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31.
Taicheng An Hui Chen Huiying Zhan Kun Zhu Ronny Berndtsson 《Environmental Geology》2005,47(4):467-474
A laboratory study was executed to investigate the effect of surfactants to enhance sorption of polycyclic aromatic hydrocarbon (PAH) contaminants in loess soil. Phenanthrene and naphthalene were chosen as organic contaminant indicators in loess soil modified by the cation surfactant hexadecyltrimethylammonium (HDTMA) bromide. The kinetic behavior of sorption during transport in natural and modified loess soil was studied. The results indicated that sorption rate in the cation surfactant modified loess soils was at least 3 times faster than that of the natural soil. A first-order kinetics model fitted the sorption data well for both soils. The sorption rates of the two organic compounds were related to their primary residual quantity on the soils. The experiments showed that sorption amounts approached constant values approximately within 30 and 90 min for naphthalene and phenanthrene at 298–318 K, respectively. The rate constants, however, displayed negative correlation with increasing temperature. With changing temperature, the activation energy was calculated at –6.196–1.172 kJ/mol for naphthalene and –28.86–15.70 kJ/mol for phenanthrene at 298–318 K. The results can be used to predict the sorption kinetics of phenanthrene and naphthalene in loess soils, and in a wider perspective, be used to better understand the transport of petroleum contaminants in the soil environment. 相似文献
32.
Antonio B. S. Poléo Sigurd A. Øxnevad Kjartan Østbye Ronny A. Andersen Deborah H. Oughton Leif A. Vøllestad 《Aquatic Sciences - Research Across Boundaries》1995,57(4):350-359
Crucian carp were exposed to three combinations of pH and inorganic aluminium concentrations for 25 days. Mortality, plasma chloride and haematocrit, and gill aluminium content were investigated. No mortality was observed in any of the three exposures. Crucian carp survived acidic Al-rich water (pH 5.17) with a high concentration of low-molecular weight inorganic Al species (242 µgl–1) for 25 days. These fish had lowered plasma chloride levels and high amounts of aluminium on their gills compared to fish exposed to acidic Al-poor water (pH 5.16 and 12 µgl–1 Ali) and control water (pH 6.29 and 4 µgl–1 Ali). Haematocrit was the same in all three exposures. Because aluminium was not acutely toxic to the anoxia tolerant crucian carp, the present results give support to the hypothesis that Al polymerization with subsequent hypoxia is of high importance for the mechanism of acute Al toxicity to fish. 相似文献
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34.
Ronny Boch Xianfeng Wang Tobias Kluge Albrecht Leis Ke Lin Hannes Pluch Florian Mittermayr Andre Baldermann Michael E. Bttcher Martin Dietzel 《Sedimentology》2019,66(2):604-635
The well‐known Erzberg site represents the largest siderite (FeCO3) deposit in the world. It consists of various carbonates accounting for the formation of prominent CaCO3 (dominantly aragonite) precipitates filling vertical fractures of different width (centimetres to decimetres) and length (tens of metres). These commonly laminated precipitates are known as ‘erzbergite’. This study focuses on the growth dynamics and environmental dependencies of these vein fillings. Samples recovered on‐site and from mineral collections were analyzed, and these analyses were further complemented by modern water analyses from different Erzberg sections. Isotopic signatures support meteoric water infiltration and sulphide oxidation as the principal hydrogeochemical mechanism of (Ca, Mg and Fe) carbonate host rock dissolution, mobilization and vein mineralization. Clumped isotope measurements revealed cool formation temperatures of ca 0 to 10°C for the aragonite, i.e. reflecting the elevated altitude Alpine setting, but unexpectedly low for aragonite nucleation. The 238U–234U–230Th dating yielded ages from 285·1 ± 3·9 to 1·03 ± 0·04 kyr bp and all samples collected on‐site formed after the Last Glacial Maximum. The observed CaCO3 polymorphism is primarily controlled by the high aqueous Mg/Ca ratios resulting from dissolution of Mg‐rich host rocks, with Mg/Ca further evolving during prior CaCO3 precipitation and CO2 outgassing in the fissured aquifer. Aragonite represents the ‘normal’ mode of erzbergite formation and most of the calcite is of diagenetic (replacing aragonite) origin. The characteristic lamination (millimetre‐scale) is an original growth feature and mostly associated with the deposition of stained (Fe‐rich) detrital particle layers. Broader zonations (centimetre‐scale) are commonly of diagenetic origin. Petrographic observations and radiometric dating support an irregular nature for most of the layering. Open fractures resulting from fault tectonics or gravitational mass movements provide water flow routes and fresh chemical reaction surfaces of the host rock carbonates and accessory sulphides. If these prerequisites are considered, including the hydrogeochemical mechanism, modern water compositions, young U‐Th ages and calculated precipitation rates, it seems unlikely that the fractures had stayed open over extended time intervals. Therefore, it is most likely that they are geologically young. 相似文献
35.
