Biodegradation of Herbicide Propanil and Its Subproduct 3,4‐Dichloroaniline in Water     

Rafael Roehrs  Miguel Roehrs  Sérgio L. de O. Machado  Renato Zanella 《洁净——土壤、空气、水》2012,40(9):958-964

The rational use of pesticides generates an impact which is normally reversed and eliminated by the environment itself. However, the indiscriminate use of pesticides makes its natural degradation rhythm difficult, prolonging their presence in the soil for a great deal of time. Aiming towards a decrease in the environmental impact of pesticides, soil microorganisms capable of degrading pesticides, such as propanil, were investigated. An Enterobacter cloacae strain, isolated from rice field soil, was exposed to the herbicide propanil alone and in a mixture containing also bentazone, clomazone, quinclorac, and 2,4‐D. This bacterium was able to eliminate 100% of the applied propanil in 28 days. Propanil degradation in the 5‐herbicide mixture was much lower than that of individual pesticide degradation. The aeration of the system helped to degrade propanil and its subproduct 3,4‐dichloroaniline much faster. LC with UV detection was used to determine the remaining concentrations of the herbicides and their subproducts.  相似文献   

The behaviour of vernacular buildings in the 2012 Emilia earthquakes   总被引：2，自引：2，他引：0  

Luigi Sorrentino  Laura Liberatore  Domenico Liberatore  Renato Masiani 《Bulletin of Earthquake Engineering》2014,12(5):2367-2382

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Treatment of Acid Mine Drainage (AMD) in South Brazil: Comparative active processes and water reuse     

Aline Nogueira da Silveira  Renato Silva  Jorge Rubio   《International Journal of Mineral Processing》2009,93(2):103-109

This work describes AMD techniques of neutralization, with lime, flocculation of the precipitates and comparative flocs/liquid separation by flotation with microbubbles or by lamellar settling (LS). The AMD treated water was characterized by its quality for recycling in terms of inorganic or organic elements, suspended or dissolved solids, among others. Two types of flocs were formed, “aerated” or not, in a special flocculation reactor, patented by this research group (RGF^®). Aerated flocs formed (within seconds) entered into contact with microbubbles under high shearing and raised-up at rates > 120 mh^− 1 allowing a rapid solid–liquid separation by flotation (HR-high rate), at about 13–15 m³m^− 2 h^− 1 loading capacity. Conversely, the non-aerated flocs settled at about 5–6 m h^− 1 in a lamella settler. Both AMD treatment techniques showed similar efficiencies (removal of ions > 90%) but the separation by lamella settling presented advantages, namely less reagents (no flotation collector required), lower power requirements and easier to operate. The operating costs (approximate values) of the AMD treatment by LS at pH 9 reaches about 0.3 US$ m^− 3 against 0.6 US$ m^− 3 for the HR-flotation process. Results found were proved to be similar to those found in recent ADM treatment installations in South Brazil. The quality of the treated water is fairly good, nearly free of heavy metals ion, low BOD (biological oxygen demand) and TOC (total organic content), low solids content and may be readily reused for irrigation, industrial processes and as wash water (among others, streets, vehicles, dust control). However, there is a need to extend the use of this treated water resource, but this, at least in Brazil, has not been legislated properly. It is concluded that this research will contribute in the discussion of this old and complex problem in acid mining effluents worldwide.  相似文献   

Quantifying rock fall probabilities and their temporal distribution associated with weather seasonality   总被引：1，自引：1，他引：0  

Renato Macciotta  Michael Hendry  David M. Cruden  Andrée Blais-Stevens  Tom Edwards 《Landslides》2017,14(6):2025-2039

