Geodynamic implications of deep mantle upwelling in the source of Tertiary volcanics from the Veneto region (South-Eastern Alps)     

Patrizia Macera  Daniela Gasperini  Claudia Piromallo  Janne Blichert-Toft  Delphine Bosch  Aldo Del Moro  Silvana Martin 《Journal of Geodynamics》2003,36(5):563

Major and trace element and Sr–Nd–Hf–Pb isotopic data for the most primitive Tertiary lavas from the Veneto region (South-Eastern Alps, Italy) show the typical features of HIMU hotspot volcanism, variably diluted by a depleted asthenospheric mantle component (⁸⁷Sr/⁸⁶Sr_i=0.70306–0.70378; _Ndi=+3.9 to +6.8; _Hfi=+6.4 to +8.1, ²⁰⁶Pb/²⁰⁴Pb_i=18.786–19.574). P-wave seismic tomography of the mantle below the Veneto region shows the presence of low-velocity anomalies at depth, which is consistent with possible upwellings of plume material. Between the depths of 100–250 km the velocity anomalies are approximately 2–2.5% slower than average, implying a temperature excess of about 220–280 K, in agreement with estimates for other mantle plumes in the world. In this context, the Veneto volcanics may represent the shallow expression of a mantle upflow. The presence of a HIMU-DM component in a collision environment has significant geodynamic implications. Slab detachment and ensuing rise of deep mantle material into the lithospheric gap is proposed to be a viable mechanism of hotspot magmatism in a subduction zone setting.  相似文献   

Stable Eocene Magnetization Carried by Magnetite and Iron Sulphides in Marine Marls (Pamplona-Arguis Formation,Southern Pyrenees,Northern Spain)     

Larrasoaña  J.C.  Parés  J.M.  Pueyo  E.L. 《Studia Geophysica et Geodaetica》2003,47(2):237-254

In order to establish the magnetic carriers and assess the reliability of previous paleomagnetic results obtained for Eocene marine marls from the south Pyrenean basin, we carried out a combined paleo- and rock-magnetic study of the Pamplona-Arguis Formation, which crops out in the western sector of the southern Pyrenees (N Spain). The unblocking temperatures suggest that the characteristic remanent magnetization (ChRM) is carried by magnetite and iron sulphides. The ChRM has both normal and reversed polarities regardless of whether it resides in magnetite or iron sulphides, and represents a primary Eocene magnetization acquired before folding. Rock magnetic results confirm the presence of magnetite and smaller amounts of magnetic iron sulphides, most likely pyrrhotite, in all the studied samples. Framboidal pyrite is ubiquitous in the marls and suggests that iron sulphides formed during early diagenesis under sulphate-reducing conditions. ChRM directions carried by magnetic iron sulphides are consistent with those recorded by magnetite. These observations suggest that magnetic iron sulphides carry a chemical remanent magnetization that coexists with a remanence residing in detrital magnetite. We suggest that the south Pyrenean Eocene marls are suitable for magnetostratigraphic and tectonic purposes but not for studies of polarity transitions, secular variations and geomagnetic excursions, because it is difficult to test for short time differences in remanence lock-in time for the two minerals. The presence of iron sulphide minerals contributing to the primary magnetization in Eocene marine marls reinforces the idea that these minerals can persist over long periods of time in the geological record.  相似文献   

Statement for the SERRA forum on the effects of vegetation     

M. S.?McLachlanEmail author  F.?Wania 《Stochastic Environmental Research and Risk Assessment (SERRA)》2003,17(4):238-240

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A consistent derivation of the wave-energy equation from basic hydrodynamic principles     

Andreas?MalcherekEmail author 《Ocean Dynamics》2003,53(3):302-308

Based on a decomposition of the velocity into mean flow, turbulent and wave components, momentum and hereafter a wave-energy equation is derived. It contains a turbulent energy dissipation term which is closed by applying a wave-related mixing length model and linear wave theory solutions. This closure produces a non-linear turbulent wave-energy dissipation including the wave energy in a 5/2 power law. The theory is able to predict correctly the shape of deep-water wave spectra according to Phillips' similarity law.Responsible Editor: Hans Burchard  相似文献   

Development and sensitivity analysis of a model for assessing stratification and safety of Lake Nyos during artificial degassing     

Martin?SchmidEmail author  Andreas?Lorke  Alfred?Wüest  Michel?Halbwachs  Gregory?Tanyileke 《Ocean Dynamics》2003,53(3):288-301

To prevent the recurrence of a disastrous eruption of carbon dioxide (CO₂) from Lake Nyos, a degassing plan has been set up for the lake. Since there are concerns that the degassing of the lake may reduce the stability of the density stratification, there is an urgent need for a simulation tool to predict the evolution of the lake stratification in different scenarios. This paper describes the development of a numerical model to predict the CO₂ and dissolved solids concentrations, and the temperature structure as well as the stability of the water column of Lake Nyos. The model is tested with profiles of CO₂ concentrations and temperature taken in the years 1986 to 1996. It reproduces well the general mixing patterns observed in the lake. However, the intensity of the mixing tends to be overestimated in the epilimnion and underestimated in the monimolimnion. The overestimation of the mixing depth in the epilimnion is caused either by the parameterization of the k-epsilon model, or by the uncertainty in the calculation of the surface heat fluxes. The simulated mixing depth is highly sensitive to the surface heat fluxes, and errors in the mixing depth propagate from one year to the following. A precise simulation of the mixolimnion deepening therefore requires high accuracy in the meteorological forcing and the parameterization of the heat fluxes. Neither the meteorological data nor the formulae for the calculation of the heat fluxes are available with the necessary precision. Consequently, it will be indispensable to consider different forcing scenarios in the safety analysis in order to obtain robust boundary conditions for safe degassing. The input of temperature and CO₂ to the lake bottom can be adequately simulated for the years 1986 to 1996 with a constant sublacustrine source of 18 l s^–1 with a CO₂ concentration of 0.395 mol l^–1 and a temperature of 26 °C. The results of this study indicate that the model needs to be calibrated with more detailed field data before using it for its final purpose: the prediction of the stability and the safety of Lake Nyos during the degassing process.Responsible Editor: Hans Burchard  相似文献   

