Corrigendum to “High-resolution seismic stratigraphy of the late Neogene of the central sector of the Colombian Pacific continental shelf: A seismic expression of an active continental margin” [J. S. Am. Earth. Sci. Volume 31 (2011) p. 28–44]     

Jaime Orlando Martínez  Eduardo López Ramos 《Journal of South American Earth Sciences》2011,31(2-3):342-343

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Production of amorphous hydrated impure magnesium carbonate through ex situ carbonation     

Andrea Orlando  Matteo Lelli  Luigi Marini 《Applied Geochemistry》2012

The evaluation of the feasibility of ex situ carbonation in landfills utilizing raw natural substances (namely serpentinites as Mg-source and the CO₂-rich fraction of biogas as C-source) was tested through a laboratory procedure comprising three steps. The first step is the acid attack of a serpentinite at 70 °C, by means of HCl 2 M, to get MgCl₂-rich solutions. Attacks of different durations were performed to evaluate the time needed. The second step is the neutralization of the MgCl₂-rich solution by addition of concentrated ammonia. The third (carbonation) step is mixing of the neutralized MgCl₂-rich solution with a solution of ammonium carbonate. This was produced in a landfill by absorption of CO₂ contained in biogas in a solution of ammonia. The neutralization of acid MgCl₂-rich solutions caused the precipitation of ferrihydrite with secondary ammonium carnallite and salammoniac, whereas abundant precipitation of Amorphous Hydrated Impure Magnesium Carbonate (AHIMC), sometimes with minor nesquehonite, occurred in the third step. This solid carbonate acts as a stable CO₂ sink up to 380 °C. The geochemical behavior of some minor elements was also investigated during the experimental processes revealing that Al, Cr and Ni were removed during neutralization (second step), in contrast to Ca which remained in the circumneutral MgCl₂-rich solution and entered into the structure of AHIMC. During the carbonation step, precipitation of artinite, hydromagnesite, lansfordite, magnesite and nesquehonite was thermodynamically impossible as the aqueous phase was undersaturated with respect to these solid phases upon separation of AHIMC.  相似文献   

Surface and groundwater pollution by organochlorine compounds in a typical soybean system from the south Pampa,Argentina   总被引：3，自引：0，他引：3  

Mariana Gonzalez  Karina S. B. Miglioranza  Valeria M. Shimabukuro  Orlando M. Quiroz Londoño  Daniel E. Martinez  Julia E. Aizpún  Víctor J. Moreno 《Environmental Earth Sciences》2012,65(2):481-491

Organochlorine pesticides (OCPs) use has been restricted or forbidden in Argentina since 1998 and technical endosulfan is the last currently used OCPs on the soybean-wheat production. As they persist in soil for several years after application, OCPs constitute a source of environmental pollution. This work aims to assess OCPs contamination of groundwater (Gw) and streamwater (Sw) in the Quequén Grande River watershed from south Argentinean Pampas in relation to the hydrogeological characteristics. OCPs were analyzed in Sw, Gw, surface bottom sediments, soils and borehole cutting sediments (Cs) by gas chromatograph-electron capture detector. Pesticide distribution in Cs was dependent on the characteristic of the non-saturated zone. Leached pesticides over 3 m in Cs showed the pattern: HCHs = endosulfan > chlordanes > DDTs, and from 3 to 6 m heptachlor was the main group as a consequence of the past use of this compound in the area, mainly on potato crops. Endosulfan reaches Gw during application season as well as during flooding events while a retard effect was observed for Sw. Levels of α- and β-isomers were in certain cases above national (7 ng L⁻¹) and international (3 ng L⁻¹) limits for aquatic biota protection. As the endosulfan sulfate metabolite was present in Gw and Sw and due to its high toxicity, it should be considered in the establishment of water quality criteria for human and environmental protection.  相似文献   

The chemical nature of Europa surface material and the relation to a subsurface ocean     

