The West Falmouth oil spill after 20 years: Fate of fuel oil compounds and effects on animals     

J. M. Teal  J. W. Farrington  K. A. Burns  J. J. Stegeman  B. W. Tripp  B. Woodin  C. Phinney 《Marine pollution bulletin》1992,24(12):607-614

The barge Florida spilled No. 2 fuel oil into Buzzards Bay, Massachusetts on 29 September 1969. Sediments from five of the original stations were sampled in August 1989 and analysed for fuel oil hydrocarbons. Two subtidal and one intertidal marsh station showed no evidence of fuel oil. One subtidal mud core had traces of biodegraded fuel oil at 10–15 cm. One marsh core contained 10⁻⁶ g g⁻¹ dry wt of weathered and biodegraded fuel oil aromatic hydrocarbons and cycloalkanes at 5–10 cm with lesser concentrations at 0–5 and 10–15 cm. Although present in trace concentrations, these hydrocarbons appear to be slightly inducing cytochrome P4501A in marsh fish (Fundulus heteroclitus).  相似文献   

Critical Data,Critical Technology in Theory and Practice     

Ryan Burns  Craig M. Dalton  Jim E. Thatcher 《The Professional geographer》2018,70(1):126-128

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Ten best practices to strengthen stewardship and sharing of water science data in Canada     

Bhaleka D. Persaud  Krysha A. Dukacz  Gopal C. Saha  Amber Peterson  Laleh Moradi  Stephen O'Hearn  Erin Clary  Juliane Mai  Michael Steeleworthy  Jason J. Venkiteswaran  Homa Kheyrollah Pour  Brent B. Wolfe  Sean K. Carey  John W. Pomeroy  Chris M. DeBeer  James M. Waddington  Philippe Van Cappellen  Jimmy Lin 《水文研究》2021,35(11):e14385

Water science data are a valuable asset that both underpins the original research project and bolsters new research questions, particularly in view of the increasingly complex water issues facing Canada and the world. Whilst there is general support for making data more broadly accessible, and a number of water science journals and funding agencies have adopted policies that require researchers to share data in accordance with the findable, accessible, interoperable, reusable (FAIR) principles, there are still questions about effective management of data to protect their usefulness over time. Incorporating data management practices and standards at the outset of a water science research project will enable researchers to efficiently locate, analyse and use data throughout the project lifecycle, and will ensure the data maintain their value after the project has ended. Here, some common misconceptions about data management are highlighted, along with insights and practical advice to assist established and early career water science researchers as they integrate data management best practices and tools into their research. Freely available tools and training opportunities made available in Canada through Global Water Futures, The Gordon Foundation DataStream, the Digital Research Alliance of Canada Portage Network, Compute Canada, and university libraries, among others are compiled. These include webinars, training videos, and individual support for the water science community that together enable researchers to protect their data assets and meet the expectations of journals and funders. The perspectives shared here have been developed as part of the Global Water Futures programme's efforts to improve data management and promote the use of common data practices and standards in the context of water science in Canada. Ten best practices are proposed that may be broadly applicable to other disciplines in the natural sciences and can be adopted and adapted globally.  相似文献   

An approach to characterisation of multi-scale pore geometry and correlation with moisture storage and transport coefficients in cement-stabilised soils     

Matthew R. Hall  Sacha J. Mooney  Craig Sturrock  Paolo Matelloni  Sean P. Rigby 《Acta Geotechnica》2013,8(1):67-79

An experimental approach to the characterisation of the complex, multi-scale pore geometry in cement-stabilised soils is presented, in which the pore size distribution inclusively spans at least six orders of magnitude from ~3 nm up to >3 mm. These most likely result from the combined effects of granular inter-particle packing, clay/cement clothing and bridging effects, cement hydration and clay/cement pozzolanic reactions, and alteration of larger pore geometries as a result of solid mass mobilisation and transport following capillary wetting/drying regimes. Experimental data are presented and were obtained through a combination of X-ray computed tomography, mercury intrusion porosimetry and N₂ physisorption supported by ‘wet mode’ environmental scanning electron microscopy. Data strongly suggest that macropore/capillary pore size distribution, mean pore size, sorptivity and transport coefficients are a function of particle size distribution (when compaction energy is constant). Mesopore size distribution, which dominates hygric sorption/desorption behaviour, occurs within the clay/cement matrix and also appears to be strongly influenced by the particle size distribution of the granular phase. All other factors being equal, manipulation of granular particle size distribution can be used to engineer the hygric (vapour) and capillary (liquid) potentials and also the fluid transport coefficients of these materials.  相似文献   

