Study of the Interaction Mechanism in the Biosorption of Copper(II) Ions onto Posidonia oceanica and Peat     

Marta Izquierdo  Paula Marzal  Carmen Gabaldón  Margherita Silvetti  Paola Castaldi 《洁净——土壤、空气、水》2012,40(4):428-437

A systematic approach was used to characterize the biosorption of copper(II) onto two biosorbents, Posidonia oceanica and peat, focusing on the interaction mechanisms, the copper(II) sorption–desorption process and the thermal behavior of the biosorbents. Sorption isotherms at pH 4–6 were obtained and the experimental data were fitted to the Langmuir model with a maximum uptake (q_max) at pH 6 of 85.78 and 49.69 mg g^?1, for P. oceanica and peat, respectively. A sequential desorption (SD) with water, Ca(NO₃)₂, and EDTA was applied to copper‐saturated biosorbents. Around 65–70% copper(II) were desorbed with EDTA, indicating that this heavy metal was strongly bound. The reversibility of copper(II) sorption was obtained by desorption with HCl and SD. Fourier transform IR spectroscopy (FTIR) analysis detected the presence of peaks associated with OH groups in aromatic and aliphatic structures, CH, CH₂, and CH₃ in aliphatic structures, COO^? and COOH groups and unsaturated aromatic structures on the surface of both biosorbents, as well as peaks corresponding to Si? O groups on the surface of peat. The results of SEM‐EDX and FTIR analysis of copper‐saturated samples demonstrated that ion exchange was one of the mechanisms involved in copper(II) retention. Thermal analysis of biosorbent samples showed that copper(II) sorption–desorption processes affected the thermal stability of the biosorbents.  相似文献   

Sediments Quality Assessment of Jacarepaguá Lagoon: The Venue of the 2011 Rock in Rio     

José Tavares Araruna Júnior  Paula Elias Benedetti  Patrício José Moreira Pires  Ricardo Froitzheim Rinelli de Almeida 《洁净——土壤、空气、水》2012,40(9):906-910

In order to aid in the efforts of the 2016 Olympic Games, the organizers of 2011 Rock in Rio decided to build a permanent venue next to the Olympic Park. The area is problematic from the geotechnical point of view since it presents soils with low shear strength, low permeability, and high plasticity, so major soil improvement works were carried out. Bored soil–cement columns were placed to increase soil shear strength and reduce compressibility. A meter thick fill composed of gneiss residual soil was placed and trenches were digged to drain rainwater. However, earlier studies conducted on Jacarepaguá Lagoon have detected the presence of heavy metals in these sediments. In this study, an environmental survey on the Jacarepaguá Lagoon sediments took place in order to choose a place where its sediments could be dredged to be later used in the drainage facilities. The results indicated areas where the threshold level 1 (low probability of adverse effects) issued by the general procedures for sediments quality assessments for dredging purposes, Resolution no 344 of the Brazilian Federal Government, was surpassed. Levels above the limits established for cadmium (Cd), lead (Pb), copper (Cu), nickel (Ni), and zinc (Zn) were detected. Based on this consideration the State Environmental Agency issued a permit allowing the organizers of 2011 Rock in Rio to dredge an area close to City of Rock in order to obtain coarse sediments for the drainage facilities. In addition, it was found that those sediments were ideal for this application since their hydraulic conductivity is on the order of 10^?2 cm/s.  相似文献   

High variability in carbon and nitrogen isotopic discrimination of tropical freshwater invertebrates     

Ana Paula C. de Carvalho  Björn Gücker  Mario Brauns  Iola G. Boëchat 《Aquatic Sciences - Research Across Boundaries》2015,77(2):307-314

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Estimation of the spectral parameter kappa in the region of the Gulf of California,Mexico     

Raúl R. Castro  Lenin Ávila-Barrientos 《Journal of Seismology》2015,19(4):809-829

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An investigation of ensemble-based assimilation of satellite altimetry and tide gauge data in storm surge prediction     

Paula Etala  Martín Saraceno  Pablo Echevarría 《Ocean Dynamics》2015,65(3):435-447

Cyclogenesis and long-fetched winds along the southeastern coast of South America may lead to floods in populated areas, as the Buenos Aires Province, with important economic and social impacts. A numerical model (SMARA) has already been implemented in the region to forecast storm surges. The propagation time of the surge in such extensive and shallow area allows the detection of anomalies based on observations from several hours up to the order of a day prior to the event. Here, we investigate the impact and potential benefit of storm surge level data assimilation into the SMARA model, with the objective of improving the forecast. In the experiments, the surface wind stress from an ensemble prediction system drives a storm surge model ensemble, based on the operational 2-D depth-averaged SMARA model. A 4-D Local Ensemble Transform Kalman Filter (4D-LETKF) initializes the ensemble in a 6-h cycle, assimilating the very few tide gauge observations available along the northern coast and satellite altimeter data. The sparse coverage of the altimeters is a challenge to data assimilation; however, the 4D-LETKF evolving covariance of the ensemble perturbations provides realistic cross-track analysis increments. Improvements on the forecast ensemble mean show the potential of an effective use of the sparse satellite altimeter and tidal gauges observations in the data assimilation prototype. Furthermore, the effects of the localization scale and of the observational errors of coastal altimetry and tidal gauges in the data assimilation approach are assessed.  相似文献   

The role of biogenic structures on the biogeochemical functioning of mangrove constructed wetlands sediments - A mesocosm approach     

