Physiological and isotopic responses of scleractinian corals to ocean acidification   总被引：1，自引：0，他引：1  

Shani Krief  Erica J. Hendy  Maoz Fine  Ruth Yam  Gavin L. Foster 《Geochimica et cosmochimica acta》2010,74(17):4988-301

Uptake of anthropogenic CO₂ by the oceans is altering seawater chemistry with potentially serious consequences for coral reef ecosystems due to the reduction of seawater pH and aragonite saturation state (Ω_arag). The objectives of this long-term study were to investigate the viability of two ecologically important reef-building coral species, massive Porites sp. and Stylophora pistillata, exposed to high pCO₂ (or low pH) conditions and to observe possible changes in physiologically related parameters as well as skeletal isotopic composition. Fragments of Porites sp. and S. pistillata were kept for 6-14 months under controlled aquarium conditions characterized by normal and elevated pCO₂ conditions, corresponding to pH_T values of 8.09, 7.49, and 7.19, respectively. In contrast with shorter, and therefore more transient experiments, the long experimental timescale achieved in this study ensures complete equilibration and steady state with the experimental environment and guarantees that the data provide insights into viable and stably growing corals. During the experiments, all coral fragments survived and added new skeleton, even at seawater Ω_arag < 1, implying that the coral skeleton is formed by mechanisms under strong biological control. Measurements of boron (B), carbon (C), and oxygen (O) isotopic composition of skeleton, C isotopic composition of coral tissue and symbiont zooxanthellae, along with physiological data (such as skeletal growth, tissue biomass, zooxanthellae cell density, and chlorophyll concentration) allow for a direct comparison with corals living under normal conditions and sampled simultaneously. Skeletal growth and zooxanthellae density were found to decrease, whereas coral tissue biomass (measured as protein concentration) and zooxanthellae chlorophyll concentrations increased under high pCO₂ (low pH) conditions. Both species showed similar trends of δ¹¹B depletion and δ¹⁸O enrichment under reduced pH, whereas the δ¹³C results imply species-specific metabolic response to high pCO₂ conditions. The skeletal δ¹¹B values plot above seawater δ¹¹B vs. pH borate fractionation curves calculated using either the theoretically derived α_B value of 1.0194 (Kakihana et al. (1977) Bull. Chem. Soc. Jpn.50, 158) or the empirical α_B value of 1.0272 (Klochko et al. (2006) EPSL248, 261). However, the effective α_B must be greater than 1.0200 in order to yield calculated coral skeletal δ¹¹B values for pH conditions where Ω_arag ? 1. The δ¹¹B vs. pH offset from the seawater δ¹¹B vs. pH fractionation curves suggests a change in the ratio of skeletal material laid down during dark and light calcification and/or an internal pH regulation, presumably controlled by ion-transport enzymes. Finally, seawater pH significantly influences skeletal δ¹³C and δ¹⁸O. This must be taken into consideration when reconstructing paleo-environmental conditions from coral skeletons.  相似文献   

Cosmogenic Be and Al exposure ages of tors and erratics, Cairngorm Mountains, Scotland: Timescales for the development of a classic landscape of selective linear glacial erosion     

William M. Phillips  Adrian M. Hall  Ruth Mottram  L. Keith Fifield  David E. Sugden 《Geomorphology》2006,73(3-4):222-245