Sulphur‐isotope study of the massive sulphide orebody at Woodlawn,New South Wales     

D. E. Ayres  M. S. Burns  J. W. Smith 《Australian Journal of Earth Sciences》2013,60(3-4):197-201

³⁴S/³²S ratios have been measured in a suite of samples from the stratabound, volcanogenic massive sulphide deposit at Woodlawn, N.S.W. ³⁴S values for the sulphides vary as follows: in the ore horizon, pyrite +6.7 to +9.2%. (mean +8.1‰), sphalerite +5.2 to +8.6‰. (mean +6.9‰), chalcopyrite +6.4 to +7.0‰ (mean +6.7‰) and galena +2.8 to +5.5‰ (mean +4.4‰); in the vein mineralization, the host volcanics—pyrite +8.7 to +11.4%. (mean +9.8‰), sphalerite +7.8 to + 10.3‰ (mean +9.2‰), chalcopyrite; +8.8 to +10.1‰ (mean +9.2‰) and galena +6.9 to +7.2‰ (mean +7.1‰). Barite from the upper ore horizon levels has an isotopic composition of +30.0‰, consistent with its having originated from Silurian ocean sulphate. The general order of ³⁴S enrichment in the sulphides is pyrite > chalcopyrite ～ sphalerite > galena. Isotopic fractionations in the systems galena/sphalerite/pyrite and chalcopyrite/pyrite indicate an equilibration temperature of 275–300°C. This temperature is considered to represent that of sulphide deposition.  相似文献   

TREE UPROOTING: REVIEW OF TYPES AND PATTERNS OF SOIL DISTURBANCE     

Randall J. Schaetzl  Scott F. Burns  Thomas W. Small  Donald L. Johnson 《自然地理学》2013,34(3):277-291

This paper reviews the processes of tree uprooting, examines the classification of pit and mound microtopography and assesses the effects of tree uprooting on soil mixing and genesis. The processes by which soil-horizon clasts are mixed as they slump off the root plate, and the ultimate patterns of soil horizonation within mounds, are primary foci of the paper. Longevity of treethrow mounds can exceed 2000 years, making these landforms more lasting features than is often assumed. Because of their great longevity, the pits and mounds formed by uprooting have lasting effects on soil morphology. Soils of these microsites often classify in different soil orders or suborders than do adjacent, less disturbed soils. The importance of tree uprooting to mass movement processes is examined. In some areas uprooting may be the primary mass wasting mechanism. Nonetheless, estimates of the amount of sediment moved and the net distance of transport vary greatly and may in some cases be overestimated. [Key words: pedoturbation, microtopography, pit/mound topography, mass wasting, geomorphology.]  相似文献   

The SORCE Spacecraft and Operations     

Thomas P. Sparn  Gary Rottman  Thomas N. Woods  Brian D. Boyle  Richard Kohnert  Sean Ryan  Randall Davis  Robert Fulton  William Ochs 《Solar physics》2005,230(1-2):71-89

The Solar Radiation and Climate Experiment, SORCE, is a satellite carrying four scientific instruments that measure the total solar irradiance and the spectral irradiance from the ultraviolet to the infrared. The instruments were all developed by the Laboratory for Atmospheric and Space Physics (LASP) at the University of Colorado, Boulder. The spacecraft carrying and accommodating the instruments was developed by Orbital Sciences Corporation in Dulles, Virginia. It is three-axis stabilized with a control system to point the instruments at the Sun, as well as the stars for calibration. SORCE was successfully launched from the Kennedy Space Center in Florida on 25 January 2003 aboard a Pegasus XL rocket. The anticipated lifetime is 5 years, with a goal of 6 years. SORCE is operated from the Mission Operations Center at LASP where all data are collected, processed, and distributed. This paper describes the SORCE spacecraft, integration and test, mission operations, and ground data system.  相似文献   

