Ancient geochemical cycling in the Earth as inferred from Fe isotope studies of banded iron formations from the Transvaal Craton   总被引：8，自引：0，他引：8  

Clark M. Johnson  Brian L. Beard  Nicolas J. Beukes  Cornelis Klein  Julie M. O'Leary 《Contributions to Mineralogy and Petrology》2003,144(5):523-547

Variations in the isotopic composition of Fe in Late Archean to Early Proterozoic Banded Iron Formations (BIFs) from the Transvaal Supergroup, South Africa, span nearly the entire range yet measured on Earth, from –2.5 to +1.0‰ in ⁵⁶Fe/⁵⁴Fe ratios relative to the bulk Earth. With a current state-of-the-art precision of ±0.05‰ for the ⁵⁶Fe/⁵⁴Fe ratio, this range is 70 times analytical error, demonstrating that significant Fe isotope variations can be preserved in ancient rocks. Significant variation in Fe isotope compositions of rocks and minerals appears to be restricted to chemically precipitated sediments, and the range measured for BIFs stands in marked contrast to the isotopic homogeneity of igneous rocks, which have δ⁵⁶Fe=0.00±0.05‰, as well as the majority of modern loess, aerosols, riverine loads, marine sediments, and Proterozoic shales. The Fe isotope compositions of hematite, magnetite, Fe carbonate, and pyrite measured in BIFs appears to reflect a combination of (1) mineral-specific equilibrium isotope fractionation, (2) variations in the isotope compositions of the fluids from which they were precipitated, and (3) the effects of metabolic processing of Fe by bacteria. For minerals that may have been in isotopic equilibrium during initial precipitation or early diagenesis, the relative order of δ⁵⁶Fe values appears to decrease in the order magnetite > siderite > ankerite, similar to that estimated from spectroscopic data, although the measured isotopic differences are much smaller than those predicted at low temperature. In combination with on-going experimental determinations of equilibrium Fe isotope fractionation factors, the data for BIF minerals place additional constraints on the equilibrium Fe isotope fractionation factors for the system Fe(III)–Fe(II)–hematite–magnetite–Fe carbonate. δ⁵⁶Fe values for pyrite are the lowest yet measured for natural minerals, and stand in marked contrast to the high δ⁵⁶Fe values that are predicted from spectroscopic data. Some samples contain hematite and magnetite and have positive δ⁵⁶Fe values; these seem best explained through production of high ⁵⁶Fe/⁵⁴Fe reservoirs by photosynthetic Fe oxidation. It is not yet clear if the low δ⁵⁶Fe values measured for some oxides, as well as Fe carbonates, reflect biologic processes, or inorganic precipitation from low-δ⁵⁶Fe ferrous-Fe-rich fluids. However, the present results demonstrate the great potential for Fe isotopes in tracing the geochemical cycling of Fe, and highlight the need for an extensive experimental program for determining equilibrium Fe isotope fractionation factors for minerals and fluids that are pertinent to sedimentary environments.  相似文献   

Évolution temporelle et architecture interne d'un banc sableux estuarien : la Longe de Boyard (littoral atlantique,France)     

Éric Chaumillon  Hervé Gillet  Nicolas Weber  Michel Tesson 《Comptes Rendus Geoscience》2002,334(2):119-126

The evolution and the internal architecture of an estuary type sand ridge has been studied with a set of bathymetric data recorded during the last two centuries and with a dense grid of recent very high resolution seismic profiles. Bathymetric data of the so-called, Longe de Boyard sand ridge, displays sand losts due to wave and tide erosion. Internal geometry, through seismic profile analysis, indicates two main phases of deposition recording both, a recent high energy environment and an older low energy one, respectively. Such an evolution is believed to record changes in sedimentation processes mainly related to the end of the Holocene transgression (8 000–5 000 yr BP). To cite this article: É. Chaumillon et al., C. R. Geoscience 334 (2002) 119–126.  相似文献   