Quantifying rock fall hazards requires information about their frequency and volumes. Previous studies have focused on quantifying rock fall volume–frequency relationships or the weather conditions antecedent to rock fall occurrences, and their potential use as prediction tools. This paper is focused on quantifying rock fall occurrence probabilities and presents approaches for quantifying rock fall temporal distributions. In particular, von Mises distributions allow direct correlation between seasonal weather variations and rock fall occurrences. The approaches are illustrated using a rock fall database along a railway corridor in the Canadian Cordillera, in which rock fall occurrences were correlated to the morphology and lithology. A Binomial probability distribution applied to the annual rock fall frequency suggests an average daily rock fall probability of 1 × 10^?2 across the study area. However, circular (von Mises) distributions associated with weather trends in the area, and fitted to monthly rock fall records, allow estimation of daily rock fall probabilities in different months. This approach allows a direct correlation between rock fall frequencies and seasonal variations in weather conditions. The results suggest daily rock fall probabilities between 4 × 10^?3 and 8 × 10^?3 for April through July and up to 2.1 × 10^?2 in October. Moreover, local peaks in rock fall monthly records are quantitatively explained through the seasonality of weather conditions. Similar values are obtained when applying the Binomial distribution to monthly records. However, this last approach does not show strong distribution fits and does not allow a correlation between rock fall frequencies and seasonal weather variations.  相似文献   

Biochemical and microbial features of shallow marine sediments along the Terra Nova Bay (Ross Sea,Antarctica)   总被引：1，自引：0，他引：1  

Franco Baldi  Davide Marchetto  Francesco Pini  Renato Fani  Luigi Michaud  Angelina Lo Giudice  Daniela Berto  Michele Giani 《Continental Shelf Research》2010

Shallow marine sediments were collected from seven stations (three of which located at Gerlache Inlet, two at Tethys Bay, one at Adelie Cove and one just beneath the Italian Research Base) along the Terra Nova Bay coast (Ross Sea, Antarctica). Their chemical, biochemical and microbiological properties were studied in order to provide further insights in the knowledge of this Antarctic benthic ecosystem. Overall, the organic carbon (OC) represented the major fraction of total carbon (TC) and displayed concentrations similar to or slightly lower than those previously measured in Antarctic bottom sediments. The biopolymeric carbon within OC ranged from 4.1% to 19.9% and showed a wide trophic range (65–834 μg g⁻¹ d.w.). Proteins (PRT) represented on average the main biochemical class contributing to labile organic carbon, followed by lipids (LIP) and carbohydrates (CHO). The activity of aminopeptidase, β-d-glucosidase, alkaline phosphatase and esterase was checked, giving the highest values at Tethys Bay and at the deepest water sediments. The principal component analysis, which was computed considering physical, chemical (elemental and biochemical sedimentary composition) and microbiological parameters (including bacterial abundance, ectoenzymatic activities, T-RFs richness and diversity indices), allowed to obtain two main clusters (“Tethys Bay” and “other stations”). Based on data obtained, two representative 16S rRNA clone libraries using samples from Tethys Bay and Gerlache Inlet were constructed. The sequences of 171 clones were compared to those available in public databases to determine their approximate phylogenetic affiliations. Both aerobic and anaerobic bacteria were disclosed, with the majority of them affiliated with the Gamma- and Deltaproteobacteria, Bacteroidetes and Acidobacteria. The occurrence of strictly anaerobic bacteria suggests that sediments might also undergo anoxic conditions that, in turn, could favor the accumulation of PRT in respect to CHO, assuming that fermentation of amino acids is slower than that of sugars from decomposing polysaccharides.  相似文献   

A pulsational approach to the luminosity of horizontal branch stellar structures     

Renato De Santis  Santi Cassisi 《Monthly notices of the Royal Astronomical Society》1999,308(1):97-110

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What factors affect the decision making process when setting TACs?: The case of Chilean fisheries     

