Composition of the Siberian cratonic mantle: evidence from Udachnaya peridotite xenoliths   总被引：31，自引：0，他引：31  

F. R. Boyd  N. P. Pokhilenko  D. G. Pearson  S. A. Mertzman  N. V. Sobolev  L. W. Finger 《Contributions to Mineralogy and Petrology》1997,128(2-3):228-246

Bulk compositions and mineral analyses for forty-one, large, garnet- and spinel-facies peridotite xenoliths from the Udachnaya kimberlite in the central Siberian platform have many similarities to those of well-studied peridotites from the Kaapvaal craton in southern Africa. Coarse Mg-rich lherzolites and harzburgites with equilibration temperatures below 1000 °C are abundant and are believed to form the principal rock type in the Siberian lithosphere. The low-temperature Udachnaya peridotites have an average mg number [Mg/(Mg+Fe)] of 92.6 with a wide dispersion in modal enstatite, ranging to over 40 wt%. High-temperature peridotites are relatively richer in Fe and Ti and are commonly deformed, with porphyroclastic or mosaic-porphyroclastic textures, some of the latter having fluidized enstatite. The Udachnaya peridotites have experienced late-stage metasomatism before, during and after eruption. Garnets and pyroxenes in many of the high-temperature rocks are zoned, probably by reaction with melt prior to eruption. Virtually all the peridotites contain secondary diopside, inhomogeneous on a micron scale, that mantles primary orthopyroxene. It is believed to have crystallized along with lesser amounts of intergranular calcite and monticellite during eruption. Bulk analyses for total Fe in many specimens are higher than whole-rock Fe calculated from the electron probe analyses and the modes. The magnitude of the difference between the two measurements of total Fe correlates with loss-on-ignition, suggesting that Fe has been introduced during serpentinization following eruption. These late metasomatic processes have thus affected some major as well minor and trace element compositions. The similarities in bulk composition of peridotites from Udachnaya and the Kaapvaal are evidence of a common origin. Low-temperature cratonic peridotites differ from oceanic peridotites in having higher mg numbers (>92) and in having relatively high but wide-ranging modal enstatite (Mg/Si = 1.06–1.49 weight fraction). The Udachnaya low-temperature peridotites have an inverse correlation between FeO (calculated from the probe analyses and modes) and SiO₂. This correlation is also present in the Kaapvaal data but is complicated by a greater range in fertility that produces a positive variation of Fe with Si. A negative trend for Fe/Si can be seen within a portion of the Kaapvaal data, that for low-Ca harzburgites, in which the variation in fertility is restricted. The negative trends for Fe/Si can be interpreted as a consequence of either segregation of olivine and orthopyroxene by metamorphic differentiation or partial sorting during cumulate formation. Received: 18 June 1996  / Accepted: 11 February 1997  相似文献   

Degradation of organic pollutants in near shore marine sediments: Part I—breakdown of pulp mill fibre     

T.H Pearson  Isobel Stanley  S.O Stanley 《Marine environmental research》1982,7(3):195-210

Cellulose levels in the sediments of Loch Linnhe and Loch Eil were measured over a period of years following the introduction of pulp mill effluent to system. Cellulose levels in experimental sediment systems subjected to pulp fibre inputs at levels simulating various possible loch input levels were measured and compared. No permanent build up of cellulose in either the loch systems or the experimental systems was observed, even at high input levels.Pulp fibre degradation rates were measured experimentally using two different techniques. No difference was found between the degradation rates of wet and predried fibre.Degradation rates equivalent to 0·2 g dry fibre m^?2 day^?1 were found in areas of low fibre input and 0·5 g dry fibre m^?2 day^?1 in areas of high input were recorded. These rates were of the same order as, but somewhat lower than, the probable input rates to the sediments in Loch Eil. Speculations as to possible reasons for this are advanced.  相似文献   