Diamond formation and source carbonation: mineral associations in diamonds from Namibia     

I.?Leost  T.?Stachel  G.?P.?BreyEmail author  J.?W.?Harris  I.?D.?Ryabchikov 《Contributions to Mineralogy and Petrology》2003,145(1):15-24

Mineral inclusions in diamonds from Namibia document a range of mantle sources, including eclogitic, websteritic and peridotitic parageneses. Based on unusual textural features a group of inclusions showing websteritic, peridotitic and transitional chemical features is assigned to an 'undetermined suite' (12% of the studied diamonds). The mutual characteristic of this group is the occurrence of lamellar intergrowths of clinopyroxene and orthopyroxene. In addition, the 'undetermined suite' is associated with a number of uncommon phases: in one diamond MgCO₃ is enclosed by clinopyroxene. Other minerals that form touching inclusions with the pyroxene lamellae are (1) a SiO₂ phase observed in three diamonds, together with CaCO₃ in one of them, (2) phlogopite and a Cr-rich 'titanate' (probably lindsleyite). The inclusions document a metamorphic path of decreasing pressures and temperatures after entrapment in diamond. First, homogeneous low-Ca clinopyroxenes were entrapped at high temperatures. They subsequently exsolved orthopyroxene and probably also SiO₂ (coesite) on cooling along a P,T trajectory that did not allow garnet to be exsolved as well. Phlogopite, carbonates and LIMA phases are the result of overprint of a peridotitic source rock by a carbon-rich agent. The resulting unusual, olivine-free mineral association and the host diamonds are interpreted as products of extensive carbonation of the peridotite.  相似文献   

A Sr isotope study on fluorite and siderite from post-orogenic mineral veins in the eastern Harz Mountains,Germany   总被引：2，自引：0，他引：2  

Jens?SchneiderEmail author  Udo?Haack  Klaus?Stedingk 《Mineralium Deposita》2003,38(8):984-991

Rb–Sr isotope data for siderite and fluorite from sediment-hosted epithermal mineral veins in the eastern Harz Mountains (Germany) are presented. Several fluorite and siderite-bearing paragenetic stages have been proposed for these veins, with the most important mineralization being related to a quartz–sulfide and a subsequent calcite–fluorite–quartz stage, which occurred at 226±1 and 209±2 Ma, respectively. Our Rb–Sr data do not permit the identification of distinct generations of siderite and fluorite, but rather reveal straight internal mixing relations, reflecting mixing of fluids or differential fluid–rock interaction processes. This indicates merely two significant phases of mineral deposition related to the quartz–sulfide and calcite–fluorite–quartz stages. It is shown that the Paleozoic sedimentary host rocks of the veins are the most likely source for the siderite Sr, whereas fluorite displays a two-component mixture between sedimentary Sr and radiogenic Sr derived from locally occurring Permian metavolcanic rocks. Editorial handling: B. Lehmann  相似文献   

Adakite-like signature of Late Miocene intrusions at the Los Pelambres giant porphyry copper deposit in the Andes of central Chile: metallogenic implications   总被引：7，自引：0，他引：7  

Martin?Reich  Miguel?A.?ParadaEmail author  Carlos?Palacios  Andreas?Dietrich  Frank?Schultz  Bernd?Lehmann 《Mineralium Deposita》2003,38(7):876-885

Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and La_N/Yb_N (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb  相似文献   

Sequential extraction procedure in columns—part 2: application of a new method     

F.?WisotzkyEmail author  N.?Cremer 《Environmental Geology》2003,44(7):805-810

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Groundwater and volcanoes: examples from the Azores archipelago     

José?Virgílio?CruzEmail author 《Environmental Geology》2003,44(3):343-355

Groundwater at the Azores archipelago is a strategic resource for the freshwater supply. Freshwater, mineral and thermal water discharges occur in the archipelago, and especially at the Fogo and Furnas volcanoes (São Miguel). These discharges provide data for case studies of groundwater chemistry from volcanic monitoring due to the stable composition of the sampled waters. The mineral and thermal discharges are mainly of sodium bicarbonate types and present a large range of temperatures, from cold springs to waters at about 90 °C. Some boiling discharges have a sulfate-dominated composition, suggesting a steam-heating mechanism. Geochemical studies on these mineral and thermal waters began in the 19th century. Data gathered since these earlier studies provide a baseline for pH, temperature, CO₂ and major-element composition. Weekly measurements of pH and temperature also denote a rather stable behavior.  相似文献