Sulphate Sources in the Sava and Ljubljanica Rivers, Slovenia, Inferred from Sulphur and Oxygen Isotope Compositions     

Barbara Vokal-Nemec  Janina Szaran  Andrzej Trembaczowski  Stanislaw Halas  Tadej Dolenec  Sonja Lojen 《Aquatic Geochemistry》2006,12(3):199-220

Measurements were made of sulphur and oxygen isotope ratios of sulphate in some Slovenian rivers, lakes and tap waters. δ³⁴S ranged from −0.2 to + 13.3‰, δ¹⁸O ranged from +4.9 to + 13.6‰, and the sulphate content varied from 0.8 to 41.4 mg/L. Rivers flowing from the Julian Alps contain a very low amount of sulphate that is leached from a thin horizon of soil by rain. As confirmed by their low δ¹⁸O values, these sulphates do not enter the rivers directly in rain, but arise from biochemical cycling in the soil. The low δ³⁴S of this sulphate indicates that it originates from the oxidation of sedimentary sulphides. The evolution of sulphates along the river course was investigated for the Sava and Ljubljanica rivers. The variations observed in sulphate from the waters studied result from variations in the contribution of sulphates of different origin. Downstream the Sava River sulphate is depleted in the heavy isotopes of both sulphur and oxygen, with δ-values gradually tending toward the δ-values of groundwater sulphates in the watershed. In contrast, the δ-values of sulphate in the Ljubljanica River are almost constant and similar to those of sulphate in local groundwater. Introduction of water from Italian and Slovenian mines was recorded in the Soča River, where the lowest δ³⁴S value of sulphate sulphur (−0.2‰) was observed. In addition, the influence of sulphate from the oxidation of sedimentary sulphides was recorded in the Sotla River. No evidence was found for introduction of sulphate from factories.  相似文献   

Peralkaline nephelinites. I. Comparative petrology of Shombole and Oldoinyo L'engai,East Africa     

Tony D. Peterson 《Contributions to Mineralogy and Petrology》1989,101(4):458-478

Shombole, a nephelinite-carbonatite volcano in south Kenya, erupted silicate lavas, carbonatite dikes and tuffs, and pyroclastic rocks similar to those at other East African alkaline centres. Shombole lavas containing cpx + nepheline + accessory minerals range from perovskite-bearing nephelinites (43% SiO₂, volatile-free) to sphene-bearing and phonolitic nephelinites (46–49% SiO₂) and phonolites (49–56% SiO₂) and have low peralkalinity ([Na+K]/Al 1.15) which does not correlate with SiO₂. Early fractionation of olivine and clinopyroxene strongly depleted Ni and Cr concentrations (10 ppm); fractionation of perovskite, melanite, sphene, and apatite produced negative correlations of all REE with SiO₂. Many lavas contain cognate intrusive xenoliths and xenocrysts and oscillatory zoning is a common feature of clinopyroxene, nepheline, and melanite crystals, indicating recycling of intrusive material. Irregular calcite-rich bodies in many samples are interpreted as quenched immiscible Ca-carbonatite liquid, and [Ca-carbonate]-silicate liquid immiscibility is observed in experiments with one nephelinite. Chemical variation in the Shombole suite can be modeled as a combination of crystal fractionation (clinopyroxene and heavy minor phases) and retention of neutral density nepheline derived from disaggregated xenoliths entrained during emplacement of dike swarms. Six newly analyzed lavas from Oldoinyo L'engai, northern Tanzania, are geochemically similar to Shombole nephelinites except that they have relatively high Na₂O+K₂O (average 18% vs 12%) and Zr (average 680 ppm vs 400 ppm). They are extremely peralkaline and are not typical of nephelinites from other centres. Three with [Na+K]/Al1.5 contain euhedral wollastonite phenocrysts; three with [Na+K]/Al2.0 contain combeite (Na₂Ca₂Si₃O₉) phenocrysts and pseudomorphs after wollastonite. Both types contain abundant sodalite phenocrysts (+nepheline+clinopyroxene+melanite+sphene). Seven other wollastonite nephelinite samples from L'engai have been described, but it is a lava type rarely seen in other centres. Combeite has been described from only two other locations (Mt. Shaheru, Zaire; Mayener Feld, Eifel). The hyperalkaline L'engai nephelinites have compositions similar to those of experimental silicate liquids immiscible with natrocarbonatite. Textural evidence for both carbonate-silicate (as carbonate globules) and silicate-silicate (as two optically discrete glasses with distinct compositions) liquid immiscibility is observed in the samples.  相似文献   

Estimation of kinetic parameters of a grinding-liberation model     

R.D Peterson  J.A Herbst 《International Journal of Mineral Processing》1985,14(2):111-126

