An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite     

Je-Hun Jang  Ryan Mathur  Laura J. Liermann  Shane Ruebush  Susan L. Brantley 《Chemical Geology》2008,250(1-4):40-48

We measured the Fe isotope fractionation during the reactions of Fe(II) with goethite in the presence and absence of a strong Fe(III) chelator (desferrioxamine mesylate, DFAM). All experiments were completed in an O₂-free glove box. The concentrations of aqueous Fe(II) ([Fe(II)_aq]) decreased below the initial total dissolved Fe concentrations ([Fe(II)_total], 2.15 mM) due to fast adsorption within 0.2 day. The concentration of adsorbed Fe(II) ([Fe(II)_ads]) was determined as the difference between [Fe(II)_aq] and the concentration of extracted Fe(II) in 0.5 M HCl ([Fe(II)_extr]) (i.e., [Fe(II)_ads] = [Fe(II)_extr] − [Fe(II)_aq]). [Fe(II)_ads] also decreased with time in experiments with and without DFAM, documenting that fast adsorption was accompanied by a second, slower reaction. Interestingly, [Fe(II)_extr] was always smaller than [Fe(II)_total], indicating that some Fe(II) was sequestered into a pool that is not HCl-extractable. The difference was attributed to Fe(II) incorporated into goethite structure (i.e., [Fe(II)_inc] = [Fe(II)_total] −[Fe(II)_extr]). More Fe(II) was incorporated in the presence of DFAM than in its absence at all time steps. Regardless of the presence of DFAM, both aqueous and extracted Fe(II) (δ^56/54Fe(II)_aq and δ^56/54Fe(II)_extr) became isotopically lighter than or similar to goethite (− 0.27‰) at day 7, implying that the isotope exchange occurred between bulk goethite and aqueous Fe. Consistently, the mass balance indicated that the incorporated Fe is isotopically heavier than extracted Fe. These observations suggested that (i) co-adsorption of Fe(II) with DFAM resulted in more pervasive electron transfer, (ii) the electron transfer from heavy Fe(II) in the adsorbed Fe(II) to light Fe(III) in goethite results in the fixation of heavy adsorbed Fe(III) on the surface and accumulation of Fe(II) within the goethite, and (iii) desorption of the reduced, light Fe from goethite does not necessarily occur at the same surface sites where adsorption occurred.  相似文献   

Spring water trace element geochemistry: A tool for resource assessment and reconnaissance mineral exploration   总被引：2，自引：0，他引：2  

Marie-Eve Caron  Stephen E. Grasby  M. Cathryn Ryan 《Applied Geochemistry》2008,23(12):3561-3578

Geochemical data from 151 spring locations within the 37,000 km² South Nahanni River Basin of the Mackenzie Mountains, Northwest Territories, were analysed as part of a reconnaissance assessment of mineral potential in this large and remote region. Statistical data analyses, graphical methods and strategic grouping of springs according to geochemistry, pH and temperature, were used to identify regions with higher mineralization potential quickly and efficiently. Testing of internal consistency indicates that known world class deposits within the basin are readily detected, but by different methods. As different deposit types have different geochemical signatures a new 3-component approach was developed to analyze trace element data for signatures of mineralisation. Estimation of circulation depth, and therefore maximum potential ore depth, further refines the assessment of economic potential. The depth of circulation of the spring waters ranged from 4.7 km to less than 200 m for the entire dataset. In total, 62 spring locations were identified as having anomalous trace metal content by one or more method (approximately 40% of the dataset). Specifically, 11 spring locations were classified as anomalous by all three methods, and 17 by at least two methods, and 34 by only one method.  相似文献   

The portrayal of the Australian monsoon equatorial monsoon shear line by GCMs: enhanced greenhouse scenario implications     

BF Ryan  DA Jones  HB Gordon 《Climate Dynamics》1992,7(4):173-180

A critical test of a general circulation model is its performance on the regional scale. In this paper we examine the summer climatology of the CSIRO4 (4-layer) climate model over the Australian tropical region. The benchmark for the study is the positioning of the monsoon equatorial trough. We compare the CSIRO4 model climatology with the climatologies from the GFDL and GISS models and we report on the sensitivity of the position of the monsoon shear line and the strength of the monsoon westerly winds to the doubling of carbon dioxide in the atmosphere. The model results show that under the greenhouse scenario the monsoon is strengthened, but the average location of the monsoon shear line is not sensitive to the doubling of CO₂. Offprint requests to: BF Ryan  相似文献   

