Validation of Arenicola marina in field toxicity bioassays using benthic cages: biomarkers as tools for assessing sediment quality     

Ramos-Gómez J  Martins M  Raimundo J  Vale C  Martín-Díaz ML  DelValls TA 《Marine pollution bulletin》2011,62(7):1538-1549

Sediment toxicity assessments using caged organisms present advantages over using laboratory and native community studies. The use of caged Arenicola marina in sediment toxicity assessments was evaluated. Lugworms were exposed in situ to sediments from coastal and port areas in Spain for seven days, and the activities of the biotransformation enzymes ethoxyresorufin O-deethylase, dibenzylfluorescein dealkylase and glutathione S-transferase, the activities of the antioxidant enzymes glutathione reductase and glutathione peroxidase and lipid peroxidation were then analyzed as biomarkers. Biomarker results and sediment physicochemical data were integrated. Cádiz Bay (SW Spain) sediments presented metal contamination that was not linked to a biochemical response. In LPGC Port (SW Spain), Pb contamination exhibited a moderate toxic potential, while PAHs, and presumably pharmaceuticals, provoked biochemical responses that efficiently prevented lipid peroxidation. In Santander Bay (N Spain), exposure to PAHs and, presumably, pharmaceuticals induced biomarker responses, but lipid peroxidation occurred nevertheless. These results indicated that caged A. marina were effective for the assessment of sediment quality and that the selected biomarkers were sufficiently sensitive to identify chemical exposure and toxicity.  相似文献   

Plastic marine debris on the Portuguese coastline: a matter of size?     

Martins J  Sobral P 《Marine pollution bulletin》2011,62(12):2649-2653

Plastic debris is a worldwide threat to marine environments and Portugal is not immune to it. Though never quantified, items of all sizes can be found in the Portuguese coastline; therefore the objective of this work is the identification of main size classes in stranded plastic debris. Beaches sediment was sampled and in the laboratory plastic items were sorted in 11 classes from <1 to >10 mm, counted and weighted. Plastic size ranged from 50 μm to 20 cm and microplastics (<5 mm) were the majority (72%). Most plastic fits in the smaller size classes, due to expected high residence time in the sea enhancing degradation processes, which increase surface exposure and potentially persistent organic pollutants (POP) adsorption. These results point out the important contribution of microplastics to marine debris pollution, its risks, and the need to set a higher focus on this size class.  相似文献   

In situ experimental decomposition studies in estuaries: A comparison of Phragmites australis and Fucus vesiculosus     

Marta Lobo Lopes  Patrícia Martins  Fernando Ricardo  Ana Maria Rodrigues  Victor Quintino 《Estuarine, Coastal and Shelf Science》2011,92(4):497-580

The decomposition rates of Phragmites australis and Fucus vesiculosus were experimentally determined in an estuarine system using the leaf-bag technique. The study was conducted in fifteen sites arranged in five areas, extending from freshwater, outside the tidal range, to the marine environment, near the mouth of the estuary. The leaf-bags (5 mm mesh), were set up with 3.0 g of dried substrate, submerged in the experimental sites at day 0 and collected at days 3, 7, 15, 30 and 60, to follow biomass loss. The biomass loss through the leaching phase (day 3) was about 16% for Phragmites australis and 33% for Fucus vesiculosus and was independent of salinity for both substrates. The difference in the remaining biomass between the two species increased with time and the decomposition rates differed along the salinity gradient. For F. vesiculosus, the decomposition rate was highest near the mouth of the estuary, corresponding to the preferential distribution area of the algae, and decreased towards freshwater. For Phragmites australis, the fastest decay was observed in the mid estuary, where Phragmites australis occurs naturally, confirming previous studies. The decomposition rates measured at different time intervals (0–15, 0–30 and 0–60 days) were always higher for the algae and decreased with time for both species. These results indicate that the use of decomposition rates as a measure of ecosystem integrity or quality status in transitional waters will not be straightforward and must take into account, among others, the test species, the study area positioning along the estuarine gradient, and the time interval for the calculation of the decomposition rate.  相似文献   

Relationship between metal levels in the vent mussel Bathymodiolus azoricus and local microhabitat chemical characteristics of Eiffel Tower (Lucky Strike)     

Inês Martins  Richard P. CossonVirginie Riou  Pierre-Marie SarradinJozée Sarrazin  Ricardo S. SantosAna Colaço 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(3):306-315

