Combined analyses of chemometrics and kriging for identifying groundwater contamination sources and origins at the Masan coastal area in Korea   总被引：2，自引：2，他引：0  

Tae Hyung Kim  Sang Yong Chung  Namsik Park  Se-Yeong Hamm  Seung Yeop Lee  Byung-Woo Kim 《Environmental Earth Sciences》2012,67(5):1373-1388

Hydrogeochemical analyses including the basic statistics of chemical components, Piper??s trilinear diagram, and Mazor??s compositional bivariate diagram revealed that the main source and origin of groundwater contamination was seawater intrusion in the study area. However, the other sources and origins of groundwater contamination could be found by the combined analyses of chemometrics and kriging. Cluster analysis was helpful for the classification on the basis of the contamination characteristics of groundwater quality; however, it was not sufficient for the apportionment of groundwater contamination sources. Factor analysis (FA) determined three factors with 81.07% in total variance: Factor 1 for seawater contamination, Factor 2 for nitrate contamination, and Factor 3 for iron contamination. Factor analysis determined the sources of groundwater contamination; however, it could not discover the origins of contaminants except Factor 1. In backward stepwise mode, discriminant analysis decreased the number of parameters from 18 to 6 in discriminating the contaminant type with 96.2% correctness. TDS, Ca, NO₃, Mn, Fe, and Br were the most significant parameters for the discrimination of contaminants. Kriging analysis was very useful for the understanding of correlation and similarity between contaminants and factors of FA, and for the investigation of contaminant origins. It also showed that the similarity between factor scores and contaminant concentrations was proportional to the magnitudes of factor loadings for contaminants. This study represented that the combined analyses of chemometrics and kriging were very indispensable to the identification of groundwater contamination sources and origins, as well as for the spatial classification and assessment of groundwater quality.  相似文献   

Characteristics of adjoint sensitivity to potential vorticity     

Hyun Mee Kim  Robert J. Beare 《Meteorology and Atmospheric Physics》2011,111(3-4):91-102

Structures of adjoint sensitivities to potential vorticity for specific initial and final norm are investigated for a short-range cyclone forecast in a three-dimensional quasigeostrophic (QG) model. Moreover, adjoint sensitivities to potential vorticity are compared with nonlinear sensitivities calculated for the same cyclogenesis case in the QG model. The adjoint sensitivities using different initial and final norms (e.g., total QG disturbance energy and potential enstrophy) show approximately similar characteristics for the horizontal and vertical structures and evolutions. Consistent with previous studies, the horizontal structure of the adjoint sensitivity is smaller for the energy norm than for the potential enstrophy norm. The dynamical mechanism of cyclone development by adjoint sensitivity coincides with that of nonlinear sensitivity, with slight differences in the region of sensitivity maxima over the upstream (nascent) low for the adjoint (nonlinear) sensitivity. The adjoint sensitivities show different vertical distributions from the nonlinear sensitivities. Consistent with the sensitive regions denoted by singular vectors and error evolution in the QG model, maxima of the adjoint sensitivities are located at both the upper and lower boundaries, with prominent secondary peaks in the lower to mid-troposphere of the domain. The level of the secondary maxima changes depending on the initial and final norm used. The secondary peak is located in the lower to mid- (mid-) troposphere for the total QG disturbance energy (potential enstrophy) as the initial and final norm. Based on the correspondence in the level of the sensitivity maxima in the interior of the domain between the adjoint and nonlinear sensitivities, adjoint sensitivities may serve as an alternative to nonlinear sensitivities given the enormous computing expenses in nonlinear sensitivity calculation.  相似文献   

<Emphasis Type="Italic">Cochlodinium polykrikoides</Emphasis> red tide detection in the South Sea of Korea using spectral classification of MODIS data     

Young Baek Son  Joji Ishizaka  Jong-Chul Jeong  Hyun-Choel Kim  Taehee Lee 《Ocean Science Journal》2011,46(4):239-263

