The origin of large low shear-wave velocity provinces (LLSVPs) in the lowermost mantle beneath the central Pacific and Africa is not well constrained. We explore numerical convection calculations for two proposed hypotheses for these anomalies, namely, thermal upwellings (e.g., plume clusters) and large intrinsically dense piles of mantle material (e.g., thermochemical piles), each of which uniquely affects the topography on Earth's core–mantle boundary (CMB). The thermochemical pile models predict a relatively flat but elevated CMB beneath piles (presumed LLSVPs), with strong upwarping along LLSVP margins. The plume cluster models predict CMB upwarping beneath upwellings that are less geographically organized. Both models display CMB depressions beneath subduction related downwelling. While each of the two models produces a unique, characteristic style of CMB topography, we find that seismic models will require shorter length scales than are currently being employed in order to distinguish between the end-member dynamic models presented here. 相似文献
This study focused on the development of a seasonal data set of the Hg air/surface exchange over soils associated with low Hg containing surfaces in a deciduous forest in the southern USA. Data were collected every month for 11 months in 2004 within Standing Stone State Forest in Tennessee using the dynamic flux chamber method. Mercury air/surface exchange associated with the litter covered forest floor was very low with the annual mean daytime flux being 0.4 ± 0.5 ng m−2 h−1 (n = 301). The daytime Hg air/surface exchange over the year oscillated between emission (81% of samples with positive flux) and deposition (19% of samples with negative flux). A seasonal trend of lower emission in the spring and summer (closed canopy) relative to the fall and winter (open canopy) was observed. Correlations were found between the air/surface exchange and certain environmental factors on specific days sampled but not collectively over the entire year. The very low magnitude of Hg air/surface exchange as observed in this study suggests that an improved methodology for determining and reporting emission fluxes is needed when the values of fluxes and chamber blanks are both very low and comparable. This study raises questions and points to a need for more research regarding how to scale the Hg air/surface exchange for surfaces with very low emissions. 相似文献
Mercury air/surface exchange was measured over litter-covered soils with low Hg concentrations within various types of forests along the eastern seaboard of the USA. The fieldwork was conducted at six forested sites in state parks in South Carolina, North Carolina, New Jersey, Pennsylvania, New York and Maine from mid-May to early June 2005. The study showed that the Hg air/surface exchange was consistently very low and similar (overall daytime mean flux = 0.2 ± 0.9 ng m−2 h−1, n = 310, for all six sites monitored) with the various forest types. These flux values are comparable with those found in a year-long study in Tennessee (yearly daytime mean = 0.4 ± 0.5 ng m−2 h−1), but lower than many previous flux results reported for background soils. The Hg fluxes at all sites oscillated around zero, with many episodes of deposition (negative fluxes) occurring in both daytime and nighttime. While there were particular days showing significant correlations among the Hg air/surface exchange and certain environmental parameters, perhaps because of the low fluxes encountered, few significant correlations were found for any particular day of sampling between the Hg flux and environmental parameters such as solar radiation, soil temperature, air temperature (little variability seen), relative humidity, and ambient air Hg concentrations. Factors driving the Hg exchange as previously found for enriched soils may not hold for these background litter-covered forest soils. The results suggest that spatial variations of the Hg air/surface exchange were small among these different forest types for this particular time of year. 相似文献
We investigated the influence of dynamical in-consistency of initial conditions on the predictive skill of decadal climate predictions. The investigation builds on the fully coupled global model “Coupled GCM for Earth Simulator” (CFES). In two separate experiments, the ocean component of the coupled model is full-field initialized with two different initial fields from either the same coupled model CFES or the GECCO2 Ocean Synthesis while the atmosphere is initialized from CFES in both cases. Differences between both experiments show that higher SST forecast skill is obtained when initializing with coupled data assimilation initial conditions (CIH) instead of those from GECCO2 (GIH), with the most significant difference in skill obtained over the tropical Pacific at lead year one. High predictive skill of SST over the tropical Pacific seen in CIH reflects the good reproduction of El Niño events at lead year one. In contrast, GIH produces additional erroneous El Niño events. The tropical Pacific skill differences between both runs can be rationalized in terms of the zonal momentum balance between the wind stress and pressure gradient force, which characterizes the upper equatorial Pacific. In GIH, the differences between the oceanic and atmospheric state at initial time leads to imbalance between the zonal wind stress and pressure gradient force over the equatorial Pacific, which leads to the additional pseudo El Niño events and explains reduced predictive skill. The balance can be reestablished if anomaly initialization strategy is applied with GECCO2 initial conditions and improved predictive skill in the tropical Pacific is observed at lead year one. However, initializing the coupled model with self-consistent initial conditions leads to the highest skill of climate prediction in the tropical Pacific by preserving the momentum balance between zonal wind stress and pressure gradient force along the equatorial Pacific.
The sloshing of liquids in storage tanks on fixed offshore structures affects both the natural frequencies and damping. Analytic procedures by which one may account for these effects are presented. Also shown is a method for design of tankage that will result in suppression of dynamic response at the fundamental flexural natural frequency of the structure. An important aspect is that no new equipment is required but only optimum configuration of tankage that is already required for storage of water, fuel, mud or crude oil. Supporting data from full scale field studies are presented. 相似文献
Coral reef ecosystems worldwide are now being harmed by various stresses accompanying the degradation of fish habitats and thus knowledge of fish-habitat relationships is urgently required. Because conventional research methods were not practical for this purpose due to the lack of a geospatial perspective, we attempted to develop a research method integrating visual fish observation with a seabed habitat map and to expand knowledge to a two-dimensional scale. WorldView-2 satellite imagery of Spermonde Archipelago, Indonesia obtained in September 2012 was analyzed and classified into four typical substrates: live coral, dead coral, seagrass and sand. Overall classification accuracy of this map was 81.3% and considered precise enough for subsequent analyses. Three sub-areas (CC: continuous coral reef, BC: boundary of coral reef and FC: few live coral zone) around reef slopes were extracted from the map. Visual transect surveys for several fish species were conducted within each sub-area in June 2013. As a result, Mean density (Ind. / 300 m2) of Chaetodon octofasciatus, known as an obligate feeder of corals, was significantly higher at BC than at the others (p < 0.05), implying that this species’ density is strongly influenced by spatial configuration of its habitat, like the “edge effect.” This indicates that future conservation procedures for coral reef fishes should consider not only coral cover but also its spatial configuration. The present study also indicates that the introduction of a geospatial perspective derived from remote sensing has great potential to progress conventional ecological studies on coral reef fishes.
The pressure-induced high-spin—low-spin transition of the transition-metal ions in octahedral coordination is studied theoretically. The relation between the crossover point and the transition point is discussed and the formula to determine the transition point is given in terms of the crystal-field splitting Δ and the spin-pairing energy Π asΔ = αΠ. The numerical coefficient α is determined by the ratio of the change of the interatomic distances between the transition-metal ion and ligands. It is proved that α is generally less than 1 and takes a value of about 0.95-0.80 for the transition-metal oxides. Based on the discussions on the P–V relation of the low-spin oxides, transition pressures are estimated to be about 700–1300 kbar for MnO, CoO and Fe2O3, and about 250–400 kbar for FeO.The magnitude of the shifts of transition pressures due to entropy changes is roughly evaluated to be about 0.1 kbar K?1 for transition-metal oxides. It is discussed whether the transition at high temperature takes place continuously or not. For MnO, FeO and Fe2O3, the high-spin—low-spin transition will take place gradually at temperatures higher than about 2000 K. For CoO, the gradual transition will take place at above 300 K. 相似文献