The turbulent mixing of hydrothermal hot fluid with cold seawater creates large chemical gradients at a small spatial scale that may induce variable physiological and biochemical adaptations within the vent fauna. The adaptation to such a variable environment by the vent mussel Bathymodiolus azoricus relies on a dual symbiosis hosted in the gills, and digestion of particulate organic matter. The surrounding environment not only provides the necessary energy sources and suspended organic particles for the vent mussel nutrition, but also potentially toxic compounds such as metals. Our main goal was to see if there is a relation between metal accumulation in mussel organs and the chemical characteristics of their close environment. Mussels were collected at six locations in a cold part of the Eiffel Tower fluid-seawater mixing zone, characterized by distinct chemical compositions. Metals (Cd, Cu, Fe and Zn) and metallothioneins were quantified in the gills and digestive gland. The physiological condition of the sampled mussels was also evaluated using tissues and gill indices. Our study indicates that the accumulation of metals in B. azoricus is related to their spatial distribution and linked to fine scale environmental conditions that influence the physiological status of the organism.  相似文献   

Downscaling projections of climate change in Sao Tome and Principe Islands,Africa     

Sin Chan Chou  Andr&#; de Arruda Lyra  Jorge Lu&#;s Gomes  Daniel Andr&#;s Rodriguez  Minella Alves Martins  Nicole Costa Resende  Priscila da Silva Tavares  Claudine Pereira Dereczynski  Isabel Lopes Pilotto  Alessandro Marques Martins  Lu&#;s Felipe Alves de Carvalho  Jos&#; Luiz Lima Onofre  Idal&#;cio Major  Manuel Penhor  Ad&#;rito Santana 《Climate Dynamics》2020,54(9):4021-4042

Sao Tome and Principe is a small insular African country extremely vulnerable to rising sea levels and impacts such as inundation, shore line change, and salt water intrusion into underground aquifers. Projections of climate change have considered coarse model resolutions. The objective of this work is to dynamically downscale the global model projections to 4-km resolution and to assess the climate change in the Sao Tome and Principe islands. The global climate projections are provided by the Canadian Earth System Model under two Representative Concentration Pathways greenhouse gas scenarios, RCP4.5 and RCP8.5. The downscaling is produced by the Eta regional climate model. The baseline period is taken between 1971 and 2000, and the future climate period is taken between 2041 and 2070. The 2-m temperature simulations show good agreement with station data. The model simulates temperature more accurately than precipitation. The precipitation simulations systematically show underestimation and delay of the rainy and the dry seasons by about 1 month, a feature inherited from the global climate model. In the middle of the 21st century, projections show the strongest warming in the elevated parts of the Sao Tome Island, especially in February under RCP8.5. Warmer nights and warmer days become more frequent in the islands when compared with those in the present. While under RCP4.5, precipitation increases in the islands; under RCP8.5, it decreases everywhere in both islands. Heavy precipitation rates should increase, especially in the south-southwestern parts of the Sao Tome islands. Detailed spatial variability of the temperature and precipitation changes in the islands can only be revealed at very high spatial model resolution. Implications for the potential energy production from two major river basins are assessed in this work.  相似文献   

Analysis and survival of amino acids in Martian regolith analogs     

James R. C. Garry  Inge Loes ten Kate  Zita Martins  Per Nrnberg  Pascale Ehrenfreund 《Meteoritics & planetary science》2006,41(3):391-405

Abstract— We have investigated the native amino acid composition of two analogs of Martian soil, JSC Mars‐1 and Salten Skov. A Mars simulation chamber has been built and used to expose samples of these analogs to temperature and lighting conditions similar to those found at low latitudes on the Martian surface. The effects of the simulated conditions have been examined using high‐performance liquid chromatography (HPLC). Exposure to energetic ultraviolet (UV) light in vacuum appears to cause a modest increase in the concentration of certain amino acids within the materials, which is interpreted as resulting from the degradation of microorganisms. The influence of low temperatures shows that the accretion of condensed water on the soils leads to the destruction of amino acids, supporting the idea that reactive chemical processes involving H₂O are at work within the Martian soil. We discuss the influence of UV radiation, low temperatures, and gaseous CO₂ on the intrinsic amino acid composition of Martian soil analogs and describe, with the help of a simple model, how these studies fit within the framework of life detection on Mars and the practical tasks of choosing and using Martian regolith analogs in planetary research.  相似文献   

Phytoremediation potential and morphological changes of plants growing in the vicinity of lead smelter plant     

M. C. S. Brandão  F. M. Martins  A. M. A. Accioly  N. M. Santos  M. V. V. Romão  A. D. Azevedo 《International Journal of Environmental Science and Technology》2018,15(2):361-372

With the increasing industrialization, heavy metals concentration in soils has greatly increased. Phytoremediation is a low-cost, non-intrusive and aesthetically harmonious technology that uses plants to remediate contaminated sites by heavy metals. The aim of the study was to determine Cd, Pb and Zn concentration in the biomass of plant species growing on a multi-metal-contaminated site of lead smelter processing, to assess the workability of using these plants for phytoremediation purposes and highlight possible damage in morphological leaf changes. Two plant species, i.e., Ipomoea asarifolia and Urochloa decumbens and the associated soil samples were collected and analyzed Cd, Pb and Zn concentrations and then calculating the bioconcentration factor and translocation factor parameters for each element. Leaves and roots samples were observed by light microscopy. Metal concentrations varied greatly and majorly depend on site sampled, plant species and tissue. Cd, Pb and Zn in tissue ranged from 0 to 102.48, 0 to 381.04 and 12.84 to 295.02 mg Kg^?1. However, none of the plant showed potential for hyperaccumulation. Both plants showed bioaccumulation factor more than one, where it was 7.66 and 6.82 for Pb and Zn in U. decumbens, respectively. Translocation factor was calculated below one for both plants and all metals. Morphological studies revealed development of adaptive features that strengthen the U. decumbens to grow in contaminated soil. Our study suggests that I. asarifolia and U. decumbens have potential for phytostabilization at multi-metal-contaminated site.  相似文献   

