The origin of basic rocks of the Korosten AMCG complex, Ukrainian shield: Implication of Nd and Sr isotope data     

Leonid Shumlyanskyy  Rob M. Ellam  Olexander Mitrokhin   《Lithos》2006,90(3-4):214-222

The Korosten complex is a Paleoproterozoic gabbro–anorthosite–rapakivi granite intrusion which was emplaced over a protracted time interval — 1800–1737 Ma. The complex occupies an area of about 12 000 km² in the north-western region of the Ukrainian shield. About 18% of this area is occupied by various mafic rocks (gabbro, leucogabbro, anorthosite) that comprise five rock suites: early anorthositic A₁ (1800–1780 Ma), main anorthositic A₂ (1760 Ma), early gabbroic G₃ (between 1760 and 1758 Ma), late gabbroic G₄ (1758 Ma), and a suite of dykes D₅ (before 1737 Ma). In order to examine the relationships between the various intrusions and to assess possible magmatic sources, Nd and Sr isotopic composition in mafic whole-rock samples were measured. New Sr and Nd isotope measurements combined with literature data for the mafic rocks of the Korosten complex are consistent and enable construction of Rb–Sr and Sm–Nd isochronous regressions that yield the following ages: 1870 ± 310 Ma (Rb–Sr) and 1721 ± 90 Ma (Sm–Nd). These ages are in agreement with those obtained by the U–Pb method on zircons and indicate that both Rb–Sr and Sm–Nd systems have remained closed since the time of crystallisation. In detail, however, measurable differences in isotopic composition of the Korosten mafic rock depending on their suite affiliation were revealed. The oldest, A₁ rocks have lower Sr (⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ = 0.70233–0.70288) and higher Nd (εNd₍₁₇₆₀₎ = 1.6–0.9) isotopic composition. The most widespread A₂ anorthosite and leucogabbro display higher Sr and lower Nd isotopic composition: ⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ = 0.70362, εNd₍₁₇₆₀₎ varies from 0.2 to − 0.7. The G₃ gabbro–norite has slightly lower εNd₍₁₇₆₀₎ varying from − 0.7 to − 0.9. Finally, G₄ gabbroic rocks show relatively high initial ⁸⁷Sr/⁸⁶Sr (0.70334–0.70336) and the lowest Nd isotopic composition (εNd₍₁₇₆₀₎ varies from − 0.8 to − 1.4) of any of the mafic rocks of the Korosten complex studied to date. On the basis of Sr and Nd isotopic composition we conclude that Korosten initial melts may have inherited their Nd and Sr isotopic characteristics from the lower crust created during the 2.05–1.95 Ga Osnitsk orogeny and 2.0 Ga continental flood basalt event. Indeed, εNd₍₁₇₆₀₎ values in Osnitsk rocks vary from 0.0 to − 1.9 and from 0.2 to 3.4 in flood basalts. We suggest that these rocks being drawn into the upper mantle might melt and give rise to the Korosten initial melts. ⁸⁷Sr/⁸⁶Sr₍₁₇₆₀₎ values also support this interpretation. We suggest that the Sr and Nd isotopic data currently available on mafic rocks of the Korosten complex are consistent with an origin of its primary melts by partial melting of lower crustal material due to downthrusting of the lower crust into upper mantle forced by Paleoproterozoic amalgamation of Sarmatia and Fennoscandia.  相似文献   

Three-dimensional lithospheric deformation and gravity anomalies associated with oblique continental collision in South Island, New Zealand     

Martin Scherwath  Tim Stern  Fred Davey  Rob Davies 《Geophysical Journal International》2006,167(2):906-916

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Geography's Strategies*     

Rob Kitchin  James D. Sidaway 《The Professional geographer》2006,58(4):485-491

In the context of debates about policy relevance, geotechnologies, and the status of and prospects for geography, we present the case for a promotional strategy based on foregrounding the impact, diversity, and wealth of geographic scholarship.  相似文献   

The effect of iron on montmorillonite stability. (II) Experimental investigation     

James Wilson  Gordon Cressey  Javier Cuadros  David Savage 《Geochimica et cosmochimica acta》2006,70(2):323-336

