in the atmosphere. During winter, the concentration of Ca2+ was also higher; it may be due to entrainment of roadside dust particles, traffic activities and low temperature. The molar ratio (1.39) between Cl? and Na+ was observed to be close to that of seawater (1.16). The presence of higher Cl? during winter is due to western disturbances and probably local emission of Cl? due to fabric bleaching activity in a number of export garment factories in the proximity of the sampling site.  相似文献   
34.
Currently, the most widely accepted hypothesis to explain high As concentrations in Bangladesh groundwaters is that dissolved organic C (DOC) reduces solid Fe (hydr)oxides and mobilizes sorbed arsenate. The nature of the DOC and its release mechanism are still controversial. Based on weekly to biweekly sampling over the course of one monsoon cycle at six monitoring wells of different depths, it is proposed that storativity changes drive natural DOC release from clay–peat layers to the adjacent aquifers. With a decrease in hydraulic heads during the dry season, total mineralization and DOC concentrations increased. With the onset of the rainy season and an increase in hydraulic heads, release of clay–peat derived components stopped and vertical water displacement due to groundwater recharge from rainwater occurred, causing aquifer flushing and a decrease in total mineralization and DOC concentrations. Total As and DOC concentrations correlated over depth. However, at the depth of maximum concentrations, the As peak was observed during the rainy season. At present, the reason for this inverse seasonal trend between As and DOC is unclear. Higher mineralization or DOC concentrations could lead to increased As sorption or the increased arsenite release is a time-lag abiotic or microbial response to the DOC peak. The vulnerability of the Pleistocene aquifer towards increased As concentrations was found to be much higher than previously assumed. Though sorption capacities were determined to be higher than in the Holocene aquifer, probably due to intact Fe (hydr)oxides, long-term continuous As input from overlying clay and peat layers by the proposed seasonal storativity changes has led to increased aqueous As concentrations of 85 μg/L, considerably higher than drinking water standards. Until now, aquifer and especially aquitard and aquiclude hydraulics have not been considered sufficiently when attempting to explain As mobilization in Bangladesh.  相似文献   
35.
Randomness in the occurrence of lithologies in a cyclical succession is evaluated in terms of entropies which can be calculated from a Markov chain matrix. Two types of entropies are linked with every lithologic state; one is the entropy before deposition E (pre) and the other is that after deposition E (post),which together form an entropy set. The entropy sets for pebbly sandstone, sandstone, shale, and coal for the Karharbari coal measures, and sandstone, shale, carbonaceous shale, and coal for the Barakar coal measures were plotted separately and compared with Hattori's idealized plots. These coal measures probably were essentially of symmetrical cyclical pattern (Type-B)of Hattori. The entropy of the whole sedimentation unit readily fits under the broad framework of fluvial cycles.  相似文献   
36.
Tungsten mineralisation in the NE Hindu Kush terrain occurs 8 km NW of the Tirich Boundary Zone suture between Karakoram and Eastern Hindu Kush. Scheelite occurs mainly in calc-silicate rocks and subordinately in tourmalinites associated with metasediments at Miniki Gol, Chitral. The investigated area underwent two phases of deformation and was metamorphosed up to sillimanite grade, followed by the emplacement of leucogranite and hydrothermal activity. The mineral assemblages of the calc-silicate rocks, comprising clinozoisite, quartz, calcic-amphibole, plagioclase, chlorite, biotite, calcite, sphene, garnet and scheelite, clearly express a skarn type environment. The coexistence of the scheelite grains with clinozoisite and the occurrence of anomalous values of ZrO2 and Ta2O5 in the scheelite grains imply a genetic link between the scheelite mineralisation and post-magmatic hydrothermal fluids. The enrichment of Zr, Hf, Be, Sn, W, Th, U, Ga, Nb, F and Y along with total REE in the scheelite-bearing calc-silicate rocks compared with the associated metasediments assigns that the rocks at Miniki Gol have undergone a pronounced hydrothermal activity. Strong positive correlations between Zr, Hf, Nb, Y, Ta, F and REE, and the mobility of REE are consistent with this consideration. Aqueous fluid inclusions in the scheelite-bearing calc-silicate rocks display very low salinity, suggesting a mixing of magmatic fluids with meteoric water. The formation of intergrown scheelite and clinozoisite indicates a high pH and CO2-deficient fluid. The tungsten mineralization may be related to the Miniki Gol leucogranite which occurs at a distance of only 400 m.  相似文献   
37.
38.
To investigate the hydrogeochemical characteristics of groundwater 23 shallow, 30 intermediate and 38 deep wells samples were collected from Sylhet district of Bangladesh, and analyzed for temperature, pH, Eh, EC,DO, DOC, Na^+, K^+, Ca2+, Mg2+, Cl^-, SO_42-, NO_3^-,HCO_3^-, SiO_2^-, Fe, Mn and As. Besides, 12 surface water samples from Surma and Kushiyara Rivers were also collected and analyzed to understand the influence into aquifers. Results revealed that, most of the groundwater samples are acidic in nature, and Na–HCO_3 is the dominant groundwater type. The mean value of temperature, EC,Na^+, K^+, Ca2+, Mg2+, Cl^-, NO_3^- and SO_42- were found within the range of permissible limits, while most of the samples exceeds the allowable limits of Fe, Mn and As concentrations. However, relatively higher concentration of Fe and Mn were found in deep water samples and reverse trend was found in case of As. The mean concentrations of As in shallow, intermediate and deep wells were 39.3, 25.3and 21.4 lg/L respectively, which varied from 0.03 to148 lg/L. From spatial distribution, it was found that Fe,Mn and As concentrations are high but patchy in northern,north-western, and south-western part of Sylhet region. The most influential geochemical process in study area were identified as silicate weathering, characterized by active cation exchange process and carbonate weathering, which thereby can enhance the elemental concentrations in groundwater. Pearson's correlation matrix, principal component analysis and cluster analysis were also employed to evaluate the controlling factors, and it was found that, both natural and anthropogenic sources were influencing the groundwater chemistry of the aquifers. However, surface water has no significant role to contaminate the aquifers,rather geogenic factors affecting the trace elemental contamination. Thus it is expected that, outcomes of this study will provide useful insights for future groundwater monitoring and management of the study area.  相似文献   
39.
40.
In recent years, the United Arab Emirates (UAE) has experienced an unprecedented growth which is coupled with the increase in seismic activity in the surroundings. Previous studies presents significant variations in their results whereas some recent studies although very detailed focus on only few cities. This study reviews the results of previous studies and presents new findings for the whole of UAE based on the improved source model and use of next generation attenuation (NGA) equations. The peak ground accelerations, spectral accelerations and deaggregation of hazard for major cities are presented. Moreover, the breakdown of the range of mapped spectral accelerations (S 0.2 and S 1) is proposed to form the basis for the development of site amplification factors in subsequent studies. The results of this study indicate almost similar values of ground motion compared to some recently published studies and smaller values compared to some earlier studies.  相似文献   
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