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221.
In this work, we consider a new model for flow in a multiporosity shale gas reservoir constructed within the framework of an upscaling procedure where hydraulic fractures are treated as (\(n-1\)) interfaces (\(n=2,3\)). Within this framework, the hydrodynamics is governed by a new pressure equation in the shale matrix which is treated as a homogenized porous medium composed of organic matter (kerogen aggregates with nanopores) and inorganic impermeable solid (clay, calcite, quartz) separated from each other by a network of interparticle pores of micrometer size. The solution of the pressure equation is strongly influenced by the constitutive response of the retardation parameter and effective hydraulic conductivity where the former incorporates gas adsorption/desorption in the nanopores of the kerogen. By focusing our analyses on this nonlinear diffusion equation in the domain occupied by the shale matrix, an optimization strategy seated on the adjoint sensitivity method is developed to minimize a cost functional related to gas production and net present value in a single hydraulic fracture. The gradient of the objective functional computed with the adjoint formulation is explored to update the controlled pressure drop aiming to optimize production in a given window of time. The combination of the direct approach and gradient-based optimization using the adjoint formulation leads to the construction of optimal production scenarios under controlled pressure decline in the well. Numerical simulations illustrate the potential of the methodology proposed herein in optimizing gas production.  相似文献   
222.
223.
Contamination with heavy metals in surface and groundwater is a threat to human health and ecosystems. Due to this, the need arises to remediate water polluted through ecological and profitable technologies, such as phytoremediation. The objective of the work was to evaluate the concentration of lead (Pb) and zinc (Zn) in the floating macrophytes Limnobium laevigatum and Ludwigia peploides, after being exposed to contaminated water experimentally. In this way to be able to determine if these plants have mechanisms that allow them to accumulate the metals in the roots and to perform the translocation of these to different vegetative organs, L. laevigatum and L. peploides were placed in solutions contaminated with Pb ([Pb]?=?5 mg/l) and Zn ([Zn]?=?20 mg/l). The concentrations of metals in water, root and leaf samples were evaluated as a function of time (0, 1, 2 and 4 days). The determination of the metals was performed by the atomic absorption spectrophotometry technique. After 4 days of exposure to Pb and Zn, the plants showed high metal removal efficiencies of water, more to 70% in all cases. Pb was accumulated fundamentally by roots, while Zn was accumulated more in the leaves. In addition, the bioconcentration and translocation factors for each metal were calculated.  相似文献   
224.
CO2 geological storage is a transitional technology for the mitigation of climate change. In the vicinity of potential CO2 reservoirs in Hungary, protected freshwater aquifers used for drinking water supplies exist. Effects of disaster events of CO2 escape and brine displacement to one of these aquifers have been studied by kinetic 1D reactive transport modelling in PHREEQC. Besides verifying that ion concentrations in the freshwater may increase up to drinking water limit values in both scenarios (CO2 or brine leakage), total porosity of the rock is estimated. Pore volume is expected to increase at the entry point of CO2 and to decrease at further distances, whereas it shows minor increase along the flow path for the effect of brine inflow. Additionally, electrical conductivity of water is estimated and suggested to be the best parameter to measure for cost-effective monitoring of both worst-case leakage scenarios.  相似文献   
225.
This study presents both qualitative and quantitative data regarding marine mollusk (gastropods and bivalves) shell bioerosion and encrustation based on death assemblages obtained from a recent supratidal environment in Playa Norte, Veracruz State. The objectives of this study were to assess the nature of bioerosion and encrustation processes and to investigate the role of these taphonomic features contributing to the deterioration of natural shell accumulations within a tropical siliciclastic tidal environment. The assemblage comprises 31 species: 13 gastropods and 18 bivalves. The bioerosion and encrustation degrees were low to moderate for both types. The most abundant traces were predatory gastropod structures (Oichnus paraboloides and O. simplex), whereas sponge borings (Entobia isp.), polychaete dwellings (Caulostrepsis taeniola), and echinoid raspings (Gnatichnus isp.) were less frequent. The encrusting organisms include polychaete serpulids, bryozoans, and rare foraminifers (Homotrema rubrum). Because of the low bioerosion and encrustation degrees occurring in this area, accumulation is expected to predominate over biotic destruction. As deposition conditions (richly fossiliferous carbonate sandstone beds) were similar to those prevailing in the Tuxpan Formation during the Miocene (Langhian), it is suggested that this study provides an equivalent reference to interpret mollusk fossil assemblages located in this site.  相似文献   
226.
