Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy   总被引：74，自引：0，他引：74  

Paula G. Coble 《Marine Chemistry》1996,51(4):325-346

High-resolution fluorescence spectroscopy was used to characterize dissolved organic matter (DOM) in concentrated and unconcentrated water samples from a wide variety of freshwater, coastal and marine environments. Several types of fluorescent signals were observed, including humic-like, tyrosine-like, and tryptophan-like. Humic-like fluorescence consisted of two peaks, one stimulated by UV excitation (peak A) and one by visible excitation (peak C). For all samples, the positions of both excitation and emission maxima for peak C were dependent upon wavelength of observation, with a shift towards longer wavelength emission maximum at longer excitation wavelength and longer wavelength excitation maximum at longer emission wavelength. A trend was observed in the position of wavelength-independent maximum fluorescence () for peak C, with maximum at shorter excitation and emission wavelengths for marine samples than for freshwater samples. Mean positions of these maxima were: rivers = nm; coastal water = nm; marine shallow transitional = nm; marine shallow eutrophic = nm; and marine deep = nm. Differences suggest that the humic material in marine surface waters is chemically different from humic material in the other environments sampled. These results explain previous conflicting reports regarding fluorescence properties of DOM from natural waters and also provide a means of distinguishing between water mass sources in the ocean.  相似文献   

Reconstruction of total annual rainfall in Andalusia (Southern Spain) during the 16th and 17th centuries from documentary sources     

F. S. Rodrigo  M. J. Esteban Parra  Y. Castro Diez 《Theoretical and Applied Climatology》1995,52(3-4):207-218

Summary This study describes a reconstruction of rainfall characteristics in Southern Spain from 1501 to 1700 AD, during the beginning of the period called the Little Ice Age. Weather information was taken from original documentary sources (urban annals, local and religious histories, municipal documents, relations, etc.) in the region. A numerical index was established to characterize the rainfall, its characteristics, evolution and geographical distribution. Results were characteristics compared with modern precipitation data and with the results of other studies of historical climate. The general conclusion is that rainfall in Western Andalusia increased from approximately 1550 to 1650 AD. Some perspectives for future research work are outlined.With 6 Figures  相似文献   

Potential for irradiation of methane to form complex organic molecules in impact craters: Implications for Mars, Titan and Europa     

John Parnell  Martin Baron  Paula Lindgren 《Journal of Geochemical Exploration》2006,89(1-3):322

The release of methane from crater sites following meteorite impact is a possible consequence of the thermal alteration of organic matter, or tapping of reservoired gas of biogenic or abiogenic origin. At least the latter is feasible on Mars. Methane and higher hydrocarbons are susceptible to polymerization and precipitation by radioactive minerals. Where such minerals are present in impact target rocks, the craters can be a preferred site for carbon concentration, and the formation of complex organic molecules. On icy bodies, such as Titan and Europa, methane released by impact could be a fuel for prebiotic chemistry involving other forms of irradiation.  相似文献   

Erratum to “Petrographic criteria for fluid mobility of graphitic carbon in terrestrial and extraterrestrial samples” [J. Geochemical Exploration 89 (2006) 235–238]     

Paula Lindgren  John Parnell 《Journal of Geochemical Exploration》2006,91(1-3)

  相似文献   

Near Wall Flow over Urban-like Roughness   总被引：3，自引：35，他引：3  

Hong Cheng  Ian P. Castro 《Boundary-Layer Meteorology》2002,104(2):229-259

In this study, comprehensive measurements over a number of urban-type surfaces with the same area density of 25% have been performed in a wind tunnel. The experiments were conducted at a free stream velocity of 10 m s^-1 and the main instrumentation was 120 ° x-wire anemometry, but measurement accuracy was checked using laser Doppler anemometry.The results haveconfirmed the strong three-dimensionalityof the turbulent flow inthe roughness sublayer and the depths of the inertial sublayer (log-law region) and roughness sublayer for each surface have been determined. Spatial averaging has been used to remove the variability of the flow in the roughness sublayer due to individual obstacles and it is shown that the spatially averaged mean velocity in the inertial sublayer and roughness sublayer can,together, be described by a single log-law with a mean zero-plane displacement and roughness length for the surface, provided that the proper surface stress is known. The spatially averaged shear stresses in the inertial sublayer and roughness sublayer are compared with the surface stress deduced from form drag measurements on the roughness elements themselves.The dispersive stress arising from the spatial inhomogeneity in the mean flow profiles was deduced from the data and is shown to be negligible compared with the usual Reynolds stresses in the roughness sublayer. Comparisons have been made between a homogeneous (regular element array) surface and one consisting of random height elements of the same total volume. Although the upper limits of the inertial sublayer for both surfaces were almost identical at equivalent fetch, the roughness sublayer was much thicker for the random surface than for the uniform surface, the friction velocity and the roughness length were significantly larger and the `roughness efficiency' was greater. It is argued that the inertial sublayer may not exist at all in some of the more extreme rough urban areas. These results will provide fundamental information for modelling urban air quality and forecasting urban wind climates.  相似文献   

