Ab initio quantum-mechanical modeling of pyrophyllite [Al2Si4O10(OH)2] and talc [Mg3Si4O10(OH)2] surfaces     

Marco Bruno  Mauro Prencipe  Giovanni Valdre’ 《Physics and Chemistry of Minerals》2006,33(1):63-71

Bulk and slab geometry optimizations and calculations of the electrostatic potential at the surface of both pyrophyllite [Al₂Si₄O₁₀(OH)₂] and talc [Mg₃Si₄O₁₀(OH)₂] were performed at Hartree–Fock and DFT level. In both pyrophyllite and talc cases, a modest (001) surface relaxation was observed, and the surface preserves the structural features of the crystal: in the case of pyrophyllite the tetrahedral and octahedral sheets are strongly distorted with respect to the ideal hexagonal symmetry (and basal oxygen are located at different heights along the direction normal to the basal plane), whereas the structure of talc deviates slightly from the ideal hexagonal symmetry (almost co-planar basal oxygen). The calculated distortions are fully consistent with those experimentally observed. Although the potentials at the surface of pyrophyllite and talc are of the same order of magnitude, large topological differences were observed, which could possibly be ascribed to the differences between the surface structures of the two minerals. Negative values of the potential are located above the basal oxygen and at the center of the tetrahedral ring; above silicon the potential is always positive. The value of the potential minimum above the center of the tetrahedral ring of pyrophyllite is ?0.05 V (at 2 Å from the surface), whereas in the case of talc the minimum is ?0.01 V, at 2.7 Å. In the case of pyrophyllite the minimum of potential above the higher basal oxygen is located at 1.1 Å and it has a value of ?1.25 V, whereas above the lower oxygen the value of the potential at the minimum is ?0.2 V, at 1.25 Å; the talc exhibits a minimum of ?0.75 V at 1.2 Å, above the basal oxygen.  相似文献   

The 1538 Monte Nuovo eruption (Campi Flegrei,Italy)     

Mauro Di Vito  Lucio Lirer  Giuseppe Mastrolorenzo  Giuseppe Rolandi 《Bulletin of Volcanology》1987,49(4):608-615

On 29 September 1538 a week-long eruption began in Campi Flegrei forming a new volcano, Monte Nuovo. From contemporary accounts of the eruption, it has been possible to reconstruct the main phases of activity. These phases may be correlated with different depositional units identified in the field. The eruption opened with a hydromagmatic phase, during which a large amount of external water (meteoric or sea water) was able to interact with the magma. The exhaustion of the water supply and decrease in volatile content initiated a change in the dynamic conditions of eruption, which became more purely magmatic in character and less explosive.  相似文献   

Trends and variability of cloud fraction cover in the Arctic, 1982–2009     

Mauro?BoccolariEmail authorView author&#;s OrcID profile  Flavio?Parmiggiani 《Theoretical and Applied Climatology》2018,132(3-4):739-749

Climatology, trends and variability of cloud fraction cover (CFC) data over the Arctic (north of 70°N), were analysed over the 1982–2009 period. Data, available from the Climate Monitoring Satellite Application Facility (CM SAF), are derived from satellite measurements by AVHRR. Climatological means confirm permanent high CFC values over the Atlantic sector during all the year and during summer over the eastern Arctic Ocean. Lower values are found in the rest of the analysed area especially over Greenland and the Canadian Archipelago, nearly continuously during all the months. These results are confirmed by CFC trends and variability. Statistically significant trends were found during all the months over the Greenland Sea, particularly during the winter season (negative, less than ?5?%?dec ^?1) and over the Beaufort Sea in spring (positive, more than +5?%?dec ^?1). CFC variability, investigated by the Empirical Orthogonal Functions, shows a substantial “non-variability” in the Northern Atlantic Ocean. Statistically significant correlations between CFC principal components elements and both the Pacific Decadal Oscillation index and Pacific North America patterns are found.  相似文献   

Improving Bayesian analysis for LISA Pathfinder using an efficient Markov Chain Monte Carlo method     

Luigi Ferraioli  Edward K. Porter  Michele Armano  Heather Audley  Giuseppe Congedo  Ingo Diepholz  Ferran Gibert  Martin Hewitson  Mauro Hueller  Nikolaos Karnesis  Natalia Korsakova  Miquel Nofrarias  Eric Plagnol  Stefano Vitale 《Experimental Astronomy》2014,37(1):109-125