Thomas M. Orlando  Thomas B. McCord 《Icarus》2005,177(2):528-533

The surface composition of Europa is of special interest due to the information it might provide regarding the presence of a subsurface ocean. One source of this information is the infrared reflectance spectrum. Certain surface regions of Europa exhibit distorted H₂O vibrational overtone bands in the 1.5 and 2.0 μm region, as measured by the Galileo mission Near Infrared Mapping Spectrometer (NIMS). These bands are clearly the result of highly concentrated solvated contaminants. However, two interpretations of their identity have been presented. One emphasizes hydrated salt minerals and the other sulfuric acid, although each does not specifically rule out some of the other. It has been pointed out that accurate chemical identification of the surface composition must depend on integrating spectral data with geochemical models, and information on the tenuous atmosphere sputtered from the surface. It is also extremely important to apply detailed chemistry when interpreting the spectral data, including knowledge of mineral dissolution chemistry and the subsequent optical signatures of ion solvation in low-temperature ice. We present studies of flash frozen acid and salt mixtures as Europa surface analogs and demonstrate that solvated protons, metal cations and inorganic anions all influence the spectra and must all, collectively, be considered when assigning Europa spectral features. These laboratory data show best correlation with NIMS Europa spectra for multi-component mixtures of sodium and magnesium bearing sulfate salts mixed with sulfuric acid. The data provide a concentration upper bound of 50-mol% for MgSO₄ and 40-mol% for Na₂SO₄. This newly reported higher sodium and proton content is consistent with low-temperature aqueous differentiation and hydrothermal processing of carbonaceous chondrite-forming materials during the formation and early evolution of Europa.  相似文献   

Seismic response of masonry-infilled steel frames via multi-scale finite-element analyses     

Federico Margiacchi  Luca Salvatori  Maurizio Orlando  Mario De Stefano  Paolo Spinelli 《Bulletin of Earthquake Engineering》2016,14(12):3529-3546

Effects of masonry infills on the seismic vulnerability of steel frames is studied through multi-scale numerical modelling. First, a micro-modelling approach is utilized to define a homogenized masonry material, calibrated on experimental tests, which is used for modelling the nonlinear response of a one-story, single span, masonry-infilled portal under horizontal loads. Based on results of the micro-model, the constitutive behavior of a diagonal strut macro-element equivalent to the infill panel is calibrated. Then, the diagonal strut is used to model infill panels in the macro-scale analysis of a multi-span multi-story infilled moment-resisting (MR) steel frame. The seismic vulnerability of the MR frame is evaluated through a nonlinear static procedure. Numerical analyses highlight that infills may radically modify the seismic response and the failure mechanism of the frame, hence the importance of the infill correct modelling.  相似文献   

Displacement capacity of masonry piers: parametric numerical analyses versus international building codes   总被引：1，自引：1，他引：0  

Maurizio Orlando  Luca Salvatori  Paolo Spinelli  Mario De Stefano 《Bulletin of Earthquake Engineering》2016,14(8):2259-2271

The nonlinear behaviour of masonry piers loaded in their plane is investigated by parametric numerical simulations. Each pier has a cantilever scheme, is loaded by a constant axial load and is subjected to an increasing horizontal displacement at the top. The macro-modelling approach is used to perform numerical analyses, adopting two different constitutive laws: a total strain crack model and a plastic model. The numerical model is calibrated on a block-masonry type for which experimental tests are available in literature. Parametric numerical simulations are performed by varying the aspect-ratio and the compression level, in order to assess the influence of such parameters on both shear strength and displacement capacity. By comparing numerical results with formulas of international codes, a good agreement for the shear strength is obtained, while significant differences are observed for the displacement capacity, which is influenced by both parameters. The authors propose a simple empirical formula for the displacement capacity, obtained by fitting the numerical results. The expression can be useful in the practical design for considering the influence of aspect-ratio and compression level, currently neglected by building codes.  相似文献   

Seismic reliability analysis of buildings with torsional eccentricities          下载免费PDF全文

Yasser Picazo  Orlando Diaz Lopez  Luis Esteva 《地震工程与结构动力学》2015,44(8):1219-1234

A study is presented of the influence of stiffness and strength eccentricities on the inelastic torsional response of buildings under the action of two simultaneous orthogonal horizontal ground motion components. Asymmetric buildings were obtained from their respective symmetric systems and were characterized by their stiffness and strength torsional eccentricities in both orthogonal directions. Based on the results of inelastic response of both building types (symmetric and asymmetric), the seismic reliability functions are determined for each system, and their forms of variation with different global system parameters are evaluated. Illustrative examples are presented about the use of this information for the formulation of seismic design criteria for in‐plan asymmetric multistory systems, in order to attain the same reliability levels implicit for symmetric systems designed in accordance with current seismic design codes. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