The occurrence of tors within glaciated regions has been widely cited as evidence for the preservation of relic pre-Quaternary landscapes beneath protective covers of non-erosive dry-based ice. Here, we test for the preservation of pre-Quaternary landscapes with cosmogenic surface exposure dating of tors. Numerous granite tors are present on summit plateaus in the Cairngorm Mountains of Scotland where they were covered by local ice caps many times during the Pleistocene. Cosmogenic ¹⁰Be and ²⁶Al data together with geomorphic relationships reveal that these landforms are more dynamic and younger than previously suspected. Many Cairngorm tors have been bulldozed and toppled along horizontal joints by ice motion, leaving event surfaces on tor remnants and erratics that can be dated with cosmogenic nuclides. As the surfaces have been subject to episodic burial by ice, an exposure model based upon ice and marine sediment core proxies for local glacial cover is necessary to interpret the cosmogenic nuclide data. Exposure ages and weathering characteristics of tors are closely correlated. Glacially modified tors and boulder erratics with slightly weathered surfaces have ¹⁰Be exposure ages of about 15 to 43 ka. Nuclide inheritance is present in many of these surfaces. Correction for inheritance indicates that the eastern Cairngorms were deglaciated at 15.6 ± 0.9 ka. Glacially modified tors with moderate to advanced weathering features have ¹⁰Be exposure ages of 19 to 92 ka. These surfaces were only slightly modified during the last glacial cycle and gained much of their exposure during the interstadial of marine Oxygen Isotope Stage 5 or earlier. Tors lacking evidence of glacial modification and exhibiting advanced weathering have ¹⁰Be exposure ages between 52 and 297 ka. Nuclide concentrations in these surfaces are probably controlled by bedrock erosion rates instead of discrete glacial events. Maximum erosion rates estimated from ¹⁰Be range from 2.8 to 12.0 mm/ka, with an error weighted mean of 4.1 ± 0.2 mm/ka. Three of these surfaces yield model exposure-plus-burial ages of 295_− 71^+ 84, 520_− 141^+ 178, and 626_− 85^+ 102 ka. A vertical cosmogenic nuclide profile across the oldest sampled tor indicates a long-term emergence rate of 31 ± 2 mm/ka. These findings show that dry-based ice caps are capable of substantially eroding tors by entraining blocks previously detached by weathering processes. Bedrock surfaces and erratic boulders in such settings are likely to have nuclide inheritance and may yield erroneous (too old) exposure ages. While many Cairngorm tors have survived multiple glacial cycles, rates of regolith stripping and bedrock erosion are too high to permit the widespread preservation of pre-Quaternary rock surfaces.  相似文献   

A Survey for EHB Stars in the Galactic Bulge     

Donald M. Terndrup  Deokkeun An  Angela Hansen  Ruth C. Peterson  Alistair R. Walker  Elaine M. Sadler 《Astrophysics and Space Science》2004,291(3-4):247-252

We present a progress report on an extensive survey to find and characterize all types of horizontal-branch stars in the nuclear bulge of the Galaxy. We have obtained wide, shallow imaging in UBV of ≈12 square degrees in the bulge, with follow-up spectroscopy for radial velocities and metal abundance determinations. We have discovered a number of metal-rich blue HB stars, whose presence in the bulge is expected by the interpretation of the extragalactic ultraviolet excess. Very deep images have been obtained in UBV and SDSS u along the bulge minor axis, which reveal a significant number of EHB candidates fainter than B=19, i.e., with the same absolute magnitudes as EHB stars in several globular clusters.  相似文献   

Role of the backstop-to-cover thickness ratio on vergence partitioning in experimental thrust wedges     

Fabrizio Storti  Ruth Soto Marin  Claudio Faccenna  & Antonio Casas Sainz 《地学学报》2001,13(6):413-417

The ratio between the thickness of the sedimentary sequences offscraped from the subducting plate ( H _c) and the average thickness of the backstop ( H _b) is expected to significantly influence vergence partitioning in thrust wedges. A series of simple sandbox experiments was performed to study the role of the H _c/ H _b ratio in model thrust wedges. The results obtained show that thrust wedges with H _c/ H _b values lower than 1 are essentially pro-ward verging, with minor retro-ward faulting; H _c/ H _b values greater than 1 imply an increase of vergence partitioning. When a threshold value is exceeded, fully partitioned, doubly vergent thrust wedges develop. Comparison with natural submarine thrust wedges suggests that these experimental results may provide useful insights on the evolution of structural architecture at convergent margins.  相似文献   

