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111.
The sources and the potential availability of chromium were investigated in ultramafic soils from Niquelândia (Goïas State, Brazil), with chemical extractions associated to mineralogical studies, in order to evaluate its bioavailability and its potential impact on the soil biodiversity. Cr contents are particularly high in the studied soils and its partitioning among the solid phase varies with the position in the landscape and depth. Most of the Cr is associated to Fe-oxides but the amount of exchangeable Cr(VI) is high, particularly in one soil profile. Cr availability is higher than expected, and Cr-tolerant vegetation is probably growing on these soils.  相似文献   
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Under the flatlands east of the Andes, the crustal basement is exposed in a few places, composed mainly of the Mitú migmatitic complex and the Parguaza granite, whose ages range between 1.78 and 1.45 Ga. Extensive outcrops of high-grade metamorphic rocks are found in several places. Two metamorphisms are dated between 1.2–1.1 and 1.0–0.9 Ga. They are considered blocks that formed during the Grenville orogeny and have Sm–Nd TDM model ages of 1.87–1.47. The Andaquí terrane is formed mainly by the Garzón Massif, composed of granulites, migmatites, and granites, and the metamorphic rocks of the Sierra de la Macarena, which are covered by undeformed Cambrian sediments. It is believed that after the Grenville orogeny, this unit remained attached to the Amazonic Craton. All the other areas grouped in the Chibcha terrane, though they formed during the Grenville orogeny, are believed to have remained either as part of another continental block or dispersed islands to be amalgamated to the Amazonic Craton during the Lower Paleozoic orogeny, which in the Quetame Massif is dated between the Silurian and Devonian and is named the Quetame orogenic event.  相似文献   
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The application of phosphorus (P)-index methodology to assess the risk of water pollution from agriculture in river basins usually takes time and expends a great amount of resources. This study adapted the P-index methodology using digital mapping of key basin risk criteria for P loss in reference areas to evaluate the wider vulnerability to P loss in a zero-order basin with an intense concentration of pigs and with a history of pig slurry additions to the soil. The P content of eleven reference areas, where ten areas have received various applications of pig slurry and one area has no history of addition, was extrapolated to a zero-order basin using principal component analysis and analysis of hierarchical groupings. Estimated loss of soil and the distance between the P source and the watercourse were mapped using satellite images and in situ evaluations. The methodology of extrapolating was well correlated with a survey of P concentrations in land runoff and provides the potential to improve land management of those areas that are most vulnerable. Principal component analysis and hierarchical clustering analysis proved to be useful tools for the separation of areas with different slurry application times. Our results suggest that the P loss risk could be reduced through the adoption of soil conservation techniques such as reduced-tillage incorporating slurry and crop residue management to provide adequate soil protection, reduce the impact of raindrops and reduce erosion risk and transport of chemical pollutants to water bodies.  相似文献   
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Two mathematical models were used to optimize the performance of a full-scale biological nutrient removal(BNR) activated treatment plant, a plug-flow bioreactors operated in a 3-stage phoredox process configuration, anaerobic anoxic oxic(A2 /O). The ASM2 d implemented on the platform of WEST2011 software and the Bio Win activated sludge/anaerobic digestion(AS/AD) models were used in this study with the aim of consistently achieving the designed effluent criteria at a low operational cost. Four ASM2 d parameters(the reduction factor for denitrification(η NO3, H), the maximum growth rate of heterotrophs( μ H), the rate constant for stored polyphosphates in PAOs(q pp), and the hydrolysis rate constant(k h)) were adjusted. Whereas three Bio Win parameters(aerobic decay rate(b H), heterotrophic dissolved oxygen(DO) half saturation(K OA), and Y P /acetic) were adjusted. Calibration of the two models was successful; both models have average relative deviations(ARD) less than 10% for all the output variables. Low effluent concentrations of nitrate nitrogen(N-NO3), total nitrogen(TN), and total phosphorus(TP) were achieved in a full-scale BNR treatment plant having low influent chemical oxygen demand(COD) to total Kjeldahl nitrogen(TKN) ratio(COD/TKN). The effluent total nitrogen and nitrate nitrogen concentrations were improved by 50% and energy consumption was reduced by approximately 25%, which was accomplished by converting the two-pass aerobic compartment of the plug-flow bioreactor to anoxic reactors and being operated in an alternating mode. Findings in this work are helpful in improving the operation of wastewater treatment plant while eliminating the cost of external carbon source and reducing energy consumption.  相似文献   
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Hydrogeology Journal - Nitrate contamination of groundwater is an important public health issue worldwide. For environmental and public health reasons, water should not contain more than...  相似文献   
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To effectively manage hydrological drought, there is an urgent need to better understand and evaluate its human drivers. Using the “downstreamness” concept, we assess the role of a reservoir network in the emergence and evolution of droughts in a river basin in Brazil. In our case study, the downstreamness concept shows the effect of a network of reservoirs on the spatial distribution of stored surface water volumes over time. We demonstrate that, as a consequence of meteorological drought and recovery, the distribution of stored volumes became spatially skewed towards upstream locations, which affected the duration and magnitude of hydrological drought both upstream (where drought was alleviated) and downstream (where drought was aggravated). The downstreamness concept thus appears to be a useful entry point for spatiotemporally explicit assessments of hydrological drought and for determining the likelihood of progression from meteorological drought to a human-modified hydrological drought in a basin.  相似文献   
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The occurrence of intersexuality in populations of the marine amphipod Echinogammarus marinus has been related to several causes, including anthropogenic contamination, microsporidian parasites and environmental sex determination (ESD). At the individual-level, the costs of intersexuality in E. marinus are reflected in reduced reproductive output of intersexes compared to normal specimens. The impacts of intersexuality and other reproductive disorders in nature will only be fully understood when individual-level effects are upscale to the population-level, which can be achieved through ecological models. The aim of the present work is to simulate the density variation of real populations of E. marinus with different intersexuality incidence, proportions of phenotypes and intersex female reproductive rates. To achieve that, we have incorporated empirical data obtained at the individual-level from three intersexed populations of E. marinus into a population dynamic model. The original model was calibrated and validated for a long-term stable population without intersexuality and sex ratio 1. In the present version, the model includes an extra population group, intersex females, but the total sum of flow rates from juveniles to adults was kept the same as in the original model to respect the previous validation. In these circumstances, results indicate that the male-biased population is very sensitive to intersexuality, even at low incidence levels, and exhibits significant density decrease if conditions do not change. On the contrary, the two populations with a preponderance of female-biased sex ratios, low or moderate intersexuality incidence (up to an average value of 9% of the population) and with intersex reproductive rates corresponding to 80% the value of normal specimens, exhibit long-term persistence.The model is highly sensitive to adult female parameters (e.g. mortality), indicating that small variations on its values can significantly change population responses.Overall the present results suggest that, in spite the costs of intersexuality in E. marinus, the temporal variation of intersexed populations depend on intersex incidence level, sex ratio fluctuations and reproductive output of intersexes. Simulations also suggest that other processes (e.g. mortality rates of normal females) may play important roles in the maintenance of populations with intersexuality. In the future, it will be crucial to improve and validate this type of models with long-term observations and monitoring of intersexed populations.  相似文献   
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