Several designs proposed for high-level nuclear waste (HLW) repositories include steel waste canisters surrounded by montmorillonite clay. This work investigates montmorillonite stability in the presence of native Fe, magnetite and aqueous solutions under hydrothermal conditions. Two series of experiments were conducted. In the first, mixtures of Na-montmorillonite, magnetite, native Fe, calcite, and NaCl solutions were reacted at 250 °C, P_sat for between 93 and 114 days. In the second series, the starting mixtures included Na-montmorillonite, native Fe and solutions of FeCl₂ which were reacted at temperatures of 80, 150, and 250 °C, P_sat, for 90-92 days. Experiments were analysed using XRD, FT-IR, TEM, ICP-AES, and ICP-MS. In the first series of experiments, native Fe oxidised to produce magnetite and the starting montmorillonite material was transformed to Fe-rich smectite only when the Fe was added predominantly as Fe metal rather than Fe oxide (magnetite). The Fe-rich smectite was initially Fe(II)-rich, which oxidised to produce an Fe(III)-rich form on exposure to air. The expansion of this material on ethylene glycol solvation was much reduced compared to the montmorillonite starting material. TEM imaging shows that partial loss of tetrahedral sheets occurred during transformation of the montmorillonite, resulting in adjacent layers becoming H-bonded with a 7 Å repeat. The reduced swelling property of the Fe-smectite product may be due predominantly to the structural disruption of smectite layers and the formation of H-bonds. Solute activities corresponded to the approximate stability field calculated for hypothetical Fe(II)-saponite. In the second series of experiments, significant smectite alteration was only observed at 250 °C and the product contained a small proportion of a 7 Å repeat structure, observable by XRD. In these experiments, solute activities coincide with berthierine. The experiments indicate that although bentonite is still a desirable choice of backfill material for HLW repositories, some loss of expandability may result if montmorillonite is altered to Fe-rich smectite at the interface between steel canisters and bentonite.  相似文献   

Petrographic and geochemical study of Jurassic dolostones from Lebanon: Evidence for superimposed diagenetic events     

Fadi H. Nader  Rudy Swennen  Rob M. Ellam   《Journal of Geochemical Exploration》2006,89(1-3):288

The Jurassic rock sequence in Lebanon is characterized by pervasive dolomitization (thickness > 1000 m). Two distinct dolostones are recognized within this rock succession: fine-to-medium crystalline seepage-reflux grey dolostone and coarse-crystalline hydrothermal beige dolostone. In this contribution, field, petrographic, and geochemical investigations on a dolostone ‘tongue’, occurring in Late Jurassic carbonates in central Lebanon, are discussed. The dolostone ‘tongue’ consists predominantly of the beige Late Jurassic hydrothermal dolostones. During and/or after the deposition of the overlying continental sandstones (Early Cretaceous), meteoric water percolated through the sand layers and into the underlying beige dolostones. This resulted first in dolomite intracrystalline dissolution, and then in the precipitation of oxides/hydroxides within the pore space. Finally, the precipitation of ferroan dolomite cement — from reduced fluids during a new stage of burial — took place. This study attempts to explain how superimposed diagenetic events result in a single pervasive dolostone body.  相似文献   

Topographic relations: developing a heuristic device for conceptualising networked relations     

Rob Inkpen  Peter Collier  Mark Riley 《Area》2007,39(4):536-543

This paper considers whether the deployment of a topographical metaphor may add value to the recent discussion of networked relations. The paper discusses how viewing relations as part of a relational landscape may add a third dimension to the discussion by allowing an appreciation of the strength, or entrenchment, of relations, and how these entrenchments impact on the development of new relations and the resistance to watershed events. The heuristic device is explored through the case of air survey in the 1920s and 1930s. This illustrative case demonstrates how relations are held together, resisted and reformed to different degrees depending on the varying topography of the relational landscape.  相似文献   

Teleseismic wavefield interpolation and signal extraction using high-resolution linear radon transforms     

C. Wilson  A. Guitton 《Geophysical Journal International》2007,168(1):171-181

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Soil properties controlling seepage erosion contributions to streambank failure     