Climatic and oceanographic changes in the Northeast Atlantic reflected by magnetic properties of sediments deposited on the Portuguese Margin during the last 340 ka   总被引：1，自引：0，他引：1  

Eva Moreno  Nicolas Thouveny  Doriane DelangheI.Nick McCave  Nick J Shackleton 《Earth and Planetary Science Letters》2002,202(2):465-480

Rock magnetic parameters measured along two giant piston cores MD95-2040 (40°34′N, 9°51′W) and MD95-2042 (37°47′N, 10°09′W) collected off the Portuguese Margin, related to other proxy-climatic data, have been used to reconstruct magnetic mineralogical changes of, in relation to environmental and climatic conditions over the North Atlantic, Western Europe and Northwest Africa during the last three climatic cycles (since isotope stage 10). Thin discrete layers containing coarse grains of titano-magnetite are associated with events of iceberg discharge during Heinrich events 1-6 [Heinrich, Quat. Res. 29 (1988) 142] that have equivalent events in isotope stages 5-8. Concentrations of fine-grained (Ti-) magnetite and hematite/goethite, varying in phase opposition, are directly linked with alternations of cold and warm climatic periods. Spectral analyses of the rock magnetic signals reveal Milankovitch periods at 100 and 41 ka, confirming the relationship with long-term climatic changes at high latitudes. The nature (Ti-magnetite) and size range of the finest ferrimagnetic fraction as well as its variation, suggest a control by deep currents carrying a colloidal/clayey fraction from remote sources (Iceland, Faeroes, mid-Atlantic Ridge). Variation of hematite/goethite contents is linked with transport by rivers and winds from the neighbouring continent. A tight correlation with the D-O cycles in Greenland ice records confirms that North Atlantic oceanic regimes and continental wind regimes were strongly influenced by millennial scale climatic changes throughout the last 350 ka.  相似文献   

Delineation of Sandstone Reservoir Flow Zones in the Central Bredasdorp Basin,South Africa,Using Core Samples     

Opuwari  Mimonitu  Magoba  Moses  Dominick  Nehemiah  Waldmann  Nicolas 《Natural Resources Research》2021,30(5):3385-3406

Natural Resources Research - This study aims to introduce a conceptual petrophysical flow zonation scheme for Valanginian age gas-bearing reservoirs in the Bredasdorp Basin, offshore of South...  相似文献   

Multi-technique monitoring of ocean tide loading in northern France     

Muriel Llubes  Nicolas Florsch  Jean-Paul Boy  Martine Amalvict  Pascal Bonnefond  Marie-Noëlle Bouin  Stphane Durand  Marie-France Esnoult  Pierre Exertier  Jacques Hinderer  Marie-Franoise Lalancette  Frdric Masson  Laurent Morel  Joëlle Nicolas  Mathilde Vergnolle  Guy Wppelmann 《Comptes Rendus Geoscience》2008,340(6):379-389

We have organised afield study of ocean tide loading in the northwestern part of France, where tidal amplitudes are known to be among the highest in the world. GPS and gravimetric techniques have already proved their capability to measure such weak and high-frequency signals. In this study, these classical observations are complemented with less usual techniques, such as tiltmeter and Satellite Laser Ranging (SLR) measurements. We present here the preliminary results for a common period of observations spanning from 12–19 May 2004. Additional measurements from the French Transportable Laser Ranging Station (FTLRS) were available during September and October 2004. Observation residuals are computed as the difference between the observed and the predicted time signals. We obtain small RMS residuals for GPS measurements (2.5/3.1/4.5 mm for the eastward, northward and upward components), for absolute and relative gravimetry (9 nm/s² and 13 nm/s²) and for tiltmeters (0.05 μrad for EW component). We also fit the amplitude of the main M2 tidal constituent to FTLRS observations and we find a value of 3.731 cm, which is comparable to the theoretical value.  相似文献   

Large wood potential,piece characteristics,and flood effects in Swiss mountain streams     

