全文获取类型
收费全文 | 32698篇 |
免费 | 535篇 |
国内免费 | 373篇 |
专业分类
测绘学 | 1231篇 |
大气科学 | 2480篇 |
地球物理 | 6405篇 |
地质学 | 11550篇 |
海洋学 | 2570篇 |
天文学 | 7752篇 |
综合类 | 143篇 |
自然地理 | 1475篇 |
出版年
2021年 | 292篇 |
2020年 | 289篇 |
2019年 | 340篇 |
2018年 | 832篇 |
2017年 | 790篇 |
2016年 | 1043篇 |
2015年 | 606篇 |
2014年 | 969篇 |
2013年 | 1731篇 |
2012年 | 1050篇 |
2011年 | 1310篇 |
2010年 | 1105篇 |
2009年 | 1426篇 |
2008年 | 1243篇 |
2007年 | 1188篇 |
2006年 | 1204篇 |
2005年 | 1002篇 |
2004年 | 891篇 |
2003年 | 895篇 |
2002年 | 885篇 |
2001年 | 782篇 |
2000年 | 760篇 |
1999年 | 687篇 |
1998年 | 631篇 |
1997年 | 636篇 |
1996年 | 574篇 |
1995年 | 544篇 |
1994年 | 510篇 |
1993年 | 438篇 |
1992年 | 392篇 |
1991年 | 416篇 |
1990年 | 415篇 |
1989年 | 392篇 |
1988年 | 365篇 |
1987年 | 439篇 |
1986年 | 369篇 |
1985年 | 461篇 |
1984年 | 491篇 |
1983年 | 477篇 |
1982年 | 456篇 |
1981年 | 373篇 |
1980年 | 375篇 |
1979年 | 318篇 |
1978年 | 315篇 |
1977年 | 312篇 |
1976年 | 260篇 |
1975年 | 259篇 |
1974年 | 291篇 |
1973年 | 317篇 |
1972年 | 199篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
S. K. Deb M. H. Manghnani K. Ross R. A. Livingston P. J. M. Monteiro 《Physics and Chemistry of Minerals》2003,30(1):31-38
A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal
is presented. Raman spectra, recorded with increasing temperature, indicate that the thermal decomposition begins at ≈55 °C,
accompanied by dehydration of water molecules from the mineral. This is in contrast to previous studies that reported higher
temperature breakdown of ettringite. The dehydration is completed by 175 °C and this results in total collapse of the crystalline
structure and the material becomes amorphous. The Raman scattering results are supported by X-ray diffraction results obtained
at increasing temperatures.
Received: 9 July 2001 / Accepted: 14 August 2002 相似文献
992.
Gregory K. Druschel Robert J. Hamers George W. Luther III Jillian F. Banfield 《Aquatic Geochemistry》2003,9(2):145-164
The oxidation kinetics of trithionate (S3O62-
) and tetrathionate (S4O
6
2-
) with hydroxyl radicals (OH*) have been investigated in systems analogous to acid mine drainage (AMD) environments. The discovery of hydroxyl radical
(OH*) formation on pyrite surfaces (Borda et al., 2003) suggests hydroxyl radicals may affect the oxidation kinetics of intermediate
sulfur species such as tetrathionate. Cyclic voltammetry experiments in acidic solutions indicate that the reaction of S4O
6
2-
with OH* goes through an unknown intermediate, tentatively assigned as S3O
4
n-
. An outer-sphere electron transfer mechanism for the reaction of S4O
6
2-
with OH* to form S3O
4
n-
is proposed based on experimental results. Oxidation rates for trithionate and tetrathionate in the presence of Fenton's
reagent (which forms hydroxyl radicals) are too fast to be directly measured using UV-Vis spectrophotometry, electrochemical,
or stop-flow spectrophotometry methods. Competitive reaction kinetics within the context of the Haber—Weiss mechanism suggests
that the rate constant for the oxidation of trithionate and tetrathionate with OH* is in excess of 108 M-1 sec-1. 相似文献
993.
Chantal Alibert Les Kinsley Malcolm T. McCulloch Felicity McAllister 《Geochimica et cosmochimica acta》2003,67(2):231-246
Massive corals in the Great Barrier Reef, analyzed at high-resolution for Sr/Ca (thermal ionization mass spectrometry) and trace elements such as Ba and Mn (laser ablation inductively coupled plasma mass spectrometry), can provide continuous proxy records of dissolved seawater concentrations, as well as sea surface temperature (SST). A 10-yr record (1989 to 1998) from Pandora Reef, an inshore reef regularly impacted by the freshwater plumes of the Burdekin River, is compared with an overlapping record from a midshelf reef, away from runoff influences. Surface seawater samples, taken away from river plumes, show little variability for Sr/Ca (8484 ± 10 μmol/mol) and Ba (33.7 ± 0.7 nmol/kg). Discrete Ba/Ca peaks in the inshore coral coincide with flood events. The magnitude of this Ba/Ca enrichment is most likely controlled by the amount of suspended sediments delivered to the estuary, which remains difficult to monitor. The maximum flow rate at peak river discharge is used here as a proxy for the sediment load and is shown to be strongly correlated with coral Ba/Ca (r = 0.97). After the wet summer of 1991, the coral Ba/Ca flood peak is followed by a plateau that lingers for several months after dissipation of plume waters, signifying an additional flux of Ba that may originate from submarine groundwater seeps and/or mangrove reservoirs. Both Mn and Y are enriched by a factor of ∼5 in inshore relative to midshelf corals. Mn/Ca ratios show a seasonal cycle that follows SST (r = 0.7), not river discharge, with an additional high variability in summer suggesting a link with biological activity. P and Cd show no significant seasonal variation and are at a low level at both inshore and midreef locations. However, leaching experiments suggest that part of the coral P is not lattice bound. 相似文献
994.
