Biosorption of Cr (VI), Cr (III), Pb (II) and Cd (II) from aqueous solutions by Sargassum wightii and Caulerpa racemosa algal biomass     

Narayanaswamyb Tamilselvan  Kumar Saurav  Krishnan Kannabiran 《中国海洋大学学报(英文版)》2012,11(1):52-58

Heavy metal pollution is one of the most important environmental problems today.Biosorption is an innovative tech-nology that employs biological materials to accumulate heavy metals from waste water through metabolic process or physicochemi-cal pathways of uptake.Even though several physical and chemical methods are available for removal of heavy metals,currently many biological materials such as bacteria,algae,yeasts and fungi have been widely used due to their good performance,low cost and large quantity of availability.The aim of the present study is to explore the biosorption of toxic heavy metals,Cr(VI),Cr(III),Pb(II) and Cd(II) by algal biomass obtained from algae Sargassum wightii(brown) and Caulerpa racemosa(green).Biosorption of algal biomass was found to be biomass concentration-and pH-dependent,while the maximal biosorption was found at pH 5.0 and with the metal concentration of 100 mg L-1.S.wightii showed the maximal metal biosorption at the biomass concentration of 25 g L-1,followed by C.racemosa with the maximal biosorption at 30 g L-1.S.wightii showed 78% biosorption of Cr(VI),Cr(III),Pb(II) and Cd(II) ions.C.racemosa exhibited 85% biosorption of Cd(II) and Cr(VI),and 50% biosorption of Cr(III) and Pb(II).The results of our study suggest that seaweed biomass can be used efficiently for  相似文献   

Removal of EDTA from Aqueous Solutions Using Activated Carbon Prepared from Rubber Wood Sawdust: Kinetic and Equilibrium Modeling     

K. Anoop Krishnan  K. G. Sreejalekshmi  Sumol Varghese  T. S. Anirudhan 《洁净——土壤、空气、水》2010,38(4):361-369

Adsorptive removal of EDTA (ethylenediaminetetraacetic acid) from aqueous solution was studied using steam pyrolyzed activated carbon. Rubber wood sawdust, obtained from a local timber facility at Kodangavila, Trivandrum, Kerala, India was used as the precursor for the production of the activated carbon. Batch adsorption experiments were employed to monitor and optimize the removal process. The experimental parameters, i. e., solution pH, agitation time, initial EDTA concentration and adsorbent dosage, affecting the adsorption of EDTA onto sawdust activated carbon (SDAC) were optimized. The inner core mechanism for the interaction between EDTA and SDAC, which resulted in the adsorption process, was also discussed. The change in amount of EDTA adsorbed onto SDAC and CAC (commercial activated carbon) was compared over a wide range of pH (2.0–8.0). The maximum removal of EDTA took place in the pH range of 4.0–6.0 for SDAC and 5.0–5.5 for CAC, which demonstrates the effectiveness of the former adsorbent. Kinetic as well as equilibrium studies were performed to determine the rate constant and adsorption capacity, respectively. The adsorption kinetic data was fitted with pseudo‐first‐order kinetics and the equilibrium data was shown to follow the Langmuir isotherm model. These observations explain the formation of a monolayer of EDTA on the surface of SDAC as confirmed by the slow approach to equilibrium after 4 h of contact time. The adsorption capacity of SDAC for the removal of EDTA was 0.526 mmol/g and is seen to be greater than that of CAC and other reported adsorbents (0.193–0.439 mmol/g). Finally, it is clear that the production of steam pyrolyzed activated carbon in the presence of K₂CO₃ greatly enhanced EDTA removal and resulted in a product with possible commercial value for wastewater treatment strategies.  相似文献   

Algorithms for time synchronization of wireless structural monitoring sensors     

Ying Lei  Anne S. Kiremidjian  K. Krishnan Nair  Jerome P. Lynch  Kincho H. Law 《地震工程与结构动力学》2005,34(6):555-573

Dense networks of wireless structural health monitoring systems can effectively remove the disadvantages associated with current wire‐based sparse sensing systems. However, recorded data sets may have relative time‐delays due to interference in radio transmission or inherent internal sensor clock errors. For structural system identification and damage detection purposes, sensor data require that they are time synchronized. The need for time synchronization of sensor data is illustrated through a series of tests on asynchronous data sets. Results from the identification of structural modal parameters show that frequencies and damping ratios are not influenced by the asynchronous data; however, the error in identifying structural mode shapes can be significant. The results from these tests are summarized in Appendix A. The objective of this paper is to present algorithms for measurement data synchronization. Two algorithms are proposed for this purpose. The first algorithm is applicable when the input signal to a structure can be measured. The time‐delay between an output measurement and the input is identified based on an ARX (auto‐regressive model with exogenous input) model for the input–output pair recordings. The second algorithm can be used for a structure subject to ambient excitation, where the excitation cannot be measured. An ARMAV (auto‐regressive moving average vector) model is constructed from two output signals and the time‐delay between them is evaluated. The proposed algorithms are verified with simulation data and recorded seismic response data from multi‐story buildings. The influence of noise on the time‐delay estimates is also assessed. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Mangerite magmatism associated with a probable Late-Permian to Triassic Hongseong–Odesan collision belt in South Korea     