Christian Rickli  Alexandre Badoux  Dieter Rickenmann  Nicolas Steeb  Peter Waldner 《自然地理学》2018,39(6):542-564

We present results of two studies on the (1) potential wood load in steep headwater streams and (2) properties of large wood (LW) transported in mountain rivers during the large August 2005 flood event in Switzerland. Ten headwater reaches of 1000 m length were surveyed in different regions of Switzerland. The potential wood load was estimated for in-channel deadwood, and possible driving factors were explored. Correlations were found with dead wood volume on hillslopes and mean channel width. We established size distributions of LW pieces and identified probable recruitment processes. Four reaches were resurveyed after an exceptionally severe flood in August 2005, showing limited LW transport in channels but considerable wood input by mass wasting processes. In addition, characteristics of deposits of LW along mountain rivers affected by the 2005 flood were investigated. Diameter and length distribution of transported and deposited pieces were comparable to those of LW from steep headwater streams, yet with considerably fewer long pieces in the deposits of mountain rivers. Most LW pieces were fresh wood, indicating that the portion of in-channel deadwood transported during the 2005 flood was limited. Findings of the study contribute to a better understanding of LW dynamics in Alpine mountain streams.  相似文献   

Integrated 3D forward stratigraphic and petroleum system modeling of the Levant Basin,Eastern Mediterranean     

Jessica Barabasch  Mathieu Ducros  Nicolas Hawie  Samer Bou Daher  Fadi Henri Nader  Ralf Littke 《Basin Research》2019,31(2):228-252

The Eastern Mediterranean Levant Basin is a proven hydrocarbon province with recent major gas discoveries. To date, no exploration wells targeted its northern part, in particular the Lebanese offshore. The present study assesses the tectono‐stratigraphic evolution and related petroleum systems of the northern Levant Basin via an integrated approach that combines stratigraphic forward modeling and petroleum systems/basin modeling based on the previous published work. Stratigraphic modeling results provide a best‐fit realisation of the basin‐scale sedimentary filling, from the post‐rift Upper Jurassic until the Pliocene. Simulation results suggest dominant eastern marginal and Arabian Plate sources for Cenozoic siliciclastic sediments and a significant contribution from the southern Nilotic source mostly from Lower Oligocene to Lower Miocene. Basin modeling results suggest the presence of a working thermogenic petroleum system with mature source rocks localised in the deeper offshore. The generated hydrocarbons migrated through the deep basin within Jurassic and Cretaceous permeable layers towards the Latakia Ridge in the north and the Levant margin and offshore topographic highs. Furthermore, the basin model indicates a possibly significant influence of salt deposition during Messinian salinity crisis on formation fluids. Ultimately, the proposed integrated workflow provides a powerful tool for the assessment of petroleum systems in underexplored areas.  相似文献   

Decision Analysis for Leachate Control at a Fractured Rock Landfill     

Nicolas Lepage  Pascal Hamel  René Lefebvre  René Therrien  Chantale Blais 《Ground Water Monitoring & Remediation》1999,19(3):157-170

The municipal landfill at the Complexe Environnemental de Saint-Michel (CESM) in Montreal, which is the third largest in North America, is located in a former quarry in fractured limestone. Impressive measures are taken to monitor and control biogas and leachate generated at the site. Leachate containment is presently performed with a pumping well completed within the waste. The efficiency of the well in controlling off-site leachate migration is questioned because field observations strongly suggest that the nearby former Francon quarry is diverting local ground water flow. To address this issue, four additional hydraulic control options are considered: (1) increased pumping at the existing waste well; (2) new pumping wells in the rock on the eastern limit of the site; (3) new injection wells in the rock on the eastern limit; and (4) combination of new injection wells at the same location and new water supply wells upgradient of the landfill. We evaluated the four hydraulic control options at the CESM using two coupled models: (1) a decision model based on an objective function weighting the risk, costs, and benefits of each option translated into dollar units; and (2) a numerical ground water flow model to represent the effect of operational conditions and ascertain success. Decision analysis offers a quantitative unbiased tool to evaluate the potential and relative cost of each option, but qualitative considerations and judgment still must be used for a complete evaluation. Our analysis confirms that scenario 4, which was the intuitively favored option, represents the best containment strategy.  相似文献   

