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The molecules constituting the first hydrate layers on montmorillonite crystal platelets appear to be characterized by preferred orientation and, depending on the exchangeable cation, by an ice-like configuration. Such organized interlamellar water is concluded to contribute to the high swelling pressure and shear resistance, as well as to the very low hydraulic conductivity at high clay bulk densities. At low densities the parallel arrangement of the lamellae alters to edge-to-face associations and the fraction of free water increases. However, even at very low densities the homogeneity of the clay gel still offers very tortuous passages to flowing water, which is manifested by a very low hydraulic conductivity.  相似文献   
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The heterogeneous character of rock suggests the use of statistical mechanics for the formulation of models of plasticity and creep. A stochastic creep model which allows for large variations in strength and size of the involved rock mass is outlined. The model, which is analogous to a previously developed concept for clastic materials, is shown to account rather well for typical creep behaviour of rock at moderate stresses and temperatures. Thus, it yields the often observed linear relation between the creep strain and the logarithm of time.  相似文献   
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A set of high-resolution IR solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, from 84/06 to 93/06, and at the National Solar Observatory McMath-Pierce solar telescope facility on Kitt Peak, Arizona, U.S.A. from 78/05 to 92/07 have been analyzed to determine the vertical column abundances of hydrogen cyanide, HCN, above the two stations. The analysis was based on least-squares curve fitting of calculated spectra to the observations encompassing the P4 and the P8 lines of HCN respectively located at 3299.5273 and 3287.2483 cm–1. The results obtained for the two stations indicate that no significant long-term trend affects either of the two databases; however, this analysis reveals variable increases during springtime of up to a factor of 2 in the HCN total column above the Jungfraujoch and even up to 3 above Kitt Peak. The calculated mean vertical column abundances, excluding the spring observations, are equal to (2.55±0.30)×1015 molec./cm2 (S.D.) and (2.75±0.30)×1015 molec./cm2 respectively above the Jungfraujoch and the Kitt Peak observatories. Based on a realistic volume mixing ratio profile, these columns translate into mean volume mixing ratios equal to 190×10–12 ppv at the respective altitudes of the stations.  相似文献   
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Surface sediment diatom assemblages for 86 Alpine lakes were analysed focusing on the dominant genusCyclotella and corresponding environmental data. The range of morphological variability of theCyclotella bodanica/radiosa, C. distinguenda, C. ocellata, C. comensis andC. stelligera complexes was documented. Significance tests included in the canonical correspondence analysis (CCA) indicated that total phosphorus, conductivity and surface water temperature were significantly correlated withCyclotella taxa assemblage distribution. Numerical species optima and tolerances were calculated in respect to these significant variables using weighted averaging (WA) regression and calibration. CCA and WA were able to provide information about the environmental preferences of the various morphotypes observed.  相似文献   
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Upper-mantle structure under the Baltic Shield is studied using non-linear high resolution teleseismic P -phase tomography. Observed relative arrival-time residuals from 52 teleseismic earthquakes recorded by the Swedish National Seismological Network (SNSN) are inverted to delineate the structure of the upper mantle. The network consists of 47 (currently working) three-component broad-band stations located in an area about 450 km wide and 1450 km long. In order to reduce complications due to possible significant three-dimensionality of Earth structure, events chosen for this study lay close to in-line with the long-axis of the array  (±30°)  . Results indicate P -wave velocity perturbations of ±3 per cent down to at least 470 km below the network. The size of the array allows inversion for structures even at greater depths, and lateral variations of velocity at depths of up to 680 km appear to be resolved. Below the central part of the array (60°–64° N), where ray coverage is best, the data reveals a large region of relatively low velocity at depths of over about 300 km. At depths less than about 250–300 km, the models include a number of features, including an apparent slab-like structure dipping gently towards the north.  相似文献   
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We present a model for pore spaces that consists of two parts related by duality: (1) a decomposition of an open polyhedral pore space into open contractible pore bodies separated by relatively open interfaces and (2) a pore network that is homotopy equivalent to the pore space. The dual model is unique and free of parameters, but it relies on regularity conditions for the pore space. We show how to approximate any pore space by the interior of a polyhedral complex such that the regularity conditions are fulfilled. Thus, we are able to calculate the dual model from synthetic porous media and images of real porous media. The pore bodies are unions of relatively open Delaunay cells with respect to the corners of the pore boundary, and the pore network consists of certain at most two-dimensional (2D) Voronoi cells with respect to the corners of the pore boundary. The pore network describes the neighborhood relations between the pore bodies. In particular, any relatively open 2D Delaunay face f separating two pore bodies has a unique (relatively open) dual network edge. In our model, f is a pore throat only if it is hit by its dual network edge. Thus, as opposed to widespread intuition, any pore throat is convex, and adjacent pore bodies are not necessarily separated by pore throats. Due to the duality between the pore network and the decomposition of the pore space into pore bodies it is straightforward to store the geometrical properties of the pore bodies [pore throats] as attributes of the dual network vertices [edges]. Such an attributed network is used to perform 2D drainage simulations. The results agree very well with those from a pore-morphology based modeling approach performed directly on the digital image of a porous medium. Contractibility of the pore bodies and homotopy equivalence of the pore space and the pore network is proven using discrete Morse theory and the nerve theorem from combinatorial topology.  相似文献   
40.
The U-Pb SHRIMP age determinations of zircons from the Habach terrane (Tauern Window, Austria) reveal a complex evolution of this basement unit, which is exposed in the Penninic domain of the Alpine orogen. The oldest components are found in zircons of a metamorphosed granitoid clast, of a migmatitic leucosome, and of a meta-rhyolitic (Variscan) tuff which bear cores of Archean age. The U-Pb ages of discordant zircon cores of the same rocks range between 540 and 520 Ma. It is assumed that the latter zircons were originally also of Archean origin and suffered severe lead loss, whilst being incorporated into Early-Cambrian volcanic arc magmas. The provenance region of the Archean (2.64-2.06 Ga) zircons is assumed to be a terrane of Gondwana affinity: i.e., the West African craton (Hoggar Shield, Reguibat Shield). The Caledonian metamorphism left a pervasive structural imprint in amphibolite facies on rocks of the Habach terrane; it is postdated by discordant zircons of a migmatitic leucosome at <440 Ma (presumably ca. 420 Ma). Alpine and Variscan upper greenschist- to amphibolite-facies conditions caused partial lead loss in zircons of a muscovite gneiss ('white schist') only, where extensive fluid flow and brittle deformation due to its position near a nappe-sole thrust enhanced the grains' susceptibility to isotopic disturbance. The Habach terrane - an active continental margin with ensialic back-arc development - showed subduction-induced magmatic activity approx. between 550 and 507 Ma. Back-arc diorites and arc basalts were intruded by ultramafic sills and subsequently by small patches of mantle-dominated unaltered and (in the vicinity of a major tungsten deposit) altered granitoids. Fore-arc (shales) and back-arc (greywackes, cherts) basin sediments as well as arc and back-arc magmatites were not only nappe-stacked by the Caledonian compressional regime closing the presumably narrow oceanic back-arc basin and squeezing mafic to ultramafic cumulates out of high-level magma chambers (496-482 Ma). It also induced uplift and erosion of deeply rooted crystalline complexes and triggered the development of a successor basin filled with predominantly clastic greywacke-arkosic sediments. The study demonstrates that the basement rocks exposed in the Habach terrane might be the 'missing link' between similar units of the more westerly positioned External domain (i.e., Aar, Aiguilles Rouges, Mont Blanc) and the Austroalpine domain to the east (Oetztal, Silvretta).  相似文献   
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