Shallow Velocity Structure at the Shagan River Test Site in Kazakhstan     

J. L. Bonner  D. C. Pearson  W. S. Phillips  S. R. Taylor 《Pure and Applied Geophysics》2001,158(11):2017-2039

—?During 1997 and 1998, twelve chemical explosions were detonated in boreholes at the former Soviet nuclear test site near the Shagan River (STS) in Kazakhstan. The depths of these explosions ranged from 2.5 to 550 m, while the explosive yield varied from 2 to 25 tons. The purpose of these explosions was for closure of the unused boreholes at STS, and each explosion was recorded at local distances by a network of seismometers operated by Los Alamos National Laboratory and the Institute of Geophysics for the National Nuclear Center (NNC). Short-period, fundamental-mode Rayleigh waves (Rg) were generated by these explosions and recorded at the local stations, resultingly the waves exhibited normal dispersion between 0.2 and 3 seconds. Dispersion curves were generated for each propagation path using the Multiple Filter Analysis and Phase Match Filtering techniques. Tomographic maps of Rg group velocity were constructed and show a zone of relatively high velocities for the southwestern (SW) region of the test site and slow propagation for the northeastern (NE) region. For 0.5?sec Rg, the regions are separated by the 2.1?km/sec contour, as propagation in the SW is greater than 2.1?km/sec and less in the NE region. At 1.0 sec period, the 2.3?km/sec contour separates the two regions. Finally, for 1.5 and 2.0 sec, the separation between the two regions is less distinct as velocities in the NE section begin to approach the SW except for a low velocity region (<2.1?km/sec) near the center of the test site. Local geologic structure may explain the different regions as the SW region is composed predominantly of crystalline intrusive rocks, while the NE region consists of alluvium, tuff deposits, and Paleozoic sedimentary rocks. Low velocities are also observed along the Shagan River as it passes through the SW region of the test site for shorter period Rg (0.5–1.0?sec). Iterative, least-squares inversions of the Rg group velocity dispersion curves show shear-wave velocities for the southwestern section that are on average 0.4?km/sec higher than the NE region. At depths greater than 1.5?km the statistical difference between the models is no longer significant. The observed group velocities and different velocity structures correlate with P-wave complexity and with spatial patterns of magnitude residuals observed from nuclear explosions at STS, and may help to evaluate the mechanisms behind those observations.  相似文献   

Evolution of Archaean Southern Indian lithospheric mantle: a geochemical study of Proterozoic Agali — Coimbatore dykes     

T. Radhakrishna  D. G. Pearson  John Mathai 《Contributions to Mineralogy and Petrology》1995,121(4):351-363

 Agali–Coimbatore dolerite dykes constitute an important Proterozoic magmatic event that affected the south Indian shield. Rb-Sr whole rock isotope data yield an “errorchron” of 2369±400 Ma (2σ error) which is within error of the reported 2030±65 Ma K-Ar age. The dyke magmas were evolved Fe-rich tholeiitic melts produced by fractionation of clinopyroxene, orthopyroxene and olivine in the initial stages. Plagioclase became a fractionation phase during the latter stages of crystallization. The dykes characteristically have high ⁸⁷Sr/⁸⁶Sr_i (0.703–0.706) and are enriched in large-ion lithophile and light rare earth elements relative to primordial mantle values and show negative Nb anomalies. These compositional characteristics are interpreted as source mantle characteristics whereas some crustal effects are visible in some samples with high initial ⁸⁷Sr/⁸⁶Sr. Peridotite with minor hydrous metasomatic phases like amphibole (and phlogopite) within the shallow lithospheric mantle could be a potential source material for the dykes. However, at this stage we cannot convincingly differentiate whether the source of the parent magmas is solely lithospheric or a product of asthenosphere-lithosphere mixing. The δ¹⁸O values of the dykes range from +5.2 to +7.2 per mil (vs standard mean oceanic water). Initial Nd isotope values at the time of dyke intrusion (ɛ_Nd at t=2.0 Ga) range from −2.3 to −4.8. Whole rocks define a correlation on an Sm-Nd isochron plot with a slope equivalent to an age of 3.15±0.53 Ga (2σ error); Sm-Nd crustal residence ages average at 2.87 Ga. The isochron age does not appear to be the result of systematic mixing with an older crustal component. These results together with trace element geochemistry suggest that the south Indian mantle lithosphere developed by addition of enriched melts/fluids at about 3.0 Ga synchronously with major crustal gene- ration in the south Indian shield. Received 20 June 1994/Accepted: 17 May 1995  相似文献   

Threshold for detection of naphthalene and other behavioral responses by the blue crab,Callinectes sapidus     

Walter H. Pearson  Bori L. Olla 《Estuaries and Coasts》1980,3(3):224-229

Using behavioral criteria developed in previous studies, the threshold concentration at which the blue crab,Callinectes sapidus, detected the petroleum hydrocarbon naphthalene was found to be 10^?7 mg/l. Oriented locomotor activity and defensive displaying began at 2 mg/l of naphthalene. No feeding behavior was observed up to and including the maximum naphthalene concentration of 5 mg/l. Below 2 mg/l the blue crab apparently had no active behavioral response to naphthalene exposure other than detection.  相似文献   

Detection of naphthalene by the blue crab,Callinectes sapidus     

Walter H. Pearson  Bori L. Olla 《Estuaries and Coasts》1979,2(1):64-65

Increases in the antennular flicking rate indicated that blue crabs,Callinectes sapidus, detected the petroleum hydrocarbon naphthalene. A low incidence of aggressive displays but no food searching or gathering followed naphthalene detection. The results suggest that the chemosensory abilities of decapod crustaceans cover a broader range of substances than previously supposed.  相似文献   

Mass transfer and carbon isotope evolution in natural water systems     

T.M.L. Wigley  L.N. Plummer  F.J. Pearson 《Geochimica et cosmochimica acta》1978,42(8):1117-1139