Comparison of Electrostatic and Non‐Electrostatic Models for U(VI) Sorption on Aquifer Sediments          下载免费PDF全文

Bhavna Arora  James A. Davis  Nicolas F. Spycher  Wenming Dong  Haruko M. Wainwright 《Ground water》2018,56(1):73-86

A non‐electrostatic generalized composite surface complexation model (SCM) was developed for U(VI) sorption on contaminated F‐Area sediments from the U.S. Department of Energy Savannah River Site, South Carolina. The objective of this study was to test if a simpler, semi‐empirical, non‐electrostatic U(VI) sorption model (NEM) could achieve the same predictive performance as a SCM with electrostatic correction terms in describing U(VI) plume evolution and long‐term mobility. One‐dimensional reactive transport simulations considering key hydrodynamic processes, Al and Fe minerals, as well as H⁺ and U surface complexation, with and without electrostatic correction terms, were conducted. The NEM was first calibrated with laboratory batch H⁺ and U(VI) sorption data on F‐Area sediments, and then the surface area of the NEM was adjusted to match field observations of dissolved U(VI). Modeling results indicate that the calibrated NEM was able to perform as well as the previously developed electrostatic model in predicting the long‐term evolution of H⁺ and U(VI) at the site, given the variability of field‐site data. The electrostatic and NEM models yield somewhat different results for the time period when basin discharge was active; however, it is not clear which modeling approach may be better to model this early time period because groundwater quality data during this period were not available. A key finding of this study is that the applicability of NEM (and thus robustness of its predictions) to the field system evolves with time and is strongly dependent on the pH range that was used to develop the model.  相似文献   

Insights of long-term geomorphological evolution of coastal landscapes in hot-spot oceanic islands     

Nicolas Ferrer-Valero  Luis Hernández-Calvento  Antonio I. Hernández-Cordero 《地球表面变化过程与地形》2019,44(2):565-580

The Canary Islands form a volcanic archipelago in which a west–east (W–E) chain of progressively older and less active islands can be observed. In the Canary Islands, unlike most hot-spot archipelagos, certain geodynamic peculiarities have promoted longer periods of island survival, exceeding 20 Myr. This factor makes these islands a suitable context for this work, which aims to analyze extensively the coastal geomorphic structure on islands with different development states. For this, three islands in different volcanic phases were selected: La Palma (1.8 Myr), Gran Canaria (14.5 Myr) and Fuerteventura (22.6 Myr). An ad hoc landform-based hierarchical taxonomy was designed to analyze the coastal geomorphic structure of the three islands. Based on a multi-sourced analysis in geographic information system (GIS) and field recognition, a comprehensive cartographic database was collected using the coastline data-storing (CDS) method as a feature abundance proxy. Three different aspects of the geomorphological structure were compared and related between the islands: (i) composition, (ii) abundance and (iii) diversity. Through their comparison, we attempt to explore geomorphological aspects of coastal evolution over geological spatiotemporal scales. Composition was explored analyzing the distribution of the feature's longshore frequencies (p). Abundance, by metrics of local abundance (N_∩) and whole density (N_U). Diversity, through four indices: normalized richness (S) and Margalef index (M) to estimate richness; Simpson index (D) and Shannon index (H’) to estimate evenness. We identified a systematic transformation in the dominant landform composition and a systematic trend in increasing geomorphological abundance and diversity from younger to older islands. The results show a long-term structural pattern defined by the increase in coastal geomorphic complexity (abundance and diversity) over geological time, as the coasts evolve from predominantly rocky-erosive to increasingly clastic-depositional environments. This long-term geomorphological pattern may be a general aspect of hot-spot island archipelagos, which can bring a new perspective to the knowledge of their coastal evolution. © 2018 John Wiley & Sons, Ltd.  相似文献