The biogeochemical fate and toxicity of mercury in Controlled Experimental Ecosystems     

Gordon T. Wallace  Don L. Seibert  Susan M. Holzknecht  W.H. Thomas 《Estuarine, Coastal and Shelf Science》1982,15(2):151-182

The affinity of mercury for organic matter was the most important parameter governing its chemical speciation, transport and toxicity in Controlled Experimental Ecosystems (CEEs) of the Controlled Ecosystem Pollution Experiment (CEPEX) deployed in Saanich Inlet, B.C., Canada, Particulate, colloidal and high molecular weight dissolved forms of mercury accounted for about 90% of the total mercury present in the water column. Bioassays indicated that organic matter in the above size classes had an important influence on the toxicity of mercury to phytoplankton.Sorption of mercury to particulate organic matter in the CEEs could be described by either Freundlich or linear adsorption isotherms. An observed depth-dependent increase in mercury content of particulate matter was attributed to selective biological degradation of non-mercury-binding organic components of the particles during settling.The high affinity of mercury for settling particulate organic matter led to rapid removal of mercury from CEEs. Removal rates could be described as first order and were a function of primary production rates. Deviations of measured half-removal times from those predicted by an empirically formulated relationship between primary production and mercury half-removal times could be related successfully to the influence of other occasionally significant biological parameters such as zooplankton grazing activity.  相似文献   

Assessment of hormonal activity of UV filters in tadpoles of frog Xenopus laevis at environmental concentrations     

Kunz PY  Galicia HF  Fent K 《Marine environmental research》2004,58(2-5):431-435

Residues of UV filters used as ultraviolet absorbers in sunscreens, cosmetics and in light protection have been found in surface water and fish. Recently some of them were shown bearing estrogenic activity, however, very little is known about possible adverse effects to aquatic life. Here we investigate whether two UV filters, 4-methylbenzylidene camphor (4-MBC) and 3-benzylidene camphor (3-BC), interfere with the thyroid and sex hormone system during frog metamorphosis. Xenopus laevis tadpoles were exposed to 1, 5 and 50 μg/L of 4-MBC and 3-BC, respectively, for 35 days (NF stage 52–66). The rate of metamorphosis was not affected, and no obvious differences in body and tail length compared to controls were observed. Neither 4-MBC, nor 3-BC led to effects on the sex ratio or gross gonad morphology of X. laevis at stage 66. Our results indicate that these UV filters do not negatively affect the thyroid system and sex ratio of frogs at environmental concentrations.  相似文献   

The Pfitsch-Mörchner Basin,an example of the post-Variscan sedimentary evolution in the Tauern Window (Eastern Alps)     

Petra Veselá  Bernd Lammerer 《Swiss Journal of Geoscience》2008,101(1):73-88

A review of post-Variscan metasedimentary and metavolcanic successions in the western Tauern Window is presented. U/Pb – datations of zircons in metavolcanic rocks reveal ages between 309 and 280 Ma. Deposition of grey conglomerates and black pelites started before 309 Ma in the northernmost basin of the Tauern, the Riffler-Schönach basin. In the more central Pfitsch-Mörchner basin, the onset of conglomerate sedimentation can be dated into the time span between 293 and 280 Ma. The Pfitsch and Windtal Formations are newly defined. The basins were filled with up to 1 km of mainly continental clastics until Early Triassic. Short marine ingressions in Middle- and Late Triassic times flooded only basinal parts of the area where we suppose a more or less continuous sedimentation until the Late Jurassic. Only the Hochstegen Marble documents a nearly complete submergence in the area of the Tauern Window. In spite of the metamorphic overprint, the tentative interpretations of the sedimentary facies give a reasonable picture and allow correlations to nonmetamorphic areas in South Germany or the External Massifs of Eastern Switzerland.  相似文献   

Natural and anthropogenic forcing of Holocene lake ecosystem development at Lake Uddelermeer (The Netherlands)     

Stefan Engels  Rogier van Oostrom  Chiara Cherli  Jennifer A. J. Dungait  Boris Jansen  J. M. van Aken  Bas van Geel  Petra M. Visser 《Journal of Paleolimnology》2018,59(3):329-347

Lake Uddelermeer (The Netherlands) is characterized by turbid conditions and annual blooms of toxic cyanobacteria, which are supposed to be the result of increased agricultural activity in the twentieth century AD. We applied a combination of classic palaeoecological proxies and novel geochemical proxies to the Holocene sediment record of Lake Uddelermeer (The Netherlands) in order to reconstruct the natural variability of the lake ecosystem and to identify the drivers of the change to the turbid conditions that currently characterize this lake. We show that the lake ecosystem was characterized by a mix of aquatic macrophytes and abundant phytoplankton between 11,500 and 6000 cal year BP. A transition to a lake ecosystem with clear-water conditions and relatively high abundances of ‘isoetids’ coincides with the first signs of human impact on the landscape around Lake Uddelermeer during the Early Neolithic (ca. 6000 cal year BP). An abrupt and dramatic ecosystem shift can be seen at ca. 1030 cal year BP when increases in the abundance of algal microfossils and concentrations of sedimentary pigments indicate a transition to a turbid phytoplankton-dominated state. Finally, a strong increase in concentrations of plant and faecal biomarkers is observed around 1950 AD. Canonical Correspondence Analysis suggests that reconstructed lake ecosystem changes are best explained by environmental drivers that show long-term gradual changes (sediment age, water depth). These combined results document the long-term anthropogenic impact on the ecosystem of Lake Uddelermeer and provide evidence for pre-Industrial Era signs of eutrophication.  相似文献   

