The partial molar volume, thermal expansivity, and compressibility of H2O in NaAlSi3O8 liquid: new measurements and an internally consistent model     

Frederick A. Ochs III.  Rebecca A. Lange 《Contributions to Mineralogy and Petrology》1997,129(2-3):155-165

The molar volumes of 19 hydrous albitic liquids (1.9 to 6.1 wt% H₂O^total) were determined at one bar and 505–765 K. These volume data were derived from density measurements on hydrous glasses at 298 K, followed by measurements of the thermal expansion of each glass from 298 K to its respective glass transition temperature. The technique exploits the fact that the volume of a glass is equal to that of the corresponding liquid at the limiting fictive temperature (T _f′), and that T _f′ can be approximated as the temperature near the onset of the rapid increase in thermal expansion that occurs in the glass transition interval. The volume data of this study were combined with available volume data for anhydrous, Na₂O-Al₂O₃-SiO₂ liquids to derive the partial molar volume (±1) of the H₂O component in an albitic melt at ∼565 K and one bar. To extend the determination of to higher temperatures and pressures, the molar volumes of the hydrous albitic liquids determined in this study were combined with those measured by previous authors at 1023–1223 K and 480–840 MPa, leading to the following fitted values (±1) at 1673 K and one bar: (±0.46)×10⁻³ cm⁻³/mol-K, and dVˉ ^H ₂ ^{O total} /dP=−3.82 (±0.36)×10⁻⁴ cm³/mol-bar. The measured molar volumes of this study and those of previous authors can be recovered with a standard deviation of 0.5%, which is within the respective experimental errors. There is a significant difference between the values for derived in this study as a function of temperature and pressure and those obtained from an existing polynomial, primarily caused by the previous absence of accurate density measurements on anhydrous silicate liquids. The coefficients of thermal expansion (=4.72×10⁻⁴/K) and isothermal compressibility ( _T =1.66×10⁻⁵/bar) for the H₂O component at 1273 K and 100 MPa, indicate that H₂O^total is the single most expansive and compressible component in silicate liquids. For example, at 1473 K and 70 MPa (conditions of a mid-ocean ridge crustal magma chamber), the presence of just 0.4 wt% H₂O will decrease the density of a basaltic liquid by more than one percent. An equivalent decrease in melt density could be achieved by increasing the temperature by 175 degrees or the decreasing pressure by 230 MPa. Therefore, even minor quantities of dissolved water will have a marked effect on the dynamic properties of silicate liquids in the crustal environment. Received: 20 August 1996 / Accepted: 15 March 1997  相似文献   

Effects of heavy metals on the survival ofDiacypris compacta (Herbst) (Ostracoda) from the Coorong,South Australia     

Anna Brooks  Rehema M. White  David C. Paton 《International Journal of Salt Lake Research》1995,4(2):133-163

The hypermarine southern Coorong is threatened by proposals to drain relatively fresh surface water and groundwater from adjacent agricultural areas into the Coorong. These influent waters carry moderate loads of heavy metals. Acute toxicity of heavy metals toDiacypris compacta, an abundant ostracod in the Coorong, was measured in the laboratory at 18°C in a static system using Coorong water (pH 7.8 salinity 50 ppt). At 4 days (96 h) the mean values of LC₅₀ for copper, zinc, lead and, cadmium respectively were 0.8, 2.1, 3.1 and 4.3 mg L^–1, and at 8 days the respective mean LC₅₀ s were 0.4, 0.7, 2.2 and 1.1 mgL^–1. The effect of two or three metals on mortality was additive in some cases and synergistic in other cases, but generally less than additive. However, in all cases mortality was greater in the presence of two or three metals than in the presence of a single metal. According to ANZECC (1992) guidelines, maximum acceptable concentrations of heavy metals should be no higher than 0.01 x the lowest LC₅₀ value. Using the lowest LC₅₀ values forDiacypris compacta obtained at 8 days, maximum acceptable concentrations in the Coorong would be 4, 5, 9 and 22 gL^–1 for copper, zinc, cadmium and lead respectively, the values for zinc and copper failling below those recommended by ANZECC (1992) for marine waters. Reported concentrations of copper and zinc in surface water and groundwater in areas adjacent to the Coorong sometimes exceed these values, hence drainage of these waters into the Coorong represents a significant hazard to the Coorong biota.  相似文献   