A method of parameter estimation is outlined for a two-component grinding-liberation model. The large number of model variables is reduced by using functional forms. The parameters for the functional forms are estimated using a modified Gauss-Newton algorithm. The technique is applied to both synthetic and real experimental data. Parameters estimated from wet grinding batch tests of Illinois No. 6 coal were used to predict mill output for a larger pilot-plant mill. The predictions were found to match the actual mill output within the limits of experimental error.  相似文献   

Mixing and cycling of uranium,thorium and ²¹⁰Pb in Puget Sound sediments     

R. Carpenter  M.L. Peterson  J.T. Bennett  B.L.K. Somayajulu 《Geochimica et cosmochimica acta》1984,48(10):1949-1963

Activity profiles of excess ²³⁴Th, excess ²¹⁰Pb, ²³²Th, ²³⁰Th, ²³⁴U and ²³⁸U, and ^228/232Th ratios determined in eight box cores of sediment from six sites in central Puget Sound provide new insights into the dynamic nature of solid phase mixing in surface sediments, the exchange of ²²⁸Ra and other soluble species across the sediment-water interface, and the cycling of U, Th and ²¹⁰Pb in this coastal zone.Comparison of excess ²³⁴Th inventories in sediments with its production rate in the overlying water column indicates a mean residence time of at most 14 days for particles in the central Puget Sound water column.Surface sediment horizons with excess ²³⁴Th have no excess ²²⁸Th which might be used to ascertain sediment accumulation rates over the past decade. Instead, deficiencies of ²²⁸Th due to loss of soluble ²²⁸Ra from pore water to the overlying water persist to 20–30 cm, revealing that exchange of soluble chemicals between pore and overlying waters reaches these depths in the extensively bioturbated sediments of Puget Sound.Solid phase U isotope concentrations tend to increase by up to a factor of two with depth in sediments, as a result of dissolved U being biologically pumped down into sediments where it is partially removed when conditions become mildly reducing. ²³²Th and ²³⁰Th activities and ^230/232Th ratios are constant with depth in sediments, indicating constant detrital phase compositions and essentially no authigenic ²³⁰Th. Steady state ²¹⁰Pb depositional activities in and fluxes to Puget Sound sediments average only about onehalf those for sediments of the open Washington coast north of the Columbia River mouth, primarily because of a much lower supply of dissolved ²¹⁰Pb in sea waters adverting into Puget Sound.Excess ²³⁴Th profiles in sediments reveal much more detail about the depth dependency, dynamic nature and recent history of solid phase mixing processes than excess ²¹⁰Pb profiles. At least six of eight ²³⁴Th profiles show that mixing within the ²¹⁰Pb-defined surface mixed layer is depth dependent. In three profiles, ²³⁴Th-derived mixing rates are fastest several centimeters below the sediment-water interface, indicating greater macro-benthic activity at these depths. Depth dependent mixing coefficients derived from the best fit of a four layer, advection-diffusion-decay model to the ²³⁴Th data are consistent with ²¹⁰Pb profiles determined for the same sediments, strongly suggesting that ²³⁴Th and ²¹⁰Pb are mixed equivalently and in a multilayered manner.  相似文献   

The trace element composition of silicate inclusions in diamonds: a review   总被引：1，自引：0，他引：1  

Thomas Stachel  Sonja Aulbach  Gerhard P. Brey  Jeff W. Harris  Ingrid Leost  Ralf Tappert  K.S. Viljoen 《Lithos》2004,77(1-4):1-19

On a global scale, peridotitic garnet inclusions in diamonds from the subcratonic lithosphere indicate an evolution from strongly sinusoidal REE_N, typical for harzburgitic garnets, to mildly sinusoidal or “normal” patterns (positive slope from LREE_N to MREE_N, fairly flat MREE_N–HREE_N), typical for lherzolitic garnets. Using the Cr-number of garnet as a proxy for the bulk rock major element composition it becomes apparent that strong LREE enrichment in garnet is restricted to highly depleted lithologies, whereas flat or positive LREE–MREE slopes are limited to less depleted rocks. For lherzolitic garnet inclusions, there is a positive relation between equilibration temperature, enrichment in MREE, HREE and other HFSE (Ti, Zr, Y), and decreasing depletion in major elements. For harzburgitic garnets, relations are not linear, but it appears that lherzolite style enrichment in MREE–HREE only occurs at temperatures above 1150–1200 °C, whereas strong enrichment in Sr is absent at these high temperatures. These observations suggest a transition from melt metasomatism (typical for the lherzolitic sources) characterized by fairly unfractionated trace and major element compositions to metasomatism by CHO fluids carrying primarily incompatible trace elements. Melt and fluid metasomatism are viewed as a compositional continuum, with residual CHO fluids resulting from primary silicate or carbonate melts in the course of fractional crystallization and equilibration with lithospheric host rocks.

