Sodium trisilicate: A new high-pressure silicate structure (Na2Si[Si2O7])     

Michael E. Fleet  Grant S. Henderson 《Physics and Chemistry of Minerals》1995,22(6):383-386

Crystals of sodium trisilicate (Na₂Si₃O₇) have been grown in the presence of melt at 9 GPa, 1200 °C using the MA6/8 superpress at Edmonton, and the X-ray structure determined at room pressure (R=2.0%). Na₂Si₃O₇ is monoclinic with a=8.922(2) Å, b= 4.8490(5) Å, c=11.567(1) Å, β=102.64(1)° (C2/c), D _x = 3.295 g·cm^-3. Silicon occurs in both tetrahedral and octahedral coordination (^[6]Si∶^[4]Si = l∶2). The SiO₄ tetrahedra form a diorthosilicate [Si₂O₇] group and are linked by the isolated SiO₆ octahedra via shared corners into a framework of 6-membered (^[4]Si-^[4]Si-^[6]Si^[4]Si-^[4] Si-^[6]Si) and 4-membered (^[4]Si-^[6]Si-^[4]Sr-^[6]Si) rings: 〈^[6]Si-O〉=1.789 Å, 〈^[4]Si-O〉= 1.625 Å, ^[4]Si-O-^[4]Si=132.9° and the bridging oxygen is overbonded (s = 2.22). Channels parallel to b-axis and [110] accommodate Na in irregular 6-fold coordination: 〈Na-O〉 = 2.511 Å.  相似文献   

X-ray absorption near-edge spectra of transition metal disulfides FeS2 (pyrite and marcasite), CoS2, NiS2 and CuS2, and their isomorphs FeAsS and CoAsS     

J. F. W. Mosselmans  R. A. D. Pattrick  G. van der Laan  J. M. Charnock  D. J. Vaughan  C. M. B. Henderson  C. D. Garner 《Physics and Chemistry of Minerals》1995,22(5):311-317

Metal K- and L₃-, sulfur K- and arsenic K- and L₃-edge X-ray absorption near-edge spectra of a series of metal disulfides, FeS₂ (both pyrite and marcasite), CoS₂, NiS₂, and CuS₂, and their isomorphs, FeAsS and CoAsS, are presented. The features in this region of these spectra are interpreted using band structure and molecular orbital calculations in terms of the transitions from the 1s or 2p_3/2 state to unoccupied states. The 3d transition metal L₃-edge spectra of these materials show dependence on the degree of multiplet splitting in the final state, and thus offer less information on the electronic ground state. There are substantial differences in the spectra of the isostructural materials, whereas the spectra of the isotopes pyrite and marcasite show several similarities, illustrating the dependence of near-edge region on electronic structure.  相似文献   

Greenhouse,gaia and global change: a personal view of the pitfalls of interdisciplinary research     

Ann Henderson‐Sellers 《The Australian geographer》1992,23(1):24-38

Recognition of the possible consequences of global‐scale pollution has spawned research programs loosely termed ‘global change’. These programs are hampered by the problems of academic apartheid first identified by those attempting to examine the Gaia hypothesis. Global change is, in many ways, a synonym for global geography: the study of processes and their consequences at the human/environment interface. Assessment of highly complex systems demands integrative, interdisciplinary research; the search for, and recognition of, negative feedbacks; and, most importantly, the courage to formulate hypotheses which bridge many single disciplines. I illustrate some of the pitfalls of interdisciplinary research with reference to my own research in atmospheric science, by the application of atmospheric science to the study of climatic impacts and consideration of the integration of climatic impacts into global change.  相似文献   

A fracture-mechanical cellular automaton model of seismicity     

Jeremy R. Henderson  Ian G. Main  Calum Maclean  Michael G. Norman 《Pure and Applied Geophysics》1994,142(3-4):545-565

