Nutrient dynamics in water and sediment of Mediterranean ponds across a wide hydroperiod gradient     

María Sahuquillo  Maria Rosa Miracle  Sara María Morata  Eduardo Vicente 《Limnologica》2012,42(4):282-290

In Mediterranean ponds, summer drought enhances seasonality whose intensity varies along topographic and climatic gradients. The alternation of wet and dry periods in rain dependent ponds affects their biogeochemistry and differentiates them from ponds fed by more stable water sources, such as groundwater springs. Superimposed onto this, land use is also a very strong factor of variability. In this study we compared nutrients and organic matter concentrations, in water and in sediment, among different types of Mediterranean ponds based on the source of water, hydroperiod and land use. Forty-three ponds were sampled in Eastern Spain corresponding to five pond types: (1) permanent spring ponds in lowlands, (2) permanent spring ponds in mountains, (3) semi-permanent rain ponds, (4) temporary rain ponds with long hydroperiod and (5) temporary rain ponds with short hydroperiod.The results of this study indicate relevant differences among these pond types. The temporary rain ponds with short hydroperiod are characterized by high turbidity due to suspension of sediment particles rich in phosphorous adsorbed onto them (argillotrophic aquatic systems). They are used for watering domestic sheep that enhance sediment suspension by trampling. Total phosphorous (TP) concentrations in the water are high (like those of hypertrophic lakes), but planktonic chlorophyll a is very low and not correlated with TP, because of the low P-bioavailavility in the water. At the other extreme, we have permanent ponds in lowlands fed by groundwater springs. They are heavily loaded with nitrates due to the surrounding intensive agriculture. In these and other permanent/semipermanent ponds chlorophyll is highly correlated with TP. Sediment characteristics provide a good indication of the hydroperiod, since desiccation has important effects on biogeochemical transformations. A threshold of 5% organic matter (OM) in the sediment separates temporary ponds with a short hydroperiod from those with a long hydroperiod, and a threshold of 8% separates the later from the semi-permanent and permanent ponds. Besides OM reduction, important loss of N occurs during desiccation through mineralization, ammonia volatization and the sequential nitrification/denitrification pathway. On the other hand, the increase of organic P mineralization in dry sediments does not represent a loss of P from the system, since o-P remains adsorbed or bound onto the soil. This leads to a low TN/TP ratio in sediments in temporary ponds with short hydroperiod. These characteristics have to be taken into account when establishing pond typologies and ecological thresholds to assess water quality in these unique aquatic habitats.  相似文献   

Quantitative reconstruction of Late Cenozoic landscapes: a case study in the Sierra de Atapuerca (Burgos,Spain)     

Alfonso Benito‐Calvo  Alfredo Pérez‐González  Josep María Parés 《地球表面变化过程与地形》2008,33(2):196-208

We have developed a method to reconstruct palaeorelief by means of detailed geomorphological and geological studies, geostatistical tools, GIS and a DEM. This method has been applied to the Sierra de Atapuerca (NE Duero Basin, Burgos, Spain), allowing us to model a three‐dimensional reconstruction of the relief evolution from the Middle Miocene to the present. The modelling procedure is based on geostatistical recovery of the palaeosurfaces characteristic of each geomorphological evolution stage, using polynomial regressions, trend surfaces and kriging. The modelling of morphology trends has been useful in establishing new geological and geomorphological relationships in the geodynamic evolution of this basin, such as uplift quantification, correlation of erosion surfaces and sedimentary units, and the evolution of fluvial base levels. The palaeosurface reconstruction together with an analysis of the slope retreat have allowed us to reconstruct the palaeoreliefs that define the Late Cenozoic landscape evolution of this area, where the Lower and Middle Pleistocene archaeopalaeontological sites of the Sierra de Atapuerca are located. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Effects of hydrological connectivity on the substrate and understory structure of riparian wetlands in the Middle Ebro River (NE Spain): Implications for restoration and management     

Álvaro Cabezas  Eduardo González  Belinda Gallardo  Mercedes García  María González  Francisco A. Comín 《Aquatic Sciences - Research Across Boundaries》2008,70(4):361-376

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A Ta,Ti–rich oxide mineral assemblage from the Nancy beryl–columbite–phosphate granitic pegmatite,San Luis,Argentina     

Galliski  Miguel Ángel  Márquez-Zavalía  María Florencia  Škoda  Radek  Novák  Milan  Čopjaková  Renata  Pagano  Diego Sebastián 《Mineralogy and Petrology》2019,113(5):687-701

Mineralogy and Petrology - An assemblage of tantalite-(Mn), tantalian rutile, tapiolite-(Fe), titanowodginite, ferrotitanowodginite, and hydroxycalciomicrolite occurs in the Nancy granitic...  相似文献   

