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A fast and economical routine sample preparation system is described for direct counting of14C for hydrological purposes. The method employs commercially available CO2 absorbers, such as Carbosorb, and liquid scintillation counters. The maximum error involved individual analyses is about ±4pmc (1 δ) on the Beckman counter and about ±2 pmc on the Quantulus counter with a resulting detection limit of 21,000–29,000 a for the Beckman LS7500 and 1220 Quantulus, respectively for a counting time of 1000 min. To avoid physical weighing procedures, an indirect method is presented to determine the grams of C absorbed in the counting solution by using the H-# quench monitor technique available in the Beckman liquid scintillation counters. On one sample preparation system at least five samples can be prepared per normal working day. The applicability of the CO2-absorption method is discussed with reference to two field sites and with reference to comparisons with data obtained on the same samples measured with conventional techniques. 相似文献
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Caroline Sassier Philippe Boulvais Denis Gapais Ramon Capdevila Hervé Diot 《International Journal of Earth Sciences》2006,95(1):2-18
We describe amphibolite-facies shear zones affecting an orthogneiss from the Armorican Hercynian belt (Ile d’Yeu, western
France). The deformation pattern is consistent with top-to-the-South thrusting followed by E–W extension, as documented elsewhere
in the region. Shearing was accompanied by channelled fluid flow that transformed the orthogneiss into a peraluminous micaschist.
Structural and mineralogical data indicate rather early strain localization. Then, temperature increase associated with crustal
thickening favoured more distributed deformations marked by shear zone stretching and the development of a HT regional foliation.
Chemical analyses made across five shear zones show mass transfers that mainly implied losses in Ca and Na, and gains in H2O, Mg, and K. Most results indicate constant volume transformation, but some suggest records of either gains or losses of
volume (between +20% and −30%). This might reflect variable records of fluid-rock interactions according to the timing of
initiation and subsequent evolution of individual shear zones, early thrusting stages being marked by up-temperature flow,
and late thrusting stages by down-temperature flow. δ18O analyses suggest that fluids experienced significant isotopic exchange with orthogneisses. 相似文献
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Underwater acoustic technologies may be used for remote sensing of estuarine and coastal benthic habitat in addition to more traditional methods of assessing the seabed. These systems use reflected sound energy to identify surface objects, texture, and subbottom density discontinuities, and to classify benthic habitat. We evaluated the ability of subbottom profiling systems, side scan sonar, and acoustic seabed classification systems (ASCS) to assess oyster habitat in the Chesapeake Bay. Our criteria were the systems' abilities to assess the quality and quantity of oyster shell resources and to integrate with Geographical Information Systems (GIS) technology for the charting of the seabed. Although all systems examined have previously been used for benthic habitat assessment, we found that ASCS offered the most promise as a stand alone system for mapping complex and heterogeneous habitat typical of oyster bottoms. The results from this study suggest that ASCS technology is highly suited for the identification and charting of oyster shell as well as distinguishing among different combinations of shell and fine sediments. Such systems also offer excellent linkage with GIS display and analysis capability. 相似文献
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Assessment of metals in sediments from Lake Macquarie, New South Wales, Australia, using normalisation models and sediment quality guidelines 总被引:7,自引:0,他引:7
Roach AC 《Marine environmental research》2005,59(5):453-472
Industrial activity since the 1890s and, more recently catchment development has resulted in significant metal contamination in Lake Macquarie, an estuary in New South Wales, Australia. This paper presents an analysis of metal concentrations in surface sediments from Lake Macquarie using normalisation models to estimate enrichment relative to natural background concentrations and by comparing concentrations with sediment quality guidelines (SQGs) and effects range median quotients to assess the potential for ecological harm. Of the 12 metals examined, cadmium, lead, mercury, selenium, silver and zinc were enriched in surface sediments throughout the lake. The greatest contamination was found in the north of the lake and, for selenium, also in areas adjacent to two power stations. Comparisons with SQGs and effects range median quotients found that sediments from a site in Cockle Bay had concentrations of metals with the highest likelihood of causing adverse effects on sediment associated biota, and that the likelihood adverse decreased with distance from Cockle Bay. Comparisons with historical sediment quality data indicated that there has been a marked reduction in surface metal concentrations throughout the lake over 15 years. Models could not be constructed for all metals due to low background concentrations. For most metals, simple linear regression models were adequate, but for selenium and arsenic a multiple regression model provided a better estimate of background concentrations. SQGs possibly overestimated effects for arsenic, which has naturally high concentrations in the lake and underestimated the potential for ecological effects in coarser sediments. 相似文献
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High-resolution, spatially distributed ground water flow models can prove unsuitable for the rapid, interactive analysis that is increasingly demanded to support a participatory decision environment. To address this shortcoming, we extend the idea of multiple cell (Bear 1979) and compartmental (Campana and Simpson 1984) ground water models developed within the context of spatial system dynamics (Ahmad and Simonovic 2004) for rapid scenario analysis. We term this approach compartmental–spatial system dynamics (CSSD). The goal is to balance spatial aggregation necessary to achieve a real-time integrative and interactive decision environment while maintaining sufficient model complexity to yield a meaningful representation of the regional ground water system. As a test case, a 51-compartment CSSD model was built and calibrated from a 100,000+ cell MODFLOW (McDonald and Harbaugh 1988) model of the Albuquerque Basin in central New Mexico (McAda and Barroll 2002). Seventy-seven percent of historical drawdowns predicted by the MODFLOW model were within 1 m of the corresponding CSSD estimates, and in 80% of the historical model run years the CSSD model estimates of river leakage, reservoir leakage, ground water flow to agricultural drains, and riparian evapotranspiration were within 30% of the corresponding estimates from McAda and Barroll (2002), with improved model agreement during the scenario period. Comparisons of model results demonstrate both advantages and limitations of the CCSD model approach. 相似文献
110.
The aim of this study is to analyze suspended sediment transport in a Mediterranean agricultural catchment under traditional soil and water conservation practices. Field measurements were conducted in Can Revull, a small ephemeral catchment (1.03 km2) on the island of Mallorca. This study uses continuous turbidity records to analyse suspended sediment transport regimes, construct and interpret multiple regression models of total suspended sediment concentration (SSC) and of SSC related to stormflow discharge, and assess the sediment loads and yields of three hydrological years (2004–2005 to 2006–2007). An annual average SSC of 17.3 mg l?1, with a maximum of 2270 mg l?1, was recorded in the middle of the winter period when rainfall intensities are high and headwater slopes are ploughed and thus bare. Strong seasonal contrasts of baseflow dynamics associated with different degrees of dilution provide a large scatter in SSC and in the derived rating curves, reflecting that other factors control the supply of suspended sediment. Multiple regression models identify rainfall intensity as the most significant variable in sediment supply. However, under baseflow conditions, physical and biological processes generate sediment in the channel that is subsequently removed during high flow. In contrast, when baseflow is not present, rainfall intensity is the only process that supplies sediment to the channel, mostly from hillslopes. Considering the study period as average in terms of total annual rainfall and intensities, suspended sediment yields were an order of magnitude lower than those obtained in other Mediterranean catchments, a factor that can be related to the historical use of soil conservation practices. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献