Accidental marine pollution can have major ecological and economic consequences at national and trans-national levels, and there is a need to achieve a better integration of science into actual decision-making systems to support prevention measures, response systems and management activities.. Effective linking mechanisms between R&D and end-users/policy stakeholders are required to ensure the relevance of R&D, effective uptake of R&D outputs, and suitable policy development. Different issues and barriers to effectively link accidental marine pollution R&D effort to end-users concerns and needs and to develop a trans-national strategic approach are identified, analysed, and further developed into recommendations. 相似文献
36.
Steffen Trümper Birgit Gaitzsch Jörg W. Schneider Bodo-Carlo Ehling Reinhard Kleeberg Ronny Rößler 《Sedimentology》2020,67(4):1973-2012
Fluvial red beds containing anatomically preserved large woody debris shed new light on seasonally dry biomes of the Pennsylvanian–Permian transition and elucidate the concurrence of river depositional systems and vegetation. As a result, the occurrence, distribution and preservation of petrified large woody debris accumulations are considered crucial to understanding the role of arborescent vegetation in shaping fluvial environments. This study reports sizeable silicified trunks and corresponding fluvial architectures from the uppermost Pennsylvanian (upper Gzhelian) Siebigerode Formation (Kyffhäuser, central Germany). The origin, taphonomy and depositional environment of the fossil woods are elucidated by using a multidisciplinary approach including geological mapping, lithofacies analysis, sediment petrography, wood anatomical studies and microstructure analyses. Results reflect the gradual burial of a gentle basement elevation by sand-bed to gravel-bed braided rivers at the north-western margin of the perimontane Saale Basin. Facies architectures resulted from a complex interplay of syndepositional tectonics, repeated palaeorelief rejuvenation, high-frequency channel avulsion, seasonally dry climate and woody debris–sediment interactions. The alluvial influx and cut-bank erosion recruited trunks from adjacent semi-riparian slope habitats vegetated by up to 40 m tall cordaitaleans and conifers. High discharge in wide braids facilitated uncongested transport of large woody debris. Trunk entombment and initial preservation resulted from grounding on barforms, anchoring by attached roots and subsequent burial. The post-depositional two-phase silicification was influenced by hydrothermal hematite mineralization and determined a selective wood preservation pattern known as ‘pointstone’. Large woody debris-induced sedimentary structures (‘LWDISS’) are introduced as a class of sediment structures formed by the biogenic impact on terrestrial deposition. 相似文献
37.
Impact of complexity on daily and multi-step forecasting of streamflow with chaotic,stochastic, and black-box models 总被引：1，自引：0，他引：1
Hakan?TongalEmail author Ronny?Berndtsson 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(3):661-682
Despite significant research advances achieved during the last decades, seemingly inconsistent forecasting results related to stochastic, chaotic, and black-box approaches have been reported. Herein, we attempt to address the entropy/complexity resulting from hydrological and climatological conditions. Accordingly, mutual information function, correlation dimension, averaged false nearest neighbor with E1 and E2 quantities, and complexity analysis that uses sample entropy coupled with iterative amplitude adjusted Fourier transform were employed as nonlinear deterministic identification tools. We investigated forecasting of daily streamflow for three climatologically different Swedish rivers, Helge, Ljusnan, and Kalix Rivers using self-exciting threshold autoregressive (SETAR), k-nearest neighbor (k-nn), and artificial neural networks (ANN). The results suggest that the streamflow in these rivers during the 1957–2012 period exhibited dynamics from low to high complexity. Specifically, (1) lower complexity lead to higher predictability at all lead-times and the models’ worst performances were obtained for the most complex streamflow (Ljusnan River), (2) ANN was the best model for 1-day ahead forecasting independent of complexity, (3) SETAR was the best model for 7-day ahead forecasting by means of performance indices, especially for less complexity, (4) the largest error propagation was obtained with the k-nn and ANN and thus these models should be carefully used beyond 2-day forecasting, and (5) higher number input variables except for the dominant variables made insignificant impact on forecasting performances for ANN and k-nn models. 相似文献
38.
