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71.
Porewater data from vent sites of the northeastern shelf off Sakhalin Island, Sea of Okhotsk, exhibit bottom-water concentrations down to a sediment depth of up to 300 cm. Below this depth, solute concentrations rapidly change due to methanogenesis and anaerobic methane oxidation (AMO). The profile shapes suggest an irrigation-like process that mixes on a meter scale. At these sites active gas emanation into the overlying water column and near-surface gas hydrates are commonly observed. We propose that methane gas bubbles rise through the soft surface sediments and cause mixing of the porewater.Mathematically, the bubble-induced irrigation can be described by eddy diffusion enhancing the diffusive transport of solutes by several orders of magnitude. A 3-D numerical transport-reaction model was developed to investigate the parameters defining the mixing process, such as bubble rise velocity, tube size, tube distribution in the sediment, and ebullition frequency.Model consistency with the field data requires eddy diffusivities ?1 × 105 cm2/a, tube densities of >4 tubes/m2 (equivalent to a tube spacing of <40 cm), active gas seepage for more than a few weeks or months, and moderate to low diagenetic reaction rates of solutes. The corresponding methane gas fluxes that are predicted from the results of the model realizations range from 1 × 103-5 × 105 L/(m2 a). Due to bubble mixing, solute fluxes in these sediments are increased by a factor of 3 and the maximum AMO rate by a factor of 7. 相似文献
72.
Nikolaus Gussone Gerald Langer Markus Geisen Blair A. Steel Ulf Riebesell 《Earth and Planetary Science Letters》2007,260(3-4):505-515
Four species of marine calcifying algae, the coccolithophores Calcidiscus leptoporus, Helicosphaera carteri, Syracosphaera pulchra and Umbilicosphaera foliosa were grown in laboratory cultures under temperatures varying between 14 and 23 °C, and one species, C. leptoporus, under varying [CO32−], ranging from 105 to 219 μmol/kg. Calcium isotope compositions of the coccoliths resemble in both absolute fractionation and temperature sensitivity previous calibrations of marine calcifying species e.g. Emiliania huxleyi (coccolithophores) and Orbulina universa (planktonic foraminifera) as well as inorganically precipitated CaCO3, but also reveal small species specific differences. In contrast to inorganically precipitated calcite, but similar to E. huxleyi and O. universa, the carbonate ion concentration of the medium has no statistically significant influence on the Ca isotope fractionation of C. leptoporus coccoliths; however, combined data of E. huxleyi and C. leptoporus indicate that the observed trends might be related to changes of the calcite saturation state of the medium. Since coccoliths constitute a significant portion of the global oceanic CaCO3 export production, the Ca isotope fractionation in these biogenic structures is important for defining the isotopic composition of the Ca sink of the ocean, one of the key parameters for modelling changes to the marine Ca budget over time. For the present ocean our results are in general agreement with the previously postulated and applied mean value of the oceanic Ca sink (Δsed) of about − 1.3‰, but the observed inter- and intra-species differences point to possible changes in Δsed through earth history, due to changing physico-chemical conditions of the ocean and shifts in floral and faunal assemblages. 相似文献
73.
Uwe Mikolajewicz Matthias Gröger Ernst Maier-Reimer Guy Schurgers Miren Vizcaíno Arne M. E. Winguth 《Climate Dynamics》2007,28(6):599-633
A new complex earth system model consisting of an atmospheric general circulation model, an ocean general circulation model,
a three-dimensional ice sheet model, a marine biogeochemistry model, and a dynamic vegetation model was used to study the
long-term response to anthropogenic carbon emissions. The prescribed emissions follow estimates of past emissions for the
period 1751–2000 and standard IPCC emission scenarios up to the year 2100. After 2100, an exponential decrease of the emissions
was assumed. For each of the scenarios, a small ensemble of simulations was carried out. The North Atlantic overturning collapsed
in the high emission scenario (A2) simulations. In the low emission scenario (B1), only a temporary weakening of the deep
water formation in the North Atlantic is predicted. The moderate emission scenario (A1B) brings the system close to its bifurcation
point, with three out of five runs leading to a collapsed North Atlantic overturning circulation. The atmospheric moisture
transport predominantly contributes to the collapse of the deep water formation. In the simulations with collapsed deep water
formation in the North Atlantic a substantial cooling over parts of the North Atlantic is simulated. Anthropogenic climate
change substantially reduces the ability of land and ocean to sequester anthropogenic carbon. The simulated effect of a collapse
of the deep water formation in the North Atlantic on the atmospheric CO2 concentration turned out to be relatively small. The volume of the Greenland ice sheet is reduced, but its contribution to
global mean sea level is almost counterbalanced by the growth of the Antarctic ice sheet due to enhanced snowfall. The modifications
of the high latitude freshwater input due to the simulated changes in mass balance of the ice sheet are one order of magnitude
smaller than the changes due to atmospheric moisture transport. After the year 3000, the global mean surface temperature is
predicted to be almost constant due to the compensating effects of decreasing atmospheric CO2 concentrations due to oceanic uptake and delayed response to increasing atmospheric CO2 concentrations before. 相似文献
74.