Chemical Characterization of Biosolids from Three Spanish WWTPs: Transfer of Organics and Metallic Pollution from Urban Wastewater to Biosolids     

Rafael Marín Galvín  Juan Manuel Cardenete López  José Miguel Rodríguez Mellado 《洁净——土壤、空气、水》2009,37(1):52-59

The production of biosolids in three Spanish wastewater treatment plants (WWTPs) has been investigated. Biosolids produced from the treatment of urban wastewater in Spain are usually intended for agricultural use. The reliable production of biosolids mainly depends on both the quantity of suspended solids and the organic load influent to the treatment systems. The quality of the generated biosolids was independent of both the amount of treated water and the treatment process applied, with 20 to 25% dried matter, and 60 to 75%, 7% and 4% of organic matter, N and P, respectively, of the total matter. The biosolids contained ca. 11 to 19 g/kg of total metals in the dry matter, with Fe, Zn, Cu and Mn representing 97% of all of the metals present, and Hg being the minority metal. Such biosolids had the ability to concentrate the organic matter and metals from the wastewater up to 417 and 869 times, respectively, and thus, can be used in agricultural practice.  相似文献   

Comparison of marine and river water humic substances in a Patagonian environment (Argentina)     

María del Carmen Scapini  Víctor Hugo Conzonno  Vilma Teresa Balzaretti  Alicia Fernández Cirelli 《Aquatic Sciences - Research Across Boundaries》2010,72(1):1-12

Structural aspects of humic substances (HSs) in marine waters of Engaño Bay (Atlantic Ocean) and water from the Chubut River (Patagonia, Argentina) were compared. The HSs were isolated, purified, and analyzed using a multiple-method approach for structural characterization: elemental analysis, nuclear magnetic resonance (¹³C and ¹H NMR), infrared spectroscopy (FTIR), UV-visible absorption and fluorescence. Similarities between the marine and freshwater components were evaluated on the basis of N and O contents, H/C and C/N atomic ratios, infrared bands from nitrogen-containing and carboxylic groups, percentage of functional groups obtained from NMR spectra, spectral slope coefficient of absorption spectra, absorbance ratios at 250 and 365 nm (E ₂/E ₃), aromaticity, excitation–emission matrices and fluorescence quantum yield. Both the Engaño Bay and Chubut River waters have HSs that are mainly composed of fulvic acids (FAs); although they are very similar, they may be distinguished from one another. Similarities include the predominance of aliphatic carbon content (low aromatic content); however, the water bodies differed in their content of proteins and carboxylic acids. The Engaño Bay FAs have mainly an aquatic origin; although the Chubut River FAs suggest a similar aquagenic origin, there is also evidence of contributions from pedogenic FAs.  相似文献   

Inventory and geometrical changes in small glaciers covering three Northern Patagonian summits using remote sensing and GIS techniques     

Alfonso Fernández  José Araos  Jorge Marín 《山地科学学报》2010,7(1):26-35

In the last few decades, a large quantity of research has been performed to elucidate the current behavior of glaciers in southern Chile, especially with respect to the volumetric changes in the outlets of the Northern and Southern Patagonian Icefields (NPI and SPI, respectively). Calculations have shown a generalized thinning and withdrawal, which greatly contributes to the increase in sea level attributed to the ice melt from non-polar glaciers. However, these icefields are surrounded by many small icecaps, which have yet to be studied in detail. A precise estimation of the volume of ice located in these mountain chains could provide new information with respect to this area's exact contribution to the increase in sea level. Thus, this study presents an inventory of relatively small Northern Patagonian glaciers in the surrounding of the three summits: Mount Queulat, and the Macá and Hudson volcanoes. The study used remote sensing techniques in a GIS environment to determine the margins, surface areas, thickness changes and hypsometry for the glaciated zones. Landsat images from different dates were analyzed using standard band ratio and screen delineation techniques. Additionally, digital elevation models from different dates were compared using map algebra, calculating thickness changes. Based on the results, we propose that there are important volumetric changes in the glaciers studied, which could be explained by precipitation trends in a general context, and an influence of the glaciers' sizes in some local response. Therefore, we suggest the exact contribution of the Patagonia to the increase in sea level corresponds to a regional pattern rather than just the behavior of a single ice field.  相似文献   

Geomorphic indices and relative tectonic uplift in the Guerrero sector of the Mexican forearc     