To distinguish true red tide water (particularly Cochlodinium polykrikoides blooms) from non-red tide water (false satellite high chlorophyll water) in the South Sea of Korea, we developed a systematic classification method using spectral information from MODIS level products and applied it to five different harmful algal bloom events. Red tide and nonred tide waters were classified based on four different criteria. The first step revealed that the radiance peaks of potential red tide water occurred at 555 and 678 nm. The second step separated optically different waters that were influenced by relatively low and high contributions of colored dissolved organic matter (CDOM) (including detritus) to chlorophyll. The third and fourth steps discriminated red tide water from non-red tide water based on the blue-to-green ratio in areas with lower and higher contributions of CDOM to chlorophyll, respectively. After applying the red tide classification (using the four criteria), the spectral response of the red tide water, which is influenced by pigment concentration, showed different slopes for the blue and green bands (lower slope at blue bands and higher slope at green bands). The opposite result was found for non-red tide water, due to decreasing phytoplankton absorption and increasing detritus/CDOM absorption at blue bands. The results were well matched with the discoloration of water (blue to dark red/brown) and delineated the areal coverage of C. polykrikoides blooms, revealing the nature of spatial and temporal variations in red tides. This simple spectral classification method led to increase user accuracy for C. polykrikoides and non-red tide blooms (>46% and >97%) and provided a more reliable and robust identification of red tides over a wide range of oceanic environments than was possible using chlorophyll a concentration, chlorophyll anomaly, fluorescence analysis, or proposed red tide detection algorithms.  相似文献   

Environmentally associated spatial changes of a macrozoobenthic community in the Saemangeum tidal flat,Korea     

Jongseong Ryu  Jong Seong Khim  Jin-Woo Choi  Hyun Chool Shin  Soonmo An  Jinsoon Park  Daeseok Kang  Chang-Hee Lee  Chul-Hwan Koh 《Journal of Sea Research》2011,65(4):390-400

Estuarine tidal flats are both ecologically and economically important, hence developing methods to reliably measure ecosystem health is essential. Because benthic fauna play a central role in the food web of tidal flats, in this study we set out to quantitatively describe the intertidal zonation of macro-invertebrates and their associations with specific environmental parameters along three transects in the Saemangeum tidal flat, Korea. The abundance and biomass of intertidal fauna with respect to five environmental parameters (i.e., shore level, mud content, coarse sand content, water content, and organic content) were measured, to identify environmental factors that influence macrofaunal distribution in intertidal soft bottom habitats. A total of 75 species were identified, with dominant species showing distinct zones of distribution along all transects. The number of species recorded in each transect was found to be dependent on sediment characteristics and salinity. Cluster analysis classified the entire study area into three faunal assemblages (i.e., location groups), which were delineated by characteristic species, including (A) ‘Periserrula–Macrophthalmus’, (B) ‘Umbonium–Meretrix’, and (C) ‘Prionospio–Potamocorbula’. Four environmental variables (i.e., shore level, water content, mud content, and organic content) appeared to determine factors that distinguished the three faunal assemblages, based on the discriminant analysis. The faunal assemblage types of the sampled locations were accurately predicted from environmental variables in two discriminant functions, with a prediction accuracy of 98%. It should be noted that the zonation of benthos in the lower section (C) of Sandong had been affected by the construction of a nearby dike, while this parameter had remained essentially unchanged at the other two location groups (A–B). Overall, the zonation of benthos from the Saemangeum tidal flat was explained adequately by the measured environmental variables, implying that faunal assemblages are closely associated with certain combinations of abiotic factors. The identification of such reliable associations may facilitate the development of statistical models to predict faunal distributions based on environmental variables at both local and regional scales. The entire study area was embanked in 2006 (one year after this study), and an integrated plan was set into force to develop claimed land into industrial, residential and agricultural districts, which also included a partial restoration program of the tidal flats located near to the study area.  相似文献   

Immobilization of As and Pb in contaminated sediments using waste resources     

Deok Hyun Moon  Da-Yeon Oh  Mahmoud Wazne  Jeong-Hun Park 《Environmental Earth Sciences》2013,69(8):2721-2729

