Biodegradation and environmental behavior of biodiesel mixtures in the sea: An initial study     

DeMello JA  Carmichael CA  Peacock EE  Nelson RK  Samuel Arey J  Reddy CM 《Marine pollution bulletin》2007,54(7):894-904

Biodiesel, a mixture of fatty acid methyl esters (FAMEs) derived from animal fats or vegetable oils, is rapidly moving towards the mainstream as an alternative source of energy. However, the behavior of biodiesel, or blends of biodiesel with fossil diesel, in the marine environment have yet to be fully understood. Hence, we performed a series of initial laboratory experiments and simple calculations to evaluate the microbial and environmental fate of FAMEs. Aerobic seawater microcosms spiked with biodiesel or mixtures of biodiesel and fossil diesel revealed that the FAMEs were degraded at roughly the same rate as n-alkanes, and more rapidly than other hydrocarbon components. The residues extracted from these different microcosms became indistinguishable within weeks. Preliminary results from physical-chemical calculations suggest that FAMEs in biodiesel mixtures will not affect the evaporation rates of spilled petroleum hydrocarbons but may stabilize oil droplets in the water column and thereby facilitate transport.  相似文献   

Planetary-Scale Wave Structures of the Earth’s Atmosphere Revealed from the COSMIC Observations   总被引：1，自引：0，他引：1       下载免费PDF全文

S. K. A. V. Prasad Rao ANISETTY  P. S. BRAHMANANDAM  G. UMA  A. Narendra BABU  HUANG Ching-Yuang  G. Anil KUMAR  S. Tulasi RAM  WANG Hsiao-Lan  CHU Yen-Hsyang 《Acta Meteorologica Sinica》2014,28(2):281-295

GPS radio occultation（GPS RO） method,an active satellite-to-satellite remote sensing technique,is capable of producing accurate,all-weather,round the clock,global refractive index,density,pressure,and temperature profiles of the troposphere and stratosphere.This study presents planetary-scale equatorially trapped Kelvin waves in temperature profiles retrieved using COSMIC（Constellation Observing System for Meteorology,Ionosphere,and Climate） satellites during 2006-2009 and their interactions with background atmospheric conditions.It is found that the Kelvin waves are not only associated with wave periods of higher than 10 days（slow Kelvin waves） with higher zonal wave numbers（either 1 or 2）,but also possessing downward phase progression,giving evidence that the source regions of them are located at lower altitudes.A thorough verification of outgoing longwave radiation（OLR） reveals that deep convection activity has developed regularly over the Indonesian region,suggesting that the Kelvin waves are driven by the convective activity.The derived Kelvin waves show enhanced（diminished） tendencies during westward（eastward） phase of the quasi-biennial oscillation（QBO） in zonal winds,implying a mutual relation between both of them.The El Nino and Southern Oscillation（ENSO） below 18 km and the QBO features between 18 and 27km in temperature profiles are observed during May 2006-May 2010 with the help of an adaptive data analysis technique known as Hilbert Huang Transform（HHT）.Further,temperature anomalies computed using COSMIC retrieved temperatures are critically evaluated during different phases of ENSO,which has revealed interesting results and are discussed in light of available literature.  相似文献   

A site-specific study on the measurement of sorption coefficients for radionuclides     

A. A. Dalvi  S. D. Kumar  A. V. R. Reddy 《International Journal of Environmental Science and Technology》2014,11(3):617-622

A study on the potential of geological media from the vicinity of the mining site in Tummalapalle region of Andhra Pradesh in India for retardation of radionuclide migration in groundwater was conducted. The studies included the measurement of sorption coefficients for six radionuclides, uranium, thorium, lead, bismuth, radium and polonium, between two groundwater simulants and two site-specific samples of geological media. Initial parametric studies involving chemical composition, pH, calcium carbonate and organic carbon contents of both geological media and ground water simulants were carried out. Significant differences in sorption coefficients were observed as a result of varying pH, calcium carbonate and presence of trace quantities of organic contents in simulant solutions. For example, uranium has a hundred fold lower distribution coefficient in the case of simulant solution having higher carbonate content. Similarly, in the case of the geological media having higher calcium carbonate and organic carbon contents, higher distribution coefficients were obtained for all radionuclides. Among the six radionuclides studied thorium showed the largest and radium the smallest distribution coefficient values for the soil samples assessed. The site-specific sorption coefficients will be used for contaminant transport study.  相似文献   

Hydrogeological processes controlling the release of arsenic in parts of 24 Parganas district,West Bengal     

Neha Singh  Ravi Prakash Singh  Saumitra Mukherjee  Kyle McDonald  K. J. Reddy 《Environmental Earth Sciences》2014,72(1):111-118

A study was conducted to understand the hydrogeological processes dominating in the North 24 Parganas and South 24 Parganas based on representative 39 groundwater samples collected from selected area. The abundance of major ions was in the order of Ca²⁺ > Na⁺ > Mg²⁺ > K⁺ > Fe²⁺ for cations and HCO₃ ^? > PO₄ ^3? > Cl^? > SO₄ ^2? > NO₃ ^? for anions. Piper trilinear diagram was plotted to understand the hydrochemical facies. Most of the samples are of Ca-HCO₃ type. Based on conventional graphical plots for (Ca + Mg) vs. (SO₄ + HCO₃) and (Na + K) vs. Cl, it is interpreted that silicate weathering and ion exchange are the dominant processes within the study area. Previous studies have reported quartz, feldspar, illite, and chlorite clay minerals as the major mineral components obtained by the XRD analysis of sediments. Mineralogical investigations by SEM and EDX of aquifer materials have shown the occurrence of arsenic as coating on mineral grains in the silty clay as well as in the sandy layers. Excessive withdrawal of groundwater for irrigation and drinking purposes is responsible for fluctuation of the water table in the West Bengal. Aeration beneath the ground surface caused by fluctuation of the water table may lead to the formation of carbonic acid. Carbonic acid is responsible for the weathering of silicate minerals, and due to the formation of clay as a product of weathering, ion exchange also dominates in the area. These hydrogeological processes may be responsible for the release of arsenic into the groundwater of the study area, which is a part of North 24 Parganas and South 24 Parganas.  相似文献   

