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Amphiboles are the main mafic minerals in most metaluminous to peralkaline alkali-feldspar granites and syenites, and they usually preserve an important record of the compositional evolution of the melts from which they crystallize. In the alkaline association of the Serra da Graciosa A-type Granites and Syenites (southern Brazil), amphibole compositions span a large range, including calcic, sodic–calcic, and sodic amphiboles. Calcic amphiboles are typically observed in the metaluminous rocks, while sodic amphiboles are characteristic of the more strongly peralkaline rocks; sodic–calcic amphiboles are found in intermediate varieties. Compositional variations record the differentiation trends within two petrographic series of the alkaline association. The overall evolution of amphibole compositions is similar in both: they reveal a progressive increase in Na and Fe3+ with differentiation (increase in alkalinity of the magmas), a characteristic shared by undersaturated peralkaline (or agpaitic) differentiation trends. In detail, however, the evolutions of the amphibole compositions in the two series are distinct. In Alkaline series 1, the cores of the crystals form a continuum from calcic to sodic compositions, with the exception of a small compositional gap within the sodic–calcic amphiboles. The rims, however, show compositions that diverge from this main trend; this divergence results from increasing amounts of the oxy-amphibole component, and reflects more oxidizing conditions at the final stages of magmatic crystallization. In Alkaline series 2, these oxidation trends are much more subtle and a reverse trend is observed in the sodic amphiboles. Sodic–calcic amphiboles are in several cases replaced by intergrowths of post-magmatic sodic amphibole and Al-poor (“tetrasilicic”) biotite. 相似文献
113.
Ajith G. Nair D. S. Suresh Babu K. L.Vivekanandan Silvio R. F. Vlach 《Resource Geology》2006,56(1):75-81
Abstract. The study based on microscopic and microprobe techniques reveals that ilmenite of Manavalakurichi deposit has generally reached the alteration phase of 'leached ilmenite'. The XRD and bulk chemical analysis confirm the limited alteration undergone by ilmenite grains. Ilmenite alteration has been found to be a process of continuous leaching of iron from the mineral lattice and hydroxylisation. The enrichment of trace elements with progressive alteration is discussed. Si and Al are enriched by more than 100 fold. The prevalence of reducing environment at present in the deposit indicates that the oxidation of ferrous iron leading to pseudorutile formation would have occurred during transportation of sediments. 相似文献
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Marcelo Bevilacqua Remor Silvio César Sampaio Sacha de Rijk Marcio Antônio Vilas Boas Jackeline Tatiane Gotardo Everton Tiago Pinto Fábio Augusto Schardong 《国际泥沙研究》2018,33(4):406-414
The objective of this study was to evaluate the concentration and distribution of heavy metals in the sediments of Paulo Gorski Lake, as well as the metals’ bioavailability and potential ecological risk, and to define the anthropogenic and natural heavy metal contributions to the lake. The chemical elements calcium (Ca), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), sodium (Na), nickel (Ni), lead (Pb), and zinc (Zn) were quantified by flame atomic absorption spectrophotometry with two extraction methods to quantify the bioavailable and non-bioavailable fractions. The data were evaluated using multivariate statistics and sediment quality indices. All sediment collection points (S1, S2, S3, S4 and S5) are different in terms of the concentration of heavy metals, except for S4 and S5, which were statistically equal. The bioavailable fraction of the elements in the sediment follows the sequence Pb>Cu>Mn>Zn>Ni>Cr>phosphorus (P) for all points. The elements Co, Cr, Pb, and Zn showed moderate to considerable contamination at all points. Only points S3 and S5 had moderate ecological risk. Urbanization has been affecting Paulo Gorski Lake via the input of chemical elements, especially Co and Pb. The points most affected by heavy metal contamination are S3 and S5 when the sedimentological sensitivity factor is considered. The lake has high hydrodynamics, causing some of the contaminants that enter the system to leave it, leading to potential negative impacts downstream. 相似文献
116.