G. V. Wilson  R. K. Periketi  G. A. Fox  S. M. Dabney  F. D. Shields  R. F. Cullum 《地球表面变化过程与地形》2007,32(3):447-459

The majority of sediment leaving catchments may be from streambank failure. Seepage erosion of unconsolidated sand above a restrictive layer is an important erosion process in incised streams that leads to streambank failure by undercutting banks. The objective of this study was to determine the impact of soil properties on seepage erosion and the resulting streambank failure. Seepage flow and sediment concentrations were measured in situ at eight locations along the banks of a deeply incised stream in northern Mississippi. Using field observations as a guide, the soil profile conditions of a shallow (45 cm) streambank, consisting of 30 cm of topsoil, a 10 cm conductive layer, and a 5 cm restrictive layer, were mimicked in laboratory lysimeter experiments to quantify the hydrologic properties controlling seepage erosion and bank failure under a 40 cm head. The time to flow initiation and the flow rate were linearly related to the slope of the restrictive layer. Seepage erosion began within minutes of flow initiation and resulted in substantial (3 to 34 cm) undercutting of the bank. Sediment concentrations of seeps were as high as 660 g l^?1 in situ and 4500 g l^?1 in the lysimeters. Sediment concentrations were related to the layer slope, thereby indicating the importance of detailed site characterization. The USDA‐ARS Streambank Stability model demonstrated the increase in instability of banks due to undercutting by seepage erosion, but failed to account for the sediment loss due to sapping for stable banks and overestimated the sediment loads for failed banks. Published in 2006 by John Wiley & Sons, Ltd.  相似文献   

Measuring streambank erosion due to ground water seepage: correlation to bank pore water pressure,precipitation and stream stage   总被引：1，自引：0，他引：1  

Garey A. Fox  Glenn V. Wilson  Andrew Simon  Eddy J. Langendoen  Onur Akay  John W. Fuchs 《地球表面变化过程与地形》2007,32(10):1558-1573

Limited information exists on one of the mechanisms governing sediment input to streams: streambank erosion by ground water seepage. The objective of this research was to demonstrate the importance of streambank composition and stratigraphy in controlling seepage flow and to quantify correlation of seepage flow/erosion with precipitation, stream stage and soil pore water pressure. The streambank site was located in Northern Mississippi in the Goodwin Creek watershed. Soil samples from layers on the streambank face suggested less than an order of magnitude difference in vertical hydraulic conductivity (K_s) with depth, but differences between lateral K_s of a concretion layer and the vertical K_s of the underlying layers contributed to the propensity for lateral flow. Goodwin Creek seeps were not similar to other seeps reported in the literature, in that eroded sediment originated from layers underneath the primary seepage layer. Subsurface flow and sediment load, quantified using 50 cm wide collection pans, were dependent on the type of seep: intermittent low‐flow (LF) seeps (flow rates typically less than 0·05 L min^?1), persistent high‐flow (HF) seeps (average flow rate of 0·39 L min^?1) and buried seeps, which eroded unconsolidated bank material from previous bank failures. The timing of LF seeps correlated to river stage and precipitation. The HF seeps at Goodwin Creek began after rainfall events resulted in the adjacent streambank reaching near saturation (i.e. soil pore water pressures greater than ?5 kPa). Seep discharge from HF seeps reached a maximum of 1·0 L min^?1 and sediment concentrations commonly approached 100 g L^?1. Buried seeps were intermittent but exhibited the most significant erosion rates (738 g min^?1) and sediment concentrations (989 g L^?1). In cases where perched water table conditions exist and persistent HF seeps occur, seepage erosion and bank collapse of streambank sediment may be significant. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Stratigraphy and petrology of the Archaean Nsuze Group,northern Natal and southeastern Transvaal,South Africa     

N.V. Armstrong  D.R. Hunter  A.H. Wilson 《Precambrian Research》1982,19(1):75-107

The Nsuze Group is the lower, dominantly volcanic, division of the Pongola Supergroup that accumulated on a sialic basement between 3.1 and 2.9 Ga. The Nsuze Group is subdivided into a lower sedimentary unit (800 m thick), a middle volcanic unit (± 7500 m thick) and an upper volcaniclastic-sedimentary unit (5–600 m thick). The predominant sediments in the lower unit are immature, medium- to very coarse-grained quartz wackes with thin intercalated lenses of quartz and arkosic arenites, and minor conglomeratic wackes. These sediments were deposited in a distal braided stream environment.There followed a major period of volcanism during which lavas showing a continuous spectrum of compositions from basalt to rhyolite were extruded subaerially. Flows of both different and similar compositions are complexly interfingered on both regional and local scales. As volcanism waned, pyroclastic and sedimentary rocks became dominant in the upper unit. The Nsuze Group is gently dipping and is metamorphosed to low greenschist grade.The Nsuze Group is significant in that it provides evidence for the existence of high-standing continental sialic crust in the southeastern part of the Kaapvaal province at ca. 3.0 Ga. Volcanism and sedimentation in the Pongola Supergroup are more typical of Proterozoic basins than of Archaean environments, despite their age. Komatiitic and high-Mg basalts were, however, being extruded in Zimbabwe contemporaneously with the Nsuze lavas.  相似文献