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71.
The main aims of the present study are to identify the major factors affecting hydrogeochemistry of groundwater resources in the Marand plain, NW Iran and to evaluate the potential sources of major and trace elements using multivariate statistical analysis such as hierarchical clustering analysis (HCA) and factor analysis (FA). To achieve these goals, groundwater samples were collected in three sampling periods in September 2013, May 2014 and September 2014 and analyzed with regard to ions (e.g., Ca2+, Mg2+, Na+ and K+, HCO3 ?, SO4 2?, Cl?, F? and NO3 ?) and trace metals (e.g., Cr, Pb, Cd, Mn, Fe, Al and As). The piper diagrams show that the majority of samples belong to Na–Cl water type and are followed by Ca–HCO3 and mixed Ca–Na–HCO3. Cross-plots show that weathering and dissolution of different rocks and minerals, ion exchange, reverse ion exchange and anthropogenic activities, especially agricultural activities, influence the hydrogeochemistry of the study area. The results of the FA demonstrate that 6 factors with 81.7% of total variance are effective in the overall hydrogeochemistry, which are attributed to geogenic and anthropogenic impacts. The HCA categorizes the samples into two clusters. Samples of cluster C1, which appear to have higher values of some trace metals like Pb and As, are spatially located at the eastern and central parts of the plain, while samples of cluster C2, which express the salinization of the groundwater, are situated mainly westward with few local exceptions.  相似文献   
72.
In order to identify factors affecting the distribution of Anabasis aphylla in rangelands of Iran, 132 climatic parameters which contributed to the species distribution (based on the ecological conditions of the study area) were selected. Factor analysis was then applied to determine the most important factors affecting species distribution. In the next stage, the spatial distribution map of An. aphylla throughout Iran was prepared. According to the results of factor analysis, ten factors with Eigenvalues greater than one explained 92.96% of the total variance. These factors were temperature below zero, winter rainfall, summer rainfall, wind, sunlight, warm season dust, rainfall in fall, thunderstorms, relative humidity in September, and cloudy days in winter and explained 34.34, 9.71, 9.69, 8.85, 5.99, 5.35, 4.97, 4.78, 4.73, and 4.51% of the total variance, respectively. Moreover, six vegetation types containing An. aphylla were identified throughout the country. These types were distributed in the central areas of Iran and also in patches within the southeastern parts of the country. The results showed that in addition to the nine above climatic factors, soil variables particularly salinity influence establishing the vegetation types in their distribution areas and the vegetation types are located in low to relatively high salinity, and soils with these salinity levels (low to relatively high salinity) are suitable for these types of plants.  相似文献   
73.
Clouds can influence climate through many complex interactions within the hydrological cycle. Due to the important effects of cloud cover on climate, it is essential to study its variability over certain geographical areas. This study provides a spatial and temporal distribution of sky conditions, cloudy, partly cloudy, and clear days, in Iran. Cloud fraction parameters were calculated based on the cloud product(collection 6_L2) obtained from the Moderate Resolution Imaging Spectroradiometer(MODIS) sensors on board the Terra(MOD06) and Aqua(MYD06) satellites. The cloud products were collected daily from January 1, 2003 to December 31, 2014(12 years) with a spatial resolution of 5 km × 5 km. First, the cloud fraction data were converted into a regular geographic coordinate network over Iran. Then, the estimations from both sensors were analyzed. Results revealed that the maximum annual frequency of cloudy days occurs along the southern shores of the Caspian Sea, while the minimum annual frequency occurs in southeast Iran. On average, the annual number of cloudy and clear-sky days was 88 and 256 d from MODIS Terra, as compared to 96 and 244 d from MODIS Aqua. Generally, cloudy and partly cloudy days decrease from north to south, and MODIS Aqua overestimates the cloudy and partly cloudy days compared to MODIS Terra.  相似文献   
74.
In the current study the application of organo‐modified bentonite for the adsorption of mycotoxins (aflatoxin B1, citrinin, patulin, and zearalenone) is presented. The modification of clays is carried out using benzyl‐tri‐n‐butyl ammonium bromide (BTB), benzethonium chloride (BTC), and dioctyl sodium sulfosuccinate (DSS). Various experimental parameters such as pH, time, adsorbent dose, and mycotoxins concentration are thoroughly studied. The modified clays (B‐BTB, B‐BTC and B‐DSS) are characterized by X‐ray fluorescence, X‐ray diffraction, and Fourier transform infrared spectroscopy. The results depicted the high detoxification efficiency (≈99%) of modified clays for the removal of mycotoxins under optimized conditions (pH 5, time: 30 min, adsorbent amount: 50 mg). The adsorption capacities of modified clays are found in the order of: B‐BTC (AFB1: 18.02, CIT: 18.35, PAT: 18.21, ZEA: 18.09 mg g?1) > B‐BTB (AFB1: 17.7, CIT: 18.11, PAT: 17.95, ZEA: 17.90 mg g?1) > B‐DSS (AFB1: 17.5, CIT: 18.02, PAT: 17.86, ZEA: 17.80 mg g?1). The obtained results fitted well with thermodynamic, isothermal (Langmuir) and pseudo‐second order kinetics. Low cost organo‐modified bentonite shows the promise in mitigating mycotoxin contamination, which could improve food safety and reduce environmental contamination.  相似文献   
75.
