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81.
82.
Remediating Ground Water with Zero-Valent Metals: Chemical Considerations in Barrier Design 总被引:2,自引:0,他引:2
Paul G. Tratnyek Timothy L. Johnson Michelle M. Scherer Gerald R. Eykholt 《Ground Water Monitoring & Remediation》1997,17(4):108-114
To gain perspective and insight into the performance of permeable reactive barriers containing granular iron metal, it is useful to compare the degradation kinetics of individual chlorinated solvents over a range of operating conditions. Pseudo first-order disappearance rate constants normalized to iron surface area concentration (kSA ) recently have been reported for this purpose. This paper presents the results of further exploratory data analysis showing the extent to which variation in kSA is due to initial halocarbon concentration, iron type, and other factors. To aid in preliminary design calculations, representative values of kSA and a reactive transport model have been used to calculate the minimum barrier width needed for different ground water flow velocities and degrees of halocarbon conversion. Complete dechlorination of all degradation intermediates requires a wider treatment zone, but the effect is not simply additive because degradation occurs by sequential and parallel reaction pathways. 相似文献
83.
Summary The origin of upper tropospheric cyclonic vortices over the South Atlantic and adjoining Brazil is discussed. Calculations of the barotropic energy exchange term based on observations indicated that in the mean, and during some days, zonal kinetic energy gets converted into eddy kinetic energy. This suggests the occurrence of barotropic instability. Examination of zonal winds for barotropic instability, however, revealed weak growth rates. Thus other mechanisms such as condensation heating, the formation of cyclonic centers downstream of the Bolivian high, and middle latitude coupling might also be important.With 3 Figures 相似文献
84.
We report specifically on a quantum electrodynamic feature of the one-photon-pair annihilation. Most of the calculation related with this process (not excluding other ones) have been carried out usually utilizing the wave functions obtained from the Dirac equation in the Landau gauge A = (0,Bx, 0), where B is oriented along the z-axis (Johnson and Lippman, 1949). Although, the eigenstates of the Dirac Hamiltonian as it was introduced by Johnson and Lippman, do not consider the coupling to the radiation field and consequently they reflect only forp
z
= 0 the same linear combination of the two degenerate polarization states.We report the transition rate function for the one-photon-pair annihilation in a strong magnetic field by using the Sokolov and Ternov eigenstate |± as far asp
z
= 0 andN > 0 is concerned. The difference between the expression for the transition rate by using the Sokolov and Ternov eigenstates and the one calculated by (Wunneret al., 1986), is just the functionI
s,s
which corresponds to the degeneracy of the orbit center of the electrons characterized by the quantum numberss ands.
Presented at the 2nd UN/ESA Workshop, held in Bogotá, Colombia, 9-13 November, 1992. 相似文献
85.
A new solution for the planetary perturbations of the Moon is being built in the frame of ELP 2000, using Bretagnon's planetary theories, and achieved at the first order. It contains the two actions commonly distinguished: direct and indirect. The internal precision of computation is 2×10–6 arcsec. First-order planetary perturbations, in the direct case (Venus & Mars), have been compared to Standaert's solution. The major discrepancy reaches 70 cm in the longitude of Venus. Perturbations of the second order with respect to planetary masses, have been undertaken and illustrations are given. Finally, new values for the perigee and node motions are proposed.Proceedings of the Conference on Analytical Methods and Ephemerides: Theory and Observations of the Moon and Planets. Facultés universitaires Notre Dame de la Paix, Namur, Belgium, 28–31 July, 1980. 相似文献
86.
V. B. Rao M. B. Rosa J. P. Bonatti S. H. Franchito 《Meteorology and Atmospheric Physics》2003,83(1-2):35-49
Summary. Using 9 years (1985–1993) data, final stratospheric warmings in the Southern Hemisphere are studied. Interannual variations
in the onset date and the temperatures are noted. In 1985 the stratosphere was colder by about 5 K and the wave activity was
less. This year the final warming got delayed. In contrast in 1988 the final warming occurred earlier when compared with the
mean picture and the wave activity was more. An examination of Eliassen-Palm fluxes showed the important role of planetary
waves in the wave-mean flow interaction. In the energetics the most spectacular change is the reduction of zonal kinetic energy.
Before the warming the energy exchanges were Pz → Pe → Ke → Kz ← Pz and after the warming they were Pz ← Pe ← Ke → Kz ← Pz. The dramatic reduction of zonal kinetic energy seems to be due to two effects: the reduction in Ke → Kz conversion and the weakening of direct meridional circulation.
Received October 3, 2001; revised June 5, 2002 相似文献
87.
J. A. Marengo I. F. A. Cavalcanti P. Satyamurty I. Trosnikov C. A. Nobre J. P. Bonatti H. Camargo G. Sampaio M. B. Sanches A. O. Manzi C. A. C. Castro C. D'Almeida L. P. Pezzi L. Candido 《Climate Dynamics》2003,21(5-6):459-475
This is a study of the annual and interannual variability of regional rainfall produced by the Center for Weather Forecasts and Climate Studies/Center for Ocean, Land and Atmospheric Studies (CPTEC/COLA) atmospheric global climate model. An evaluation is made of a 9-member ensemble run of the model forced by observed global sea surface temperature (SST) anomalies for the 10-year period 1982–1991. The Brier skill score and, Relative Operating Characteristics (ROC) are used to assess the predictability of rainfall and to validate rainfall simulations, in several regions world wide. In general, the annual cycle of precipitation is well simulated by the model for several continental and oceanic regions in the tropics and mid latitudes. Interannual variability of rainfall during the peak rainy season is realistically simulated in Northeast Brazil, Amazonia, central Chile, and southern Argentina–Uruguay, Eastern Africa, and tropical Pacific regions, where the model shows good skill. Some regions, such as northwest Peru–Ecuador, and southern Brazil exhibit a realistic simulation of rainfall anomalies associated with extreme El Niño warming conditions, while in years with neutral or La Niña conditions, the agreement between observed and simulated rainfall anomalies is not always present. In the monsoon regions of the world and in southern Africa, even though the model reproduces the annual cycle of rainfall, the skill of the model is low for the simulation of the interannual variability. This is indicative of mechanisms other than the external SST forcing, such as the effect of land–surface moisture and snow feedbacks or the representation of sub-grid scale processes, indicating the important role of factors other than external boundary forcing. The model captures the well-known signatures of rainfall anomalies of El Niño in 1982–83 and 1986–87, indicating its sensitivity to strong external forcing. In normal years, internal climate variability can affect the predictability of climate in some regions, especially in monsoon areas of the world. 相似文献
88.
