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91.
Chesil Beach (Dorset) is one of the most famous coastal landforms on the British coast. The gravel beach is over 18 km long and is separated for much of its length from land by a tidal lagoon known as The Fleet. The beach links the Isle of Portland in the east to the mainland in the west. Despite its iconic status there is little available information on its internal geometry and evolutionary history. Here we present a three-fold model for the evolution of Chesil Beach based on a series of nine ground penetrating radar (GPR) traverses located at three sites along its length at Abbotsbury, Langton Herring and at Ferry Bridge. The GPR traverses reveal a remarkably consistent picture of the internal structure of this barrier beach. The first phase of evolution involves the landward transgression of a small sand and gravel beach which closed upon the coast leading to deposition of freshwater peat between 5 and 7 k yr BP. The second evolutionary phase involves the ‘bulking-out’ of the beach during continued sea level rise, but in the presence of abundant gravel supplied by down-drift erosion of periglacial slope deposits. This episode of growth was associated with a series of washover fans which accumulated on the landward flank of the barrier increasing its breadth and height but without significant landward transgression of the barrier as a whole. The final phase in the evolution of Chesil Beach involves the seaward progradation of the beach crest and upper beach face associated with continued sediment abundance, but during a still-stand or slight fall in relative sea level. This phase may provide further evidence of a slight fall in relative sea level noted elsewhere along the South Coast of Britain and dated to between 1.2 and 2.4 k yr BP. Subsequently the barrier appears to have become largely inactive, except for the reworking of sediment on the beach face during storm events. The case study not only refines the evolutionary picture of Chesil Beach, but illustrates the importance of the subtle interplay between relative sea level and sediment supply in the evolution of a barrier system. In addition, it also illustrates the potential of GPR in resolving the evolutionary history of gravel-rich coastal landforms such as Chesil Beach.  相似文献   
92.
Trace and minor elements in sphalerite: A LA-ICPMS study   总被引:18,自引:0,他引:18  
Sphalerite is an important host mineral for a wide range of minor and trace elements. We have used laser-ablation inductively coupled mass spectroscopy (LA-ICPMS) techniques to investigate the distribution of Ag, As, Bi, Cd, Co, Cu, Fe, Ga, Ge, In, Mn, Mo, Ni, Pb, Sb, Se, Sn and Tl in samples from 26 ore deposits, including specimens with wt.% levels of Mn, Cd, In, Sn and Hg. This technique provides accurate trace element data, confirming that Cd, Co, Ga, Ge, In, Mn, Sn, As and Tl are present in solid solution. The concentrations of most elements vary over several orders of magnitude between deposits and in some cases between single samples from a given deposit. Sphalerite is characterized by a specific range of Cd (typically 0.2-1.0 wt.%) in each deposit. Higher Cd concentrations are rare; spot analyses on samples from skarn at Baisoara (Romania) show up to 13.2 wt.% (Cd2+ ↔ Zn2+ substitution). The LA-ICPMS technique also allows for identification of other elements, notably Pb, Sb and Bi, mostly as micro-inclusions of minerals carrying those elements, and not as solid solution. Silver may occur both as solid solution and as micro-inclusions. Sphalerite can also incorporate minor amounts of As and Se, and possibly Au (e.g., Magura epithermal Au, Romania). Manganese enrichment (up to ∼4 wt.%) does not appear to enhance incorporation of other elements. Sphalerite from Toyoha (Japan) features superimposed zoning. Indium-sphalerite (up to 6.7 wt.% In) coexists with Sn-sphalerite (up to 2.3 wt.%). Indium concentration correlates with Cu, corroborating coupled (Cu+In3+) ↔ 2Zn2+ substitution. Tin, however, correlates with Ag, suggesting (2Ag+Sn4+) ↔ 3Zn2+ coupled substitution. Germanium-bearing sphalerite from Tres Marias (Mexico) contains several hundred ppm Ge, correlating with Fe. We see no evidence of coupled substitution for incorporation of Ge. Accordingly, we postulate that Ge may be present as Ge2+ rather than Ge4+. Trace element concentrations in different deposit types vary because fractionation of a given element into sphalerite is influenced by crystallization temperature, metal source and the amount of sphalerite in the ore. Epithermal and some skarn deposits have higher concentrations of most elements in solid solution. The presence of discrete minerals containing In, Ga, Ge, etc. also contribute to the observed variance in measured concentrations within sphalerite.  相似文献   
93.
Constraining the speed of sea level rise at the start of an interglacial is important to understanding the size of the ‘window of opportunity’ available for hominin migration. This is particularly important during the last interglacial when there is no evidence for significant hominin occupation anywhere in Britain. There are very few finer grained fossiliferous sequences in the Channel region that can be used to constrain sea level rise and they are preserved only to the north of the Channel, in England. Of these, the sequence at Stone Point SSSI is by far the most complete. Data from this sequence has been previously reported, and discussed at a Quaternary Research Association Field Meeting, where a number of further questions were raised that necessitated further data generation. In this paper, we report new data from this sequence – thin section analysis, isotopic determinations on ostracod shells, new Optical Stimulated Luminescence ages and Amino Acid Recem analyses. These show early sea level rise in this sequence, starting during the pre-temperate vegetation zone IpI, but no early warming. The implications of this almost certainly last interglacial sequence for the human colonisation of Britain and our understanding of the stratigraphic relationship of interglacial estuarine deposits with their related fluvial terrace sequences is explored.  相似文献   
94.