Matthias Mauder Steven P. Oncley Roland Vogt Tamas Weidinger Luis Ribeiro Christian Bernhofer Thomas Foken Wim Kohsiek Henk A. R. De Bruin Heping Liu 《Boundary-Layer Meteorology》2007,123(1):29-54
The eddy-covariance method is the primary way of measuring turbulent fluxes directly. Many investigators have found that these
flux measurements often do not satisfy a fundamental criterion—closure of the surface energy balance. This study investigates
to what extent the eddy-covariance measurement technology can be made responsible for this deficiency, in particular the effects
of instrumentation or of the post-field data processing. Therefore, current eddy-covariance sensors and several post-field
data processing methods were compared. The differences in methodology resulted in deviations of 10% for the sensible heat
flux and of 15% for the latent heat flux for an averaging time of 30 min. These disparities were mostly due to different sensor
separation corrections and a linear detrending of the data. The impact of different instrumentation on the resulting heat
flux estimates was significantly higher. Large deviations from the reference system of up to 50% were found for some sensor
combinations. However, very good measurement quality was found for a CSAT3 sonic together with a KH20 krypton hygrometer and
also for a UW sonic together with a KH20. If these systems are well calibrated and maintained, an accuracy of better than
5% can be achieved for 30-min values of sensible and latent heat flux measurements. The results from the sonic anemometers
Gill Solent-HS, ATI-K, Metek USA-1, and R.M. Young 81000 showed more or less larger deviations from the reference system.
The LI-COR LI-7500 open-path H2O/CO2 gas analyser in the test was one of the first serial numbers of this sensor type and had technical problems regarding direct
solar radiation sensitivity and signal delay. These problems are known by the manufacturer and improvements of the sensor
have since been made.
The National Center for Atmospheric Research is supported by the National Science Foundation. 相似文献
75.
A. N. Platonov A. N. Tarashchan K. Langer M. Andrut G. Partzsch S. S. Matsyuk 《Physics and Chemistry of Minerals》1998,25(3):203-212
A selected set of five different kyanite samples was analysed by electron microprobe and found to contain chromium between <0.001 and 0.055 per formula unit (pfu). Polarized electronic absorption spectroscopy on oriented single crystals,
R1, R2-sharp line luminescence and spectra of excitation of λ3- and λ4-components of R1-line of Cr3+-emission had the following results: (1) The Fe2+–Ti4+ charge transfer in c-parallel chains of edge connected M(1) and M(2) octahedra shows up in the electronic absorption spectra
as an almost exclusively c(||Z′)-polarized, very strong and broad band at 16000 cm−1 if <, in this case the only band in the spectrum, and at an invariably lower energy of 15400 cm−1 in crystals with ≥ . The energy difference is explained by an expansion of the Of–Ok, and Ob–Om edges, by which the M(1) and M(2) octahedra are interconnected (Burnham 1963), when Cr3+ substitutes for Al compared to the chromium-free case. (2) The Cr3+ is proven in two greatly differing crystal fields a and b, giving rise to two sets of bands, derived from the well known
dd transitions of Cr3+
4A2g→4T2g(F)(I), →4T1g(F)(II), and →4T1g(P)(III). Band energies in the two sets a and b, as obtained by absorption, A, and excitation, E, agree well: I: 17300(a, A),
17200(a, E), 16000(b, A), 16200(b, E); II: 24800(a, A), 24400(a, E); 22300(b, A), 22200(b, E); III: 28800(b,A) cm−1. Evaluation of crystal field parameters from the bands in the electronic spectra yield Dq(a)=1730 cm−1, Dq(b)=1600 cm−1, B(a)=790 cm−1, B(b)=620 cm−1 (errors ca. ±10 cm−1), again in agreement with values extracted from the λ3, λ4 excitation spectra. The CF-values of set a are close to those typical of Cr3+ substituting for Al in octahedra of other silicate minerals without constitutional OH− as for sapphirine, mantle garnets or beryl, and are, therefore, interpreted as caused by Cr3+ substituting for Al in some or all of the M(1) to M(4) octaheda of the kyanite structure, which are crystallographically
different but close in their mean Al–O distances, ranging from 1.896 to 1.919 A (Burnham 1963), and slight degrees of distortion.