Maria Eugenia Varela Michelle Bonnin- Mosbah Jean Paul Gallien 《Geochimica et cosmochimica acta》2003,67(6):1255-1265
Measured were the abundance and distribution of nitrogen in glasses of glass inclusions in olivines of CV3, CO3, CR, C4, CH3, and LL chondritic meteorites by means of the 14N(d, p)15N nuclear reaction. Similar to what was observed with carbon, nitrogen is present in low concentrations (<20 ppm) in the structure of olivines but can by stored in variable amounts in glasses of glass inclusions. These primitive glasses, characterized by a Si-Al-Ca-rich composition, have highly variable nitrogen contents (30 to 1500 ppm) and highly inhomogeneous nitrogen distribution. Nitrogen contents are independent of the chemical composition of the glasses. The heterogeneous distribution is a common feature of all studied inclusions, as is evidenced by the variable contents of nitrogen in glass inclusions occurring in the same olivine grain. Nitrogen heterogeneity is suggestive of trapping of solid nitrogen carrier phases during formation of the constituents of chondrules. However, part of the originally trapped nitrogen appears to have been lost, possibly, by ulterior oxidation and subsequent transformation into volatile species. 相似文献
89.
Craig E. Divine Tracy Roth Michelle Crimi Abrahm C. DiMarco Matt Spurlin Jeff Gillow Gastón Leone 《Ground Water Monitoring & Remediation》2018,38(1):56-65
A new in‐situ remediation concept termed a Horizontal Reactive Media Treatment Well (HRX Well®) is presented that utilizes horizontal wells filled with reactive media to passively treat contaminated groundwater in‐situ. The approach involves the use of large‐diameter directionally drilled horizontal wells filled with granular reactive media generally installed parallel to the direction of groundwater flow. The design leverages natural “flow‐focusing” behavior induced by the high in‐well hydraulic conductivity of the reactive media relative to the aquifer hydraulic conductivity to passively capture and treat proportionally large volumes of groundwater within the well. Clean groundwater then exits the horizontal well along its downgradient sections. Many different types of solid granular reactive media are already available (e.g., zero valent iron, activated carbon, ion exchange resins, zeolite, apatite, chitin); therefore, this concept could be used to address a wide range of contaminants. Three‐dimensional flow and transport simulations were completed to assess the general hydraulic performance, capture zones, residence times, effects of aquifer heterogeneity, and treatment effectiveness of the concept. The results demonstrate that capture and treatment widths of up to tens of feet can be achieved for many aquifer settings, and that reductions in downgradient concentrations and contaminant mass flux are nearly immediate. For a representative example, the predicted treatment zone width for the HRX Well is approximately 27 to 44 feet, and contaminant concentrations immediately downgradient of the HRX Well decreased an order of magnitude within 10 days. A series of laboratory‐scale physical tests (i.e., tank tests) were completed that further demonstrate the concept and confirm model prediction performance. For example, the breakthrough time, peak concentration and total mass recovery of methylene blue (reactive tracer) was about 2, 35, and 20 times (respectively) less than chloride (conservative tracer) at the outlet of the tank‐scale HRX Well. 相似文献
90.
Predominant period and equivalent viscous damping ratio identification for a full‐scale building shake table test
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Michelle C. Chen Rodrigo Astroza José I. Restrepo Joel P. Conte Tara Hutchinson Yehuda Bock 《地震工程与结构动力学》2017,46(14):2459-2477
The predominant period and corresponding equivalent viscous damping ratio, also known in various loading codes as effective period and effective damping coefficient, are two important parameters employed in the seismic design of base‐isolated and conventional building structures. Accurate determination of these two parameters can reduce the uncertainty in the computation of lateral displacement demands and interstory drifts for a given seismic design spectrum. This paper estimates these two parameters from data sets recorded from a full‐scale five‐story reinforced concrete building subjected to seismic base excitations of various intensities in base‐isolated and fixed‐base configurations on the outdoor shake table at the University of California, San Diego. The scope of this paper includes all test motions in which the yielding of the reinforcement has not occurred and the response can still be considered ‘elastic’. The data sets are used with three system identification methods to determine the predominant period of response for each of the test configurations. One of the methods also determines the equivalent viscous damping ratio corresponding to the predominant period. It was found that the predominant period of the fixed‐base building lengthened from 0.52 to 1.30 s. This corresponded to a significant reduction in effective system stiffness to about 16% of the original stiffness. The paper then establishes a correlation between predominant period and peak ground velocity. Finally, the predominant periods and equivalent viscous damping ratios recommended by the ASCE 7‐10 loading standard are compared with those determined from the test building. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献