Primary cumulus platinum minerals in the Monts de Cristal Complex,Gabon: magmatic microenvironments inferred from high-definition X-ray fluorescence microscopy     

Stephen J. Barnes  Louise A. Fisher  Bélinda Godel  Mark A. Pearce  Wolfgang D. Maier  David Paterson  Daryl L. Howard  Christopher G. Ryan  Jamie S. Laird 《Contributions to Mineralogy and Petrology》2016,171(3):23

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High Prevalence and Potential Impacts of Caligid Ectoparasites on Larval Atlantic Croaker (<Emphasis Type="Italic">Micropogonias undulatus</Emphasis>) in the Chesapeake Bay     

Filipe Ribeiro  Eric J. Hilton  Ryan B. Carnegie 《Estuaries and Coasts》2016,39(2):583-588

Larvae of Atlantic croaker Micropogonias undulatus enter Mid-Atlantic Bight estuaries annually between September and February. A high prevalence of ectoparasitic crustacean infection of ingressing larval M. undulatus was observed in Chesapeake Bay; this ectoparasite was identified as a species of Lepeophtheirus within the copepod family Caligidae from analysis of cytochrome oxidase I sequences and scanning electron microscopy. Between 2007 and 2011, seasonal differences in prevalence were observed, with higher infection rates on fall ingressing larvae (20 % mean monthly infection rate) than in larvae entering the estuary in the winter (monthly infection rate of 6 %); the head region had the highest parasite attachment rate, being observed in 78 % of the infected fish. The potential effects of this ectoparasite on larval M. undulatus could include reductions in feeding (and thus growth) and increased susceptibility to predation.  相似文献   

Cape cormorants decrease,move east and adapt foraging strategies following eastward displacement of their main prey     

RJM Crawford  RM Randall  TR Cook  PG Ryan  BM Dyer  R Fox 《African Journal of Marine Science》2016,38(3):373-383

Numbers of Cape cormorants Phalacrocorax capensis breeding in South Africa decreased by nearly 50% from approximately 107 000 pairs in 1977–1981 to 57 000 pairs in 2010–2014. Although four colonies had >10 000 pairs in 1977–1981, there was just one such colony in 2010–2014. Almost all the decrease occurred after the early 1990s off north-west South Africa, between the Orange River estuary and Dassen Island. South of this, the number breeding in the two periods was stable, with some colonies being formed or growing rapidly in the 2000s. The proportion of South Africa’s Cape cormorants that bred south of Dassen Island increased from 35% in 1977–1981 to 66% in 2010–2014, with the opposite situation observed in the north-west. This matched a shift to the south and east in the distributions of two of the Cape cormorant’s main prey species, anchovy Engraulis encrasicolus and sardine Sardinops sagax. In 2014, an apparent scarcity of prey in the north-west resulted in Cape cormorants attempting to take bait from hooks of fishing lines over an extended period, a behaviour not previously recorded. The number of Cape cormorants breeding in the south may be constrained by the absence of large islands between Dyer Island in the west and Algoa Bay in the east. If so, it may be possible to bolster the southern population through the provision of appropriate breeding habitat, such as platforms, or restricting human disturbance at suitable mainland cliff breeding sites.  相似文献   

Histories that root us: neighborhood,place, and the protest of school closures in Philadelphia     

Ryan M. Good 《Urban geography》2017,38(6):861-883

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The gamma ray spectrometer for the Solar Maximum Mission     

D. J. Forrest  E. L. Chupp  J. M. Ryan  M. L. Cherry  I. U. Gleske  C. Reppin  K. Pinkau  E. Rieger  G. Kanbach  R. L. Kinzer  G. Share  W. N. Johnson  J. D. Kurfess 《Solar physics》1980,65(1):15-23