Krzysztof Gaidzik  María Teresa Ramírez-Herrera 《地学前缘(英文版)》2017,8(4):885-902

Tectonically active areas, such as forearc regions, commonly show contrasting relief, differential tectonic uplift, variations in erosion rates, in river incision, and in channel gradient produced by ongoing tectonic deformation. Thus, information on the tectonic activity of a defined area could be derived via landscape analysis. This study uses topography and geomorphic indices to extract signals of ongoing tectonic deformation along the Mexican subduction forearc within the Guerrero sector. For this purpose, we use field data, topographical data, knickpoints, the ratio of volume to area (R_VA), the stream-length gradient index (SL), and the normalized channel steepness index (k_sn).The results of the applied landscape analysis reveal considerable variations in relief, topography and geomorphic indices values along the Guerrero sector of the Mexican subduction zone. We argue that the reported differences are indicative of tectonic deformation and of variations in relative tectonic uplift along the studied forearc. A significant drop from central and eastern parts of the study area towards the west in values of R_VA (from ～500 to ～300), SL (from ～500 to ca. 400), maximum SL (from ～1500–2500 to ～1000) and k_sn (from ～150 to ～100) denotes a decrease in relative tectonic uplift in the same direction. We suggest that applied geomorphic indices values and forearc topography are independent of climate and lithology. Actual mechanisms responsible for the observed variations and inferred changes in relative forearc tectonic uplift call for further studies that explain the physical processes that control the forearc along strike uplift variations and that determine the rates of uplift. The proposed methodology and results obtained through this study could prove useful to scientists who study the geomorphology of forearc regions and active subduction zones.  相似文献   

Magnetic properties of surface sediments as proxies of recent anthropogenic pollution in the Anllóns riverbed (NW Spain)     

Vincenzo Costanzo-Álvarez  Rosa Devesa-Rey  Milagrosa Aldana  María Teresa Barral  Diego López-Rodríguez  Belkys Andrade 《Environmental Earth Sciences》2017,76(13):454

A study of surface sediments from the Anllóns riverbed (northwestern Spain) was conducted to assess the use of their magnetic properties as proxies of recent trace element contamination (i.e., As, Zn, Pb, Cr, Ni and Cu). Thermomagnetic curves, hysteresis parameters, specific magnetic susceptibility χ, frequency-dependent magnetic susceptibility κ _FD%, magnetic remanence and saturation isothermal remanent magnetization ratios (i.e., S and SIRM/χ) reveal the presence of mostly fine-grained magnetite and maghemite in these samples. The Tomlinson Pollution Load Index (PLI), as well as the magnetic parameters χ, κ _FD%, SIRM/χ and S-ratios, vary more or less in agreement to each other when they are sequentially arranged throughout a 30-km-long transect that goes from the town of Carballo to the river mouth in Ponteceso. From that profile, it is possible to identify an anomaly of χ that lies between two small peaks of the PLI and seems to define a contaminated area probably linked to a diffuse low-impact source of pollution. There is also a conspicuous peak of the PLI that is likely associated to a nearby gold mine. The variations of the κ _FD%’s along the transect are the ones that best reflect the changes in the PLI values, regardless of the level of contamination. This result suggests that adsorption is the main mechanism of trace elements removal by Fe oxides in these samples. Direct signal analyses, used to decompose the isothermal remanent magnetization curves, reveal the presence of four magnetic fractions, with varying relative concentrations all over the profile, namely single-domain magnetite, close to the superparamagnetic threshold (SD/SP) and/or maghemite (\(\log B_{1/2}\) ca 1.2), single-domain magnetite (\(\log B_{1/2}\) ca 2), hematite (\(\log B_{1/2}\) ca 2.5) and goethite (\(\log B_{1/2}\) ca 3.5). Integrating all the available information, it was sketched out a likely sequence of events that included magnetic minerals neoformation in parent soils, their subsequent chemical transformations and the contamination episodes that affected the region.  相似文献   

Accumulation of lead and associated metals (Cu and Zn) at different growth stages of soybean crops in lead-contaminated soils: food security and crop quality implications     

Andrés Blanco  María J. Salazar  Carolina Vergara Cid  María L. Pignata  Judith H. Rodriguez 《Environmental Earth Sciences》2017,76(4):182

The Pb, Cu and Zn content, the physicochemical parameters in soils (EC, OM%, soil texture and pH) and the metal accumulation of Glycine max plants at different growth stages were evaluated. Topsoil and soybean samples were collected in the vicinity of a former battery-recycling plant, with the results showing that only the concentrations of Pb in soils corresponding to sites located near to the lead emission source were above the maximum permissible levels. However, soybean crops accumulated Pb above the permitted levels at all studied sites, revealing a potential toxicological risk for direct consumption. Thus, the accumulation of Pb in soybean was directly related to the translocation factor of the metal from roots to aerial parts of the plant. This was evidenced as a lower accumulation at early growth stages and a higher accumulation at maturity, with the distribution between organs coinciding with nutrient incorporation and remobilization in the plant. Moreover, the bioconcentration factor revealed that the bioaccumulation of lead in soybean was a consequence of the lead-recycling plant activity in the past. Taken together, results of the present study demonstrated that soybean crops can incorporate and accumulate potentially toxic metals, such as lead.  相似文献