As and Pb-contaminated sediment obtained from the Nakdong Lake and Yeongsan River in the Republic of Korea was stabilized using a combination of calcined oyster shell (COS), waste cow bone (WCB) and coal mine drainage sludge (CMDS). The effectiveness of the stabilization treatment was evaluated using the Korean Standard Test (KST). The KST tests were performed using 1 N HCl extraction fluid for As and 0.1 N HCl extraction fluid for Pb. Scanning electron microscopy–energy dispersive X-ray spectroscopy (SEM–EDX) analyses were performed to investigate the mechanism responsible for As and Pb immobilization upon treatment. The treatment results showed that effective stabilization of As and Pb-contaminated sediment was obtained. Specifically, 10 wt% COS–5 wt% CMDS was the best treatment for As immobilization and 5 wt% COS–5 wt% WCB was the best treatment for Pb immobilization. The COS–WCB treatment outperformed the COS–CMDS treatment in immobilizing Pb in the contaminated sediment. SEM–EDX results indicated that Pb immobilization was strongly associated with Ca, Si, Al and P while As immobilization was strongly associated with Fe and O. Therefore, utilization of COS, WCB and CMDS is beneficial for the stabilization of contaminated sediment.  相似文献   

Simultaneous stabilization of arsenic, lead, and copper in contaminated soil using mixed waste resources   总被引：1，自引：0，他引：1  

Keun-Young Lee  Deok Hyun Moon  Sang-Ho Lee  Kyoung-Woong Kim  Kyung-Hoon Cheong  Jeong-Hun Park  Yong Sik Ok  Yoon-Young Chang 《Environmental Earth Sciences》2013,69(6):1813-1820

In the present study, stabilization treatment using waste resource stabilizers was performed for soil contaminated with As and heavy metals (Pb and Cu). Calcined oyster shell (COS) and coal mine drainage sludge (CMDS) were used as a mixed stabilizing agent for a wet-curing duration of 28 days. After the stabilization treatment, the treatment process efficiency was evaluated by the results of various batch- and column-leaching tests. Neutral and weak acid extraction methods, such as water-soluble extraction and SPLP, did not exhibit satisfactory results for heavy metal stabilization, even if they showed very low leachability. On the other hand, TCLP and 0.1 M HCl extraction showed that the stabilizers significantly reduced the amount of heavy metals leached from the soil, which strongly supports the thesis that the stabilization treatment is efficient in the acidic leaching conditions that were explored. Specifically, in the 0.1 M HCl extraction, the reduction efficiencies of As, Pb, and Cu leachings were more than 90 %, compared with control experiments. This study demonstrates that the application of waste resources for the stabilization of As and heavy metals is feasible. However, some limitations observed in the experiments should be considered in future studies, such as the mobilization of alkali-soluble elements, and in particular, exchangeable fractions of Cu. In addition, the treatment efficiency can be evaluated by different leaching methods, which suggests that multidirectional approaches are required for the proper evaluation of stabilization treatment.  相似文献   

Analytical solution for transient groundwater flow during slug test in vertical cutoff walls     

Jeehee Lim  Dongseop Lee  Hyun‐Jun Choi  Hangseok Choi 《国际地质力学数值与分析法杂志》2014,38(17):1855-1870

An analysis method for transient groundwater flow during slug tests performed in vertical cutoff walls is presented. The analytical solution for evaluating hydraulic conductivity of vertical cutoff walls is derived by applying the method of images to the previously developed analytical solution that is exclusively applicable to an infinite aquifer. Two distinct boundary conditions are considered to account for the configuration of the vertical cutoff wall: the wall‐soil formation interfaces with or without the existence of filter cakes, that is, constant‐head boundary and no‐flux boundary conditions. A series of type curves is constructed from the analytical solution and compared with those of a partially penetrated well within an aquifer. The constant‐head boundary condition provides faster hydraulic head recovery than the aquifer case. On the other hand, the no‐flux boundary condition leads to a delayed hydraulic head recovery. The greater the shape factor and well offset from the center of the cutoff wall, and the smaller the width of the cutoff wall, the greater the effect of the boundary condition observed in the type curves. This result shows the significance of considering proper boundary conditions at the vertical cutoff wall in analyzing slug tests. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Effect of Data Assimilation Parameters on The Optimized Surface CO<Subscript>2</Subscript> Flux in Asia     

Hyunjung Kim  Hyun Mee Kim  Jinwoong Kim  Chun-Ho Cho 《Asia-Pacific Journal of Atmospheric Sciences》2018,54(1):1-17

