Petrology and geochemistry of a diamondiferous lherzolite from the Premier diamond mine, South Africa     

K.S. Viljoen  Ren Dobbe  Braam Smit  Emilie Thomassot  Pierre Cartigny 《Lithos》2004,77(1-4):539-552

This paper reports on the petrology and geochemistry of a diamondiferous peridotite xenolith from the Premier diamond mine in South Africa.

The xenolith is altered with pervasive serpentinisation of olivine and orthopyroxene. Garnets are in an advanced state of kelyphitisation but partly fresh. Electron microprobe analyses of the garnets are consistent with a lherzolitic paragenesis (8.5 wt.% Cr₂O₃ and 6.6 wt.% CaO). The garnets show limited variation in trace element composition, with generally low concentrations of most trace elements, e.g. Y (<11 ppm), Zr (<18 ppm) and Sr (<0.5 ppm). Garnet rare earth element concentrations, when normalised against the C1 chondrite of McDonough and Sun (Chem. Geol. 120 (1995) 223), are characterised by a rare earth element pattern similar to garnet from fertile lherzolite.

All diamonds recovered are colourless. Most crystals are sharp-edged octahedra, some with minor development of the dodecahedral form. A number of crystals are twinned octahedral macles, while aggregates of two or more octahedra are also common. Mineral inclusions are rare. Where present they are predominantly small black rosettes believed to consist of sulfide. In one instance a polymineralic (presumably lherzolitic) assemblage of reddish garnet, green clinopyroxene and a colourless mineral is recognised.

Infrared analysis of the xenolith diamonds show nitrogen contents generally lower than 500 ppm and variable nitrogen aggregation state, from 20% to 80% of the ‘B’ form. When plotted on a nitrogen aggregation diagram a well defined trend of increasing nitrogen aggregation state with increasing nitrogen content is observed. Carbon isotopic compositions range from −3.6 ‰ to −1.3 ‰. These are broadly correlated with diamond nitrogen content as determined by infrared spectroscopy, with the most negative C-isotopic compositions correlating with the lowest nitrogen contents.

Xenolith mantle equilibration temperatures, calculated from nitrogen aggregation systematics as well as the Ni in garnet thermometer are on the order of 1100 to 1200 °C.

It is concluded that the xenolith is a fertile lherzolite, and that the lherzolitic character may have resulted from the total metasomatic overprinting of pre-existing harzburgite. Metasomatism occurred prior to, or accompanied, diamond growth.  相似文献   

Modélisation morphodynamique cross-shore d'un estran vaseux     

Benoı̂t Waeles  Pierre Le Hir  Ricardo Silva Jacinto 《Comptes Rendus Geoscience》2004,336(11):1025-1033

Numerical experiments were performed to simulate the profile evolution of an intertidal mudflat with a 1D cross-shore morphodynamical model. First, the hydrodynamical forcing is a cross-shore tidal current due to semi-diurnal variations of the free surface elevation at the open boundary. Further, considering the conservation of the action density of surface gravity waves, a wave height (and resulting bottom shear stress) calculation is added to the morphodynamical model. Results of the numerical experiments show that the shape of the profile reaches equilibrium. The mudflat progrades continually when the forcing is tide only, whereas it can be steady under the simultaneous action of tide and waves. To cite this article: B. Waeles et al., C. R. Geoscience 336 (2004).  相似文献   

Hydromechanical coupling in response to earthquakes: on the possible consequences for aftershocks   总被引：1，自引：0，他引：1  

Pierre Gavrilenko 《Geophysical Journal International》2005,161(1):113-129

  相似文献   

Variations of U and Sr isotope ratios in Alsace and Luxembourg rain waters: origin and hydrogeochemical implications     

Franois Chabaux  Jean Riotte  Anne-Dsire Schmitt  Jean Carignan  Pierre Herckes  Marie-Claire Pierret  Henry Wortham 《Comptes Rendus Geoscience》2005,337(16):4612