Stratigraphic status,age, and paleobathymetry of the Grey shale Member,Dalmiapuram Formation,Cauvery Basin,India     

R. Nagendra  P. Sathiyamoorthy  A. N. Reddy  Harry Gilbert  B. C. Jaiprakash 《Arabian Journal of Geosciences》2014,7(10):4133-4144

Grey shale Member of the Dalmiapuram Formation, Ariyalur Group, Cauvery Basin, India was studied for its stratigraphic position, age, and paleobathymetry with a re-look into the lithological relationship and foraminifer assemblages in the deepened limestone mine excavations at M/s Dalmia Cements, Dalmiapuram. Twenty grey shale samples from Kovandankurchchi (pit-4) and Kallakkudi mines yielded diversified calcareous, benthic, and rare index planktic foraminifera. The foraminiferal assemblages suggest a latest Albian age and middle neritic depositional conditions. The abundance of kaolinite and smectite clay minerals relate to warm/humid climate which corroborate with rising relative sea level during grey shale deposition. The grey shale occurs in patches within the marl bedded limestone member which exhibits cyclic deposition of limestone and marl. The limestone mine sections demonstrate that the grey shale forms part of basal marl bedded limestone, directly overlying the coral algal limestone. The present study demonstrates that the grey shale outcrops in Dalmiapuram Formation should be placed stratigraphically as part of marl bedded limestone. The member status for grey shale which is current usage stands discounted.  相似文献   

Discrimination between anthropogenic (pollution) and lithogenic magnetic fraction in urban soils (Delhi,India) using environmental magnetism     

Narendra K. Meena  Sabyasachi Maiti  Ankush Shrivastava 《Journal of Applied Geophysics》2011,73(2):121-129

In this paper magnetic property of the Delhi topsoil has been used to characterize the potentially polluted areas in terms of magnetic minerals and grain (Magnetic Domain) concentration as a factor of toxic metals and other mutagenic pollutant concentration. The Saturation magnetisation (Ms) and Saturation remanence (Mrs) has been taken as proxy for ferrimagnetic mineral concentration. However, delineation of anthropogenic magnetic fraction from lithogenic (geogenic) magnetic fraction has been done by the paramagnetic/diamagnetic contribution of soil with the fact that the fresh soil contains higher paramagnetic and diamagnetic minerals than polluted. Predominantly, the topsoils of Delhi are dominated with ferrimagnetic minerals (Magnetite and Maghemite phase). Significantly the industrial areas contain highest concentration of the ferrimagnetic minerals with negligible paramagnetic/diamagnetic fraction which leads to anthropogenic contribution. Heavy traffic and densely populated areas of the Delhi exhibit moderate to low soil pollution while green areas show lowest with higher paramagnetic/diamagnetic contribution. The soils in Delhi are dominated with Pseudo-Single Domain (PSD) magnetic grain, though the industrial areas in Delhi show coarser Multidomain (MD) grains in comparison to Stable Single Domain (SSD) in forest areas. Our study reveals that the fine grain particle does not show significant link with higher concentration of ferrimagnetic minerals at least in soils. The presence of the lithogenic magnetite crystal in the forest soil and anthropogenically produced spherules in industrial areas and higher concentration of the heavy metal in Delhi soil strengthen our findings.  相似文献   

Exact bianchi type-II,VIII, and IX cosmological models with matter and electromagnetic fields in Lyra's manifold     

R. Venkateswarlu  D. R. K. Reddy 《Astrophysics and Space Science》1991,182(1):97-103

Spatially-homogeneous and anisotropic Bianchi type-II, VIII, and IX stiff-fluid cosmological models in the presence of source-free electromagnetic fields are obtained in Lyra's manifold. Some properties of the models are also discussed.  相似文献   

Bianchi type-II,VIII, and IX cosmologies with conformally-invariant scalar field and electromagnetic fields     

R. Venkateswarlu  D. R. K. Reddy 《Astrophysics and Space Science》1991,184(1):153-156

In the expansive nondecelerative universe creation of matter happens as a result of a fundamental relationship and mutual compatibility of the field and matter.  相似文献   

Hall effects on oscillatory MHD boundary-layer flow under variable suction     

M. U. S. Reddy  N. K. Samria  R. Prasad  H. N. Gupta 《Astrophysics and Space Science》1991,183(2):273-283

The effects of Hall current on the oscillatory hydromagnetic boundary-layer flow under variable suction, past an infinite porous flat plate in the presence of a transverse magnetic field is discussed. The expressions for velocity and skin-friction are obtained and their variations for small and large frequency of oscillations are extensively discussed.  相似文献   

Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: field measurements and theoretical analysis     

Michael M. Reddy  Micaela B. Reddy  Kenneth L. Kipp  Aaron Burman  Paul Schuster  Peter S. Rawlik Jr. 《水文研究》2008,22(11):1713-1724

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.  相似文献