In the paper, a novel inversion approach is used for the solution of the problem of factor analysis. The float-encoded genetic algorithm as a global optimization method is implemented to extract factor variables using open-hole logging data. The suggested statistical workflow is used to give a reliable estimate for not only the factors but also the related petrophysical properties in hydrocarbon formations. In the first step, the factor loadings and scores are estimated by Jöreskog’s fast approximate method, which are gradually improved by the genetic algorithm. The forward problem is solved to calculate wireline logs directly from the factor scores. In each generation, the observed and calculated well logs are compared to update the factor population. During the genetic algorithm run, the average fitness of factor populations is maximized to give the best fit between the observed and theoretical data. By using the empirical relation between the first factor and formation shaliness, the shale volume is estimated along the borehole. Permeability as a derived quantity also correlates with the first factor, which allows its determination from an independent source. The estimation results agree well with those of independent deterministic modeling and core measurements. Case studies from Hungary and the USA demonstrate the feasibility of the global optimization based factor analysis, which provides a useful tool for improved reservoir characterization.  相似文献   
227.
Multiphase solid inclusions in minerals formed at ultra-high-pressure (UHP) provide evidence for the presence of fluids during deep subduction. This study focuses on barian mica, which is a common phase in multiphase solid inclusions enclosed in garnet from mantle-derived UHP garnet peridotites in the Saxothuringian basement of the northern Bohemian Massif. The documented compositional variability and substitution trends provide constraints on crystallization medium of the barian mica and allow making inferences on its source. Barian mica in the multiphase solid inclusions belongs to trioctahedral micas and represents a solid solution of phlogopite KMg3(Si3Al)O10(OH)2, kinoshitalite BaMg3(Al2Si2)O10(OH)2 and ferrokinoshitalite BaFe3(Al2Si2)O10(OH)2. In addition to Ba (0.24–0.67 apfu), mica is significantly enriched in Mg (XMg ~ 0.85 to 0.95), Cr (0.03–0.43 apfu) and Cl (0.04–0.34 apfu). The substitution vector involving Ba in the I-site which describes the observed chemical variability can be expressed as BaFeIVAlClK?1Mg?1Si?1(OH)?1. A minor amount of Cr and VIAl enters octahedral sites following a substitution vector VI(Cr,Al)2VI(Mg,Fe)?3 towards chromphyllite and muscovite. As demonstrated by variable Ba and Cl contents positively correlating with Fe, barian mica composition is partly controlled by its crystal structure. Textural evidence shows that barian mica, together with other minerals in multiphase solid inclusions, crystallized from fluids trapped during garnet growth. The unusual chemical composition of mica reflects the mixing of two distinct sources: (1) an internal source, i.e. the host peridotite and its garnet, providing Mg, Fe, Al, Cr, and (2) an external source, represented by crustal-derived subduction-zone fluids supplying Ba, K and Cl. At UHP–UHT conditions recorded by the associated diamond-bearing metasediments (c. 1100 °C and 4.5 GPa) located above the second critical point in the pelitic system, the produced subduction-zone fluids transporting the elements into the overlying mantle wedge had a solute-rich composition with properties of a hydrous melt. The occurrence of barian mica with a specific chemistry in barium-poor mantle rocks demonstrates the importance of its thorough chemical characterization.  相似文献   
228.
