Melt extraction pathways and stagnation depths beneath the Madeira and Desertas rift zones (NE Atlantic) inferred from barometric studies     

Stefanie?SchwarzEmail author  Andreas?Klügel  Cora?Wohlgemuth-Ueberwasser 《Contributions to Mineralogy and Petrology》2004,147(2):228-240

The Madeira and Desertas Islands (eastern North Atlantic) show well-developed rift zones which intersect near the eastern tip of Madeira (São Lourenço peninsula). We applied fluid inclusion barometry and clinopyroxene-melt thermobarometry to reconstruct levels of magma stagnation beneath the two adjacent rifts and to examine a possible genetic relationship during their evolution. Densities of CO₂-dominated fluid inclusions in basanitic to basaltic samples from São Lourenço yielded frequency maxima at pressures of 0.57–0.87 GPa (23–29 km depth) and 0.25–0.32 GPa (8–10 km), whereas basanites, basalts and xenoliths from the Desertas indicate 0.3–0.72 GPa (10–24 km) and 0.07–0.12 GPa (2–3 km). Clinopyroxene-melt thermobarometry applied to Ti-augite phenocryst rim and glass/groundmass compositions indicates pressures of 0.45–1.06 GPa (15–35 km; São Lourenço) and 0.53–0.89 GPa (17–28 km; Desertas Islands) which partly overlap with pressures indicated by fluid inclusions. We interpret our data to suggest a multi-stage magma ascent beneath the Madeira Archipelago: main fractionation occurs at multiple levels within the mantle (>15 km depth) and is followed by temporary stagnation within the crust prior to eruption. Depths of crustal magma stagnation beneath São Lourenço and the Desertas differ significantly, and there is no evidence for a common shallow magma reservoir feeding both rift arms. We discuss two models to explain the relations between the two adjacent rift systems: Madeira and the Desertas may represent either a two-armed rift system or two volcanic centres with separate magma supply systems. For petrological and volcanological reasons, we favour the second model and suggest that Madeira and the Desertas root in distinct regions of melt extraction. Magma focusing into the Desertas system off the hotspot axis may result from lithospheric bending caused by the load of the Madeira and Porto Santo shields, combined with regional variations in melt production due to an irregularly shaped plume.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: J. Hoefs  相似文献   

Dynamics of magma mixing and degassing recorded in plagioclase at Stromboli (Aeolian Archipelago,Italy)   总被引：12，自引：0，他引：12  

Patrizia?LandiEmail author  Nicole?Métrich  Antonella?Bertagnini  Mauro?Rosi 《Contributions to Mineralogy and Petrology》2004,147(2):213-227

Crystal-rich materials (scoriae and lava flows) emitted during the 1985–2000 activity of Stromboli were taken into consideration for systematic study of bulk rock/matrix glass chemistry and in particular for the study of chemical and textural zoning of plagioclase, the most abundant mineral phase. Over the considered time period, bulk rock composition remained fairly constant in both major (SiO₂ 49.2–50.9 wt% and K₂O 1.96–2.18 wt%) and trace elements. The quite constant chemistry of matrix glasses also indicates that the degree of crystallization of magma was maintained at around 50 vol%. Plagioclase ranges in composition between An₆₂ and An₈₈ and is characterized by alternating, <10–100 m thick, bytownitic and labradoritic concentric layers, although the dominant and representative plagioclase of scoriae is An_68. The labradoritic layers (An_62–70) show small-scale (1–5 µm), oscillatory zoning, are free of inclusions, and appear to record episodes of slow crystal growth in equilibrium with a degassed liquid having the composition of the matrix glass. In contrast the bytownitic layers (An₇₀-An₈₈) are patchy zoned, show sieve structure with abundant micrometric glass inclusions and voids, and are attributed to rapid crystal growth.A key to understanding the origin of bytownitic layers can be retrieved from the texture and composition of the coronas of plagioclase xenocrysts, inherited from crystal-rich magma, in nearly aphyric pumice which are erupted during more energetic events and represent a deep, volatile-rich, HK-basaltic magma. They show a continuum from fine-sieve to evident skeletal texture from the inner to the outer part of the corona associated with normal compositional zoning from An₉₀ to An₇₅. In the light of these observations, we propose that input of H₂O-rich melt blobs, and their mixing with the residing magma, causes partial dissolution of the labradoritic layers followed by the growth of bytownitic composition whose sieve texture attests of rapid crystallization occurring under undercooling conditions mainly induced by degassing. As a whole, the zoning of plagioclase in the scoriae records successive and discrete intrusions of volatile-rich magma blobs, its degassing and mixing with the resident degassed magma at shallow level.Editorial responsibility: T.L. GroveAn erratum to this article can be found at  相似文献   

Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane     

Shyh-Lung?HwangEmail author  Pouyan?Shen  Hao-Tsu?Chu  Tzen-Fu?Yui  Juhn?G.?Liou  Nikolay?V.?Sobolev  Ru-Yuan?Zhang  Vladislav?S.?Shatsky  Anton?A.?Zayachkovsky 《Contributions to Mineralogy and Petrology》2004,148(3):380-389

Kokchetavite, a new polymorph of K-feldspar (KAlSi₃O₈), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 ų, Z=1, and is found to be associated with phengite + /-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar.  相似文献   

Oxidized sulfur-rich mafic magma at Mount Pinatubo,Philippines   总被引：3，自引：2，他引：1  

J.?C.?M.?de?HoogEmail author  K.?H.?Hattori  R.?P.?Hoblitt 《Contributions to Mineralogy and Petrology》2004,146(6):750-761

Basaltic fragments enclosed in andesitic dome lavas and pyroclastic flows erupted during the early stages of the 1991 eruption of Mount Pinatubo, Philippines, contain amphiboles that crystallized during the injection of mafic magma into a dacitic magma body. The amphiboles contain abundant melt inclusions, which recorded the mixing of andesitic melt in the mafic magma and rhyolitic melt in the dacitic magma. The least evolved melt inclusions have high sulfur contents (up to 1,700 ppm) mostly as SO₄ ^2–, which suggests an oxidized state of the magma (NNO+1.4). The intrinsically oxidized nature of the mafic magma is confirmed by spinel–olivine oxygen barometry. The value is comparable to that of the dacitic magma (NNO+1.6). Hence, models invoking mixing as a means of releasing sulfur from the melt are not applicable to Pinatubo. Instead, the oxidized state of the dacitic magma likely reflects that of parental mafic magma and the source region in the sub-arc mantle. Our results fit a model in which long-lived SO₂ discharge from underplated mafic magma accumulated in the overlying dacitic magma and immiscible aqueous fluids. The fluids were the most likely source of sulfur that was released into the atmosphere during the cataclysmic eruption. The concurrence of highly oxidized basaltic magma and disproportionate sulfur output during the 1991 Mt. Pinatubo eruption suggests that oxidized mafic melt is an efficient medium for transferring sulfur from the mantle to shallow crustal levels and the atmosphere. As it can carry large amounts of sulfur, effectively scavenge sulfides from the source mantle and discharge SO₂ during ascent, oxidized mafic magma forms arc volcanoes with high sulfur fluxes, and potentially contributes to the formation of metallic sulfide deposits.Editorial responsibility: J. Hoefs

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J. C. M. de HoogEmail:

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Polycrystalline calcite to aragonite transformation kinetics: experiments in synthetic systems     

Shueh-Jung?Lin  Wuu-Liang?HuangEmail author 《Contributions to Mineralogy and Petrology》2004,147(5):604-614

The kinetics of the calcite to aragonite transformation have been investigated using synthetic polycrystalline calcite aggregates, with and without additional minerals present. The reaction progresses as a function of time were measured at four temperature/pressure conditions: (1) 550 °C/1.86 GPa; (2) 600 °C/2.11 GPa; (3) 650 °C/2.11 GPa, and (4) 700 °C/2.29 GPa. Experiments reveal that Mg-calcite and Fe-calcite transforms to aragonite at considerably slower rates than pure calcite, and that Sr-bearing calcite and calcite + quartz aggregates transform at significantly higher rates than pure calcite. The reaction progresses vs. time data for pure calcite were fitted to Cahns grain-boundary nucleation and interface-controlled growth model. Evidence for interface-controlled growth is provided by petrographic observations of grain boundaries. The activation energy for aragonite growth from the synthetic polycrystalline calcite determined in this study is significantly lower than that previously determined from a natural marble. The discrepancy in rates and activation energy may be attributed to the nature of grain boundaries, to deformational strain or the presence of impurities in the studied samples, and likely to uncertainties in experimental conditions. The results of this study imply that the variation of local petrologic conditions, in addition to temperature, pressure and grain size, may play an important role in determining the rates for the calcite to aragonite transformation in nature.Editorial responsibility: W. Schreyer  相似文献   

U–Pb and Hf-isotope analysis of zircons in mafic xenoliths from Fuxian kimberlites: evolution of the lower crust beneath the North China craton     