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Comparative Accuracy in Four Civil War Maps of the Shenandoah Valley: A GIS Analysis*     

Brooks C. Pearson 《The Professional geographer》2005,57(3):376-394

This study compares the accuracy of four maps available to Union and Confederate officers during the 1862 Shenandoah Valley campaign of the American Civil War. It examines historical maps of the Valley of Virginia by the following cartographers: James W. Abert, Hermann Böÿe and Lewis von Buchholtz, Jedediah Hotchkiss, and Franz Kappner. Both simple and three‐tiered sinuosity measures are derived for reference points along study map representations of the Shenandoah river system. These data are then statistically compared to corresponding sinuosity data from USGS topographic quadrangles to identify the relative accuracies of the historical maps. This article offers evidence to refute the common historical assumption that Hotchkiss provided Maj. Gen. Thomas “Stonewall” Jackson with terrain intelligence that was far superior to that available to his Union opponents. Evidence indicates that maps by Union cartographers as well as the prewar Böÿe‐Buchholtz map were at least as accurate, or superior to, the work of Hotchkiss.  相似文献   

Trace element partitioning during high-P partial melting and melt-rock interaction; an example from northern Fiordland, New Zealand   总被引：2，自引：0，他引：2  

F. C. Schröter  J. A. Stevenson  N. R. Daczko  G. L. Clarke  N. J. Pearson  K. A. Klepeis 《Journal of Metamorphic Geology》2004,22(5):443-457

Pods of granulite facies dioritic gneiss in the Pembroke Valley, Milford Sound, New Zealand, preserve peritectic garnet surrounded by trondhjemitic leucosome and vein networks, that are evidence of high‐P partial melting. Garnet‐bearing trondhjemitic veins extend into host gabbroic gneiss, where they are spatially linked with the recrystallization of comparatively low‐P two‐pyroxene‐hornblende granulite to fine‐grained high‐P garnet granulite assemblages in garnet reaction zones. New data acquired using a Laser Ablation Inductively Coupled Plasma Mass Spectrometer (LA‐ICPMS) for minerals in various textural settings indicate differences in the partitioning of trace elements in the transition of the two rock types to garnet granulite, mostly due to the presence or absence of clinozoisite. Garnet in the garnet reaction zone (gabbroic gneiss) has a distinct trace element pattern, inherited from reactant gabbroic gneiss hornblende. Peritectic garnet in the dioritic gneiss and garnet in trondhjemitic veins from the Pembroke Granulite have trace element patterns inherited from the melt‐producing reaction in the dioritic gneiss. The distinct trace element patterns of garnet link the trondhjemitic veins geochemically to sites of partial melting in the dioritic gneiss.  相似文献   

Rare earth element partitioning between clinopyroxene and silicate liquid at moderate to high pressure   总被引：5，自引：0，他引：5  

T. H. Green  N. J. Pearson 《Contributions to Mineralogy and Petrology》1985,91(1):24-36

Experimental determination of over seventy sets of clinopyroxene/silicate liquid (glass) partitition coefficients (D) for four rare earth elements (REE — La, Sm, Ho, Lu) in a range of REE-enriched natural rock compositions (basalt, basaltic andesite, andesite and rhyodacite) demonstrate a convex upward pattern, favouring the heavy REE (Ho, Lu) and markedly discriminating against the light REE (La). These patterns are consistent with previously documented clinopyroxene D values reported from natural phenocryst/matrix pairs and from experimental work using either REE-enriched compositions and electron microprobe analytical techniques (as in the present study) or natural or synthetic undoped compositions and mass spectrometric, ion probe or X-ray autoradiographic analytical techniques. However, the large data base in the present study allows evaluation of the effect of compositional and physical parameters on REE partitioning relationships. Considering D_Ho, it is shown that (1) D increases 6-fold with increasing SiO₂ content of the coexisting liquid from 50 to 70 wt% SiO₂ (2) D increases 4-fold with decreasing temperature from 1,120°C to 900° C (3) D increases 2-fold with increasing pressure from 2.5 to 20 kb. (4) D increases 2-fold fO₂ increases from approximately that of the MW buffer to the HM buffer (5) D remains unchanged within experimental error as the water content of the melt changes from 0.3 to 10% by weight H₂O.The absolute REE content of the clinopyroxene shows no consistent trend with temperature, but decreases slightly with increasing pressure, paralleling an increase in the jadeite component of the pyroxene. Thus the increase in D with increasing pressure is attributed to changes in the silicate liquid structure, which discriminate against accommodation of REE with increasing pressure. The clinopyroxene REE content increases with increasing fO₂, and in this case the increase in D with increasing fO₂ may be attributed mainly to this change in the clinopyroxene composition. Application of the present results to geochemical modelling allows a more appropriate choice of D values, according to the liquid composition and physical conditions applicable in the modelled system. They may also be used to evaluate cognate or xenocrystic relationships between clinopyroxene megacrysts and their host matrix.  相似文献