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51.
Pollutant delivery through artificial subsurface drainage networks to streams is an important transport mechanism, yet the impact of drainage tiles on groundwater hydrology at the watershed scale has not been well documented. In this study, we developed a two‐dimensional, steady‐state groundwater flow model for a representative Iowa agricultural watershed to simulate the impact of tile drainage density and incision depth on groundwater travel times and proportion of baseflow contributed by tile drains. Varying tile drainage density from 0 to 0.0038 m?1, while maintaining a constant tile incision depth at 1.2 m, resulted in the mean groundwater travel time to decrease exponentially from 40 years to 19 years and increased the tile contribution to baseflow from 0% to an upper bound of 37%. In contrast, varying tile depths from 0.3 to 2.7 m, while maintaining a constant tile drainage density of 0.0038 m?1, caused mean travel times to decrease linearly from 22 to 18 years and increased the tile contribution to baseflow from 30% to 54% in a near‐linear manner. The decrease in the mean travel time was attributed to decrease in the saturated thickness of the aquifer with increasing drainage density and incision depth. Study results indicate that tile drainage affects fundamental watershed characteristics and should be taken into consideration when evaluating water and nitrate export from agricultural regions. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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Lower crustal xenoliths erupted from an intraplate diatreme reveal that a portion of the New Zealand Gondwana margin experienced high‐temperature (HT) to ultrahigh‐temperature (UHT) granulite facies metamorphism just after flat slab subduction ceased at c. 110–105 Ma. PT calculations for garnet–orthopyroxene‐bearing felsic granulite xenoliths indicate equilibration at ~815 to 910°C and 0.7 to 0.8 GPa, with garnet‐bearing mafic granulite xenoliths yielding at least 900°C. Supporting evidence for the attainment of HT and UHT conditions in felsic granulite comes from re‐integration of exsolution in feldspar (~900–950°C at 0.8 GPa), Ti‐in‐zircon thermometry on Y‐depleted overgrowths on detrital zircon grains (932°C ± 24°C at aTiO2 = 0.8 ± 0.2), and correlation of observed assemblages and mineral compositions with thermodynamic modelling results (≥850°C at 0.7 to 0.8 GPa). The thin zircon overgrowths, which were mainly targeted by drilling through the cores of grains, yield a U–Pb pooled age of 91.7 ± 2.0 Ma. The cause of Late Cretaceous HT‐UHT metamorphism on the Zealandia Gondwana margin is attributed to collision and partial subduction of the buoyant oceanic Hikurangi Plateau in the Early Cretaceous. The halt of subduction caused the fore‐running shallowly dipping slab to rollback towards the trench position and permitted the upper mantle to rapidly increase the geothermal gradient through the base of the extending (former) accretionary prism. This sequence of events provides a mechanism for achieving regional HT–UHT conditions in the lower crust with little or no sign of this event at the surface.  相似文献   
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This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons.  相似文献   
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Baltic clams (Macoma balthica) were the predominant food items of 323 canvasbacks (Aythya valisineria) collected throughout Chesapeake Bay during 1970–1979. Natural vegetation constituted 4% of the food volume. Widgeongrass (Ruppia maritima) and redhead grass (Potamogeton perfoliatus) constituted the greatest percent volume and frequency of occurrence among the plant species, whereas wild celery (Vallisneria americana) constituted only a trace of the food volume. These results contrast with historical records of food habits of canvasbacks in Chesapeake Bay. Canvasback population estimates during the 1970’s were examined to detect annual and seasonal changes in distribution. Linear regression analyses of winter canvasback populations in the bay showed a significant decline in the upper-bay and middle-bay populations, but no significant changes in the lower-bay and Potomac River populations. The changes in winter distribution and abundance of the canvasback appear related to changes in natural food availability, which is the result of altered environmental conditions.  相似文献   
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Argon diffusion domains in K-feldspar II: kinetic properties of MH-10   总被引:2,自引:0,他引:2  
Viewing K-feldspars as containing a discrete distribution of diffusion domain sizes reconciles otherwise disconsonant features common in their 40Ar/39Ar age spectra and Arrhenius plots but raises a fundamental question. What are the features in K-feldspar that endow it with this behavior? We report here the results of two different kinds of experiments that help isolate the nature of the responsible diffusion properties. To assess the thermal stability of the diffusion domains during laboratory treatment, MH-10 K-feldspar was step-heated to 850°C, removed from the furnace and split. One split was reirradiated and the other returned to the furnace and completely degassed. Following re-irradiation, the original heating schedule was used to degas the second aliquot. Apart from the first 5% of gas released, the diffusion properties show little change relative to the original result but, it appears, the physical character of a portion of the smallest domain has been altered. Results of duplicate step-heating experiments of samples treated at 750°C, 950°C and 1100°C prior to irradiation are consistent with the conclusions of the double irradiation experiment. In a second series of experiments, sized aggregates of MH-10 K-feldspar were analyzed by the 40Ar/39Ar step-heating method. The resultant log(r/r o) plots reveal that the largest domain is annihilated when the particle size is reduced to about 50 μm. From this result we infer that the largest diffusion domain size is between 60 and about 130 μm in diameter. This estimate, together with knowledge of the relative domain size distribution obtained from modeling the log(r/r o) plot, sets the size of the smallest domain to be less than about 1 μm. Microstructural examination of MH-10 K-feldspar identifies sub-grain features that correspond in size to our independent estimates for the largest and smallest diffusion domains. These results strongly support the view that low-temperature K-feldspars contain a distribution of diffusion length scales that are well approximated as discrete domain sizes and that laboratory heating below the onset of melting does not significatly affect the ability to obtain thermal reconstructions from the 40Ar/39Ar systematics.  相似文献   
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Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced by studies conducted over the past 15 years that span Holocene and pre-historical timescales.  相似文献   
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