Hydrogen and oxygen isotope exchange reactions between clay minerals and water   总被引：1，自引：0，他引：1  

James R O&#x;Neil  Yousif K Kharaka 《Geochimica et cosmochimica acta》1976,40(2):241-246

The extent of hydrogen and oxygen isotope exchange between clay minerals and water has been measured in the temperature range 100–350° for bomb runs of up to almost 2 years. Hydrogen isotope exchange between water and the clays was demonstrable at 100°. Exchange rates were 3–5 times greater for montmorillonite than for kaolinite or illite and this is attributed to the presence of interlayer water in the montmorillonite structure.Negligible oxygen isotope exchange occurred at these low temperatures. The great disparity in D and O¹⁸ exchange rates observed in every experiment demonstrates that hydrogen isotope exchange occurred by a mechanism of proton exchange independent of the slower process of O¹⁸ exchange.At 350° kaolinite reacted to form pyrophyllite and diaspore. This was accompanied by essentially complete D exchange but minor O¹⁸ exchange and implies that intact structural units in the pyrophyllite were inherited from the kaolinite precursor.  相似文献   

The decay of the mean solar magnetic field     

Neil R. Sheeley Jr.  C. Richard DeVore 《Solar physics》1986,103(2):203-224

We have analyzed the effects that differential rotation and a hypothetical meridional flow would have on the evolution of the Sun's mean line-of-sight magnetic field as seen from Earth. By winding the large-scale field into strips of alternating positive and negative polarity, differential rotation causes the mean-field amplitude to decay and the mean-field rotation period to acquire the value corresponding to the latitude of the surviving unwound magnetic flux. For a latitudinally broad two-sector initial field such as a horizontal dipole, the decay is rapid for about 5 rotations and slow with a t ^–1/2 dependence thereafter. If a poleward meridional flow is present, it will accelerate the decay by carrying the residual flux to high latitudes where the line-of-sight components are small. The resulting decay is exponential with an e-folding time of 0.75 yr (10 rotations) for an assumed 15 m s^–1 peak meridional flow speed.E.O. Hulburt Center for Space Research.Laboratory for Computational Physics.  相似文献   

Trace element and molecular markers of organic carbon dynamics along a shelf–basin continuum in sediments of the western Arctic Ocean     

Laura L. Belicka  Robie W. Macdonald  H. Rodger Harvey 《Marine Chemistry》2009,115(1-2):72-85

Molecular organic biomarkers together with trace element composition were investigated in sediments east of Barrow Canyon in the western Arctic Ocean to determine sources and recycling of organic carbon in a continuum from the shelf to the basin. Algal biomarkers (polyunsaturated and short-chain saturated fatty acids, 24-methylcholesta-5,24(28)-dien-3β-ol, dinosterol) highlight the substantial contribution of organic matter from water column and sea-ice primary productivity in shelf environments, while redox markers such as acid volatile sulfide (AVS), Mn, and Re indicate intense metabolism of this material leading to sediment anoxia. Shelf sediments also receive considerable inputs from terrestrial organic carbon, with biomarker composition suggesting the presence of multiple pools of terrestrial organic matter segregated by age/lability or hydrodynamic sorting. Sedimentary metabolism was not as intense in slope sediments as on the shelf; however, sufficient labile organic matter is present to create suboxic and anoxic conditions, at least intermittently, as organic matter is focused towards the slope. Basin sediments also showed evidence for episodic delivery of labile organic carbon inputs despite the strong physical controls of water depth and sea-ice cover. Principal components analysis of the lipid biomarker data was used to estimate fractions of preserved recalcitrant (of terrestrial origin) and labile (of marine origin) organic matter in the sediments, with ranges of 12–79%, 14–45%, and 37–66% found for the shelf, slope, and basin cores, respectively. On average, the relative preserved terrestrial organic matter in basin sediments was 56%, suggesting exchange of organic carbon between nearshore and basin environments in the western Arctic.  相似文献   

Sedimentological,geomorphological and dynamic context of debris-mantled glaciers,Mount Everest (Sagarmatha) region,Nepal     

Michael J. Hambrey  Duncan J. Quincey  Neil F. Glasser  John M. Reynolds  Shaun J. Richardson  Samuel Clemmens 《Quaternary Science Reviews》2009,28(11-12):1084

This paper presents the sediment, landform and dynamic context of four avalanche-fed valley glaciers (Khumbu, Imja, Lhotse and Chukhung) in the Mount Everest (Sagarmatha) region of Nepal. All four glaciers have a mantle of debris dominated by sandy boulder-gravel that suppresses melting to an increasing degree towards the snout, leading to a progressive reduction in the overall slope of their longitudinal profile. Prominent lateral–terminal moraine complexes, also comprising sandy bouldergravel, enclose the glaciers. These terminal moraines originally grew by accretion of multiple sedimentary facies of basal glacial and supraglacial origin, probably by folding and thrusting when the glaciers were more dynamic during the Little Ice Age. The four glaciers are in various stages of recession, and demonstrate a range of scenarios from down-wasting of the glacier tongue, through morainedammed lake development, to post-moraine-dam breaching. Khumbu Glacier is at the earliest stage of supraglacial pond formation and shows no sign yet of developing a major lake, although one is likely to develop behind its >250 m high composite terminal moraine. Imja Glacier terminates in a substantial body of water behind a partially ice-cored moraine dam (as determined from geophysical surveys), but morphologically appears unlikely to be an immediate threat. Chukhung Glacier already has a breached moraine and a connected debris fan, and therefore no longer poses a threat. Lhotse Glacier has an inclined, free-draining tongue that precludes hazardous lake development. From the data assembled, a conceptual model, applicable to other Himalayan glaciers, is proposed to explain the development of large, lateral-terminal moraine complexes and associated potentially hazardous moraine dams. – 2008 Elsevier Ltd. All rights reserved.  相似文献   