Automated facies identification by Direct Push-based sensing methods (CPT,HPT) and multivariate linear discriminant analysis to decipher geomorphological changes and storm surge impact on a medieval coastal landscape     

Hanna Hadler  Andreas Vött  Timo Willershäuser  Dennis Wilken  Ruth Blankenfeldt  Claus von Carnap-Bornheim  Kurt Emde  Peter Fischer  Ulf Ickerodt  Stefanie Klooß  Bente Majchczack  Lea Obrocki  Wolfgang Rabbel 《地球表面变化过程与地形》2021,46(15):3228-3251

In ad 1362, a major storm surge drowned wide areas of cultivated medieval marshland along the north-western coast of Germany and turned them into tidal flats. This study presents a new methodological approach for the reconstruction of changing coastal landscapes developed from a study site in the Wadden Sea of North Frisia. Initially, we deciphered long-term as well as event-related short-term geomorphological changes, using a geoscientific standard approach of vibracoring, analyses of sedimentary, geochemical and microfaunal palaeoenvironmental parameters and radiocarbon dating. In a next step, Direct Push (DP)-based Cone Penetration Testing (CPT) and the Hydraulic Profiling Tool (HPT) were applied at vibracore locations to obtain in situ high-resolution stratigraphic data. In a last step, multivariate linear discriminant analysis (LDA) was successfully applied to efficiently identify different sedimentary facies (e.g., fossil marsh or tidal flat deposits) from the CPT and HPT test dataset, to map the facies' lateral distribution, also in comparison to reflection seismic measurements and test their potential to interpolate the borehole and CPT/HPT data. The training dataset acquired for the key site from coring and DP sensing finally allows an automated facies classification of CPT/HPT data obtained elsewhere within the study area. The new methodological approach allowed a detailed reconstruction of the local coastal landscape development in the interplay of natural marsh formation, medieval land reclamation and storm surge-related land losses.  相似文献   

Kinetics of neptunium(V) sorption and desorption on goethite: An experimental and modeling study     

Ruth M. Tinnacher  Mavrik Zavarin  Annie B. Kersting 《Geochimica et cosmochimica acta》2011,75(21):6584-6599

Various sorption phenomena, such as aging, hysteresis and irreversible sorption, can cause differences between contaminant (ad)sorption and desorption behavior and lead to apparent sorption ‘asymmetry’. We evaluate the relevance of these characteristics for neptunium(V) (Np(V)) sorption/desorption on goethite using a 34-day flow-cell experiment and kinetic modeling. Based on experimental results, the Np(V) desorption rate is much slower than the (ad)sorption rate, and appears to decrease over the course of the experiment. The best model fit with a minimum number of fitting parameters was achieved with a multi-reaction model including (1) an equilibrium Freundlich site (site 1), (2) a kinetically-controlled, consecutive, first-order site (site 2), and (3) a parameter ψ_2,de, which characterizes the desorption rate on site 2 based on a concept related to transition state theory (TST). This approach allows us to link differences in adsorption and desorption kinetics to changes in overall reaction pathways, without assuming different adsorption and desorption affinities (hysteresis) or irreversible sorption behavior a priori. Using modeling as a heuristic tool, we determined that aging processes are relevant. However, hysteresis and irreversible sorption behavior can be neglected within the time-frame (desorption over 32 days) and chemical solution conditions evaluated in the flow-cell experiment. In this system, desorption reactions are very slow, but they are not irreversible. Hence, our data do not justify an assumption of irreversible Np(V) sorption to goethite in transport models, which effectively limits the relevance of colloid-facilitated Np(V) transport to near-field environments. However, slow Np(V) desorption behavior may also lead to a continuous contaminant source term when metals are sorbed to bulk mineral phases. Additional long-term experiments are recommended to definitely rule out irreversible Np(V) sorption behavior at very low surface loadings and environmentally-relevant time-scales.  相似文献   

Enacting separate social worlds: ‘International’ and ‘local’ students in public space in central Melbourne     