Background

Hydrogen is known to occur in the groundwaters of some ancient cratons. Where associated gases have been dated, their age extends up to a billion years, and the hydrogen is assumed also to be very old. These observations are interpreted to represent the radiolysis of water and hydration reactions and migration of hydrogen into fracture systems. A hitherto untested implication is that the overwhelming bulk of the ancient low-permeability basement, which is not adjacent to cross-cutting fractures, constitutes a reservoir for hydrogen.

Results

New data obtained from cold crushing to liberate volatiles from fluid inclusions confirm that granites and gneiss of Archean and Palaeoproterozoic (>1600 Ma) age typically contain an order of magnitude greater hydrogen in their entrained fluid than very young (<200 Ma) granites. Sedimentary rocks containing clasts of old basement also include a greater proportion of hydrogen than the young granites.

Conclusions

The data support the case for a global reservoir of hydrogen in both the ancient basement and in the extensive derived sediments. These reservoirs are susceptible to the release of hydrogen through a variety of mechanisms, including deformation, attrition to reduce grain size and diagenetic alteration, thereby contributing to the hydrogen required by chemolithoautotrophs in the deep biosphere.
  相似文献   
95.
The structures of two distinctive series of C3n highly branched alkanes (HBAs), previously detected in sedimentary and aquatic extracts, were identified as polypropylene (PP) oligomers with different end groups, using gas chromatography (GC) and mass spectrometry (MS) correlation with diastereoisomeric mixtures of authentic C15 and C18 standards. A C15 member of the earlier eluting series was assigned as 2,4,6,8-tetramethylundecane and a C15 member of the later eluting series as 4,6,8-trimethyldodecane. The C3n HBA GC–MS profiles of extracts from a typical PP GC sample vial lid were also shown to closely match those previously detected in sediment and water extracts, providing convincing evidence that the purported environmental occurrences are a result of PP contamination. Both C3n series correspond to the first eluting diastereoisomer of the respective standards, also consistent with an industrial isotactic PP source. Mass spectra of all five standards are presented to help assignment of new polymethyl alkanes.  相似文献   
96.
The Etendeka Igneous Province in NW Namibia forms the eastern most extent of the Paraná–Etendeka Flood Basalt Province and, despite only covering about 5% of the Paraná–Etendeka, has been the focus of much interest, due to its extremely well exposed nature. The Huab Basin in NW Namibia forms the focus of this study, and formed a connected basin with the Paraná throughout Karoo times (late Palaeozoic) into the Lower Cretaceous. It contains a condensed section of the Karoo deposits, which indicate early periods of extension, and Lower Cretaceous aeolian and volcanic Etendeka deposits, which have their correlatives in the Paraná. In the Huab Basin, the volcanic rocks of the Etendeka Group consists of the Awahab and Tafelberg Formations, which are separated by a disconformity. Detailed examination of the Awahab Formation reveals an additional disconformity, which separates olivine-phyric basalts (Tafelkop-type) from basalt/basaltic andesites (Tafelberg-type) marking out a shield volcanic feature which is concentrated in an area to the SE of the Huab River near to the Doros igneous centre. Early volcanism consisted of pahoehoe style flows of limited lateral extent, which spilled out onto aeolian sands of an active aeolian sand sea 133 million years ago. This sand sea is equivalent to the sands making up the Botucatu Formation in the Paraná basin. The early expression of flood volcanism was that of laterally discontinuous, limited volume, pahoehoe flows of Tafelkop-type geochemistry, which interleaved with the aeolian sands forming the Tafelkop–Interdune Member basalts. These basalts are on-lapped by more voluminous, laterally extensive, basalt/basaltic andesite flows indicating a step-up in the volume and rate of flood volcanism, leading to the preservation of the shield volcanic feature. These geochemically distinct basalts/basaltic andesites form the Tsuhasis Member, which are interbeded with the Goboboseb and Sprinkbok quartz latite flows higher in the section. The Tsuhasis Member basalts, which form the upper parts of the Awahab Formation, are of Tafelberg-type geochemistry, but are stratigraphically distinct from the Tafelberg lavas, which are found in the Tafelberg Formation above. Thus, the internal stratigraphy of the flood basalt province contains palaeo-volcanic features, such as shield volcanoes, and other disconformities and is not that of a simple layer-cake model. This complex internal architecture indicates that flood volcanism started sporadically, with low volume pahoehoe flows of limited lateral extent, before establishing the more common large volume flows typical of the main lava pile.  相似文献   
97.