Chang Whan Oh  Sajeev Krishnan  Sung Won Kim  Yong Wan Kwon 《Gondwana Research》2006,9(1-2):95

The Odesan area in the eastern Gyeonggi Massif, South Korea, consists principally of migmatitic and porphyroblastic gneisses intruded by mangerite. Mafic mangerites with SiO₂ contents from 52.40 to 54.20 wt.% have higher FeO* + MgO (14.98–18.28 wt.%) and CaO contents (5.80–7.84 wt.%) but lower total alkali contents (4.74 < Na₂O + K₂O < 5.80 wt.%) than felsic mangerites (55.9 < SiO₂ < 60.61 wt.%, 9.51< FeO* + MgO < 11.62 wt.%, 3.28 < CaO < 5.68 wt.%, 6.72 < Na₂O + K₂O < 8.05 wt.%). Fe-numbers (FeO* / [MgO + FeO*]) are 0.44–0.47 for mafic mangerites and 0.38–0.42 for felsic mangerites. The mangerites show calc-alkaline affinities in an AFM plot and resemble high-Ba–Sr granitoids with low Rb / Sr ratios of 0.25–0.10. Their MORB-normalized compositions show enrichment in LILE (decoupled LIL/HFS pattern) and negative anomalies in Ti–Nb–Ta. Their geochemical characters are consistent with their formation by partial melting of a basaltic source at temperatures higher than 1025 °C. The mangerites of the present study differ from mangerite formed in a typical within-plate tectonic setting in their high mg# and Sr concentrations and negative Nb and Ta anomalies. Their LILE enrichment and negative Ti–Nb–Ta anomalies could well have been inherited from a pre-collision subduction event. A mean U–Pb zircon age of 257 Ma for the mangerite demonstrates that the tectonic belt connecting the Hongseong and Odesan areas represents a probable extension of the late Permian–Triassic collision belt between the North China and South China blocks into South Korea, with collision occurred earlier in South Korea.  相似文献   

Source depth as a useful parameter in the discrimination of earthquakes and underground explosions     

S. K. Arora  T. K. Basu  C. A. Krishnan 《Tectonophysics》1983,91(1-2)

In order to identify whether observed seismic signals are generated by an underground nuclear explosion or an earthquake, it is adequate to rely on one efficient identifier that provides a reasonably good clue in an unambiguous way. Although it is generally accepted that multi-station, multi-parameter discrimination can provide separation between explosions and earthquakes, it has been observed that cases do arise where signal characteristics cannot be established distinctly and satisfactorily. In the so-called “difficult” cases which are associated with some ambiguity in deducing the nature of the source using single-station seismograms, it is shown in this paper that a reliable estimate of source depth proves extremely useful. Out of the eleven typical examples of “not-easy-to-discriminate” events recorded at the Gauribidanur short-period seismic array in Southern India, seven could be successfully identified as earthquakes and the remaining four as probable underground explosions on the basis of focal-depth estimates from multi-station data.  相似文献   

Deccan Trap volcanism     

M. S. Krishnan 《Bulletin of Volcanology》1963,26(1):387-399

The Deccan Traps, now occupying an area of 200,000 sq. miles, must originally have been more wide-spread. Their thickness in Western India reaches 6000 ft. They have been encountered at depths of over 1500 ft. in Kathiawar and Sind (Pakistan), and have been faulted down to a depth of over 6000 ft. in the Cambay area. They are composed of numerous flows whose thickness varies from a few ft. to 200 ft. The flows are often compact in the lower portions and vesicular in the upper portions. Over most of the area (east of the Western Ghats) the rock is a tholeiitic basalt (50 to 51.5 % silica) whose pyroxene is intermediate in composition between pigeonite and diopside, and whose CIPW norm generally shows the presence of some quartz. In the Bombay Kathiawar region there are numerous eruptive Centres associated with a large range of differentiated types comprising both very basic and acid types. The study of the analyses of the various types indicates the presence of both the alkali-olivine basalt as well as the Calc-alkali lines of differentiation, which has brought up the question of the nature of the primary magma. It is noted that while the greater part of the area shows tholeiitic rock, olivine basalts and connected types appear in the more western areas, perhaps as a result of the local tectonic conditions. Recent geophysical data point to the presence of an « oceanic basalt » layer all around the earth both in oceanic and continental crust, while a less dense (presumably tholeiitic) layer overlies it (below the sial) in the continental segments. The « oceanic basalt » should therefore be taken as representing the primary magma, and tholeiite as a major type derived from it in the continental crust.  相似文献   

Will the South Asian monsoon overturning circulation stabilize any further?     

