Ba同位素揭示上地幔中广泛存在再循环的沉积物     

Sune G.Nielsen  Tristan J.Horner  Helena V.Pryer  Jerzy Blusztajn  Yunchao Shu  Mark D.Kurz  Veronique Le Roux 《矿物岩石地球化学通报》2018,(4)

正Ba同位素由于具有在低温环境中分馏的特性,相比放射性同位素与微量元素,可以更好地示踪地球深部动力学过程中的再循环物质。研究表明沉积物与蚀变洋壳具有明显不同的Ba同位素组成(沉积物富集来自重晶石的Ba),使得Ba同位素成为研究表层与地幔储库间物质交换的有力工具。最近美国伍兹霍尔海洋研究所报道了来自全球洋中脊的21个MORB样品的Ba、Sr、Nd同位素和微量元素组成以及两个钻井中沉积物和蚀变洋壳  相似文献   

Danian cool-water coral reefs in southern Scandinavia localised over seafloor highs     

Morten Bjerager  Finn Surlyk  Holger Lykke-Andersen  Nicolas Thibault  Lars Stemmerik 《Marine and Petroleum Geology》2010

Danian (Paleocene) reefs formed by ahermatypic scleractinian corals in relatively deep water are known in a few localities in southern Scandinavia. Reflection and shallow seismic profiles, and samples from drilling and scuba diving in bridge pier excavations in Øresund, the strait between Denmark and Sweden, for the first time allow interpretation of the factors that controlled the localisation of the reefs.  相似文献   

Pyroxene-melt equilibria: an updated model     

Roger L. Nielsen  Paula M. Davidson  Timothy L. Grove 《Contributions to Mineralogy and Petrology》1988,100(3):361-373

An updated model for pyroxene-melt equilibria at 1 atm has been developed and calibrated using new and existing experimental data in order to refine calculations of liquid lines of descent, which simulate the effect of igneous differentiation processes. We combine the Davidson and Lindsley (1985) model for activities of components in clinopyroxene and orthopyroxene solid solutions, a _i ^p , where i represents a quadrilateral endmember, with the Nielsen and Drake (1979) expressions for component activities in the melt, a _i ^L (two-lattice melt model). The chemical potential differences for pyroxene-melt equilibria are expressed in the form: $$\Delta \mu _{\iota } = 0 = In \left( {{{a_i^p } \mathord{\left/{\vphantom {{a_i^p } {a_i^L }}} \right.\kern-\nulldelimiterspace} {a_i^L }}} \right) + A_i + {{B_i } \mathord{\left/{\vphantom {{B_i } T}} \right.\kern-\nulldelimiterspace} T}$$ Pyroxene compositions were projected to quadrilateral compositions with the method of Lindsley and Anderson (1983). The regression constants A _i and B _i were calculated from experimental data that consists of 282 pyroxene-melt pairs, including 83 orthopyroxene-melt pairs. These experiments were all performed at 1 atm and represent compositions ranging from basalts (alkali to lunar) to dacites (42–66 wt% SiO₂). The model is calibrated for 1000相似文献   

FTIR studies of reactions between the nitrate radical and haloethenes     

I. M. W. Noremsaune  J. Hjorth  C. J. Nielsen 《Journal of Atmospheric Chemistry》1995,21(3):223-250

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.  相似文献   

Resistance of a soil layer to horizontal vibration of a pile     

Mette Thiel Nielsen 《地震工程与结构动力学》1982,10(3):497-510

The resistance of a soil to horizontal harmonic vibration of a vertical, end bearing pile with circular cross-section is theoretically investigated. The soil is considered to be a continuum with material damping of the hysteretic type. The motions of the soil and pile are expressed as series, and a resistance coefficient on each term in the series of the pile motion is found. The resistance is found to depend on the excitation frequency, the pile slenderness and on the material properties of the soil. Finally a study of the influence of the parameters is carried out.  相似文献   

Low pressure mineral-melt equilibria in natural anhydrous mafic systems     

Nielsen  Roger L.  Dungan  Michael A. 《Contributions to Mineralogy and Petrology》1983,84(4):310-326

Contributions to Mineralogy and Petrology - Low pressure phase equilibria for natural mafic systems may be calculated utilizing empirically derived single component distribution coefficients and...  相似文献   