Adsorption of methylene blue and crystal violet on low-cost adsorbent: waste fruits of <Emphasis Type="Italic">Rapanea ferruginea</Emphasis> (ethanol-treated and H<Subscript>2</Subscript>SO<Subscript>4</Subscript>-treated)     

Tamiris Chahm  Bruna Aparecida Martins  Clovis Antonio Rodrigues 《Environmental Earth Sciences》2018,77(13):508

This study assesses the ability of two low-cost adsorbents made from waste of Rapanea ferruginea treated with ethanol (WRf) and its H₂SO₄-treated analog (WRf/H₂SO₄) for the removal of two cationic dyes methylene blue (MB) and crystal violet (CV) from aqueous solutions. The adsorbent was characterized by scanning electron microscopy, Fourier transform infrared spectrometry, thermogravimetric analysis, point of zero charge (pH_pzc), specific surface, and functional groups. The adsorption of dye onto the adsorbents was studied as a function of pH solution (2–12), contact time (up to 120 min) and initial concentration (20–120 mg/L), and temperature (25, 35, and 55 °C). The influence of these parameters on adsorption capacity was studied using the batch process. The response surface methodology (RSM) was used in the experimental design, modeling of the process, and optimizing of the variables and was optimized by the response involving Box–Behnken factorial design (15 runs). The results show that the data correlated well with the Sips isotherm. The maximum adsorption capacities of MB and CV onto WRf were found to be 69 and 106 mg/g, and onto WRf/H₂SO₄, the adsorption capacities were 33 and 125 mg/g, respectively. The kinetic data revealed that adsorption of cationic dyes onto the adsorbents closely follows the pseudo-second-order kinetic model. Regression analysis showed good fit of the experimental data to the second-order polynomial model, with coefficient of determination (R²) values for MB (R²?=?0.9685) and MB (R²?=?0.9832) for WRf and CV (R²?=?0.9685) and CV (R²?=?0.9832) for WRf/H₂SO₄ indicated that regression analysis is able to give a good prediction of response for the adsorption process in the range studied. The results revealed that waste from R. ferruginea is potentially an efficient and low-cost adsorbent for adsorption of MB and CV.  相似文献   

Using machine learning methods for disambiguating place references in textual documents   总被引：3，自引：0，他引：3  

João Santos  Ivo Anastácio  Bruno Martins 《GeoJournal》2015,80(3):375-392

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What is wrong with post-fire soil erosion modelling? A meta-analysis on current approaches,research gaps,and future directions     

A.R. Lopes  A. Girona-García  S. Corticeiro  R. Martins  J.J. Keizer  D.C.S. Vieira 《地球表面变化过程与地形》2021,46(1):205-219

In the near future, a higher occurrence of wildfires is expected due to climate change, carrying social, environmental, and economic implications. Such impacts are often associated with an increase of post-fire hydrological and erosive responses, which are difficult to predict. Soil erosion models have been proven to be a valuable tool in the decision-making process, from emergency response to long-term planning, however, they were not designed for post-fire conditions, so need to be adapted to include fire-induced changes. In recent years, there have been an increasing number of studies testing different models and adaptations for the prediction of post-fire soil erosion. However, many of these adaptations are being applied without field validation or model performance assessment. Therefore, this study aims to describe the scientific advances in the last 20 years in post-fire soil erosion modelling research and evaluate model adaptations to burned areas that aim to include: (i) fire-induced changes in soil and ground cover; (ii) fire-induced changes in infiltration; (iii) burn severity; and (iv) mitigation measures in their predictions. This study also discusses the strengths and weaknesses of these approaches, suggests potential improvements, and identifies directions for future research. Results show that studies are not homogeneously distributed worldwide, according to the model type used or by region most affected by wildfire. During calibration, 73% of cases involved model adaptation to burned conditions, and only 21% attempted to accommodate new processes. Burn severity was addressed in 75% of cases, whilst mitigation measures were simulated in 27%. Additionally, only a minor percentage of model predictions were validated with independent field data (17%) or assessed for uncertainties (13%). Therefore, further efforts are required in the adaptation of erosion models to burned conditions, to be widely used for post-fire management decisions. © 2020 John Wiley & Sons, Ltd.  相似文献