Pre-flare association of magnetic fields and millimeter-wave radio emission     

E. B. Mayfield  K. P. White III 《Solar physics》1976,47(1):277-284

Observations of radio emission at 3.3 mm wavelength associated with magnetic fields in active regions are reported. Results of more than 200 regions during the years 1967–1968 show a strong correlation between peak enhanced millimeter emission, total flux of the longitudinal component of photospheric magnetic fields and the number of flares produced during transit of active regions. For magnetic flux greater than 10²¹ maxwells flares will occur and for flux of 10²³ maxwells the sum of the H flare importance numbers is about 40. The peak millimeter enhancement increases with magnetic flux for regions which subsequently flared. Estimates of the magnetic energy available and the correlation with flare production indicate that the photospheric fields and probably chromospheric currents are responsible for the observed pre-flare heating and provide the energy of flares.This work was supported in part by NASA Contract No. NAS2-7868 and in part by Company funds of The Aerospace Corporation.  相似文献   

Molecular simulation of humic substance-Ca-montmorillonite complexes     

Rebecca Sutton  Garrison Sposito 《Geochimica et cosmochimica acta》2006,70(14):3566-3581

An understanding of the processes that lead to long-term stabilization of organic matter in soils is essential to the effective implementation of strategies designed to mitigate CO₂ loss from the soil carbon reservoir in temperate climatic zones. Decomposition studies indicate that montmorillonite, a smectite that often forms with interlayers rich in Ca²⁺, greatly retards the microbial mineralization of soil organic matter. We performed a series of atomistic simulations designed to identify favorable molecular-scale organo-mineral interactions within nanoscale, hydrated complexes consisting of a humic substance and Ca-montmorillonite. Both protonated and Ca-saturated forms of the model humic molecule, representing acidic and circumneutral solution conditions, respectively, were studied within the hydrated interlayer region of a rigid-atom model of Ca-montmorillonite. The protonated humic substance formed direct hydrophobic and hydrogen bonding (H-bonding) interactions with the clay mineral. A few polar organic groups adsorbed via water bridging interactions. The Ca-saturated humic substance adsorbed via numerous cation bridges, less numerous water bridges, and indirect H-bonding interactions mediated by water molecules. Application of molecular modeling techniques to this complex organo-mineral system thus allowed identification of interactions favorable to carbon sequestration under both acidic and circumneutral conditions.  相似文献   

Molybdenum and uranium geochemistry in continental margin sediments: Paleoproxy potential   总被引：4，自引：0，他引：4  

James McManus  William M. Berelson  Rebecca L. Poulson  Gary P. Klinkhammer 《Geochimica et cosmochimica acta》2006,70(18):4643-4662

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Asymmetric vegetation responses to mid-Holocene aridity at the prairie-forest ecotone in south-central Minnesota     

Charles E. Umbanhowar Jr.  Philip Camill  Rebecca Teed 《Quaternary Research》2006,66(1):53-66

The mid-Holocene (ca. 8000-4000 cal yr BP) was a time of marked aridity throughout much of Minnesota, and the changes due to mid-Holocene aridity are seen as an analog for future responses to global warming. In this study, we compare the transition into (ca. 9000-7000 yr ago) and out of (ca. 5000-2500 yr ago) the mid-Holocene (MH) period at Kimble Pond and Sharkey Lake, located along the prairie forest ecotone in south-central Minnesota, using high resolution (∼ 5-36 yr) sampling of pollen, charcoal, sediment magnetic and loss-on-ignition properties. Changes in vegetation were asymmetrical with increasing aridity being marked by a pronounced shift from woodland/forest-dominated landscape to a more open mix of grassland and woodland/savanna. In contrast, at the end of the MH, grassland remained an important component of the landscape despite increasing effective moisture, and high charcoal influxes (median 2.7-4.0 vs. 0.6-1.7 mm² cm^− 2 yr^− 1 at start of MH) suggest the role of fire in limiting woodland expansion. Asymmetric vegetation responses, variation among and within proxies, and the near-absence of fire today suggest caution in using changes associated with mid-Holocene aridity at the prairie forest boundary as an analog for future responses to global warming.  相似文献   

Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya   总被引：1，自引：0，他引：1  

Minghua Ren  Peter A. Omenda  Elizabeth Y. Anthony  John C. White  Ray Macdonald  D.K. Bailey   《Lithos》2006,91(1-4):109-124

The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO₂ > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas.  相似文献   

Variable vegetation cover and episodic sand movement on longitudinal desert sand dunes   总被引：6，自引：0，他引：6  

Paul P. Hesse  Rebecca L. Simpson 《Geomorphology》2006,81(3-4):276-291

Longitudinal (linear) sand dunes of the Simpson and Strzelecki dunefields in eastern central Australia present a paradox. Low levels of activity today stand in contrast to luminescence dating which has repeatedly shown deep deposits of sand on dune crests dating to within the late Holocene. In order to investigate the nature of dune activity in the Simpson–Strzelecki dunefield, vegetation and sand mobility were investigated by detailed vegetation survey and measurement of rippled area and loose sand depth of dunes at three sites along a climatic gradient. The response of both vegetation and sand movement to inter-annual climate variability was examined by repeat surveys of two sites in drought and non-drought conditions. Projected plant cover and plant + crust cover were found to have inverse linear relationships with rippled area and the area of deep loose sand. No relationship was found between these measures of sand movement and the plant frontal area index. A negative exponential relationship between equivalent mobile sand depth on dune surfaces and both vascular plant cover and vascular + crust cover was also found. There is no simple threshold of vegetation cover below which sand transport begins. Dunes with low perennial plant cover may form small dunes with slip faces leading to a positive feedback inhibiting ephemeral plant growth in wet years and accelerating sand transport rates. The linear dunefields are largely within the zone in which plant cover is sufficient to enforce low sand transport rates, and in which there is a strong response of vegetation and sand transport to inter-annual variation in rainfall. Both ephemeral plants (mostly forbs) and crust were found to respond rapidly to large (> 20 mm/month) rainfall events. On millennial time-scales, the level of dune activity is controlled by vegetation cover and probably not by fluctuations of wind strength. Land use or extreme, decadal time-scale, drought may destabilise dunes by removing perennial plant cover, accelerating wind erosion.  相似文献   

Lithospheric structure of an active backarc basin: the Taupo Volcanic Zone, New Zealand   总被引：3，自引：0，他引：3  

Antony Harrison  Robert S. White 《Geophysical Journal International》2006,167(2):968-990

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Net Energy Payback and CO2 Emissions from Three Midwestern Wind Farms: An Update     

Scott W. White 《Natural Resources Research》2006,15(4):271-281

This paper updates a life-cycle net energy analysis and carbon dioxide emissions analysis of three Midwestern utility-scale wind systems. Both the Energy Payback Ratio (EPR) and CO₂ analysis results provide useful data for policy discussions regarding an efficient and low-carbon energy mix. The EPR is the amount of electrical energy produced for the lifetime of the power plant divided by the total amount of energy required to procure and transport the materials, build, operate, and decommission the power plants. The CO₂ analysis for each power plant was calculated from the life-cycle energy input data. A previous study also analyzed coal and nuclear fission power plants. At the time of that study, two of the three wind systems had less than a full year of generation data to project the life-cycle energy production. This study updates the analysis of three wind systems with an additional four to eight years of operating data. The EPR for the utility-scale wind systems ranges from a low of 11 for a two-turbine system in Wisconsin to 28 for a 143-turbine system in southwestern Minnesota. The EPR is 11 for coal, 25 for fission with gas centrifuge enriched uranium and 7 for gaseous diffusion enriched uranium. The normalized CO₂ emissions, in tonnes of CO₂ per GW_eh, ranges from 14 to 33 for the wind systems, 974 for coal, and 10 and 34 for nuclear fission using gas centrifuge and gaseous diffusion enriched uranium, respectively.  相似文献