The use of model compounds to investigate the release of covalently bound biomarkers via hydropyrolysis     

Will Meredith  Chen-Gong Sun  Colin E. Snape  Mark. A. Sephton  Gordon D. Love 《Organic Geochemistry》2006,37(12):1705

This study describes the reduction of functionalised model compounds to their corresponding hydrocarbons by catalytic hydropyrolysis to provide information on the release of biomarkers from kerogens and asphaltenes covalently bound through the functional groups investigated. Five model compounds were investigated, the n-C₁₈ carboxylic acids, stearic and oleic acids; the C₂₄ steroidal acid, 5β-cholanic acid; and the saturated and unsaturated C₂₇ sterols, 5α-cholestanol and cholesterol. The yield and distribution of the hydrocarbons generated were assessed for the model compounds adsorbed to silica and carbon substrates, and unsupported on a bed of catalyst. The n-C₁₈ acids are shown to be reduced to the n-C₁₈ alkane, with a selectivity of >95% for stearic acid, although due to its unsaturated structure, oleic acid is prone to cracking, with shorter chained n-alkanes also being formed. The conversion of these compounds, adsorbed to either silica or carbon is relatively low, even at hydropyrolysis temperatures significantly above their boiling point, suggesting that interactions between the acids and substrate leading to the formation of stable entities (Si–O–C linkages in the case of silica) significantly retard volatilisation. The yield can be increased by placing the compounds directly onto a bed of catalyst, but for low boiling compounds such as stearic acid this can result in volatilisation and cracking at temperatures below that of the activation point of the catalyst. This method produced improved yields of >95% pure product for higher boiling compounds such as 5β-cholanic acid. The presence of the functional group attached to the ring system of compounds such as 5α-cholestanol does not diminish the selectivity of the technique. The double bond in cholesterol resulted in more incomplete hydrogenation with sterenes being generated, and in addition to 5α and 5β-cholestane, diasteranes were also generated via migration of the double bond.  相似文献   

Comparison of Water Quality Profiles from Shallow Monitoring Wells and Adjacent Multilevel Samplers     

Meredith J. Metcalf  Gary A. Robbins 《Ground Water Monitoring & Remediation》2007,27(1):84-91

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Lake basin response to tectonic drainage diversion: Eocene Green River Formation, Wyoming   总被引：1，自引：0，他引：1  

Jeffrey T. Pietras  Alan R. Carroll  Meredith K. Rhodes 《Journal of Paleolimnology》2003,30(2):115-125

A previously unidentified major sequence boundary within the Eocene Green River Formation separates fluctuating profundal facies of the Tipton Shale Member from evaporative facies of the Wilkins Peak Member. During deposition of the Tipton Shale Member, rivers entered the basin from the north, across the subdued Wind River Mountains, and deposited the southward prograding deltaic complex of the Farson Sandstone Member. Boulder-rich alluvial fan deposits overlie the Farson Sandstone adjacent to the Continental Fault, and correlate basinward to hypersaline lacustrine deposits of the Wilkins Peak Member. The alluvial fan deposits record a period of reverse motion on the Continental Fault and uplift of the southeastern Wind River Range, which diverted drainage away from the greater Green River Basin. This decreased inflow caused Lake Gosiute to shrink, exposing its bed to desiccation and erosion, and contributed to hydrologically-closed conditions and periodic evaporite deposition thereafter. This study is one of the first to demonstrate a direct relationship between movement along a specific basin-bounding structure, and a change in the overall style of lacustrine sedimentation. The identification of similar relationships elsewhere may challenge conventional interpretations of climate as the dominant factor influencing the character of lake deposits, and provide an important, but previously unexploited, approach to interpreting continental deformation and regional drainage organization.  相似文献   

A laboratory discharge lamp source for the O2 atmospheric bands and OI 5577 Å and 6300 Å lines of a known line width     

R.N. Peterson  L.L. Cogger  H.T. Meredith  G.G. Shepherd 《Planetary and Space Science》1979,27(9):1209-1212

A laboratory discharge lamp is described which strongly emits the forbidden OI 5577 and 6300 Å lines and the O₂ (0?0) atmospheric band. Experimental measurements confirm that these atomic and molecular species are in thermal equilibrium with one another, so that a rotational temperature measurement of the O₂ atmospheric band allows one to deduce the line widths of the 5577 and 6300 Å emissions. This thus provides a useful calibration source for interferometric measurements of these emissions.  相似文献   

Patterns of growth in cold-seep vestimenferans including Seepiophila jonesi: a second species of long-lived tubeworm     

Erik E. Cordes  Derk C. Bergquist  Meredith L. Redding  & Charles R. Fisher 《Marine Ecology》2007,28(1):160-168