The spin of accreting stars: dependence on magnetic coupling to the disc   总被引：2，自引：0，他引：2  

Sean Matt †  Ralph E. Pudritz † 《Monthly notices of the Royal Astronomical Society》2005,356(1):167-182

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Evidence for high temperature and 18O‐enriched fluids in the Arab‐D of the Ghawar Field,Saudi Arabia          下载免费PDF全文

Peter K. Swart  Dave L. Cantrell  Monica M. Arienzo  Sean T. Murray 《Sedimentology》2016,63(6):1739-1752

Using the clumped isotope method, the temperature of dolomite and calcite formation and the oxygen isotopic composition (δ¹⁸O_w) of the diagenetic fluids have been determined in a core taken from the Arab‐D of the Ghawar field, the largest oil reservoir in the world. These analyses show that while the dolomites and limestones throughout the major zones of the reservoir recrystallized at temperatures between ca 80°C and 100°C, the carbonates near the top of the reservoir formed at significantly lower temperatures (20 to 30°C). Although the δ¹⁸O values of the diagenetic fluids show large variations ranging from ca <0‰ to ca +8‰, the variations exhibit consistent downhole changes, with the highest values being associated with the portion of the reservoir with the highest permeability and porosity. Within the limestones, dolomites and dolomites associated with the zone of high permeability, there are statistically significant different trends between the δ¹⁸O_w values and recrystallization temperature. These relationships have different intercepts suggesting that fluids with varying δ¹⁸O_w values were involved in the formation of dolomite and limestone compared to the formation of dolomite associated with the zone of high permeability. These new data obtained using the clumped isotope technique show how dolomitization and recrystallization by deep‐seated brines with elevated δ¹⁸O_w values influence the δ¹⁸O values of carbonates, possibly leading to erroneous interpretations unless temperatures can be adequately constrained.  相似文献   

Removal of dissolved selenium by siderite,pyrite, and sphalerite: Implications to selenium sequestration in water-saturated,anoxic coal waste rock     

Sean G. Deen  M. Jim Hendry  S. Lee Barbour  Soumya Das  Joseph Essilfie-Dughan 《Chemie der Erde / Geochemistry》2022,82(1):125863

The mechanisms of abiotic sequestration of Se(VI) and Se(IV) on a sample of coal waste rock collected from the Elk Valley, Canada and on three pure mineral species (i.e., siderite, pyrite, and sphalerite) present in coal waste rock were assessed using sterile batch testing under water-saturated, anoxic conditions. Only siderite removed measurable Se(VI) from the test solutions with ~90% removal after 100 d attributed to initial adsorption to the siderite surface as Se(VI) and subsequent reduction to Se(IV) and Se(0). In contrast to Se(VI), all samples removed Se(IV) from the aqueous solutions. The rate of Se(IV) removal was pyrite > siderite > waste rock > sphalerite. The waste rock sample removed Se(IV) from solution in two stages: up to ~40% of the aqueous Se(IV) was rapidly removed (by day 1) followed by slower removal of Se(IV) with up to ~97% removal after 99 d. Se(IV) removal is attributed to the adsorption of Se(IV) and subsequent reduction to Se(0) onto the siderite and pyrite phases of the waste rock. The initial (1 d) removal of Se(IV) by waste rock was characterized using a distribution coefficient (K_d) of 15.5 L/kg. Longer-term Se(IV) removal was fitted with zero and first order removal rates. The removal of Se(IV) by sphalerite was minor and deemed to have a minimal effect on Se sequestration in the waste rock. Desorption tests on waste rock showed that the fraction of sequestered Se susceptible to desorption decreased with time as adsorbed Se(IV) was reduced to insoluble Se(0). These findings show that abiotic Se sequestration can occur in saturated, anoxic zones in coal waste rock dumps.  相似文献