Ruth Fincher 《Geoforum》2011,42(5):539-549

In creating separate and distinct spaces and forms of socialising for themselves, ‘international’ and ‘local’ university students in central Melbourne are influenced by three key, spatially-linked processes. The first is institutional - it includes the allocation of international students to a certain type of housing which differs from that chosen by local students, and the practice of universities, student clubs and local churches to gather international and local students into separate groupings. The second is locational. It is the process by which international students find themselves living principally in and around the edge of the central city, an entertainment district with rowdy characteristics that these students often find distasteful. Local students, in contrast, locate in the inner suburbs for the most part, at a distance from the city centre hotspot. The third process sees socialising habits that are enacted in and by virtue of the public places in which they occur. This self-enacting socialisation further separates local students from international students. All three processes demonstrate how certain characteristics of the built environment can be invested with particular meanings and become complicit in shaping racialised social interactions.  相似文献   

Calcium isotopes in a proglacial weathering environment: Damma glacier, Switzerland     

Ruth S. Hindshaw  Ben C. Reynolds  Ruben Kretzschmar 《Geochimica et cosmochimica acta》2011,75(1):106-7046

The biogeochemical cycling and isotopic fractionation of calcium during the initial stages of weathering were investigated in an alpine soil chronosequence (Damma glacier, Switzerland). This site has a homogeneous silicate lithology and minimal biological impacts due to sparse vegetation cover. Calcium isotopic compositions, obtained by TIMS using a ⁴³Ca-⁴⁶Ca double spike, were measured in the main Ca pools. During this very early stage of weathering, the young soils which have formed (δ^44/42Ca=+0.44‰) were indistinguishable to the rocks from which they were derived (δ^44/42Ca=+0.44‰) and stream water (δ^44/42Ca=+0.48‰) was also within error of the average rock. This lack of variation indicates that the dissolution of the bulk silicate rock does not strongly fractionate Ca isotopes. The only Ca pool which was strongly fractionated from bulk rock was vegetation, which exhibited an enrichment of light Ca isotopes. Significant Ca isotope fractionation between bulk rock and the dissolved flux of Ca is likely to only occur where the Ca biogeochemical cycle is dominated by secondary processes such as biological cycling, adsorption and secondary mineral precipitation.  相似文献   

Type I and Type II chlorophyll-a transformation products associated with algal senescence     

Nicole J. Bale  Ruth L. AirsCarole A. Llewellyn 《Organic Geochemistry》2011,42(5):451-464

Microalgal culture experiments to track chlorophyll-a (chl-a) transformation during senescence were characterised by the production of demetallated Type I chl-a transformation products in Pavlova gyrans and by the production of oxidative Type I transformation products in Isochrysis galbana. Dark-induced senescence in I. galbana produced a different distribution of Type I products from nutrient depletion induced senescence. Several novel Type I compounds were detected, including a chl-d like compound in I. galbana and a chl-a precursor like compound in P. gyrans. Type II chl-a transformation products were detected in the dissolved phase of I. galbana cultures; this is the first report of such compounds associated with marine algae.  相似文献   

A model of boiling for fluid inclusion studies: Application to the Bolaños Ag–Au–Pb–Zn epithermal deposit,Western Mexico     

Carles Canet  Sara I. Franco  Rosa María Prol-Ledesma  Eduardo González-Partida  Ruth Esther Villanueva-Estrada 《Journal of Geochemical Exploration》2011

Boiling can be inferred from fluid inclusion microthermometry studies when a progressive increase in apparent salinity is observed along with a decrease of homogenization temperature (T_H) and depth, thus reflecting the partitioning of non-volatile solutes into the liquid phase during steam loss. We propose a model for fluid evolution during boiling based on mass and heat balance equations, which establishes paths in the T_H-salinity space that can be compared with fluid inclusion data to confirm or discard boiling. Additionally, the model allows calculating paleo-depths, for which the effect of steam bubbles lowering the hydrostatic pressure is taken into account.  相似文献