Organic contaminants present as nonaqueous phase liquids (NAPLs) in the subsurface often pose a long-term risk to human health and the environment. Investigating the distribution of NAPLs in porous media remains a major challenge in risk assessment and management of contaminated sites. Conventional soil coring and monitoring wells have been widely used over past decades as the primary means of subsurface investigation to determine NAPL extent. Known limitations of conventional approaches have led us to explore an alternative or a complementary technique to provide high-quality information of NAPL source zone architecture. This work advances an imaging tool for a variety of organic NAPL contaminants in unconsolidated soils through magnetic resonance imaging (MRI) of frozen cores. Using trichloroethylene (TCE) and o-xylene as model species, we illustrate that discriminatory freezing of water, while keeping the NAPL in a liquid state, enables high-resolution qualitative delineation of NAPL distribution within porous media. This novel approach may help improve site conceptual models and consequentially lead to highly tailored, more efficient remedial measures.  相似文献   
76.
Topography can have significant effects on seismic ground response during an earthquake because topographic irregularities cause considerable differences between the seismic waves emitted by the source and the waves reaching the ground surface. When a seismic motion happens in a topographically irregular area, seismic waves are trapped and reflected between the topographic features. Therefore, the interaction between topographies can amplify seismic ground response. In order to reveal how interaction between topographies influences seismic response, several numerical finite element studies have been performed by using the ABAQUS program. The results show that topographic features a greater distance between the seismic source and the site would cause greater seismic motion amplification and is perceptible for the hills far away from the source and the ridges. Also, site acceleration response is impacted by surrounding topography further than site velocity and displacement response.  相似文献   
77.
In the recent years,the Red Sea coast of Yemen has been severely affected by intensive anthropogenic activities.The current study constitutes a thorough inquiry to evaluate the extent of heavy metals pollution in Yemen's Red Sea coast sediment and identifies the possible sources of pollution.The concentrations of five metals(copper(Cu),zinc(Zn),cadmium(Cd),lead(Pb),and nickel(Ni))collected from nine sites along the Red Sea coast of Yemen were assessed using an atomic absorption spectrophotometer(ASS).Sediment quality indices,such as the sediment quality guidelines(SQGs),potential ecological risk(RI),contamination factor(CF),pollution load index(PLI),geoaccumulation index(Igeo),and modified degree of contamination(mCd)were computed.In addition,multivariate statistical techniques(principal component analysis(PCA),hierarchical cluster analysis,and Pearson's correlation analysis)were applied to identify the potential sources of metals.The mean concentrations of Cu,Zn,Cd,Pb,and Ni were 51.3,61.9,4.02,9.9,and 33.4 mg/kg dry wt,respectively.The spatial distribution revealed that the metals concentrations were high at the middle zone and low southward of Hodeida city.According to the SQGs,the adverse biological effects of metals were occasionally associated with Cu and Cd,frequently associated with Ni,and not expected to occur with Zn and Pb.The RI indicated that the sediment of the studied sites pose low(RI<50)to considerable(100≤RI<200)ecological risk.The mean effect range-median quotient(M-ERM-Q)indicated that the combination of the studied metals had the toxicity probability of 21%at all studied sites.Igeo and CF indicated that the metals concentrations were in the descending order of:Zn>Ni>Pb>Cd>Cu,whereas the PLI and mCd indicated that Ras Isa(Site 5)and Urj village(Site 6)were the most polluted sites.PCA,cluster analysis,and correlation analysis found that Cd,Pb,and Ni mostly originated from anthropogenic sources while Cu and Zn were mainly derived from natural sources.Thus,it is evident that the intensive anthropogenic activities had negative influence on metals accumulation in the sediment of the Red Sea coast of Yemen leading to detrimental effects to the whole ecosystem.These comprehensive findings provide valuable information and data for future monitoring studies regarding heavy metals pollution and sediment quality at the Red Sea coast of Yemen.  相似文献   
78.
Natural Resources Research - During the last few decades, open pit mines have been deepened to the remote depths of the ground such that removing great volumes of waste rocks may jeopardize their...  相似文献   
79.
The Beerkan method based on in situ single‐ring water infiltration experiments along with the relevant specific Beerkan estimation of soil transfer parameters (BEST) algorithm is attractive for simple soil hydraulic characterization. However, the BEST algorithm may lead to erroneous or null values for the saturated hydraulic conductivity and sorptivity especially when there are only few infiltration data points under the transient flow state, either for sandy soil or soils in wet conditions. This study developed an alternative algorithm for analysis of the Beerkan infiltration experiment referred to as BEST‐generalized likelihood uncertainty estimation (GLUE). The proposed method estimates the scale parameters of van Genuchten water retention and Brooks–Corey hydraulic conductivity functions through the GLUE methodology. The GLUE method is a Bayesian Monte Carlo parameter estimation technique that makes use of a likelihood function to measure the goodness‐of‐fit between modelled and observed data. The results showed that using a combination of three different likelihood measurements based on observed transient flow, steady‐state flow and experimental steady‐state infiltration rate made the BEST‐GLUE procedure capable of performing an efficient inverse analysis of Beerkan infiltration experiments. Therefore, it is more applicable for a wider range of soils with contrasting texture, structure, and initial and saturated water content. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
80.
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