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71.
72.
Lead isotopic measurements were made on Andean igneous rocks of Jurassic to Recent age in Moquegua and Tacna Departments, southernmost Peru, to clarify the petrogenesis of the rocks and, in particular, to investigate the effect of crustal thickness on rock composition. This location in the Cordillera Occidental is ideal for such a study because the ca. 2 Ga Precambrian basement rocks (Arequipa massif) have a distinct Pb isotopic signature which is an excellent tracer of crustal interaction, and because geomorphological research has shown that the continental crust was here thickened drastically in the later Tertiary.Seven samples of quartz diorites and granodiorites from the Ilo and Toquepala intrusive complexes, and seven samples of Toquepala Group subaerial volcanics were analyzed for Pb isotopic compositions. The plutonic rocks range in age from Jurassic to Eocene; the volcanic rocks are all Late Cretaceous to Eocene. With one exception, the Pb isotopic ratios are in the ranges 206Pb/204Pb= 18.52–18.75, 207Pb/204Pb= 15.58–15.65, and 208Pb/204Pb= 38.53–38.74. The data reflect very little or no interaction with old continental material of the Arequipa massif type.Lead from four Miocene Huaylillas Formation ash-flow tuffs, two Pliocene Capillune Formation andesites and five Quaternary Barroso Group andesites has lower 206Pb/204Pb than that in the pre-Miocene rocks, but relatively high 207Pb/204Pb and 208Pb/204Pb (206Pb/204Pb= 18.16–18.30, 207Pb/204Pb= 15.55–15.63, 208Pb/204Pb= 38.45–38.90). Tilton and Barreiro [9] have shown that contamination by Arequipa massif granulites can explain the isotopic composition of the Barosso Group lavas, and the new data demonstrate that this effect is evident, to varying degrees, in all the analysed Neogene volcanic rocks. The initial incorporation of such basement material into the magma coincided with the Early Miocene uplift of this segment of the Cordillera Occidental [32], and thus with the creation of a thick crustal root. The data strongly imply a relationship between crustal thickness and degree of crustal contamination of magmas in this area, but a rigorous relationship is not yet established.  相似文献   
73.
74.
The results of a research study of the carbon monoxide concentration from California to 90° S, Antarctica are presented. The data both extend and support other research studies of the latitudinal distribution of carbon monoxide in that higher concentrations are evident over the Northern Hemisphere than over the Southern Hemisphere. Carbon monoxide concentrations range between 50 to 60 ppb with a few peaks into the 60s in the latitudinal area south of the ITCZ and values of 80 ppb or higher at latitudes north of Hawaii. A comparison is also made of carbon monoxide and ozone concentrations along the flight tract between California and Antarctica, over the Ellsworth Mountains of Antarctica, and between 78° S and the South Pole. These ozone-carbon monoxide data show statistically significant negative correlations in the upper troposphere and lower stratosphere over Antarctica. It is believed that this is a good indication of mixing across the tropopause.  相似文献   
75.
The oxygen fugacity (fO2) of the Earth's upper mantle appears to lie somewhat above that of the iron-wüstite buffer, its fO2 is assumed to have been similar to the present value at the time of core formation. In the upper mantle, the Fe-rich liquid protocore that would form under such conditions of fO2 at elevated temperatures would lie predominantly in the system Fe-S-O. Distribution coefficients for Co, Cu, Ni, Ir, Au, Ir, W, Re, Mo, Ag and Ga between such liquids and basalt are known and minimum values are known for Ge. From these coefficients, upper mantle abundances for the above elements can be calculated by assuming cosmic abundances for the whole Earth and equilibrium between the Fe-S-O protocore and upper mantle. These calculated abundances are surprisingly close to presently known upper mantle abundances; agreements are within a factor of 5, except for Cu, W, and Mo. Therefore, siderophile element abundances in the upper mantle based on known distribution coefficients do not demand a late-stage meteoritic bombardment, and a protocore formed from the upper mantle containing S and O seems likely.As upper mantle abundances fit a local equilibrium model, then either the upper mantle has not been mixed with the rest of the mantle since core formation, or else partition coefficients between protocore and mantle were similar for the whole mantle regardless of P, T, and fO2. The latter possibility seems unlikely over such a P-T range.  相似文献   
76.
This article demonstrates the importance of context on forecast errors. It de J.scribes the development of an unrealistic transportation planning forecast for Denver, Colorado, noting its influence on air quality planning for Denver. The importance of two contextual features, procedural rationality and conflict of interest, to the introduction of error is discussed. The case described implies that different decision-making contexts define different rules of rationality, and substantive rationality may not fit the rules. The type of context and not necessarily a code of ethics will determine this.  相似文献   
77.