Soil temperature regime and vulnerability due to extreme soil temperatures in Croatia     

Petra Sviličić  Višnja Vučetić  Suzana Filić  Ante Smolić 《Theoretical and Applied Climatology》2016,123(1-2):247-261

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Integrating parameter uncertainty of a process-based model in assessments of climate change effects on forest productivity     

Christopher P. O. Reyer  Michael Flechsig  Petra Lasch-Born  Marcel van Oijen 《Climatic change》2016,135(3-4):395-408

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Gamma dose rate and soil gas radon concentration measured at low soil thickness (Czech Republic)     

Ivan Barnet  Petra Pacherová 《Environmental Earth Sciences》2016,75(7):620

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Multi‐criterial validation of TOPMODEL in a mountainous catchment     

A. Güntner  S. Uhlenbrook  J. Seibert  Ch. Leibundgut 《水文研究》1999,13(11):1603-1620

The need for powerful validation methods for hydrological models including the evaluation of internal stages and spatially distributed simulations has often been emphasized. In this study a multi‐criterial validation scheme was used for validation of TOPMODEL, a conceptual semi‐distributed rainfall–runoff model. The objective was to test TOPMODEL's capability of adequately representing dominant hydrological processes by simple conceptual approaches. Validation methods differed in the type of data used, in their target and in mode. The model was applied in the humid and mountainous Brugga catchment (40 km²) in south‐west Germany. It was calibrated by a Monte Carlo method based on hourly runoff data. Additional information for validation was derived from a recession analysis, hydrograph separation with environmental tracers and from field surveys, including the mapping of saturated areas. Although runoff simulations were satisfying, inadequacies of the model structure compared with the real situation with regard to hydrological processes in the study area were found. These belong mainly to the concept of variable contributing areas for saturation excess overland flow and their dynamics, which were overestimated by the model. The simple TOPMODEL approach of two flow components was found to be insufficient. The multi‐criterial validation scheme enables not only to demonstrate limitations with regard to process representation, but also to specify where and why these limitations occur. It may serve as a valuable tool for the development of physically sound model modifications. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Assessing the impact of land use change on hydrology by ensemble modelling (LUCHEM) II: Ensemble combinations and predictions   总被引：1，自引：0，他引：1  

Neil R. Viney  H. Bormann  L. Breuer  A. Bronstert  B.F.W. Croke  H. Frede  T. Gräff  L. Hubrechts  J.A. Huisman  A.J. Jakeman  G.W. Kite  J. Lanini  G. Leavesley  D.P. Lettenmaier  G. Lindström  J. Seibert  M. Sivapalan  P. Willems 《Advances in water resources》2009

This paper reports on a project to compare predictions from a range of catchment models applied to a mesoscale river basin in central Germany and to assess various ensemble predictions of catchment streamflow. The models encompass a large range in inherent complexity and input requirements. In approximate order of decreasing complexity, they are DHSVM, MIKE-SHE, TOPLATS, WASIM-ETH, SWAT, PRMS, SLURP, HBV, LASCAM and IHACRES. The models are calibrated twice using different sets of input data. The two predictions from each model are then combined by simple averaging to produce a single-model ensemble. The 10 resulting single-model ensembles are combined in various ways to produce multi-model ensemble predictions. Both the single-model ensembles and the multi-model ensembles are shown to give predictions that are generally superior to those of their respective constituent models, both during a 7-year calibration period and a 9-year validation period. This occurs despite a considerable disparity in performance of the individual models. Even the weakest of models is shown to contribute useful information to the ensembles they are part of. The best model combination methods are a trimmed mean (constructed using the central four or six predictions each day) and a weighted mean ensemble (with weights calculated from calibration performance) that places relatively large weights on the better performing models. Conditional ensembles, in which separate model weights are used in different system states (e.g. summer and winter, high and low flows) generally yield little improvement over the weighted mean ensemble. However a conditional ensemble that discriminates between rising and receding flows shows moderate improvement. An analysis of ensemble predictions shows that the best ensembles are not necessarily those containing the best individual models. Conversely, it appears that some models that predict well individually do not necessarily combine well with other models in multi-model ensembles. The reasons behind these observations may relate to the effects of the weighting schemes, non-stationarity of the climate series and possible cross-correlations between models.  相似文献   

Seasonal and runoff-related changes in total organic carbon concentrations in the River Öre, Northern Sweden     

Anneli Ågren  Mats Jansson  Hans Ivarsson  Kevin Bishop  Jan Seibert 《Aquatic Sciences - Research Across Boundaries》2008,70(1):21-29

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