Major and trace element concentrations, as well as Sr and U isotope ratios, were measured in rainwater samples collected in three different locations in Alsace (East of France) and Luxembourg: a mid-altitude mountain site (Aubure Environment HydroGeochemical Observatory), an urban site (Strasbourg) and a peri-urban site located in an area of well developed industrial activity (Esch-sur-Alzette in Luxembourg). Results highlight the quite high spatial and temporal variability of the chemical and isotopic characteristics of rainwater at the regional scale. They also suggest a quite systematic contribution of a local component in the chemical composition of rainwater. In urban and peri-urban sites, the local component is certainly linked to human activities, as it is well illustrated in this study with the Esch-sur-Alzette samples. On the other hand, for the Aubure site, i.e. a small forested watershed of mid-altitude mountain, data presented in this study demonstrate the influence of the vegetation on the chemical composition of rainwater for alkali and calc-alkali elements, as well as for the Sr isotope ratios. Such a result questions the reliability of the method classically used to estimate the rainwater contribution on the river chemical budget. In addition, data of the present study confirm the very low content of uranium in rainwater and demonstrate, especially through the U isotope analysis of Aubure rainwater, the negligible effect of rainwater on U budget of river waters. This work thus outlines the property of U to be a geochemical tracer specific of weathering fluxes carried by rivers. To cite this article: F. Chabaux et al., C. R. Geoscience 337 (2005).  相似文献   

Lateglacial palaeoenvironments and palaeoclimates from Conty and Houdancourt, northern France, reconstructed from Beetle remains     

Philippe Ponel  Russell Coope  Pierre Antoine  Nicole Limondin-Lozouet  Chantal Leroyer  Andr-Valentin Munaut  Jean-Franois Pastre  Frdric Guiter 《Quaternary Science Reviews》2005,24(23-24):2449-2465

Two Lateglacial insect sequences are described (a) from Conty, in the Selle valley and (b) from Houdancourt in the Oise valley, both in northern France. These investigations are part of a multidisciplinary investigation involving archaeology, sedimentology, geomorphology, geochronology and palaeontology (pollen, macroscopic plant remains, vertebrates, molluscs and insect fossils). The sequences of insect assemblages date from the latter part of the Bølling to the end of the Allerød periods. Environmental analysis of these faunas shows that rivers with riffles and pools meandered across flood plains. The river was extensively fringed with reedy vegetation. The only trees growing close to the river were of Salix and/or Populus. All the insect assemblages indicate that the thermal climates during the Bølling and Allerød periods were similar to one another and during both periods were very nearly as warm as that of the present day. No insect fossils were recovered from the sediments attributed to the Older Dryas interval though other evidence from these sites suggests that this event was decidedly colder than those immediately preceding and succeeding it. Comparisons are made between Lateglacial climatic patterns in northern France with those elsewhere in Europe.  相似文献   

Les laves du mont Bangou : une première manifestation volcanique éocène, à affinité transitionnelle,de la Ligne du Cameroun     

Jacob Fosso  Jean-Jacques Ménard  Jacques-Marie Bardintzeff  Pierre Wandji  Félix M. Tchoua  Hervé Bellon 《Comptes Rendus Geoscience》2005,337(3):315-325

Mount Bangou, an Eocene volcano (⁴⁰K–⁴⁰Ar ages between 44.7 and 43.1 ± 1 Ma) is the oldest dated volcano of the Cameroon Line. In this region, two magmatic series, evolving by fractional crystallization, show transitional affinities that are exceptionally known in this sector. Mineral compositions of basaltic rocks (scarce modal olivine and occurrence of normative hypersthene) as well as geochemical characteristics (low Ba, La, Ta contents and high Y/Nb ratios) are in agreement with this trend. The succession of magmas evolving in time from transitional to more typical alkaline compositions is evidenced in a continental setting. To cite this article: J. Fosso et al., C. R. Geoscience 337 (2005).  相似文献   