The evolution of the Colima volcanic complex can be divided into successive periods characterized by different dynamic and magmatic processes: emission of andesitic to dacitic lava flows, acid-ash and pumice-flow deposits, fallback nuées ardentes leading to pyroclastic flows with heterogeneous magma, plinian air-fall deposits, scoriae cones of alkaline and calc-alkaline nature. Four caldera-forming events, resulting either from major ignimbrite outbursts or Mount St. Helens-type eruptions, separate the main stages of development of the complex from the building of an ancient shield volcano (25 × 30 km wide) up to two summit cones, Nevado and Fuego.The oldest caldera, C1 (7–8 km wide), related to the pouring out of dacitic ash flows, marks the transition between two periods of activity in the primitive edifice called Nevado I: the first one, which is at least 0.6 m.y. old, was mainly andesitic and effusive, whereas the second one was characterized by extrusion of domes and related pyroclastic products. A small summit caldera, C2 (3–3.5 km wide), ended the evolution of Nevado I.Two modern volcanoes then began to grow. The building of the Nevado II started about 200,000 y. ago. It settled into the C2 caldera and partially overflowed it. The other volcano, here called Paleofuego, was progressively built on the southern side of the former Nevado I. Some of its flows are 50,000 y. old, but the age of its first outbursts is not known. However, it is younger than Nevado II. These two modern volcanoes had similar evolutions. Each of them was affected by a huge Mount St. Helens-type (or Bezymianny-type) event, 10,000 y. ago for the Paleofuego, and hardly older for the Nevado II. The landslides were responsible for two horseshoe-shaped avalanche calderas, C3 (Nevado) and C4 (Paleofuego), each 4–5 km wide, opening towards the east and the south. In both cases, the activity following these events was highly explosive and produced thick air-fall deposits around the summit craters.The Nevado III, formed by thick andesitic flows, is located close to the southwestern rim of the C3 caldera. It was a small and short-lived cone. Volcan de Fuego, located at the center of the C4 caldera, is nearly 1500 m high. Its activity is characterized by an alternation of long stages of growth by flows and short destructive episodes related to violent outbursts producing pyroclastic flows with heterogeneous magma and plinian air falls.The evolution of the primitive volcano followed a similar pattern leading to formation of C1 and then C2. The analogy between the evolutions of the two modern volcanoes (Nevado II–III; Paleofuego-Fuego) is described. Their vicinity and their contemporaneous growth pose the problem of the existence of a single reservoir, or two independent magmatic chambers, after the evolution of a common structure represented by the primitive volcano.  相似文献   
78.
79.
Volcan Pico de Orizaba, which marks the eastern end of the Trans-Mexican Volcanic Belt, is one of the largest andesitic composite volcanoes in America. It is located above a series of crustal distensive faults making the boundary of the Coast Plains of the Gulf of Mexico from theAltiplano. For this reason, the volcano shows an asymmetry: from the west, its elevation is about 3,000 m whereas on the eastern side it reaches 4,000 to 4,500 m from its base. The Pico de Orizaba is composed of a primitive stratovolcano raised by a recent summit cone. It has been built by three very distinct volcanic and magmatic phases.
  1. The first one, probably discontinuous effusive activity, lasted more than one million years. It is mainly composed of two pyroxenes-andesites with scarce associated basaltic and dacitic lava-flows. Amphibole is an accessory mineral in most differentiated lavas. On the eastern flank, numerous massive and autobrecciated lava-flows pass outward into thick conglomeratic formations. This effusive phase has built a primitive central volcano and a parasitic cone: the Sierra Negra.
  2. The second phase is of short duration — about 100,000 years or less — in comparison with the first period. It seems that this period began with the formation of a caldera followed by the extrusion of amphibole dacite domes and the overflow of viscous silica-rich (andesite to dacite) lava flows on the northern flank. An intense explosive activity develops:pelean nuées ardentes are associated with extrusion of the domes; numerous plinian eruptions leading to widespread dacitic pumiceous air-falls are produced by both the central and the adventive volcanoes. This sequence of events is interpreted as the progressive emptying of a superficial chamber containing differenciated magma. A rhyolite flow erupted during this phase.
  3. The age of the recent phase is better defined. It started 13,000 years B.P. with the eruption of a dacitic ash-flow containing pumice and scoria-bombs. This was such an intense event that products were found 30 km S.E. of the summit, erasing the top of the former volcano and creating a large crater (4–5 km wide). The present cone, of 1,400–1,500 m elevation, grew in this crater. During a period of 7,000 to 8,000 years, the new stratovolcano experienced various important pyroclastic eruptions with a cycle of the order of 1,000 to 1,500 years. The pyroclastic flows (ash, pumice, and bombs) associated with air-fall deposits are of Saint-Vincent type. They present an heterogeneous dacitic and andesitic magma. The dacitic component is similar to previous differenciated materials. On the other hand, the andesitic magma appears somewhat similar to lava-flows from morphologically young cones erupted outside the central vent system. This eruptive cycle can be interpreted as the result of reoccurring injections of deep basic magma within the crustal chamber. For the last 5,000 years the activity of the modern Pico de Orizaba has again been essentially effusive (andesites) with periodic plinian eruptions.
  相似文献   
80.
Mössbauer measurements at 300 K, 77 K and 4.2 K and X-ray data are presented for synthetic aluminous goethites (α Fe1?x Al x OOH) in two series containing up to 15 mole percent aluminium (hydrothermal preparation) and 19 mole percent aluminium (low-temperature preparation). The Mössbauer spectra for specimens at 300 K and 77 K display broadened and relaxed line-shapes with the relaxation rate increasing with aluminium substitution, whereas all the 4.2 K spectra can be described by a single magnetically split spectrum. At 4.2 K the magnitude of this splitting is 505 kOe for pure goethite and it decreases by 0.52 kOe per mole percent aluminium substitution. The absolute value of the recoil-free fraction f at 4.2 K has been measured for pure goethite and for aluminous goethites containing 7, 15 and 19 mole percent aluminium; it increases from f=0.69±0.02 to f=0.89±0.02 in this range. The increase is attributed to a stiffening of the goethite lattice as it contracts to accommodate the smaller aluminium ion. At 300 K f is found to decrease from f=0.65±0.05 for pure goethite to f=0.50±0.03 for goethite with 19 mole percent aluminium.  相似文献   
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