Tsuyoshi Watanabe Michael K. Gagan Heather Scott-Gagan Wahyoe S. Hantoro 《Geochimica et cosmochimica acta》2003,67(7):1349-1358
Diploastrea heliopora forms dense, robust, dome-shaped coral colonies throughout the reef ecosystems of the tropical Pacific and Indian Oceans. This slow-growing (2 to 6 mm/yr) coral has the potential to yield continuous paleoclimate records spanning up to 1000 yr for the warmest waters on Earth, the Indo-Pacific Warm Pool, and has a long fossil history as a single recognizable species. Despite the potential of Diploastrea to be an important new paleoclimate archive, little is known about the systematics of geochemical tracers incorporated into its skeleton. To fill this knowledge gap, we compared skeletal δ18O signatures in live Diploastrea and Porites colonies from Southwest Lagoon, near Amédée Lighthouse, New Caledonia (at the southern latitudinal limit for Diploastrea) and Alor, Indonesia (in the core area of the Indo-Pacific Warm Pool). We designed a new microsampling technique to minimize smoothing and distortion of the isotopic records due to the complex calyx architecture and slow growth of Diploastrea. High-resolution isotope profiles from the septal portion of the Diploastrea corallite are attenuated, whereas those restricted to the central columella are similar in quality to those extracted from the well-established Porites coral archive. The δ18O-temperature relationship for the columellar portion of Diploastrea (−0.18‰/°C) is in good agreement with that derived for a nearby Porites (−0.19‰/°C; Quinn et al., 1996), on the basis of comparison with an in situ sea surface temperature record from Amédée Lighthouse. There is a measurable difference of 0.3 ± 0.1‰ between the kinetic/biological disequilibrium offsets from seawater δ18O composition for Diploastrea and Porites. Despite this offset in mean δ18O, Diploastrea accurately records the regional differences in mean temperature and salinity between New Caledonia and the Indo-Pacific Warm Pool. Additional tests show that Diploastrea records El Niño-Southern Oscillation (ENSO) interannual variability in sea surface temperature and salinity across the southwestern Pacific, indicating that it should yield dependable paleo-ENSO records. Based on these results, we propose that D. heliopora has the potential to provide an important new coral archive of tropical paleoclimate. 相似文献
995.
K. Pecher D. McCubbery E. Kneedler J. Bargar L. Cox B. Tonner 《Geochimica et cosmochimica acta》2003,67(6):1089-1098
We have applied Scanning Transmission Soft X-ray Microscopy (STXM) to investigate the charge state distribution of Mn in two kinds of Mn-biominerals, Mn nodules collected from Lake Michigan sediments and Mn precipitates formed by spores of a marine bacillus SG-1 under transport limited reaction conditions. A data analysis technique was developed, which allows for extraction of spatially resolved 2-d charge state maps of manganese on a submicron level. We find that the charge state of Mn dominates the spectral shape of L-edge spectra of environmentally important single oxidation state Mn minerals and that spectra of mixed oxidation state oxides can be modelled by a combination of appropriate single oxidation state reference spectra. Two-dimensional maps of charge state distributions clearly reveal domains of different oxidation states within single particles of Mn-micronodules. Spots of preferred accumulation of Mn(II) were found, which indicates biogenic precipitation of Mn(II)-species as a first step of nodule formation. The presence of Mn(III) in the studied sediment samples suggests the involvement of one-electron oxidation processes and reaction conditions which inhibit or slow down the disproportionation of Mn(III)-products. Under transport limited conditions, Mn oxidation products formed by spores of the marine bacillus SG-1 can vary from cell to cell. The presence of significant amounts of Mn(III) containing species points to the involvement of one-electron oxidation reactions as in the case of the micro-nodules. Our technique and the results obtained form a new basis for the mechanistic understanding of the formation of Mn biominerals in the environment. 相似文献
996.