We present a cellular automaton model which simulates the process of seismogenesis using rules for evolution which are derived from the field of fracture mechanics, and include an interplay of positive and negative feedbacks. We describe the implementation of this model, and its analysis, in a massively parallel environment using the Connection Machine. Starting from a lattice with a fractal distribution of fracture toughnesses, theb value evolves in a way which closely mimics both the evolutions ofb value observed in the laboratory and derived from earthquake catalogues, reaching a broad and irregular maximum in the period preceding a major event, and declining rapidly during catastrophic failure. We conclude that the processes modelled are a reasonable representation of those occurring in Nature, and that the cellular automaton paradigm is a valuable way of simulating these processes on a large scale in an economical manner.  相似文献   

Geochemical Reduction of Hexavalent Chromium in the Trinity Sand Aquifer   总被引：3，自引：0，他引：3  

Thomas Henderson 《Ground water》1994,32(3):477-486

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Late Palaeozoic arc flank and fore‐arc basin sequence of the New England fold belt in the stanage bay region,central Queensland     

E. C. Leitch  C. L. Fergusson  R. A. Henderson  V. J. Morand 《Australian Journal of Earth Sciences》2013,60(4):301-310

Devonian and Carboniferous (Yarrol terrane) rocks, Early Permian strata, and Permian‐(?)Triassic plutons outcrop in the Stanage Bay region of the northern New England Fold Belt. The Early‐(?)Middle Devonian Mt Holly Formation consists mainly of coarse volcaniclastic rocks of intermediate‐silicic provenance, and mafic, intermediate and silicic volcanics. Limestone is abundant in the Duke Island, along with a significant component of quartz sandstone on Hunter Island. Most Carboniferous rocks can be placed in two units, the late Tournaisian‐Namurian Campwyn Volcanics, composed of coarse volcaniclastic sedimentary rocks, silicic ash flow tuff and widespread oolitic limestone, and the conformably overlying Neerkol Formation dominated by volcaniclastic sandstone and siltstone with uncommon pebble conglomerate and scattered silicic ash fall tuff. Strata of uncertain stratigraphic affinity are mapped as ‘undifferentiated Carboniferous’. The Early Permian Youlambie Conglomerate unconformably overlies Carboniferous rocks. It consists of mudstone, sandstone and conglomerate, the last containing clasts of Carboniferous sedimentary rocks, diverse volcanics and rare granitic rocks. Intrusive bodies include the altered and variably strained Tynemouth Diorite of possible Devonian age, and a quartz monzonite mass of likely Late Permian or Triassic age.

The rocks of the Yarrol terrane accumulated in shallow (Mt Holly, Campwyn) and deeper (Neerkol) marine conditions proximal to an active magmatic arc which was probably of continental margin type. The Youlambie Conglomerate was deposited unconformably above the Yarrol terrane in a rift basin. Late Permian regional deformation, which involved east‐west horizontal shortening achieved by folding, cleavage formation and east‐over‐west thrusting, increases in intensity towards the east.  相似文献   

Ophiolitic and metamorphic rocks in the Percy Isles and Shoalwater Bay region,New England Fold Belt,central Queensland     

E. C. Leitch  C. L. Fergusson  R. A. Henderson  V. J. Morand 《Australian Journal of Earth Sciences》2013,60(6):571-579

Ophiolitic and metamorphic rocks of the eastern part of the New England Fold Belt in the Shoalwater Bay region and the Percy Isles are grouped in the Marlborough and Shoalwater terranes, respectively. Marlborough terrane units occur on South Island (Percy Isles) and comprise the Northumberland Serpentinite, antigorite serpentinite with rodingite and more silicic dykes and mafic inclusions, the Chase Point Metabasalt, some 800+ metres of pillow lava, and the intervening South Island Shear Zone containing fault‐bounded slices of mafic and ultramafic igneous rocks, schist, and volcaniclastic sedimentary rocks, and zones of mélange. The Shoalwater terrane, an ancient subduction complex, consists of the Shoalwater Formation greenschist facies metamorphosed quartz sandstone and mudstone on North East Island and on the mainland at Arthur Point, the Townshend Formation, amphibolite‐grade quartzite, schist and metabasalt on Townshend Island, and the Broome Head Metamorphics on the western side of Shoalwater Bay, upper amphibolite facies quartz‐rich gneiss. With the exception of a sliver emplaced onto the western Yarrol terrane, possibly by gravity sliding, Shoalwater terrane rocks show the effects of Late Permian polyphase deformation. The Shacks Mylonite Zone along the northwest edge of the Broome Head Metamorphics marks a zone of oblique thrusting and is part of the major Stanage Fault Zone. The latter is a northeast‐striking oblique‐slip dextral tear fault active during Late Permian west‐directed thrusting that emplaced large ultramafic sheets farther south. Marlborough terrane rocks were emplaced along the Stanage Fault Zone, probably from the arc basement on which rocks of the Yarrol terrane were deposited. Structural trends and the distribution of rock units in the Shoalwater Bay‐Percy Isles region are oblique to the overall structural trend of the northern New England Fold Belt, probably due to the presence of a promontory in the convergent margin active in this region in Devonian and Carboniferous time.  相似文献   