Hence, band set a originates from substitutive Cr3+ in the kyanite structural matrix. The CF-data of Cr3+ type b, expecially B, resemble those of Cr3+ in oxides, especially of corundum type solid solutions or eskolaite. This may be interpreted by the assumption that a fraction
of the total chromium contents might be allocated in a precursor of a corundum type exsolution.
Received: 3 January 1997 / Revised, accepted: 2 May 1997 相似文献
76.
Matthias Zillmer Boris Kashtan & Dirk Gajewski 《Geophysical Journal International》1998,132(3):643-653
Wave propagation in weakly anisotropic inhomogeneous media is studied by the quasi-isotropic approximation of ray theory. The approach is based on the ray-tracing and dynamic ray-tracing differential equations for an isotropic background medium. In addition, it requires the integration of a system of two complex coupled differential equations along the isotropic ray.
The interference of the qS waves is described by traveltime and polarization corrections of interacting isotropic S waves. For qP waves the approach leads to a correction of the traveltime of the P wave in the isotropic background medium.
Seismograms and particle-motion diagrams obtained from numerical computations are presented for models with different strengths of anisotropy.
The equivalence of the quasi-isotropic approximation and the quasi-shear-wave coupling theory is demonstrated. The quasi-isotropic approximation allows for a consideration of the limit from weak anisotropy to isotropy, especially in the case of qS waves, where the usual ray theory for anisotropic media fails. 相似文献
The interference of the qS waves is described by traveltime and polarization corrections of interacting isotropic S waves. For qP waves the approach leads to a correction of the traveltime of the P wave in the isotropic background medium.
Seismograms and particle-motion diagrams obtained from numerical computations are presented for models with different strengths of anisotropy.
The equivalence of the quasi-isotropic approximation and the quasi-shear-wave coupling theory is demonstrated. The quasi-isotropic approximation allows for a consideration of the limit from weak anisotropy to isotropy, especially in the case of qS waves, where the usual ray theory for anisotropic media fails. 相似文献
77.
78.
Mössbauer and polarized optical absorption spectra of the kyanite-related mineral yoderite were recorded. Mössbauer spectra of the purple (PY) and green yoderite (GY) from Mautia Hill, Tanzania, show that the bulk of the iron is Fe3+ in both varieties, with Fe2+/(Fe2++Fe3+) ratios near 0.05. Combining this result with new microprobe data for PY and with literature data for GY gives the crystallochemical formulae: $$\begin{gathered} ({\text{Mg}}_{{\text{1}}{\text{.95}}} {\text{Fe}}_{{\text{0}}{\text{.02}}}^{{\text{2 + }}} {\text{Mn}}_{{\text{0}}{\text{.01}}}^{{\text{2 + }}} {\text{Fe}}_{{\text{0}}{\text{.34}}}^{{\text{3 + }}} {\text{Mn}}_{{\text{0}}{\text{.07}}}^{{\text{3 + }}} {\text{Ti}}_{{\text{0}}{\text{.01}}} {\text{Al}}_{{\text{3}}{\text{.57}}} )_{5.97}^{[5,6]} \hfill \\ {\text{Al}}_{{\text{2}}{\text{.00}}}^{{\text{[5]}}} [({\text{Si}}_{{\text{3}}{\text{.98}}} {\text{P}}_{{\text{0}}{\text{.03}}} ){\text{O}}_{{\text{18}}{\text{.02}}} ({\text{OH)}}_{{\text{1}}{\text{.98}}} ] \hfill \\ \end{gathered}$$ and PY and $$\begin{gathered} ({\text{Mg}}_{{\text{1}}{\text{.98}}} {\text{Fe}}_{{\text{0}}{\text{.02}}}^{{\text{2 + }}} {\text{Mn}}_{{\text{< 0}}{\text{.001}}}^{{\text{2 + }}} {\text{Fe}}_{{\text{0}}{\text{.45}}}^{{\text{3 + }}} {\text{Ti}}_{{\text{0}}{\text{.01}}} {\text{Al}}_{{\text{3}}{\text{.56}}} )_{6.02}^{[5,6]} \hfill \\ {\text{Al}}_{{\text{2}}{\text{.00}}}^{{\text{[5]}}} [({\text{Si}}_{{\text{3}}{\text{.91}}} {\text{O}}_{{\text{17}}{\text{.73}}} {\text{(OH)}}_{{\text{2}}{\text{.27}}} ] \hfill \\ \end{gathered}$$ for GY. The Mössbauer spectra at room temperature contain one main doublet with isomer shifts and quadrupole splittings of 0.36 (PY), 0.38 (GY) and 1.00 (PY), 0.92 (GY) mm s?1, respectively. These values correspond to Fe3+ in six or five-fold coordination. The doublet components have anomalously large half widths indicating either accomodation of Fe3+ in more than one position (e.g., octahedraA1 and five coordinatedA2) or the yet unresolved