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61.
Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas–pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones that dominated in the inner column portions. The plate tube pumice proportion decreased abruptly up to disappearance during the emplacement of the main pyroclastic currents and lithic-rich breccias related to extensive caldera collapse at the eruption climax, as a consequence of an overall widening of the magma feeder system through the opening of multiple conduits and eruptive vents, along with fissure erosion, concomitant to the disruption of the collapsing block.  相似文献   
62.
Determination of annual lamination provides important additional constraints to radiometric dates on speleothems, both for dating the duration of specific growth intervals and optimizing growth models. In the absence of visible laminae, however, speleothem age models are reliant upon curve fitting through discretely dated points and are therefore inherently more uncertain than annual chronologies from laminae. Given that the impact of seasonality on speleothems is expected to be strong enough to generate an annual pulse in trace element chemistry regardless of whether or not visible or fluorescent growth laminae are visible, we demonstrate the potential for deriving high-resolution stalagmite chronologies from non-laminated samples using annual chemical variations in stalagmites from two Alpine caves (Obir, Austria and Ernesto, NE Italy). Trace element data were obtained by ion microprobe analyses for H, P, Mg, Na, Sr and Ba and the annual signal was sought using spectral and wavelet analysis. An automated chemical peak-counting software tool was developed in MATLAB©. It counts significant annual peaks using criteria of minimum amplitude in relation to the local standard deviation of signal variation and minimum separation between peaks determined by the thickness of the preceding layers. Verification of the tool using visibly laminated samples suggests the software is a reliable and accurate method of chronology building, with hit ratios greater than 0.93 and less than 0.75% false alarm occurrences. Used in conjunction with other dating methods such as radiocarbon, U–Th and sulphur peak dating, the automated chemical laminae chronology-building approach provides a more meaningful alternative to simple age-depth curve fitting for non-laminated samples.  相似文献   
63.
The estimate of seismic site effects by experimental approaches is based on different assumptions aimed at simplifying the complex actual site conditions and related uncertainties.However,the reliability of the results can increase if the experimental data is focused on quite strong seismic sequences and the on-site acquisition of a large number of signals is deemed strategic for the assessment of the expected phenomena.Based on these considerations,the ground motion at the Red Zone sector of Amatrice hill,violently struck by the 2016-2017 Central Italy seismic sequence,was analyzed via an observational approach.A large set of weak motions(moment magnitude Mw 2.5-3.9)was analyzed in this study by means of standard(SSR)and horizontal to vertical(HVSR)spectral ratio techniques.The results from the experimental analysis of the site effects by using weak motion and noise signals show a significant amplification at the top of Amatrice hill with a remarkable polarization of the motion and changes in spectral shapes according to the topographic setting of the relief.  相似文献   
64.
Recent decades, particularly since the late 1970s, have witnessed a rapid retreat of glaciers in the tropical Andes. We compiled the changes in glacier surfaces along the eastern cordilleras of the tropical Andes of Peru and Bolivia since the early 1980s from the literature. Water levels from two Brazilian river basins in the Amazon basin (one (Madeira River) glacially fed by meltwater from the Andes and the other (Envira River) non‐glacially fed), were analysed for a 30‐year period between 1985?2014. Furthermore, precipitation data near these two basins were also analysed in order to understand the differential contributions of glacier melting and rainfall. Variations in the water levels from the glacially fed Madeira River showed that some years were associated with higher water levels even when the precipitation remained low during the corresponding season (May‐October). This observation was common when El Niño events occurred during the positive phase of Pacific Decadal Oscillation (PDO). Water levels in glacier‐fed Madeira River were slightly higher during the periods where El Niño and warm PDO co‐occurred. On the other hand, water levels in the Envira River were precipitation dependent; water levels were higher when the rainfall was high.  相似文献   
65.
The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)3SnS4, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu+, Sn4+ and Fe3+. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.  相似文献   
66.
67.