Near-Wall Flow Development After A Step Change In Surface Roughness     

H. Cheng  Ian P. Castro 《Boundary-Layer Meteorology》2002,105(3):411-432

An experimental study of the initial flow field downstream of a step change in surface roughness is presented. The roughness length of the downstream surface was approximately tenfold that of the upstream roughness and, unlike all previous studies, attention was concentrated on the roughness sublayer region beneath the inertial (log-law) region. The experiments were conducted at a boundary layer Reynolds number of about 6 × 10⁴ (based on layer thickness andfree-stream velocity) and around a longitudinal location where the (downstream) roughness length, z_o2, was about 1% of the boundary-layer thickness atthe roughness change point.The thickness of the roughness sublayer was found for the two roughness. It was observed that the vertical profiles of mean velocity and turbulence characteristics started to show similarity after about 160z₀₂ downstream of the roughness change. The presence of a shear stress overshoot is shown to depend strongly on the precise location (with respect to the roughness elements) at which the measurements are made and the thickness of the equilibrium layer is shown to be very sensitive to the way it is defined. It is demonstrated that the growing equilibrium layer has first to encompass the roughness sublayer before any thickness of inertial sublayer can be developed. It follows that, in somepractical cases, like flows across some urban environments, the latter(log-law) region may never exist at all.  相似文献   

Numerical Analysis of Space–Time Finite Element Formulations for Miscible Displacements     

Rigoberto G. Sanabria Castro  Sandra M. C. Malta  Abimael F. D. Loula  Luiz Landau 《Computational Geosciences》2002,5(4):301-330

A finite element formulation is proposed to approximate a nonlinear system of partial differential equations, composed by an elliptic subsystem for the pressure–velocity and a transport equation (convection–diffusion) for the concentration, which models the incompressible miscible displacement of one fluid by another in a rigid porous media. The pressure is approximated by the classical Galerkin method and the velocity is calculated by a post-processing technique. Then, the concentration is obtained by a Galerkin/least-squares space–time (GLS/ST) finite element method. A numerical analysis is developed for the concentration approximation. Then, stability, convergence and numerical results are presented confirming the a priori error estimates.  相似文献   

Simulation of a long-lived meso-β scale convective system over the mediterranean coast of Spain. Part II: Sensitivity to external forcings     

C. Fernández  M. A. Gaertner  C. Gallardo  M. Castro 《Meteorology and Atmospheric Physics》1997,62(3-4):179-200

Summary The numerical simulation of a long-lived, stationary mesoscale convective system (MCS) already described in a previous paper (Fernández et al., 1995) is analyzed in greater detail. The influence of various external forcings, such as sea surface temperature, local orography or terrain roughness, upon the characteristics of the system is studied. This analysis makes it possible not only to identify the most important factors, but also to deduce the importance of some other internal forcings and to propose explanations for some dynamic features of the system that were difficult to understand. Hence, the sensitivity test methodology applied seems to be a useful tool to clarify the complex dynamics of some moist convective events. In the modelled MCS, sea surface temperature and orography are identified as key factors. The results also indicate that the upstream triggering of convection provoked by an orographic blocking effect is the main cause of the development of the system, while upslope triggering plays a secondary role.With 18 Figures  相似文献   

Steady, annual, and monthly recharge implied by deep unconfined aquifer flow     

David W. Ostendorf  Paula L. S. Rees  Shawn P. Kelley  Alan J. Lutenegger 《Journal of Hydrology》2004,290(3-4):259-274

We consider the response of a deep unconfined horizontal aquifer to steady, annual, and monthly recharge. A groundwater divide and a zero head reservoir constrain the aquifer, so that sinusoidal monthly and aperiodic annual recharge fluctuations create transient specific discharge near the reservoir and an unsteady water table elevation inland. One existing and two new long-term data sets from the Plymouth-Carver Aquifer in southeastern Massachusetts calibrate and confirm hydraulic properties in a set of analytical models. [Geohydrology and simulated groundwater flow, 1992] data and a new power law for tritiugenic helium to tritium ratios calibrate the steady recharge that drives the classical parabolic model of steady hydraulics [Applied Hydrogeology, 2001]. Observed water table and gradient fluctuations calibrate the transient recharge models. In the latter regard, monitoring wells within 1 km of Buttermilk Bay exhibit appreciable specific discharge and reduced water table fluctuations. We apply [Trans Am Geophys Union 32(1951)238] periodic model to the monthly hydraulics and a recharge convolution integral [J Hydrol 126(1991)315] to annual flow. An infiltration fraction of 0.79 and a consumptive use coefficient of 1.08×10⁻⁸ m/s °C relate recharge to precipitation and daylight weighted temperature across all three time scales. Errors associated with this recharge relation decrease with increasing time scale.  相似文献   

Assessing land use/cover changes: a nationwide multidate spatial database for Mexico     

Jean-Franois Mas  Alejandro Velzquez  Jos Reyes Díaz-Gallegos  Rafael Mayorga-Saucedo  Camilo Alcntara  Gerardo Bocco  Rutilio Castro  Tania Fernndez  Azucena Prez-Vega 《International Journal of Applied Earth Observation and Geoinformation》2004,5(4):249-261

A nationwide multidate GIS database was generated in order to carry out the quantification and spatial characterization of land use/cover changes (LUCC) in Mexico. Existing cartography on land use/cover at a 1:250,000 scale was revised to select compatible inputs regarding the scale, the classification scheme and the mapping method. Digital maps from three different dates (the late 1970s, 1993 and 2000) were revised, evaluated, corrected and integrated into a GIS database. In order to improve the reliability of the database, an attempt was made to assess the accuracy of the digitalisation procedure and to detect and correct unlikely changes due to thematic errors in the maps. Digital maps were overlaid in order to generate LUCC maps, transition matrices and to calculate rates of conversion. Based upon this database, rates of deforestation between 1976 and 2000 were evaluated as 0.25 and 0.76% per year for temperate and tropical forests, respectively.  相似文献