Nishank Saxena Ronny Hofmann Seán Dolan Rituparna Sarker Chen Bao Stephan Gelinsky 《Geophysical Prospecting》2019,67(4):843-871
The measured geophysical response of sand – shale sequences is an average over multiple layers when the tool resolution (seismic or well log) is coarser than the scale of sand – shale mixing. Shale can be found within sand – shale sequences as laminations, dispersed in sand pores, as well as load bearing clasts. We present a rock physics framework to model seismic/sonic properties of sub-resolution interbedded shaly sands using the so-called solid and mineral substitution models. This modelling approach stays consistent with the conceptual model of the Thomas–Stieber approach for estimating volumetric properties of shaly sands; thus, this work connects established well log data-based petrophysical workflows with quantitative interpretation of seismic data for modelling hydrocarbon signature in sand – shale sequences. We present applications of the new model to infer thickness of sand – shale lamination (i.e., net to gross) and other volumetric properties using seismic data. Another application of the new approach is fluid substitution in sub-resolution interbedded sand–shale sequences that operate directly at the measurement scale without the need to downscale; such a procedure has many practical advantages over the approach of “first-downscale-and-then-upscale” as it is not very sensitive to errors in estimated sand fraction and end member sand/shale properties and remains stable at small sand/shale fractions. 相似文献
39.
Tor Arne Johansen Bent Ole Ruud Ronny Tømmerbakke Kristian Jensen 《Geophysical Prospecting》2019,67(3):532-549
Geophysical surveying of the Arctic will become increasingly important in future prospecting and monitoring of the terrestrial and adjacent areas in this hemisphere. Seismic data acquired on floating ice are hampered with extensive noise due to ice vibrations related to highly dispersive ice flexural waves generated by the seismic source. Several experiments have been conducted on floating ice in van Mijenfjorden in Svalbard in the Norwegian Arctic to specifically analyse the extent of flexural waves recorded with various seismic receivers and sources deployed both on top of ice and in the water below. The data show that flexural waves are severely damped at 5 m or deeper below the ice and hydrophone data suffer less from these vibrations compared with data recorded on the ice. Aliasing of single receiver hydrophone data can to some extent be suppressed using an in-line line source of detonating cord. Experiments on ice on shallow water show prominent guided wave modes often referred to as Scholte waves propagating along the seabed. In this case, both flexural and Scholte waves interfere and make a complicated pattern of coherent noise. On shallow water, the positioning and type of the seismic source must be evaluated with respect to the coherent noise generated by these waves. Geophone strings of 25 m effectively suppress both flexural and Scholte waves due to their relative short wavelengths. An airgun generates relative more low-frequency energy than a surface source of detonating cord. Accordingly, seismic mapping of deep seismic horizons seem to be best achieved using geophone strings of such length and an airgun source. For shallow targets, the use of hydrophones in combination with detonating cord is an appropriate solution. Seismic surveying in the Arctic always have to follow environmental restrictions of not disturbing or harming wildlife and not causing permanent footprints into the vulnerable tundra, which implies that the choice of seismic acquisition strategy might occur as a trade-off between optimum data quality and environmental constraints. 相似文献
40.
Harald Milsch Ronny Giese Mathias Poser Stefan Kranz Elvira Feldbusch Simona Regenspurg 《Environmental Earth Sciences》2013,70(8):3459-3463
A versatile fluid–chemical monitoring unit has been developed in the framework of the geothermal research platform Groß Schönebeck, Germany. It enables selective online and in situ measurements of various physico-chemical parameters at different surface locations of a geothermal fluid loop. Sensors are provided for pressure, temperature, volumetric flow rate, density, pH-value, redox potential, oxygen content, and electrical conductivity. In addition, the apparatus features two fluid samplers to manually collect fluid under in situ conditions and ultimately analyze the solution composition. All devices are mounted on a rack allowing easy transfer of the apparatus to other geothermal plants. The maximum operating pressure and temperature of the unit are 15 bar and 150 °C, respectively. The scientific and technical purpose of the system is to monitor a compositional variability of the produced fluid and chemical processes potentially occurring within the plant. These may result from reactions between the fluid and the surrounding materials, e.g., corrosion. Also, mineral precipitation as a consequence of temperature and/or pressure decrease or oxygen contamination may occur. This information is of paramount importance as so induced reactions might lead to failure of plant components or may damage the geothermal reservoir upon fluid reinjection and thus decrease injectivity. 相似文献