In this study, CarbonTracker, an inverse modeling system based on the ensemble Kalman filter, was used to evaluate the effects of data assimilation parameters (assimilation window length and ensemble size) on the estimation of surface CO₂ fluxes in Asia. Several experiments with different parameters were conducted, and the results were verified using CO₂ concentration observations. The assimilation window lengths tested were 3, 5, 7, and 10 weeks, and the ensemble sizes were 100, 150, and 300. Therefore, a total of 12 experiments using combinations of these parameters were conducted. The experimental period was from January 2006 to December 2009. Differences between the optimized surface CO₂ fluxes of the experiments were largest in the Eurasian Boreal (EB) area, followed by Eurasian Temperate (ET) and Tropical Asia (TA), and were larger in boreal summer than in boreal winter. The effect of ensemble size on the optimized biosphere flux is larger than the effect of the assimilation window length in Asia, but the importance of them varies in specific regions in Asia. The optimized biosphere flux was more sensitive to the assimilation window length in EB, whereas it was sensitive to the ensemble size as well as the assimilation window length in ET. The larger the ensemble size and the shorter the assimilation window length, the larger the uncertainty (i.e., spread of ensemble) of optimized surface CO₂ fluxes. The 10-week assimilation window and 300 ensemble size were the optimal configuration for CarbonTracker in the Asian region based on several verifications using CO₂ concentration measurements.  相似文献   

Effects of Resolution,Cumulus Parameterization Scheme,and Probability Forecasting on Precipitation Forecasts in a High-Resolution Limited-Area Ensemble Prediction System     

Nuri On  Hyun Mee Kim  SeHyun Kim 《Asia-Pacific Journal of Atmospheric Sciences》2018,54(4):623-637

This study investigates the effects of horizontal resolution, cumulus parameterization scheme (CPS), and probability forecasting on precipitation forecasts over the Korean Peninsula from 00 UTC 15 August to 12 UTC 14 September 2013, using the limited-area ensemble prediction system (LEPS) of the Korea Meteorological Administration. To investigate the effect of resolution, the control members of the LEPS with 1.5- and 3-km resolution were compared. Two 3-km experiments with and without the CPS were conducted for the control member, because a 3-km resolution lies within the gray zone. For probability forecasting, 12 ensemble members with 3-km resolution were run using the LEPS. The forecast performance was evaluated for both the whole study period and precipitation cases categorized by synoptic forcing. The performance of precipitation forecasts using the 1.5-km resolution was better than that using the 3-km resolution for both the total period and individual cases. The result of the 3-km resolution experiment with the CPS did not differ significantly from that without it. The 3-km ensemble mean and probability matching (PM) performed better than the 3-km control member, regardless of the use of the CPS. The PM complemented the defect of the ensemble mean, which better predicts precipitation regions but underestimates precipitation amount by averaging ensembles, compared to the control member. Further, both the 3-km ensemble mean and PM outperformed the 1.5-km control member, which implies that the lower performance of the 3-km control member compared to the 1.5-km control member was complemented by probability forecasting.  相似文献   

Chemical weathering of granite under acid rainfall environment, Korea   总被引：1，自引：0，他引：1  

Seung Yeop Lee  Soo Jin Kim  Min Hoon Baik 《Environmental Geology》2008,55(4):853-862

Chemical weathering was investigated by collecting samples from five selected weathering profiles in a high elevation granitic environment located in Seoul, Korea. The overall changes of chemistry and mineralogical textures were examined reflecting weathering degrees of the samples, using polarization microscopy, X-ray diffraction (XRD), electron probe micro analysis (EPMA), X-ray fluorescence spectroscopy (XRF), and inductively coupled plasma–mass spectroscopy (ICP–MS). The chemical distribution in the weathering profiles shows that few trace elements are slightly immobile, whereas most major (particularly Ca and Na) and trace elements are mobile from the beginning of the granite weathering. On the other hand, there were mineralogical changes initiated from a plagioclase breakdown, which shows a characteristic circular dissolved pattern caused by a preferential leaching of Ca cation along grain boundaries and zoning. The biotite in that region is also supposed to be sensitive to exterior environmental condition and may be easily dissolved by acidic percolated water. As a result, it seems that some rock-forming minerals in the granitic rock located in Seoul are significantly unstable due to the environmental condition of acidic rainfall and steep slopes, where they are susceptible to be dissolved incongruently leading some elements to be highly depleted.  相似文献