Modélisation géométrique 3D des granites stéphaniens du massif du Pelvoux (Alpes,France)     

Pierre Strzerzynski  Stéphane Guillot  Gabriel Courrioux  Patrick Ledru 《Comptes Rendus Geoscience》2005,337(14):1284-1292

The structural analysis and the 3D modelling of Stephanian granites of the Pelvoux Massif characterize an emplacement along sinistral NW–SE- and dextral NE–SW-trending shear zones in the Pelvoux and in the Aiguilles Rouges–Mont Blanc Massifs, respectively. This Carboniferous shear system is consistent with a north–south extension direction known in the whole Variscan belt at this time. To cite this article: P. Strzerzynski et al., C. R. Geoscience 337 (2005).  相似文献   

Modeling the impact of microbial activity on redox dynamics in porous media     

Martin Thullner  Philippe Van Cappellen  Pierre Regnier 《Geochimica et cosmochimica acta》2005,69(21):5005-5019

The present study investigates the interaction between microbial growth and activity and the redox dynamics in natural porous media. The impact the transport regime has on this interaction is also addressed. Expressions for microbial growth are incorporated into a geochemical reaction network linking redox reaction rates to the activity of the microorganisms. A flexible simulation environment, the Biogeochemical Reaction Network Simulator (BRNS) is used for this purpose. Two reactive transport applications relevant to fields of contaminant hydrology and early diagenesis are simulated with the BRNS. Model results are evaluated based on a comparison with comprehensive datasets on the biodegradation of lactate in a sand column experiment and on the distribution of redox-sensitive chemical species in marine sediments of the Skagerrak, Denmark. It is shown that, despite quite different transport regimes, the geomicrobiological model performs equally well in the reproduction of measured chemical species distribution for both applications. This result emphasizes the broad applicability of the proposed approach. Our simulations support that the competitive behavior between various microbial groups is a process controlling the development of redox stratified environments. Furthermore, it is also shown that the transport regime is a key controlling factor for the degree of spatial correlation between microbial biomass distributions and redox reaction rates. Although all our simulations yield a pronounced stratification of the redox processes in the system, the biomass distribution is related to the associated reaction rates only in case of the advection controlled column experiment. In the early diagenetic application, mixing due to bioturbation is the dominant transport process for particulate matter, hence leading to fairly homogeneous distribution of bacterial biomasses which are unrelated to the spatial distribution of redox reaction rates. This homogeneous biomass distribution combined with the 1G carbon degradation model approach might explain why the steady state concentration profiles in such systems can be reproduced by diagenetic models without explicit representation of microbial growth.  相似文献   

A Comparison of Various Methods for the Numerical Evaluation of Porous Media Permeability Tensors from Pore-Scale Geometry     

Romain Guibert  Pierre Horgue  Gérald Debenest  Michel Quintard 《Mathematical Geosciences》2016,48(3):329-347

  相似文献   

Low melting temperature for calcite at 1000 bars on the join CaCO3‐H2O – some geological implications          下载免费PDF全文

Cyril Durand  Lukas P. Baumgartner  Didier Marquer 《地学学报》2015,27(5):364-369

Melting experiments of calcite were performed on the join CaCO₃‐H₂O at a pressure of 1000 bars. The system evolves to the ternary CaO‐H₂O‐CO₂ system during melting experiments. Our experiments show that partial melting of calcite begins at a low temperature, below 650 °C. Such a low partial melting temperature for carbonates revives the debate about the presence of carbonate melts in the upper crust. More specifically, the conditions for carbonate partial melting are present in carbonate host rocks undergoing contact metamorphism at high temperatures in the presence of water‐rich fluid. The presence of carbonate melts influences physical parameters such as viscosity and permeability in contact aureoles, and, furthermore, decarbonation reactions release massive amounts of CO₂.  相似文献