Jianping?Zheng  W.?L.?GriffinEmail author  Suzanne?Y.?O’Reilly  Fengxiang?Lu  Chunmei?Yu  Ming?Zhang  Huimin?Li 《Contributions to Mineralogy and Petrology》2004,148(1):79-103

Mafic xenoliths from the Paleozoic Fuxian kimberlites in the North China craton include garnet granulite, and minor pyroxene amphibolite, metagabbro, anorthosite and pyroxenite. The formation conditions of the amphibolites are estimated at 745–820 °C and 7.6–8.8 Kb (25–30 km); the granulites probably are derived from greater depths in the lower crust. LAM-ICPMS U–Pb dating of zircons from four granulites reveals multiple age populations, recording episodes of magmatic intrusion and metamorphic recrystallisation. Concordant ages and upper intercept ages, interpreted as minimum estimates for the time of magmatic crystallisation, range from 2,620 to 2,430 Ma in three granulites, two amphibolites and two metagabbros. Lower intercept ages, represented by near-concordant zircons, are interpreted as reflecting metamorphic recrystallisation, and range from 1,927 to 1,852 Ma. One granulite contains two metamorphic zircon populations, dated at 1,927±55 Ma and 600–700 Ma. Separated minerals from one granulite and one amphibolite yield Sm–Nd isochron ages of 1,619±48 Ma (¹⁴³Nd/¹⁴⁴Nd)i=0.51078), and 1,716±120 Ma (¹⁴³Nd/¹⁴⁴Nd)i=0.51006), respectively. These ages are interpreted as recording cooling following metamorphic resetting; model ages for both samples are in the range 2.40–2.66 Ga. LAM-MC-ICPMS analyses of zircon show a range in ¹⁷⁶Hf/¹⁷⁷Hf from 0.28116 to 0.28214, corresponding to a range of _Hf from –34 to +12. The relationships between ²⁰⁷Pb/²⁰⁶Pb age and _Hf show that: (1) the granulites, amphibolites and metagabbro were derived from a depleted mantle source at 2.6–2.75 Ga; (2) zircons in most samples underwent recrystallisation and Pb loss for 100–200 Ma after magmatic crystallisation, consistent with a residence in the lower crust; (3) metamorphic zircons in several samples represent new zircon growth, incorporating Hf liberated from breakdown of silicates with high Lu/Hf; (4) in other samples metamorphic and magmatic zircons have identical ¹⁷⁶Hf/¹⁷⁷Hf, and the younger ages reflect complete resetting of U–Pb systems in older zircons. The Fuxian mafic xenoliths are interpreted as the products of basaltic underplating, derived from a depleted mantle source in Neoarchean time, an important period of continental growth in the North China craton. Paleoproterozoic metamorphic ages indicate an important tectonic thermal event in the lower crust at 1.8–1.9 Ga, corresponding to the timing of collision between the Eastern and Western Blocks that led to the final assembly of the North China craton. The growth of metamorphic zircon at 600–700 Ma may record an asthenospheric upwelling in Neoproterozoic time, related to uplift and a regional disconformity in the North China craton.  相似文献   

Metasomatism and melting history of a Variscan lithospheric mantle domain: evidence from the Puy Beaunit xenoliths (French Massif Central)     

Olivier?FéméniasEmail author  Nicolas?Coussaert  Julien?Berger  Jean-Claude?C.?Mercier  Daniel?Demaiffe 《Contributions to Mineralogy and Petrology》2004,148(1):13-28

Mantle xenoliths from Puy Beaunit (French Massif Central) are compositionally varied, ranging from relatively fertile spinel lherzolites to refractory spinel dunites. Fertile peridotites have registered a modal (amphibole-bearing lherzolites) and cryptic metasomatic event that took place before the last Permian (257 Ma) melting episode. Depletion processes have been constrained by chemical modelling: the depletion is related to different degrees of partial melting, but two major melt extraction episodes are needed to explain the range of major element composition. The second event was responsible for the local large-scale dunitification of former residues. The first melting event (F25%) and metasomatic enrichment are attributed to an ancient fluid and/or liquid infiltration that could be related to a pre-Variscan regional subduction (located to the north of the Beaunit area). Texture acquisition and major deformation of the mantle xenoliths were sub-contemporaneous of the subduction and would result from lithospheric delamination. The second melting event (F17%) produced high-Mg basalts with calc-alkaline trace element signature that gave rise to the Permian underplating episode recognised in western Europe.  相似文献   

Intra-oceanic production of continental crust in a Th-depleted ca. 3.0 Ga arc complex,western Superior Province,Canada     