The Solar Maximum Mission Gamma Ray Experiment (SMM GRE) utilizes an actively shielded, multicrystal scintillation spectrometer to measure the flux of solar gamma rays. The instrument provides a 476-channel pulse height spectrum (with energy resolution of 7% at 662 keV) every 16.38 s over the energy range 0.3–9 MeV. Higher time resolution (2 s) is available in three windows between 3.5 and 6.5 MeV to study prompt gamma ray line emission at 4.4 and 6.1 MeV. Gamma ray spectral analysis can be extended to 15 MeV on command. Photons in the energy band from 300–350 keV are recorded with a time resolution of 64 ms. A high energy configuration also gives the spectrum of photons in the energy range from 10–100 MeV and the flux of neutrons 20 MeV. Both have a time resolution of 2 s. Auxiliary X-ray detectors will provide spectra with 1-sec time resolution over the energy range of 10–140 keV. The instrument is designed to measure the intensity, energy, and Doppler shift of narrow gamma ray lines as well as the intensity of extremely broadened lines and the photon continuum. The main objective is to use this time and spectral information from both nuclear gamma ray lines and the photon continuum in a direct study of the dynamics of the solar flare/particle acceleration phenomena.  相似文献   

Biological and chemical consequences of the 1997–1998 El Niño in central California waters     

F. P. Chavez  J. T. Pennington  C. G. Castro  J. P. Ryan  R. P. Michisaki  B. Schlining  P. Walz  K. R. Buck  A. McFadyen  C. A. Collins 《Progress in Oceanography》2002,54(1-4)

The physical, chemical and biological perturbations in central California waters associated with the strong 1997–1998 El Niño are described and explained on the basis of time series collected from ships, moorings, tide gauges and satellites. The evolution of El Niño off California closely followed the pattern observed in the tropical Pacific. In June 1997 an anomalous influx of warm southerly waters, with weak signatures on coastal sea level and thermocline depth, marked the onset of El Niño in central California. The timing was consistent with propagation from the tropics via the equatorial and coastal wave-guide. By late 1997, the classical stratified ocean condition with a deep thermocline, high sea level, and warm sea surface temperature (SST) commonly associated with El Niño dominated the coastal zone. During the first half of 1998 the core of the California Current, which is normally detected several hundred kilometers from shore as a river of low salinity, low nutrient water, was hugging the coast. High nutrient, productive waters that occur in a north–south band from the coast to approximately 200 km offshore during cool years disappeared during El Niño. The nitrate in surface waters was less than 20% of normal and new production was reduced by close to 70%. The La Niña recovery phase began in the fall of 1998 when SSTs dropped below normal, and ocean productivity rebounded to higher than normal levels. The reduction in coastal California primary productivity associated with El Niño was estimated to be 50 million metric tons of carbon (5×10¹³ g C). This reduction certainly had deleterious effects on zooplankton, fish, and marine mammals. The 1992–1993 El Niño was more moderate than the 1997–1998 event, but because its duration was longer, its overall chemical and biological impact may have been comparable. How strongly the ecosystem responds to El Niño appears related to the longer-term background climatic state of the Pacific Ocean. The 1982–1983 and 1992–1993 El Niños occurred during the warm phase of the Pacific Decadal Oscillation (PDO). The PDO may have changed sign during the 1997–1998 El Niño, resulting in weaker ecological effects than would otherwise have been predicted based on the strength of the temperature anomaly.  相似文献   

Physiography and deposition on a distal deep-sea system: The Valencia Fan (Northwestern Mediterranean)     

Andrés Maldonado  Alberto Palanques  Belén Alonso  Kim A. Kastens  C. Hans Nelson  Suzanne O'Connell  William B. F. Ryan 《Geo-Marine Letters》1985,5(3):157-164

The Valencia Fan developed as the distal fill of a deep-sea valley, detached from the continental slope and the main sedimentary source. A survey of side-scan sonar, Sea Beam and reflection seismics shows that the sediment is largely fed through the Valencia Valley. The upper fan comprises large channels with low-relief levees, and the middle fan has sinuous distributary channels. Depositional bedforms predominate on the valley floor and levees, and erosional bedforms are common in the valley walls. A change to slope on the fan apex and the presence of volcanoes on the upper fan are the main factors influencing fan-growth pattern.  相似文献