Alessandro Bemporad Paolo Pagano Silvio Giordano Silvano Fineschi 《Experimental Astronomy》2017,44(1):83-96
Observations of the solar corona in the FeXIV 530.3 nm “green line” have been very important in the past, and are planned for future coronagraphs on-board forthcoming space missions such as PROBA-3 and Aditya. For these instruments, a very important parameter to be optimized is the spectral width of the band-pass filter to be centred over the “green line”. Focusing on solar eruptions, motions occurring along the line of sight will Doppler shift the line profiles producing an emission that will partially fall out of the narrower pass-band, while broader pass-band will provide observations with reduced spectral purity. To address these issues, we performed numerical (MHD) simulation of CME emission in the “green line” and produced synthetic images assuming 4 different widths of the pass-band (Δλ = 20 Å, 10 Å, 5 Å, and 2 Å). It turns out that, as expected, during solar eruptions a significant fraction of “green line” emission will be lost using narrower filters; on the other hand these images will have a higher spectral purity and will contain emission coming from parcels of plasma expanding only along the plane of the sky. This will provide a better definition of single filamentary features and will help isolating single slices of plasma through the eruption, thus reducing the problem of superposition of different features along the line of sight and helping physical interpretation of limb events. For these reasons, we suggest to use narrower band passes (Δλ ≤ 2 Å) for the observations of solar eruptions with future coronagraphs. 相似文献
117.
Alessia Borghini Silvio Ferrero Patrick J. O’Brien Oscar Laurent Christina Günter Martin A. Ziemann 《Journal of Metamorphic Geology》2020,38(3):207-234
Garnet of eclogite (formerly termed garnet clinopyroxenite) hosted in lenses of orogenic garnet peridotite from the Granulitgebirge, NW Bohemian Massif, contains unique inclusions of granitic melt, now either glassy or crystallized. Analysed glasses and re-homogenized inclusions are hydrous, peraluminous, and enriched in highly incompatible elements characteristic of the continental crust such as Cs, Li, B, Pb, Rb, Th, and U. The original melt thus represents a pristine, chemically evolved metasomatic agent, which infiltrated the mantle via deep continental subduction during the Variscan orogeny. The bulk chemical composition of the studied eclogites is similar to that of Fe-rich basalt and the enrichment in LILE and U suggest a subduction-related component. All these geochemical features confirm metasomatism. In comparison with many other garnet+clinopyroxene-bearing lenses in peridotites of the Bohemian Massif, the studied samples from Rubinberg and Klatschmühle are more akin to eclogite than pyroxenites, as reflected in high jadeite content in clinopyroxene, relatively low Mg, Cr, and Ni but relatively high Ti. However, trace elements of both bulk rock and individual mineral phases show also important differences making these samples rather unique. Metasomatism involving a melt requiring a trace element pattern very similar to the composition reported here has been suggested for the source region of rocks of the so-called durbachite suite, that is, ultrapotassic melanosyenites, which are found throughout the high-grade Variscan basement. Moreover, the Th, U, Pb, Nb, Ta, and Ti patterns of these newly studied melt inclusions (MI) strongly resemble those observed for peridotite and its enclosed pyroxenite from the T-7 borehole (Staré, České Středhoři Mountains) in N Bohemia. This suggests that a similar kind of crustal-derived melt also occurred here. This study of granitic MI in eclogites from peridotites has provided the first direct characterization of a preserved metasomatic melt, possibly responsible for the metasomatism of several parts of the mantle in the Variscides. 相似文献
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Laurent Eyer Lovro Palaversa Nami Mowlavi Pierre Dubath Richard I. Anderson Dafydd W. Evans Thomas Lebzelter Vincenzo Ripepi Laszlo Szabados Silvio Leccia 《Astrophysics and Space Science》2012,341(1):207-214
The ESA Gaia mission will bring a new era to the domain of standard candles. Progresses in this domain will be achieved thanks to unprecedented astrometric precision, whole-sky coverage and the combination of photometric, spectrophotometric and spectroscopic measurements. The fundamental outcome of the mission will be the Gaia catalogue produced by the Gaia Data Analysis and Processing Consortium (DPAC), which will contain a variable source classification and specific properties for stars of specific variability types. We review what will be produced for Cepheids, RR Lyrae, Long Period Variable stars and eclipsing binaries. 相似文献
120.