Seepiophila jonesi is a vestimentiferan tubeworm (Siboglinidae: Polychaeta) inhabiting the cold seeps of the upper slope of the Gulf of Mexico. It commonly co‐occurs with Lamellibrachia luymesi, which is among the most long‐lived non‐clonal animals known. The growth pattern of S. jonesi is best described by a model including a size‐specific probability of growth and an average growth rate that does not vary with individual size. This model, based on growth data from in situ staining and collection approximately 1 year later, predicts that S. jonesi is very slow growing and may attain ages comparable with L. luymesi. The efficacy of this model in describing L. luymesi growth rate was assessed, but the previously employed model of declining growth rate with individual size provided the better fit to the empirical data. Comparisons of both S. jonesi and L. luymesi growth rates among sites and among aggregations within a site indicate that there is some degree of habitat variability contributing to differences in growth rates. However, position of the anterior end of the worm within an aggregation did not have a significant effect on growth rate in comparisons among groups of L. luymesi from different distances from the center of an aggregation. The evolution of longevity in these species of vestimentiferans was favored by the relative stability of the seep habitat and sulfide sources, in contrast to the hydrothermal vent environment inhabited by relatively short‐lived and fast‐growing vestimentiferan species.  相似文献   

GEOGRAPHICAL NAMES CONFERENCE IN GENEVA     

Meredith F. Burrill 《The Professional geographer》1968,20(1):43-43

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Laboratory measurement of hydrodynamic saline dispersion within a micro-fracture network induced in granite     

Nicholas W.A. Odling  Stephen C. Elphick  Philip Meredith  Ian Main  Bryne T. Ngwenya   《Earth and Planetary Science Letters》2007,260(3-4):407-418

We report the first measurements of hydrodynamic dispersion in a microfractured granite using a combination of novel techniques. A fracture network was induced in a cylindrical plug of Ailsa Craig micro-granite by thermal stressing, to produce an isotropic network of fractures with an average aperture of  0.3 μm, a density of approximately 4 × 10⁴ fractures/mm³ and a permeability of 5.5 × 10^− 17 m². After saturating the cores with 0.01 M NaCl solution a step in the concentration profile to 1 M was advected into the plug at flow rates of 0.07 to 2.13 cm³ h^− 1. The longitudinal electrical impedance of the plug was measured continuously as the solute front advected through its length until the plug was saturated with the concentrated electrolyte. Analysis of the impedance versus time relationships allows the derivation of the longitudinal dispersion coefficient, D_L, and hydrodynamic retardation, R_H. The Peclet number–dispersion relationship for the micro-fracture network is very similar to that predicted for other, radically different, fracture networks. Thus dispersion may be more dependent on fracture connectivity and length than fracture density and display a relationship similar to that shown by particle beds and clastic sandstones. The high retardation values observed (2.2–4.9) reflect flow behaviour within a fracture network with a proportion of ‘blind’ sections, and demonstrates how such networks can slow the advance of conservative solute components.  相似文献   

Application of a modified Griffith criterion to the evolution of fractal damage during compressional rock failure   总被引：4，自引：0，他引：4  

Ian G. Main  Peter R. Sammonds  Philip G. Meredith 《Geophysical Journal International》1993,115(2):367-380

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Drivers of afforestation in Northern Vietnam: Assessing local variations using geographically weighted regression   总被引：2，自引：0，他引：2  

Floriane Clement  Didier Orange  Meredith Williams  Corinne Mulley  Michael Epprecht 《Applied geography (Sevenoaks, England)》2009,29(4):561-576

This article identifies drivers of forest transition in a province of Northern Vietnam between 1993 and 2000 by applying geographically weighted regression (GWR) analysis to remotely sensed and statistical data. The regression model highlighted the spatial variation of the relationship between the percentage of land afforested and its proximate causes. Factors identified as having a major impact on afforestation are: the presence or proximity of a wood-processing industry, the distance to highways, and land allocation to households. Whereas the two former variables are in most areas of the province positively correlated with afforestation, an unexpected negative correlation was observed for the latter. The analysis of these results, supported by an in-depth knowledge of the area and of the political context, leads to the conclusion that, during the time period considered, afforestation was largely driven by state organisations on protected state-owned land, and forestry was not a significant component of household economic activities.  相似文献   

Effects of energy and pitch angle mixed diffusion on radiation belt electrons     

Qiuhua Zheng  Mei-Ching Fok  Jay Albert  Richard B. Horne  Nigel P. Meredith 《Journal of Atmospheric and Solar》2011,73(7-8):785-795

Understanding the dynamics of the Earth’s radiation belts is important for modeling and forecasting the intensities of energetic electrons in space. Wave diffusion processes are known to be responsible for loss and acceleration of electrons in the radiation belts. Several recent studies indicate pitch angle and energy mixed-diffusion are also important when considering the total diffusive effects. In this study, a two-dimensional Fokker Planck equation is solved numerically using the Alternating Direction Implicit method. Mixed diffusion due to whistler-mode chorus waves tends to slow down the total diffusion in the energy-pitch angle space, particularly at smaller equatorial pitch angles. We then incorporate the electron energy and pitch angle mixed diffusions due to whistler-model chorus waves into the 4-dimensional Radiation Belt Environment (RBE) model and study the effect of mixed diffusion during a storm in October 2002. The 4-D simulation results show that energy and pitch angle mixed diffusion decrease the electron fluxes in the outer belt while electron fluxes in the slot region are enhanced (up to a factor of 2) during storm time.  相似文献