Joseph?B.?WhalenEmail author  John?A.?Percival  Vicki?J.?McNicoll  Frederick?J.?Longstaffe 《Contributions to Mineralogy and Petrology》2004,146(5):654-655

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Geological and SHRIMP II U-Pb constraints on the age and origin of the Breves Cu-Au-(W-Bi-Sn) deposit,Carajás,Brazil     

Fernando?Henrique?Bucco?TallaricoEmail author  Neal?Jesse?McNaughton  David?Ian?Groves  Ian?R.?Fletcher  Bernardino?Ribeiro?Figueiredo  Jéssica?Beatriz?Carvalho  José?Luzimar?Rego  Alfredo?Rossetto?Nunes 《Mineralium Deposita》2004,39(1):68-86

The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives ²⁰⁷Pb/²⁰⁶Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined ²⁰⁷Pb/²⁰⁶Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin  相似文献   

Noril’sk–Talnakh Cu–Ni–PGE deposits: a revised tectonic model     

Alexander?YakubchukEmail author  Anatoly?Nikishin 《Mineralium Deposita》2004,39(2):125-142

The Norilsk mining district is located at the northwest margin of the Tunguska basin, in the centre of the 3,000×4,000 km Siberian continental flood basalt (CFB) province. This CFB province was formed at the Permo-Triassic boundary from a superplume that ascended into the geometric centre of the Laurasian continent, which was surrounded by subducting slabs of oceanic crust. We suggest that these slabs could have reached the core–mantle boundary, and they may have controlled the geometric focus of the superplume. The resulting voluminous magma intruded and erupted in continental rifts and related extensive flood basalt events over a 2–4 Ma period. Cu–Ni–PGE sulfide mineralization is found in olivine-bearing differentiated mafic intrusions beneath the flood basalts at the northwestern margin of the Siberian craton and also in the Taimyr Peninsula, some 300 km east of a triple junction of continental rifts, now buried beneath the Mesozoic–Cenozoic sedimentary basin of western Siberia. The Norilsk-I and Talnakh-Oktyabrsky deposits occur in the Norilsk–Kharaelakh trough of the Tunguska CFB basin. The Cu–Ni–PGE-bearing mineralized intrusions are 2–3 km-wide and 20 km-long differentiated chonoliths. Previous studies suggested that parts of the magma remained in intermediate-level crustal chambers where sulfide saturation and accumulation took place before emplacement. The 5–7-km-thick Neoproterozoic to Palaeozoic country rocks, containing sedimentary Cu mineralization and evaporites, may have contributed additional metal and sulfur to this magma. Classic tectonomagmatic models for these deposits proposed that subvertical crustal faults, such as the northeast-trending Norilsk–Kharaelakh fault, were major trough-parallel conduits providing access for magmas to the final chambers. However, geological maps of the Norilsk region show that the Norilsk–Kharaelakh fault offsets the mineralization, which was deformed into folds and offset by related reverse faults, indicating compressional deformation after mineralization in the Late Triassic to Early Jurassic. In addition, most of the intrusions are sills, not dykes as should be expected if the vertical faults were major conduits. A revised tectonic model for the Norilsk region takes into account the fold structure and sill morphology of the dominant intrusions, indicating a lateral rather than vertical emplacement direction for the magma into final chambers. Taking into account the fold structure of the country rocks, the present distribution of the differentiated intrusions hosting the Norilsk-I and Talnakh–Oktyabrsky deposits may represent the remnants of a single, >60 km long, deformed and eroded palm-shaped cluster of mineralized intrusions, which are perceived as separate intrusions at the present erosional level. The original direction of sill emplacement may have been controlled by a northeast-trending paleo-rise, which we suggest is present at the southeastern border of the Norilsk–Kharaelakh trough based on analysis of the unconformity at the base of the CFB. The mineralized intrusions extend along this rise, which we interpret as a structure that formed above the extensionally tilted block in the metamorphic basement. Geophysical data indicate the presence of an intermediate magma chamber that could be linked with the Talnakh intrusion. In turn, this T-shaped flat chamber may link with the Yenisei–Khatanga rift along the northwest-trending Pyasina transform fault, which may have served as the principal magma conduit to the intermediate chamber. It then produced the differentiated mineralized intrusions that melted through the evaporites with in situ precipitation of massive, disseminated, and copper sulfide ore. The Norilsk–Kharaelakh crustal fault may not relate to mineralization and possibly formed in response to late Mesozoic spreading in the Arctic Ocean.Editorial handling: P. Lightfoot  相似文献