An MSSS-preconditioned matrix equation approach for the time-harmonic elastic wave equation at multiple frequencies     

M. Baumann  R. Astudillo  Y. Qiu  E. Y. M. Ang  M. B. van Gijzen  R.-É. Plessix 《Computational Geosciences》2018,22(1):43-61

In this work, we present a new numerical framework for the efficient solution of the time-harmonic elastic wave equation at multiple frequencies. We show that multiple frequencies (and multiple right-hand sides) can be incorporated when the discretized problem is written as a matrix equation. This matrix equation can be solved efficiently using the preconditioned IDR(s) method. We present an efficient and robust way to apply a single preconditioner using MSSS matrix computations. For 3D problems, we present a memory-efficient implementation that exploits the solution of a sequence of 2D problems. Realistic examples in two and three spatial dimensions demonstrate the performance of the new algorithm.  相似文献   

Active hydrothermal fluids circulation triggering small-scale collapse events: the case of the 2001–2002 fissure in the Lakki Plain (Nisyros Island,Aegean Sea,Greece)     

Stefania Venturi  Franco Tassi  Orlando Vaselli  Georges E. Vougioukalakis  Heba Rashed  Christos Kanellopoulos  Chiara Caponi  Francesco Capecchiacci  Jacopo Cabassi  Andrea Ricci  Luciano Giannini 《Natural Hazards》2018,90(2):601-621

Rip currents are fast moving, offshore flows that have the ability to move even the strongest swimmers into deeper waters. Miami Beach, Florida is one of the most visited beaches in the USA and a sought after destination for citizens and international tourists alike. It is also known to be a rip current “hot spot.” These factors greatly increase the risk of drowning; however, no previous research has focused on beachgoer perception of rip-related risks in South Florida. Over a 12-month period, 203 public surveys were collected to determine the rip current knowledge of beachgoers at Miami Beach based on factors such as swimming ability and frequency of beach visits. The responses were analyzed by constructing a normalized component factor to determine the respondent’s comprehensive knowledge of rips, and multiple regression models were used to assess the net influences of sociodemographic and behavioral characteristics on the responses. A significant proportion of the survey respondents showed insufficient knowledge, indicating they are at risk of drowning in a rip current. Frequent beachgoer’s exposure to the beach environment, maturation, and nativity is identified as the main contributors to knowledge net of other sociodemographic compositions. The most at-risk groups were determined to be young adults, foreign tourists, poor swimmers, and those who infrequently visited the beach. Miami Beach needs to initiate a rip current safety campaign to target these at-risk beachgoers, where interventions beyond familial and educational institutions should be introduced.  相似文献   

Comparison of soil bacterial communities associated with actinorhizal, non-actinorhizal plants and the interspaces in the sclerophyllous matorral from Central Chile in two different seasons     

F. Farías  J. Orlando  L. Bravo  R. Guevara  M. Carú   《Journal of Arid Environments》2009,73(12):1117-1124

The spatial heterogeneity of resources in desert and semi-arid shrubland appears to be important in determining higher soil bacteria abundance around plants than in soil without plant cover. Thus, these bacterial communities could be important contributors to nutrient cycling in arid ecosystems. Bacterial diversity from Chilean sclerophyllous matorral was determined by Terminal Restriction Fragment Length Polymorphism (T-RFLP). Soil samples associated with the actinorhizal plant Colletia hystrix, non-actinorhizal plants and interspace soil without plant cover, were collected in May and October. The non-actinorhizal and interspace soil differed significantly in their potassium content in May and pH in October. The T-RFLP analysis revealed differences in the bacterial community structure from the different habitats. The soil bacterial communities associated with plants were the most similar, whereas the interspace soil community differed in both sampling times. The factors that best explained the groupings were potassium and pH. The greatest diversity was observed in the interspace soil. The Microbial Community Analysis showed a significant proportion of T-RFs identified as Firmicutes and Proteobacteria. Likewise, spatial and temporal differences were observed in the main groups' abundance. The dominance of Firmicutes suggests that the sclerophyllous matorral could be a different ecosystem to other arid and semi-arid soils with respect to the bacterial community structure.  相似文献