R. Krishnan  T. P. Sabin  D. C. Ayantika  A. Kitoh  M. Sugi  H. Murakami  A. G. Turner  J. M. Slingo  K. Rajendran 《Climate Dynamics》2013,40(1-2):187-211

Understanding the response of the South Asian monsoon (SAM) system to global climate change is an interesting scientific problem that has enormous implications from the societal viewpoint. While the CMIP3 projections of future changes in monsoon precipitation used in the IPCC AR4 show major uncertainties, there is a growing recognition that the rapid increase of moisture in a warming climate can potentially enhance the stability of the large-scale tropical circulations. In this work, the authors have examined the stability of the SAM circulation based on diagnostic analysis of climate datasets over the past half century; and addressed the issue of likely future changes in the SAM in response to global warming using simulations from an ultra-high resolution (20 km) global climate model. Additional sensitivity experiments using a simplified atmospheric model have been presented to supplement the overall findings. The results here suggest that the intensity of the boreal summer monsoon overturning circulation and the associated southwesterly monsoon flow have significantly weakened during the past 50-years. The weakening trend of the monsoon circulation is further corroborated by a significant decrease in the frequency of moderate-to-heavy monsoon rainfall days and upward vertical velocities particularly over the narrow mountain ranges of the Western Ghats. Based on simulations from the 20-km ultra high-resolution model, it is argued that a stabilization (weakening) of the summer monsoon Hadley-type circulation in response to global warming can potentially lead to a weakened large-scale monsoon flow thereby resulting in weaker vertical velocities and reduced orographic precipitation over the narrow Western Ghat mountains by the end of the twenty-first century. Supplementary experiments using a simplified atmospheric model indicate a high sensitivity of the large-scale monsoon circulation to atmospheric stability in comparison with the effects of condensational heating.  相似文献   

Heavy metal accumulation in the surficial sediments along southwest coast of India     

P. Udayakumar  J. Jean Jose  K. Anoop Krishnan  C. S. Ratheesh Kumar  M. N. Manju  P. M. Salas 《Environmental Earth Sciences》2014,72(6):1887-1900

Concentration and distribution of heavy metals (Cd, Cr, Cu, Hg, Ni, Pb and Zn) in surface sediments collected from five stations located along the southwest coast of India were investigated seasonally to assess whether there is insidious buildup of heavy metals. Spatial variation was in accordance with textural characteristics and organic matter content. The concentration of the metals in sediments of the study area followed the order: Zn > Cr > Ni > Cu > Pb > Cd > Hg. The use of geochemical tools and sediment quality guidelines to account for the magnitude of heavy metal contamination revealed high contamination in monsoon and impoverishment during post-monsoon. Estimated total metal concentrations in the present investigation were comparable with other studies; however, concentrations of Ni and Zn were higher than that of other coastal regions. Concentrations of metals in sediment largely exceed NOAA effects range:low (e.g., Cu, Cr, Hg) or effects range:median (e.g., Ni) values. This means that adverse effects for benthic organisms are highly probable.  相似文献   

Organic carbon and iron modulate nitrification rates in mangrove swamps of Goa, south west coast of India     

K.P. Krishnan  P.A. Loka Bharathi   《Estuarine, Coastal and Shelf Science》2009,84(3):419

Nitrification, fuelled by ammonium is the pivotal oxidative pathway to nitrogen cycling. In spite of its ecological significance, the factors regulating nitrification rates in the benthic realm remain poorly understood. The present study therefore examines some of the factors like ammonium, nitrite, nitrate, organic carbon, iron and manganese on down-core variability in benthic nitrification rates in two different mangrove ecosystems, one under the influence of ferromanganese ore mining (experiment) and the other relatively undisturbed (control). We hypothesize that besides organic carbon, iron could also influence the rate of nitrification. The study also contrasts the distributive pattern of autotrophic and heterotrophic nitrifiers in the two regions. The concentration of iron at the control site ranged from 1.1% to 15.1% while at the experimental site it ranged from 2.9% to 46%. The levels of organic carbon at control and experimental sites ranged from 0.02% to 6.9% and 0.1% to 6.5%, respectively. The nitrification rates at the control and experimental sites are comparable and ranged from 3.2 ± 1.2 to 18.4 ± 1.9 ng at-N g(sediment)⁻¹ h⁻¹ and 2.7 ± 1.5 to 18.2 ± 0.6 ng at-N g(sediment)⁻¹ h⁻¹, respectively. While the abundance of heterotrophic nitrifiers at both the sites ranged from 10^2–3 cells g⁻¹ sediment, the autotrophic nitrifiers at the experimental site was higher by an order at 10³ cells g⁻¹ sediment reflecting the relatively higher refractile nature of organic carbon at the experimental site (Straus and Lamberti, 2000). Though organic carbon and nitrification rates are similar in both the sites, the underlying mechanisms governing the processes could be different. Our studies suggest that at the control site, heterotrophic nitrifiers govern nitrification rates (r = 0.28, p < 0.05, n = 64) using organic carbon (r = 0.32, p < 0.01, n = 64). At the experimental site, nitrification was governed more by autotrophic nitrifiers (r = 0.43, p < 0.001, n = 64) at the expense of iron (r = 0.47, p < 0.001, n = 64). Therefore at the experimental site with higher load of iron, autotrophic nitrification could be more important. It is therefore inferred that both the quality of organic carbon and quantity of iron govern nitrification rates in these mangrove swamps.  相似文献