In the first known kinetic application of the technique, synchrotron 57Fe-Mössbauer spectroscopy was used to follow the rate of heterogeneous electron transfer between aqueous reagents and a solid phase containing Fe. The solid, a synthetic 57Fe-enriched Fe(III)-bearing pyroaurite-like phase having terephthalate (TA) in the interlayer [Mg3Fe(OH)8(TA)0.5 · 2H2O], was reduced by Na2S2O4 and then reoxidized by K2Cr2O7 by means of a novel flow-through cell. Synchrotron Mössbauer spectra were collected in the time domain at 30-s intervals. Integration of the intensity obtained during a selected time interval in the spectra allowed sensitive determination of Fe(II) content as a function of reaction time. Analysis of reaction end member specimens by both the synchrotron technique and conventional Mössbauer spectroscopy yielded comparable values for Mössbauer parameters such as center shift and Fe(II)/Fe(III) area ratios. Slight differences in quadrupole splitting values were observed, however. A reactive diffusion model was developed that fit the experimental Fe(II) kinetic data well and allowed the extraction of second-order rate constants for each reaction. Thus, in addition to rapidly collecting high quality Mössbauer data, the synchrotron technique seems well suited for aqueous rate experiments as a result of the penetrating power of 14.4 keV X-rays and high sensitivity to Fe valence state. 相似文献
997.
Mass-independent isotope effects in Archean (2.5 to 3.8 Ga) sedimentary sulfides determined by ion microprobe analysis 总被引:1,自引:0,他引:1
We report sulfur isotope anomalies with Δ33S, the deviation from a mass-dependent fractionation line for the three-isotope system (34S/32S vs. 33S/32S), ranging up to ±2‰ within individual Archean sedimentary sulfides from a variety of localities. Our measurements, which are made in situ by multicollector secondary ion mass spectrometry, unequivocally corroborate prior bulk measurements of mass-independent fractionations (MIF) in sulfur and provide additional evidence for an anoxic atmosphere on the Earth before ∼2 Ga. This technique also offers new opportunities for exploring ancient sulfur metabolisms preserved in the rock record. The presence of MIF sulfur in sulfides from a >3.8-Ga Fe-rich quartzite from Akilia (island), West Greenland, is consistent with a marine sedimentary origin for this rock. 相似文献
998.
Geoid determination using adapted reference field, seismic Moho depths and variable density contrast 总被引:4,自引:0,他引:4
The traditional remove-restore technique for geoid computation suffers from two main drawbacks. The first is the assumption
of an isostatic hypothesis to compute the compensation masses. The second is the double consideration of the effect of the
topographic–isostatic masses within the data window through removing the reference field and the terrain reduction process.
To overcome the first disadvantage, the seismic Moho depths, representing, more or less, the actual compensating masses, have
been used with variable density anomalies computed by employing the topographic–isostatic mass balance principle. In order
to avoid the double consideration of the effect of the topographic–isostatic masses within the data window, the effect of
these masses for the used fixed data window, in terms of potential coefficients, has been subtracted from the reference field,
yielding an adapted reference field. This adapted reference field has been used for the remove–restore technique. The necessary
harmonic analysis of the topographic–isostatic potential using seismic Moho depths with variable density anomalies is given.
A wide comparison among geoids computed by the adapted reference field with both the Airy–Heiskanen isostatic model and seismic
Moho depths with variable density anomaly and a geoid computed by the traditional remove–restore technique is made. The results
show that using seismic Moho depths with variable density anomaly along with the adapted reference field gives the best relative
geoid accuracy compared to the GPS/levelling geoid.
Received: 3 October 2001 / Accepted: 20 September 2002
Correspondence to: H.A. Abd-Elmotaal 相似文献
999.
In the present study, an attempt has been made to delineate and characterize the different geomorphic units of Tundiya river
catchment in a part of Lower Maharahstra Metamorphic Plateau, north-eastern part of Nagpur district, Maharashtra. The drainage,
contour and delineated geological units have been overlaid on IRS-ID LISS III satellite imagery (bands 2,3 and 4) in EASI/PACE
analysis system to delineate and characterize different geomorphological units and analysis of their processes based on the
field observations. The study area is basically of metamorphic in origin with different geological formations and is influenced
by the various fluvio-morphological processes. Based on the satellite data analysis, the distinct geomorphological units viz.,
table top summits, structural hills, subdued plateau, linear ridges, shallow, moderate and deeply buried foot slopes, shallow
valley fills and deep valley fills have been delineated and characterized. The information generated from satellite data in
the form of vector layers has been used in GIS to generate geological and geomorphological maps of the study area. The present
study demonstrates that IRS-ID LISS-III data in conjunction with geology, drainage and contour parameters to enable detailed
evaluation of different geomorphological units and analysis of their processes based on the field observations. The delineated
geomorphological units can be utilized for evaluation and management of natural resources and geo-environment on sustainable
basis at river catchment level. 相似文献
1000.
The paper discusses the land damage assessment and change detection analysis with reference to a mineral bearing zone in Manjhi,
Manuni and Churan valleys. The area is located in environmentally sensitive and fragile region of Himalaya and constitutes
of nearly 400 small-scale mines of slate, which were operative since last one hundred years and are stopped by court of law
since 1995 on account of environment deterioration. The status of land degradation has been studied using IRS-1B satellite
data of 1988,1992 and 1995. The geo-coded data on 1:50,000 scale has been interpreted and an increase in land degradation
status was noticed. Finally, the management strategy for arresting the further land damage in a broader perspective is suggested. 相似文献