Learning from the Pros: The Role of ISSRM,SNR, and IASNR in Our Careers     

Naomi Krogman  Carla Koons Trentelman  Joan Brehm  Courtney Flint 《社会与自然资源》2013,26(2):176-183

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Recent advances in isotopes as palaeolimnological proxies     

Melanie J. Leng  Andrew C. G. Henderson 《Journal of Paleolimnology》2013,49(3):481-496

Isotope geochemistry is an essential part of environmental and climate change research and over the last few decades has contributed significantly to our understanding of a huge array of environmental problems, not least in palaeolimnology and limnogeology. Here we describe some of the recent developments in the use of stable isotopes in palaeo-lake research. These are: better preparation, analysis, and interpretation of biogenic silica oxygen and silicon isotopes; extraction and characterisation of specific compounds such as leaf waxes and algal lipids for isotope analysis; determining the excess of ¹³C–¹⁸O bonds in clumped isotopes; and the measurement of multiple isotope ratios in chironomid chitin. These advances have exciting prospects and it will be interesting to see how these techniques develop further and consequently offer a real advancement in our science over the next decade.  相似文献   

A numerical model for one‐dimensional simulation of stratospheric chemistry     

G.S. Henderson  J.C. McConnell  E.M.J. Templeton  W.F.J. Evans 《大气与海洋》2013,51(4):427-459

Abstract

We describe a one‐dimensional (1‐D) numerical model developed to simulate the chemistry of minor constituents in the stratosphere. The model incorporates most of the chemical species presently found in the upper atmosphere and has been used to investigate the effect of increasing chlorofluorocarbon (CFC) emissions on ozone (O₃).

Our calculations confirm previous results that O₃ depletions in the 20–25 km region, the region of the O₃ maximum, are very sensitive to the relative abundances of Cl_x and NO_y in the lower stratosphere for high Cl_x amounts. The individual abundances of lower stratospheric Cl_x and NO_y amounts are very sensitive to upper tropospheric mixing ratios, which, in turn, are determined largely by surface input fluxes and heterogeneous loss processes. Thus the behaviour of column O₃ depletions at high Cl_x levels is greatly affected, albeit indirectly, by tropospheric processes. For high Cl_x levels the O_x flux from the stratosphere to the troposphere is dramatically reduced, leading to a large reduction in tropospheric O₃. Some of the variation between different published 1‐D model results is most likely due to this critical dependence of O₃ depletion on NO_y‐Cl_x ratios.

Model simulations of time‐dependent CFC effects on ozone indicate that if CFCs were to remain at constant 1980 emission rates while N₂O increased at 0.25% a^?1 and CH₄ increased at 1% a^?1, we could expect a 2.2% decrease in total column O₃ (relative to the 1980 atmosphere) by the year 2000. However, if CFC emission rates were to increase by 3% a^?1 (current estimates are 5–6% a^?1), we would predict a depletion of 2.7% by the year 2000. The calculations for times beyond the year 2000 suggest that the effects on total O₃ will begin to accelerate. If methyl chloroform emissions are added at 7% a^?1 (current estimates are 7–9% a^?1) to the above CFC‐N₂O‐CH₄ scenario we calculate total O₃ depletions by the year 2000 that are 41% larger than those calculated without. This suggests that if the emissions of methyl chloroform continue to increase at their present rate then methyl chloroform could have a significant effect upon total O₃.  相似文献