Geochronological investigations in high- and ultra-high-pressure metamorphic rocks are problematic since firstly the low temperatures lead to fine grain size and disequilibrium assemblages, and secondly the problem of “excess argon” affects 40Ar-39Ar systematics, the most commonly used isotopic system. The Tavsanli Zone is a belt of high-pressure low-temperature (HP-LT) rocks spanning NW Turkey and is one such region where previous geochronological studies have produced a range of estimates for the age of HP-LT metamorphism, raising the question of whether they are geologically significant. This study presents new data from the Tavsanli Zone; 40Ar-39Ar ages are in the range 60 Ma to 175 Ma, whilst Rb-Sr ages are restricted to 79.7 Ma to 82.8 Ma, confirming the presence of excess argon. Detailed ultra-violet laser ablation microprobe (UVLAMP) studies have revealed younger 40Ar-39Ar ages in the cores of coarser white micas, which in conjunction with 40Ar-39Ar ages from the finest grained lithologies and the Rb-Sr white mica crystallisation ages, constrain the post-HP-LT metamorphism exhumation rates of these rocks. Petrological and regional constraints suggest that syn-subduction exhumation and cooling took place initially by synchronous subduction and exhumation by underplating. This is followed by a phase of syn-continent-continent collision at a rate of approximately 1.5 mma−1 and exhumation to the surface via thrusting. The 40Ar-39Ar hornblende data from a granodiorite intruding the HP-LT rocks constrain the later parts of exhumation path. This study highlights the importance of a multi-system geochronological approach when attempting to determine the history of HP-LT rocks. Received: 12 May 1998 / Accepted: 21 April 1999  相似文献   
98.
In terminal fluvial-fan systems, characteristic proximal to distal variations in sedimentary architectures are recognized to arise from progressive downstream loss of water discharge related to both infiltration and evaporation. This work aims to elucidate downstream trends in facies and architecture across the medial and distal zones of terminal-fan systems, which record transitions from deposits of channel elements to lobe-like and sheet-like elements. This is achieved via a detailed characterization of ancient ephemeral fluvial deposits of the well-exposed Kimmeridgian Tordillo Formation (Neuquén Basin, Argentina). The fine sand-prone and silt-prone succession associated with the medial to distal sectors of the system has been studied to understand relationships between depositional processes and resulting architectures. Facies and architectural-element analyses, and quantification of resulting sedimentological data at multiple scales, have been undertaken to characterize sedimentary facies, facies transitions, bed types, architectural elements and larger-scale architectural styles. Eight bed types with distinct internal facies transitions are defined and interpreted in terms of different types of flood events. Channelized and non-channelized architectural elements are defined based on their constituent bed types and their external geometry. The most common elements are terminal lobes, which are composite bodies within which largely unconfined sandy deposits are stacked in a compensational manner; a hierarchical arrangement of internal components is recognized. Proximal feeder-channel avulsion events likely controlled the evolution of terminal-lobe elements and their spatiotemporal shifts. Stratigraphic relations between architectural elements record system-wide trends, whereby a proximal sector dominated by channel elements passes downstream via a gradational transition to a medial sector dominated by sandy terminal-lobe elements, which in turn passes further downstream to a distal sector dominated by silty terminal lobe-margin and fringing deposits. This work enhances current understanding of the stratigraphic record of terminal fluvial systems at multiple scales, and provides insight that can be applied to predict the facies and architectural complexity of terminal fluvial successions.  相似文献   
99.
The velocity of overland flow has been conventionally measured using tracers, but it is difficult to measure the mean flow velocity directly because the centroid of the tracer plume is not easily identified. Consequently, previous investigators have measured the velocity of the leading edge of the plume and multiplied it by a correction factor α to obtain an estimate of mean velocity. An alternative method is to measure the velocity of the peak concentration in the tracer plume and multiply this velocity by another correction factor β to estimate mean velocity. To investigate the controls of α and β and develop predictive models for these correction factors, 40 experiments were performed in a flume with a mobile sand bed. Multiple regression analyses reveal that both α and β vary inversely with slope and directly with Reynolds number. The derived regression equations may be used to calculate the mean velocity of other shallow overland flows, at least within the range of slope and Reynolds number for which the equations were developed. In the experiments, slope ranged from 2.7;° to 10° and Reynolds number from 1900 to 12 600.  相似文献   
100.
The number of crop genebanks, designed to conserve crop genetic resources and make them available to breeders, has risen dramatically in recent years. While few dispute the need to conserve crop germplasm to help boost and sustain agricultural productivity, the role of genebanks and their global distribution has become embroiled in controversy. Some suggest that genebanks are servicing mainly multinational seed companies and that industrial countries harbor the lion's share of crop germplasm collections. This article describes the importance of genebanks, analyzes their distribution and beneficiaries, and outlines how geographers can become more involved in the conservation and use of crop genetic resources.  相似文献   
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