Time-dependent thermal state of the lithosphere in the foreland of the Eastern Carpathians bend. Insights from new geothermal measurements and modelling results     

C. Demetrescu  H. Wilhelm  M. Tumanian  S.B. Nielsen  A. Damian  V. Dobric&#;  M. Ene 《Geophysical Journal International》2007,170(2):896-912

  相似文献   

Scalar advection schemes for ocean modelling on unstructured triangular grids     

William Paul Budgell  Anabela Oliveira  Morten D. Skogen 《Ocean Dynamics》2007,57(4-5):339-361

Several schemes for scalar advection on unstructured triangular grids are assessed for possible use in ocean modelling applications. Finite element, finite volume and finite volume–element approaches are evaluated. A series of tests, including a numerical order of convergence analysis, idealized rotating cone and cylinder experiments, and transport of a tracer through the Stommel Gyre representation of ocean basin-scale circulation, are carried out. Volume element Eulerian–Lagrangian and third-order Runge-Kutta discontinuous Galerkin schemes are recommended for use in tracer studies. Taylor–Galerkin and second-order Runge–Kutta discontinuous Galerkin are found to be robust and accurate second-order schemes. When positivity is required, a fluctuation redistribution scheme was found to be an easily implemented, accurate, and computationally efficient approach. Responsible editor: Phil Dyke  相似文献   

Impedance of flexible suction caissons     

Morten Liingaard  Lars Andersen  Lars Bo Ibsen 《地震工程与结构动力学》2007,36(14):2249-2271

The dynamic response of offshore wind turbines is affected by the properties of the foundation and the subsoil. The aim of this paper is to evaluate the dynamic soil–structure interaction of suction caissons for offshore wind turbines. The investigations include evaluation of the vertical and coupled sliding–rocking vibrations, influence of the foundation geometry and examination on the properties of the surrounding soil. The soil is simplified as a homogenous linear viscoelastic material and the dynamic stiffness of the suction caisson is expressed in terms of dimensionless frequency‐dependent coefficients corresponding to different degrees of freedom. The dynamic stiffness coefficients for the skirted foundation are evaluated using a three‐dimensional coupled boundary element/finite element model. Comparisons with known analytical and numerical solutions indicate that the static and dynamic behaviours of the foundation are predicted accurately using the applied model. The analysis has been carried out for different combinations of the skirt length, Poisson's ratio of the subsoil and the ratio of the soil stiffness to the skirt stiffness. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Experimentally determined mineral-melt partition coefficients for Sc,Y and REE for olivine,orthopyroxene, pigeonite,magnetite and ilmenite   总被引：6，自引：0，他引：6  

Roger L. Nielsen  William E. Gallahan  Florence Newberger 《Contributions to Mineralogy and Petrology》1992,110(4):488-499

Our current lack of understanding of the partitioning behavior of Sc, Y and the REE (rare-earth elements) can be attributed directly to the lack of a sufficiently large or chemically diverse experimental data set. To address this problem, we conducted a series of experiments using several different natural composition lavas, doped with the elements of interest, as starting compositions. Microprobe analyses of orthopyroxene, pigeonite, olivine, magnetite, ilmenite and co-existing glasses in the experimental charges were used to calculate expressions that describe REE partitioning as a function of a variety of system parameters. Using expressions that represent mineral-melt reactions (versus element ratio distribution coefficients) it is possible to calculate terms that express low-Ca pyroxene-melt partitioning behavior and are independent of both pyroxene and melt composition. Compositional variations suggest that Sc substitution in olivine involves either a paired substitution with Al or, more commonly, with vacancies. The partitioning of Sc is dependent both on melt composition and temperature. Our experimentally determined olivine-melt REE Ds (partition coefficients) are similar to, but slightly higher than those reported by McKay (1986) and support their conclusions that olivines are strongly LREE depleted. Y and REE mineral/melt partition coefficients for magnetite range from 0.003 for La to 0.02 for Lu. Ilmenite partition coefficients range from 0.007 for La to 0.029 for Lu. These experimental values are two orders of magnitude lower than many of the published values determined by phenocryst/matrix separation techniques.  相似文献