superstructure. Besides strong absorption in the ultraviolet (UV) starting from about 25,000 cm?1, the polarized optical absorption spectra are dominated by strong bands around 16,500 and 21,000 cm?1 (PY) and a medium strong band at around 13,800 cm?1 (GY). Position and polarization of these bands, in combination with the UV absorption, explain the colour and pleochroism of the two varieties. The bands in question are assigned to homonuclear metal-to-metal charge transfer transitions: Mn2+(A1) Mn3+(A1′) ? Mn3+(A1) Mn2+(A1′) and Mn2+(A1) Mn3+(A2 ? Mn3+(A1) Mn2+(A2) in PY and Fe2+(A1) Fe3+(A1′) ? Fe3+(A1) Fe2+(A1′) in GY. The evidence for homonuclear Mn2+ Mn3+ charge transfer (CTF) is not quite clear and needs further study. Heteronuclear FeTi CTF does not contribute to the spectra. In PY, additional weak bands were resolved at energies around 17,700, 18,700, 21,000, and 21,900 cm?1 and assigned to Mn3+ in two positions. Weak bands around 10,000 cm?1 in both varieties are assigned to Fe2+ spin-alloweddd-transitions. Very weak and sharp bands, around 15,400, 16,400, 21,300, 22,100, 23,800, and 25,000 cm?1 are identified in GY and assigned to Fe3+ spin-forbiddendd-transitions. 相似文献
79.
Deerite, Fe
12
2+
Fe
6
3+
[Si12O40](OH)10, thus far known from ten localities in glaucophane schist terranes, was synthesized at water pressures of 20–25 kb and temperatures of 550–600 °C under the
of the Ni/NiO buffer. The X-ray powder diagram, lattice constants and infrared spectrum of the synthetic phase are closely similar to those of the natural mineral. A solid solution series extends from this ferri-deerite end member to some 20 mole % of a hypothetical alumino-deerite, Fe
12
2+
Al
6
3+
[Si12O40](OH)10. The upper temperature breakdown of ferri-deerite to the assemblage ferrosilite +magnetite+quartz+water occurs at about 490 °C at 15 kb, and 610 °C at 25 kb fluid pressure for the
of the Ni/NiO buffer. Extrapolation of these data to lower water pressures indicates that deerite can be a stable mineral only in very low-temperature, high-pressure environments. 相似文献
80.
Tracing variability of run‐off generation in mountainous permafrost of semi‐arid north‐eastern Mongolia 下载免费PDF全文
The headwaters of mountainous, discontinuous permafrost regions in north‐eastern Mongolia are important water resources for the semi‐arid country, but little is known about hydrological processes there. Run‐off generation on south‐facing slopes, which are devoid of permafrost, has so far been neglected and is totally unknown for areas that have been affected by recent forest fires. To fill this knowledge gap, the present study applied artificial tracers on a steppe‐vegetated south‐facing and on two north‐facing slopes, burned and unburned. Combined sprinkling and dye tracer experiments were used to visualize processes of infiltration and water fluxes in the unsaturated zone. On the unburned north‐facing slope, rapid and widespread infiltration through a wet organic layer was observed down to the permafrost. On the burned profile, rapid infiltration occurred through a combusted organic and underlying mineral layer. Stained water seeped out at the bottom of both profiles suggesting a general tendency to subsurface stormflow (SSF). Ongoing SSF could directly be studied 24 h after a high‐intensity rainfall event on a 55‐m hillslope section in the burned forest. Measurements of water temperature proved the role of the permafrost layer as a base horizon for SSF. Repeated tracer injections allowed direct insights into SSF dynamics: A first injection suggested rather slow dispersive subsurface flow paths; whereas 18 h later, a second injection traced a more preferential flow system with 20 times quicker flow velocities. We speculate that these pronounced SSF dynamics are limited to burned slopes where a thermally insulating organic layer is absent. On three south‐facing soil profiles, the applied tracer remained in the uppermost 5 cm of a silt‐rich mineral soil horizon. No signs of preferential infiltration could be found, which suggested reduced biological activity under a harsh, dry and cold climate. Instead, direct observations, distributed tracers and charcoal samples provided evidence for the occurrence of overland flow. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献