We present a parameter estimation procedure based on a Bayesian framework by applying a Markov Chain Monte Carlo algorithm to the calibration of the dynamical parameters of the LISA Pathfinder satellite. The method is based on the Metropolis-Hastings algorithm and a two-stage annealing treatment in order to ensure an effective exploration of the parameter space at the beginning of the chain. We compare two versions of the algorithm with an application to a LISA Pathfinder data analysis problem. The two algorithms share the same heating strategy but with one moving in coordinate directions using proposals from a multivariate Gaussian distribution, while the other uses the natural logarithm of some parameters and proposes jumps in the eigen-space of the Fisher Information matrix. The algorithm proposing jumps in the eigen-space of the Fisher Information matrix demonstrates a higher acceptance rate and a slightly better convergence towards the equilibrium parameter distributions in the application to LISA Pathfinder data. For this experiment, we return parameter values that are all within ～1σ of the injected values. When we analyse the accuracy of our parameter estimation in terms of the effect they have on the force-per-unit of mass noise, we find that the induced errors are three orders of magnitude less than the expected experimental uncertainty in the power spectral density.  相似文献   

Connectivity and single/dual domain transport models: tests on a point-bar/channel aquifer analogue     

Diana Dell’Arciprete  Chiara Vassena  Fulvia Baratelli  Mauro Giudici  Riccardo Bersezio  Fabrizio Felletti 《Hydrogeology Journal》2014,22(4):761-778

In porous aquifers, groundwater flow and solute transport strongly depend on the sedimentary facies distribution at fine scale, which determines the heterogeneity of the conductivity field; in particular, connected permeable sediments could form preferential flow paths. Therefore, properly defined statistics, e.g. total and intrinsic facies connectivity, should be correlated with transport features. In order to improve the assessment of the relevance of this relationship, some tests are conducted on two ensembles of equiprobable realizations, obtained with two different geostatistical simulation methods—sequential indicator simulation and multiple point simulation (MPS)—from the same dataset, which refers to an aquifer analogue of sediments deposited in a fluvial point-bar/channel association. The ensembles show different features; simulations with MPS are more structured and characterised by preferential flow paths. This is confirmed by the analysis of transport connectivities and by the interpretation of data from numerical experiments of conservative solute transport with single and dual domain models. The use of two ensembles permits (1) previous results obtained for single realizations to be consolidated on a more firm statistical basis and (2) the application of principal component analysis to assess which quantities are statistically the most relevant for the relationship between connectivity indicators and flow and transport properties.  相似文献   

Evaluation of liquefaction potential in an intermountain Quaternary lacustrine basin (Fucino basin,central Italy)     

Paolo Boncio  Sara Amoroso  Giovanna Vessia  Marco Francescone  Mauro Nardone  Paola Monaco  Daniela Famiani  Deborah Di Naccio  Alessia Mercuri  Maria Rosaria Manuel  Fabrizio Galadini  Giuliano Milana 《Bulletin of Earthquake Engineering》2018,16(1):91-111

In this study, we analyse the susceptibility to liquefaction of the Pozzone site, which is located on the northern side of the Fucino lacustrine basin in central Italy. In 1915, this region was struck by a M 7.0 earthquake, which produced widespread coseismic surface effects that were interpreted to be liquefaction-related. However, the interpretation of these phenomena at the Pozzone site is not straightforward. Furthermore, the site is characterized by an abundance of fine-grained sediments, which are not typically found in liquefiable soils. Therefore, in this study, we perform a number of detailed stratigraphic and geotechnical investigations (including continuous-coring borehole, CPTu, SDMT, SPT, and geotechnical laboratory tests) to better interpret these 1915 phenomena and to evaluate the liquefaction potential of a lacustrine environment dominated by fine-grained sedimentation. The upper 18.5 m of the stratigraphic succession comprises fine-grained sediments, including four strata of coarser sediments formed by interbedded layers of sand, silty sand and sandy silt. These strata, which are interpreted to represent the frontal lobes of an alluvial fan system within a lacustrine succession, are highly susceptible to liquefaction. We also find evidence of paleo-liquefaction, dated between 12.1–10.8 and 9.43–9.13 kyrs ago, occurring at depths of 2.1–2.3 m. These data, along with the aforementioned geotechnical analyses, indicate that this site would indeed be liquefiable in a 1915-like earthquake. Although we found a broad agreement among CPTu, DMT and shear wave velocity “simplified procedures” in detecting the liquefaction potential of the Pozzone soil, our results suggest that the use and comparison of different in situ techniques are highly recommended for reliable estimates of the cyclic liquefaction resistance in lacustrine sites characterized by high content of fine-grained soils. In geologic environments similar to the one analysed in this work, where it is difficult to detect liquefiable layers, one can identify sites that are susceptible to liquefaction only by using detailed stratigraphic reconstructions, in situ characterization, and laboratory analyses. This has implications for basic (Level 1) seismic microzonation mapping, which typically relies on the use of empirical evaluations based on geologic maps and pre-existing sub-surface data (i.e., age and type of deposits, prevailing grain size, with particular attention paid to clean sands, and depth of the water table).  相似文献   

