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161.
162.
Two long-term studies were conducted to determine toxicity, uptake and depuration of Kepone in blue crabs (Callinectes sapidus). In the first, Kepone was administered to crabs in seawater (0.03 or 0.3 μg Kepone/I) or food (eastern oyster,Crassostrea virginica, containing 0.25 μg/g Kepone). Uptake of Kepone in 28 days was primarily through the contaminated oysters. When these crabs were held in Kepone-free seawater and fed Kepone-free oysters for 28 days, no loss of the insecticide was evident. There were adverse effects on molting and survival in crabs fed oysters that contained 0.25 μg/g Kepone. A second study was conducted to determine: (1) the depuration of Kepone over a 90-day period in blue crabs fed oysters from the James River, Virginia (containing 0.15 μg/g Kepone); and (2) the effects of Kepone on molting and survival of blue crabs fed James River oysters or laboratory-contaminated oysters that contained 0.15 or 1.9 μg/g Kepone. Crabs fed Kepone-contaminated oysters followed by a diet of Kepone-free oysters for 90 days had detectable concentrations of the insecticide in tissues. Also, blue crabs that ate oysters containing Kepone in concentrations similar to those found in oysters from the James River, died or molted less frequently than crabs fed Kepone-free oysters meats.  相似文献   
163.
An analysis of the vertical structure of nontidal longitudinal currents and salinity in a reach of the lower Potomac River Estuary suggests that values for vertical eddy viscosity and eddy diffusivity scale with water depth H, tidal current amplitude U and bulk Richardson number according to conventional empirical formulas. However, the constant which relates the vertical eddy coefficients under conditions of neutral stability to UH is found to be an order of magnitude less than that expected for tidal conditions. Analyses also suggest that the degree of enhancement of longitudinal dispersion by the shear effect associated with the nontidal currents is a strong function of bulk Richardson number.  相似文献   
164.
Montmorillonite, kaolinite, goethite, and particulate and soluble natural organic materials influence the rate of Mn(II) oxidation. While surfaces accelerate the reaction, apparently by bonding Mn2+ in a manner which fulfills the requirements of the transition state, soluble organic materials retard the reaction by complexing the oxidizable species. It is doubtful whether particulate matter would influence the oxidation process under natural loading conditions since 50–500 mg l?1quantities are required to produce measurable changes in the reaction rate. Complexation by humic materials, however, might be expected to reduce the rate of oxidation by an amount proportional to the dissolved organic carbon concentration. Oxidation followed by precipitation is predicted to be an important mechanism for Mn2+ removal in oceanic waters. The situation is less predictable in lake waters.  相似文献   
165.
166.
Data from analyses of three coexisting pairs of pyroxenes with a wide range of Fe content from each of two localities are used to show the large systematic variation and predictable correlation of Fe (or Mg) of a pyroxene with its content of Al, Mn and Na in mafic granulites. Comparisons of pyroxenes can then be made more meaningful by normalizing Al, or other elements, to an appropriate Mg value. As both P and T may affect the element distribution of the two pyroxenes differently (especially Al and Na) the factor used in normalizing is found to vary from region to region.  相似文献   
167.
Plagioclase in the range An2-An10 in a relatively undeformed Quartz—feldspar pegmatite is compared with similar material in a strongly deformed and recrystallized shear zone. Optical and transmission electron microscope observations and chemical data are discussed in terms of established mechanisms of strain induced recrystallization.Recrystallization occurs by the formation of subgrains from recovery, and their subsequent growth by boundary migration or coalescence by rotation. It is suggested that the recrystallization and grain growth are enhanced by a small increase in the anorthite content. Peristerite formation in the recrystallized grains is associated with the migration of high angle boundaries under upper greenschist facies conditions.  相似文献   
168.
Three pairs of coexisting pyroxenes of mafic granulites from each of two locations 100 km apart show large chemical differences, especially in Al, Fe, Mn, Ti and Na. Al content of the pyroxenes at the higher pressure locality is more nearly independent of Al of the host rock than are the pyroxenes from the lower pressure locality. All the data confirm that although no significant difference in temperature has emerged, there was a large difference in pressure between the two localities. Al is found to be a more effective discriminant of metamorphic conditions than . As the three pairs of pyroxenes cover a wide range of Fe at each locality, the close relationship of Al and Na (and of Ca-tschermak and jadeite) to Fe becomes evident. This shows that a normalizing procedure should be adopted before comparing localities with different Al, Mn, Ti, Na and other elements or derived components such as jadeite and Ca-tschermak.  相似文献   
169.
Epstein and Yapp's criticism of our paper is answered. It is shown that for all trees so far studied, the cellulose laid down in a warmer period contains C-H hydrogens depleted in deuterium with respect to cellulose laid down in a colder period. Since this is the opposite to that predicted by thermodynamics it is probably due to the temperature effects on one or more of the biochemical reactions leading to cellulose.  相似文献   
170.
Metamorphic biotites examined by transmission electron microscopy contain planar defects on the (001) plane, superlattices, twins and a microstructure causing streaking of k≠3n rows. Analysis of the fringe contrast shows that the fault vectors associated with the planar defects are either R 1=±1/3 [010], R 2=±1/6 [310] or R 3=±1/6 [3 \(\bar 1\) 0]. Structural considerations indicate that a stacking fault R 1, R 2 or R 3 is most likely to exist in the octahedral layer rather than the potassium layer. The result of such a fault on a unit layer of mica is effectively to rotate it through ±120° about c* (equivalent to the common mica twin law). These stacking faults can provide the mechanism for producing the ±120° rotations associated with the common mica polytypes. Furthermore, many of the observed microstructures can be generated by these stacking faults.  相似文献   
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