Gil Penha-Lopes  Erik Kristensen  Perrine Mangion  José Paula 《Marine pollution bulletin》2010,60(4):560-572

Benthic metabolism (measured as CO₂ production) and carbon oxidation pathways were evaluated in 4 mangrove mesocosms subjected daily to seawater or 60% sewage in the absence or presence of mangrove trees and biogenic structures (pneumatophores and crab burrows). Total CO₂ emission from darkened sediments devoid of biogenic structures at pristine conditions was comparable during inundation (immersion) and air exposure (emersion), although increased 2-7 times in sewage contaminated mesocosms. Biogenic structures increased low tide carbon gas emissions at contaminated (30%) and particularly pristine conditions (60%). When sewage was loaded into the mesocosms under unvegetated and planted conditions, iron reduction was substituted by sulfate reduction and contribution of aerobic respiration to total metabolism remained above 50%. Our results clearly show impacts of sewage on the partitioning of electron acceptors in mangrove sediment and confirm the importance of biogenic structures for biogeochemical functioning but also on greenhouse gases emission.  相似文献   

An atmospheric-to-marine synoptic classification for statistical downscaling marine climate     

Paula Camus  Ana Rueda  Fernando J. Méndez  Iñigo J. Losada 《Ocean Dynamics》2016,66(12):1589-1601

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An OLS regression model for context-aware tile prefetching in a web map cache     

Ricardo García Martín  Juan Pablo de Castro Fernández  Elena Verdú Pérez  María Jesús Verdú Pérez  Luisa María Regueras Santos 《International journal of geographical information science》2013,27(3):614-632

The increasing popularity of web map services has motivated the development of more scalable services in the spatial data infrastructures. Tiled map services have emerged as a scalable alternative to traditional map services. Instead of rendering map images on the fly, a collection of pre-generated image tiles can be served very fast from a server-side cache. However, during the start-up of the service, the cache is initially empty and users experience a poor quality of service. Tile prefetching attempts to improve hit rates by proactively fetching map images without waiting for client requests.

While most popular prefetching policies in traditional web caching consider only the previous access history to make predictions, significant improvements could be achieved in web mapping by taking into account the background geographic information.

This work proposes a regressive model to predict which areas are likely to be requested in the future based on spatial cross-correlation between an unconstrained catalog of geographic features and a record of past cache requests. Tiles that are anticipated to be most frequently requested can be pre-generated and cached for faster retrieval. Trace-driven simulations with several million cache requests from two different nation-wide public web map services in Spain demonstrate that accurate predictions and performance gains can be obtained with the proposed model.  相似文献   

Damage seismic scenarios for Angra do Heroísmo, Azores (Portugal)     

Idalina Veludo  Paula Teves-Costa  Pierre-Yves Bard 《Bulletin of Earthquake Engineering》2013,11(2):423-453

Angra do Heroísmo, located in Terceira Island, is the main town of the Central Group of Azores Archipelago and it is classified as World Heritage by Unesco. The preservation of this patrimony, located inside a seismic region, includes the implementation of a policy to protect it against earthquakes. The development of credible damage scenarios could help this objective, as they can be used in prevention measures to minimize the impact of future earthquakes. Two methods were used for seismic damage estimation: the capacity spectrum method and a new method, based on the direct response of a 1D non-linear oscillator to simulate the building seismic performance. Both methods seem to overestimate the damages for the near sources, but this could be due to the empirical model used to estimate the input ground motion. Comparison with the damage observed after the January 1st, 1980 earthquake show a large discrepancy with an underestimation bias, which can be explained, mainly, by the difference of building performance and on the plausible hypothesis of 2D site effects.  相似文献   

Ionospheric Scintillation and Dynamics of Fresnel-Scale Irregularities in the Inner Region of the Equatorial Ionization Anomaly     

Marcio T. A. H. Muella  Eurico R. de Paula  Alan A. Monteiro 《Surveys in Geophysics》2013,34(2):233-251

This paper reports differences in the occurrence statistics of global positioning system (GPS) L-band scintillations at observational sites located in the inner regions of the northern and southern crests of the equatorial ionization anomaly. Ground-based GPS data acquired at the closed magnetically aligned stations of Manaus (3.1°S; 59.9°W; dip lat. 6.2°N) and Cuiabá (15.5°S; 56.1°W; dip. lat. 6.2°S), Brazil, from December 2001 to February 2007 are used in the analysis. The drift dynamics of Fresnel-scale ionospheric irregularities at the southern station of Cuiabá are also investigated. Only geomagnetically quiet days with the sum of daily Kp < 24 were used in the analysis statistics and in the irregularity drift studies. The results reveal a clear dependence of the scintillation occurrence with the solar activity, but there exists an asymmetry in the percentage of scintillation occurrence between the two stations throughout the period analyzed. The nocturnal occurrence of the scintillations over Cuiabá is predominantly larger than over Manaus, but this scenario seems to change with the decline in the solar activity (mainly during local post-midnight hours). A broad minimum and maximum in the scintillation occurrence appears to occur over both the stations, respectively, during the June solstice (winter) and December solstice (summer) months. The dynamics of the Fresnel-scale irregularities, as investigated from the estimations of the mean zonal drift velocities, reveals that the amplitude of the eastward drifts tends to reduce with the decline in the solar activity. The magnitude of the zonal drift velocities during the December solstice months is larger than during the equinoxes, with the differences being more pronounced at solar maximum years. Other relevant aspects of the observations, with complementary data from a low-latitude ionospheric model, are highlighted and discussed.  相似文献