Observations of near-inertial oscillations along the Brazilian continental shelf break     

de Freitas  Pedro Paulo  Amorim  Felipe de Luca Lopes  Mill  Guilherme Nogueira  da Costa  Vladimir Santos  Gabioux  Mariela  Cirano  Mauro  Paiva  Afonso de Moraes 《Ocean Dynamics》2019,69(10):1203-1215

Ocean Dynamics - Near-inertial oscillations (NIO) are intermittent motions with a frequency close to the inertial frequency and represent an important fraction of the energy to the currents in the...  相似文献   

Uniform fragility spectra for the performance‐based seismic design of structures considering variabilities in structural properties          下载免费PDF全文

Mauro Niño  Gustavo Ayala  Saúl López 《地震工程与结构动力学》2018,47(8):1742-1754

This paper presents a new methodology based on structural performance to determine uniform fragility design spectra, i.e., spectra with the same probability of exceedance of a performance level for a given seismic intensity. The design spectra calculated with this methodology provide directly the lateral strength, in terms of yield‐ pseudo‐accelerations, associated with the rate of exceedance of a specific ductility characterizing the performance level for which the structures will be designed. This procedure involves the assessment of the seismic hazard using a large enough number of seismic records of several magnitudes; these records are simulated with an improved empirical Green function method. The statistics of the performance of a single degree of freedom system are obtained using Monte Carlo simulation considering the seismic demand, the fundamental period, and the strength of the structure as uncertain variables. With these results, the conditional probability that a structure exceeds a specific performance level is obtained. The authors consider that the proposed procedure is a significant improvement to others considered in the literature and a useful research tool for the further development of uniform fragility spectra that can be used for the performance‐based seismic design and retrofit of structures.  相似文献   

Soil erosion processes in subtropical plantations (Diospyros kaki) managed under flood irrigation in Eastern Spain     

Jesús Rodrigo-Comino  Mauro Ponsoda-Carreres  David Salesa  Enric Terol  Yeboah Gyasi-Agyei  Artemi Cerdà 《Singapore journal of tropical geography》2020,41(1):120-135

Persimmons (Diospyros kaki) are trees cultivated under subtropical environmental conditions but are also found in other regions such as the Mediterranean. However, no research has been conducted to investigate soil erosion processes under Mediterranean soil management systems characterized by flood irrigation and/or tillage. The Improved Stock Unearthing Method (ISUM) for assessing long-term soil mobilization was applied to two fields, one under tillage and the other under no-till with herbicide within a 25-year old Mediterranean persimmon plantation. Replicating methods used in vineyard studies, graft unións on persimmon plants were used as passive bio-indicators of soil surface changes in this study. The tilled field showed a total soil mobilization volume of 48.4 m³ on a 408.5 m² plot, representing a total soil loss of 52.6 Mg ha^-1 yr^-1. For the plot (468 m²) managed with no-till and herbicide, the results indicated total soil mobilization of 33.6 m³ which translates to 31.9 Mg ha^-1 yr^-1. It is concluded that flood irrigation is able to modify the runoff pathways and landforms in Mediterranean persimmon plantations, and the flood impact is more extensive when combined with tillage. For the first time, ISUM has been successfully applied to estimate soil erosion in a plantation under flood irrigation.  相似文献   

Organic waste impact of capture-based Atlantic bluefin tuna aquaculture at an exposed site in the Mediterranean Sea     

Luigi Vezzulli  Mariapaola Moreno  Valentina Marin  Elisabetta Pezzati  Marco Bartoli  Mauro Fabiano 《Estuarine, Coastal and Shelf Science》2008

A variety of pelagic and benthic parameters were measured at an aquaculture farm used for the fattening of Atlantic bluefin tuna (Thunnus thynnus) which is located at an exposed site (700 m from the coast, average bottom depth of 45 m and average current speed of 6 cm s⁻¹) in the Mediterranean Sea. The objective was to test whether modern off-shore tuna fattening industries can exert a sustainable organic waste impact on the receiving environment as has been reported for the offshore culture of more traditional Mediterranean species such as sparids. In the water column, the concentration of phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of mesozooplankton (at the species level) were assessed. In the sediment, we assessed the concentration of reduced sulphur pools, phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of meiofauna (at the taxa level) and nematodes (at the genus level). For most parameters, we found no substantial differences between farm and control sites. Deviations of farm values from control values, when they occurred, were small and did not indicate any significant impact on either the pelagic and benthic environment. Deviations were more apparent in the benthic compartment where lower redox potential values, higher bacterial production rates and a change in nematode genus composition pointed out to early changes in the sediment's metabolism. In addition, indigenous potential pathogenic bacteria showed higher concentration at the fish farm stations and were a warning of an undesirable event that may become established following aquaculture practice in oligotrophic environments. The overall data from this study provide extensive experimental evidence to support the sustainability of modern offshore farming technology in minimizing the hypertrophic-dystrophic risks associated with the rapidly-expanding tuna-fattening industry in the Mediterranean Sea.  相似文献