Nutrient sources of San Quintin Bay, a coastal lagoon affected by coastal upwelling off Baja California (Mexico), were traced using generalized additive (mixed) models (GAMM) to the stable nitrogen isotopic composition, C:N and N content of two co-occurring macrophytes (the macroalgae Ulva spp. and the seagrass Zostera marina). The geochemical tracers followed a spatial trend that partly responded to the long-term nutrient gradient from the ocean towards the interior of the bay. N content in Z. marina and Ulva spp. decreased linearly (while C:N increased) towards the middle section of the bay to concentration levels that indicate potential N limitation for growth. Concurrently midway into the bay (6–9 km), the δ15N of both macrophytes showed a gradual enrichment in 15N reflecting progressive denitrification. The spatial pattern of δ15N and the decrease in C:N of the macrophytes towards the innermost section of the bay indicated an additional nonoceanic source of dissolved nitrogen in this zone. The similarity of the δ15N pattern of Z. marina and Ulva spp. implies that their δ15N composition is mainly controlled by the availability of N, in spite of the physiological differences between taxa. A better fit of GAMM to N content and C:N was obtained for Z. marina than for Ulva spp. indicating that the former delineate more steadily and smoothly the influence of upwelling along the spatial gradient. Nonetheless, Ulva spp. may be analyzed in combination with Z. marina to characterize the environmental conditions at the time of sampling.  相似文献   
68.
The spatial resolution of digital elevation models (DEMs) is an important factor for reliable landslide studies. Multi-interferometric techniques such as persistent scatterer interferometric synthetic aperture radar (PSInSAR) are used to evaluate the landslide state of activity and its ground deformation velocity, which is commonly measured along the satellite line of sight (LOS). In order to compare velocities measured by different satellites in different periods, their values can be projected along the steepest slope direction, which is the most probable direction of real movement. In order to achieve this result, DEM-derived products are needed. In this paper, the effectiveness of different DEM resolutions was evaluated in order to project ground deformation velocities measured by means of PSInSAR technique in two different case studies in the Messina Province (Sicily, southern Italy): San Fratello and Giampilieri. Three DEMs were used: (i) a 20-m resolution DEM of the Italian Military Geographic Institute (IGM), (ii) a 2-m resolution DEM derived from airborne laser scanning (ALS) light detection and ranging (LiDAR) data for the San Fratello 2010 landslide, and (iii) a 1-m resolution DEM derived from ALS LiDAR data for the area of Giampilieri. The evaluation of the applied method effectiveness was performed by comparing the DEMs elevation with those of each single permanent scatterer (PS) and projecting the measured velocities along the steepest slope direction. Results highlight that the higher DEM resolution is more suitable for this type of analysis; in particular, the PS located nearby the watershed divides is affected by geometrical problems when their velocities are projected along the steepest slope.  相似文献   
69.
The state-of-the-art monitoring of drinking water hygiene is based on the cultivation and enumeration of indicator bacteria. Despite its proven reliability, this approach has the disadvantages of being (a) relatively slow and (b) limited to a small number of indicator bacteria. Ideally, alternative methods would be less time-consuming while providing information about a larger set of hygienically relevant microorganisms including viruses. In this paper, we present insights into the design of a modular concentration and detection system for bacteria, bacteriophages and viruses. Following further validation, this or similar techniques have the potential to extend and speed up the monitoring of raw and drinking water hygiene in the future. The system consists of different modules for the concentration of microorganisms, an amplification and detection unit that includes a module for the differentiation between live and dead microorganisms, and an automated system for decision support and self-diagnosis. The ongoing testing under controlled laboratory conditions and real-life conditions in the water supply industry yields further system improvements. Moreover, the increased sensitivity and broader range of microbiological parameters emphasize the need for a reconsideration of the currently used criteria for the assessment of (drinking) water hygiene.  相似文献   
70.
In this project we investigated the ecotoxicological effects of endocrine disrupters in a four-year survey of the Mediterranean population of swordfish (Xiphias gladius). In the Mediterranean environment, top predators, such as swordfish, accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, potentially incurring high toxicological risk. The effects of organochlorines and trace elements (Hg, Cd and Pb) in 192 swordfish specimens, caught in the Strait of Messina, Sicily, Italy, were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and CYP1A (BPMO, EROD) activities. Vtg and Zrp were found to be dramatically induced in some adult male specimens, suggesting that this species is highly exposed to estrogens in the Mediterranean Sea. A role of organochlorines in this induction phenomenon is suggested by the statistically significant correlations between Zrp in plasma and PCB concentrations in muscle (p<0.032) and Vtg in plasma and PCB concentrations in liver (p<0.034) of male specimens. Levels of trace elements in liver were in the following ranges: Hg 1-22, Cd 1-28 and Pb 0-1.6 ppm d.w. These data indicate potential reproductive alterations in large pelagic fish and suggest the need for continuous monitoring to avoid reductions in the population of this fish species of high commercial and ecological interest.  相似文献   
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