The WOCE-era 3-D Pacific Ocean circulation and heat budget   总被引：2，自引：0，他引：2  

A.M. Macdonald  S. Mecking  P.E. Robbins  J.M. Toole  G.C. Johnson  L. Talley  M. Cook  S.E. Wijffels 《Progress in Oceanography》2009,(4):281-325

To address questions concerning the intensity and spatial structure of the three-dimensional circulation within the Pacific Ocean and the associated advective and diffusive property flux divergences, data from approximately 3000 high-quality hydrographic stations collected on 40 zonal and meridional cruises have been merged into a physically consistent model. The majority of the stations were occupied as part of the World Ocean Circulation Experiment (WOCE), which took place in the 1990s. These data are supplemented by a few pre-WOCE surveys of similar quality, and time-averaged direct-velocity and historical hydrographic measurements about the equator.An inverse box model formalism is employed to estimate the absolute along-isopycnal velocity field, the magnitude and spatial distribution of the associated diapycnal flow and the corresponding diapycnal advective and diffusive property flux divergences. The resulting large-scale WOCE Pacific circulation can be described as two shallow overturning cells at mid- to low latitudes, one in each hemisphere, and a single deep cell which brings abyssal waters from the Southern Ocean into the Pacific where they upwell across isopycnals and are returned south as deep waters. Upwelling is seen to occur throughout most of the basin with generally larger dianeutral transport and greater mixing occurring at depth. The derived pattern of ocean heat transport divergence is compared to published results based on air–sea flux estimates. The synthesis suggests a strongly east/west oriented pattern of air–sea heat flux with heat loss to the atmosphere throughout most of the western basins, and a gain of heat throughout the tropics extending poleward through the eastern basins. The calculated meridional heat transport agrees well with previous hydrographic estimates. Consistent with many of the climatologies at a variety of latitudes as well, our meridional heat transport estimates tend toward lower values in both hemispheres.  相似文献   

The origin of the 28- to 29-day recurrent patterns of the solar magnetic field     

Neil R. Sheeley Jr.  C. Richard DeVore 《Solar physics》1986,104(2):425-429

Numerical simulations of the Sun's mean line-of-sight magnetic field suggest an origin for the 28-to 29-day recurrent patterns of the field and its associated interplanetary phenomena. The patterns are caused by longitudinal fluctuations in the eruption of new magnetic flux, the transport of this flux to mid latitudes by supergranular diffusion and meridional flow, and the slow rotation of the resulting flux distributions at the 28- to 29-day periods characteristic of those latitudes.E. O. Hulburt Center for Space Research.Laboratory for Computational Physics.  相似文献   

Dives into outer Coronado Canyon System     

Francis P. Shepard  Neil F. Marshall 《Marine Geology》1975,18(5):313-323

Dives in Lockheed's submarine “Deep Quest” followed the floor of the fan valley and outer gorge of Coronado Canyon, southwest of the California—Baja California border. Both the fan valley and outer gorge have meandering courses. Basin depressions and intermittent steep descents characterize the outer gorge. No indications were found of recent activity of turbidity currents at either location, but a sand layer 30 cm below the surface is interpreted as related to a lower stand of sea level at the close of the last ice age. Abundant organisms were seen on the valley floor and in the overlying water.  相似文献   

Distribution of diagenetic alterations within depositional facies and sequence stratigraphic framework of fluvial sandstones: Evidence from the Petrohan Terrigenous Group,Lower Triassic,NW Bulgaria     

Mohamed Ali Kalefa El-Ghali  Sadoon Morad  Howri Mansurbeg  Miguel Angel Caja  George Ajdanlijsky  Neil Ogle  Ihsan Al-Aasm  Manhal Sirat 《Marine and Petroleum Geology》2009

Sequence stratigraphy of fluvial deposits is a controversial topic because changes in relative sea level will eventually have indirect impact on the spatial and temporal distribution of depositional facies. Changes in the relative sea level may influence the accommodation space in fluvial plains, and hence have impact on types of fluvial system, frequency of avulsion, and style of vertical and lateral accretion. This study aims to investigate whether depositional facies and changes in the fluvial system of the Lower Triassic Petrohan Terrigenous Group sandstones (NW Bulgaria) in response to changes in the relative sea level have an impact on the spatial and temporal distribution of diagenetic alterations.  相似文献   

Comments on “Japan's Direct Manufacturing Investment”     

Neil Reid 《The Professional geographer》1990,42(2):223-226

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Similarity of new palaeomagnetic data from the Santa Rosa Mountains with those from Steens Mountain gives wide regional evidence for a two-stage process of geomagnetic field reversal     

Neil Roberts  Mike Fuller 《Geophysical Journal International》1990,100(3):521-526

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