Sánchez  Y.  Martínez-Graña  A.  Santos-Francés  F.  Yenes  M. 《Natural Hazards》2018,90(3):1407-1426
The random forest method was used to generate susceptibility maps for debris flows, rock slides, and active layer detachment slides in the Donjek River area within the Yukon Alaska Highway Corridor, based on an inventory of landslides compiled by the Geological Survey of Canada in collaboration with the Yukon Geological Survey. The aim of this study is to develop data-driven landslide susceptibility models which can provide information on risk assessment to existing and planned infrastructure. The factors contributing to slope failure used in the models include slope angle, slope aspect, plan and profile curvatures, bedrock geology, surficial geology, proximity to faults, permafrost distribution, vegetation distribution, wetness index, and proximity to drainage system. A total of 83 debris flow deposits, 181 active layer detachment slides, and 104 rock slides were compiled in the landslide inventory. The samples representing the landslide free zones were randomly selected. The ratio of landslide/landslide free zones was set to 1:1 and 1:2 to examine the results of different sample ratios on the classification. Two-thirds of the samples for each landslide type were used in the classification, and the remaining 1/3 were used to evaluate the results. In addition to the classification maps, probability maps were also created, which served as the susceptibility maps for debris flows, rock slides, and active layer detachment slides. Success and prediction rate curves created to evaluate the performance of the resulting models indicate a high performance of the random forest in landslide susceptibility modelling.  相似文献   
229.
The calibration errors on experimental slant total electron content (TEC) determined with global positioning system (GPS) observations is revisited. Instead of the analysis of the calibration errors on the carrier phase leveled to code ionospheric observable, we focus on the accuracy analysis of the undifferenced ambiguity-fixed carrier phase ionospheric observable determined from a global distribution of permanent receivers. The results achieved are: (1) using data from an entire month within the last solar cycle maximum, the undifferenced ambiguity-fixed carrier phase ionospheric observable is found to be over one order of magnitude more accurate than the carrier phase leveled to code ionospheric observable and the raw code ionospheric observable. The observation error of the undifferenced ambiguity-fixed carrier phase ionospheric observable ranges from 0.05 to 0.11 total electron content unit (TECU) while that of the carrier phase leveled to code and the raw code ionospheric observable is from 0.65 to 1.65 and 3.14 to 7.48 TECU, respectively. (2) The time-varying receiver differential code bias (DCB), which presents clear day boundary discontinuity and intra-day variability pattern, contributes the most part of the observation error. This contribution is assessed by the short-term stability of the between-receiver DCB, which ranges from 0.06 to 0.17 TECU in a single day. (3) The remaining part of the observation errors presents a sidereal time cycle pattern, indicating the effects of the multipath. Further, the magnitude of the remaining part implies that the code multipath effects are much reduced. (4) The intra-day variation of the between-receiver DCB of the collocated stations suggests that estimating DCBs as a daily constant can have a mis-modeling error of at least several tenths of 1 TECU.  相似文献   
230.
This study aims to quantify the landscape spatio-temporal dynamics including Land Use/Land Cover (LULC) changes occurred in a typical Mediterranean ecosystem of high ecological and cultural significance in central Greece covering a period of 9 years (2001–2009). Herein, we examined the synergistic operation among Hyperion hyperspectral satellite imagery with Support Vector Machines, the FRAGSTATS® landscape spatial analysis programme and Principal Component Analysis (PCA) for this purpose. The change analysis showed that notable changes reported in the experimental region during the studied period, particularly for certain LULC classes. The analysis of accuracy indices suggested that all the three classification techniques are performing satisfactorily with overall accuracy of 86.62, 91.67 and 89.26% in years 2001, 2004 and 2009, respectively. Results evidenced the requirement for taking measures to conserve this forest-dominated natural ecosystem from human-induced pressures and/or natural hazards occurred in the area. To our knowledge, this is the first study of its kind, demonstrating the Hyperion capability in quantifying LULC changes with landscape metrics using FRAGSTATS® programme and PCA for understanding the land surface fragmentation characteristics and their changes. The suggested approach is robust and flexible enough to be expanded further to other regions. Findings of this research can be of special importance in the context of the launch of spaceborne hyperspectral sensors that are already planned to be placed in orbit as the NASA’s HyspIRI sensor and EnMAP.  相似文献   
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