Carlos P. Leal  Renato A. Quiñones  Carlos Chávez 《Marine Policy》2010

Although failures and successes in fisheries management are related to decision making processes, these are rarely analyzed in detail and even less often following quantitative or semi-quantitative approaches. Herein, we study the decision making process for Chile's most important fisheries using a binary decision model. This model evaluates the probability that an annual total allowable catch (TAC) will or will not be modified by the National Fisheries Council (NFC) based on biological, economic, and social factors. We also analyze some aspects of individual voting, particularly whether the members vote against or abstain from voting on the proposed TAC and if they prioritize resource conservation objectives. Our results indicate that the risk of over exploitation for many important stocks in Chile is aggravated by failures at the decision making level: the scientifically recommended TACs for those fisheries that generate higher levels of employment and have greater economic value are normally increased. This analysis shows that the NFC has clearly prioritized short-term economic and social objectives over resource conservation goals. We discuss the need to adjust the composition and functioning of the NFC in order to ensure long-term sustainability of the fisheries.  相似文献   

Late Quaternary environmental and climate changes registered in lacustrine sediments of the Serra Sul de Carajás,south‐east Amazonia          下载免费PDF全文

José Tasso Felix Guimarães  Prafulla Kumar Sahoo  Pedro Walfir M. Souza‐Filho  Clóvis Wagner Maurity  Renato Oliveira Silva Júnior  Francisco Ribeiro Costa  Roberto Dall'Agnol 《第四纪科学杂志》2016,31(2):61-74

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The Juiz De Fora Granulite Complex of the Central Ribeira Belt, SE Brazil: A Paleoproterozoic Crustal Segment Thrust During the Pan-African Orogeny     

Monica Heilbron  Beatriz Paschoal Duarte  Jos Renato Nogueira 《Gondwana Research》1998,1(3-4):373-381

The granulites of the Juiz de Fora complex occur within thick basement thrust slices associated with the Pan-African shortening process in the central segment of the Ribeira belt. Five lithological units of the Intermediate tectonic domain of the belt can be identified on the basis of detailed geological mapping: a) orthogranulites, b) orthogneisses; c) kinzigite; d) intrusive garnet charnockite and e) amphibolite facies metasediments of probable Meso to Neoproterozoic age, correlated to the cover of the belt. Petrological data indicate high temperatures and intermediate to low lithostatic pressure conditions for the Paleoproterozoic granulite facies metamorphism. Textures and CO₂-rich fluid inclusions are probably related to an IBC path. Geochemical data do not show relevant compositional change as a result of the granulite metamorphism. Two calc-alkaline suites and tholeiitic to alkaline basic rocks can be related to compressional and extensional settings, respectively. The overall composition of the granulites, the lack of substantial LILE depletion as well as the composition of the fluid inclusion points to granulitization process driven by CO₂-rich fluids. Orthogranulites gave rise to banded gneisses as a result of the Pan-African retrograde metamorphism and intense deformation. The U and Th depletion detected in few rocks is possibly related with the hydrated conditions of the retrograde reactions.  相似文献   

Investigation of the carrageenans extracted from Solieria filiformis and Agardhiella subulata from Mar Piccolo, Taranto     

Erminio Murano  Renato Toffanin  Ester Cecere  Roberto Rizzo  Svein Halvor Knutsen 《Marine Chemistry》1997,58(3-4)

Dried samples of the red algae Solieria filiformis and Agardhiella subulata from Mar Piccolo, Taranto, were extracted by stirring in water at 25 (Cold), 85 (Hot) and 120 (pressure) °C. For each species, six successive cold, three hot and two pressure extractions were performed and analyzed separately. Water-soluble polysaccharides were isolated after treatment with amylase, alcohol precipitation, dialysis and freeze drying. The total, starch-free yields were 27 and 24% of the dry weight for S. filiformis (SF) and A. subulata (AS), respectively. FTIR and NMR spectroscopic analysis showed that the different cold and hot water extracts had a similar structural backbone, which can be characteristic of gelling type carrageenans with a dominant iota repeating structure (DA2S-G4S). However, some irregularities were detected by NMR, which may be attributed to 6-sulphated 4-linked precursor units. The occurrence of such and other irregularities was more frequent in the SF samples, giving a possible explanation for the enhanced extractability in cold water of carrageenan polymers from this species.  相似文献