Eclogitic garnet inclusions show “normal” REE_N patterns, with LREE at about 1× and HREE at about 30× chondritic abundance. Clinopyroxenes approximately mirror the garnet patterns, being enriched in LREE and having chondritic HREE abundances. Positive and negative Eu anomalies are observed for both garnet and clinopyroxene inclusions. Such anomalies are strong evidence for crustal precursors for the eclogitic diamond sources. The trace element composition of an “average eclogitic diamond source” based on garnet and clinopyroxene inclusions is consistent with derivation from former oceanic crust that lost about 10% of a partial melt in the garnet stability field and that subsequently experienced only minor reenrichment in the most incompatible trace elements. Based on individual diamonds, this simplistic picture becomes more complex, with evidence for both strong enrichment and depletion in LREE.

Trace element data for sublithospheric inclusions in diamonds are less abundant. REE in majoritic garnets indicate source compositions that range from being similar to lithospheric eclogitic sources to strongly LREE enriched. Lower mantle sources, assessed based on CaSi–perovskite as the principal host for REE, are not primitive in composition but show moderate to strong LREE enrichment. The bulk rock LREE_N–HREE_N slope cannot be determined from CaSi–perovskites alone, as garnet may be present in these shallow lower mantle sources and then would act as an important host for HREE. Positive and negative Eu anomalies are widespread in CaSi–perovskites and negative anomalies have also been observed for a majoritic garnet and a coexisting clinopyroxene inclusion. This suggests that sublithospheric diamond sources may be linked to old oceanic slabs, possibly because only former crustal rocks can provide the redox gradients necessary for diamond precipitation in an otherwise reduced sublithospheric mantle.  相似文献   

Modelling frequency-dependent seismic anisotropy in fluid-saturated rock with aligned fractures: implication of fracture size estimation from anisotropic measurements   总被引：5，自引：0，他引：5  

Sonja Maultzsch  Mark Chapman  Enru Liu  Xiang Yang Li 《Geophysical Prospecting》2003,51(5):381-392

Measurements of seismic anisotropy in fractured rock are used at present to deduce information about the fracture orientation and the spatial distribution of fracture intensity. Analysis of the data is based upon equivalent-medium theories that describe the elastic response of a rock containing cracks or fractures in the long-wavelength limit. Conventional models assume frequency independence and cannot distinguish between microcracks and macrofractures. The latter, however, control the fluid flow in many subsurface reservoirs. Therefore, the fracture size is essential information for reservoir engineers. In this study we apply a new equivalent-medium theory that models frequency-dependent anisotropy and is sensitive to the length scale of fractures. The model considers velocity dispersion and attenuation due to a squirt-flow mechanism at two different scales: the grain scale (microcracks and equant matrix porosity) and formation-scale fractures. The theory is first tested and calibrated against published laboratory data. Then we present the analysis and modelling of frequency-dependent shear-wave splitting in multicomponent VSP data from a tight gas reservoir. We invert for fracture density and fracture size from the frequency dependence of the time delay between split shear waves. The derived fracture length matches independent observations from borehole data.  相似文献   

The geo-politics of sustainable development: bureaucracies and politicians in search of the holy grail     

Sonja Boehmer-Christiansen 《Geoforum》2002,33(3):351-365

Debates about implementing `sustainable development', `sustainability' or even `sustainable futures and resource use' are now engaging most intergovernmental and national bureaucracies. The notion itself appears to have replaced or become confused with efforts specifically directed at environmental protection, also a vague and contested notion. The origin, academic approaches and use of the idea is documented and discussed with reference to selected bureaucracies engaged in environmental `governance'. I ask why and with what impact these bureaucracies have adopted the term in the post cold-war era. The methodology used is political interest analysis: why have bureaucracies adopted the notion so eagerly since the later 1980s? I argue that the sustainability debate served to strengthen bureaucracy during an era when its powers were under attack. The debate promised to extend the role of bureaucracy from that of agent of policy implementation to that of significant political actor, required to select experts as well as futures. But to what purpose and in whose interest? In seeking `sustainability' have governments found more than a new tool for governing? I wish to stimulate theoretical and empirical investigations that replace the ubiquitous `policy-maker' of much academic research with an `actor' whose spatial nature, political roles and ambitions, as well as legal and resource limitations, are not ignored.  相似文献   

Holocene paleoenvironmental change inferred from two sediment cores collected in the Tibetan lake Taro Co     

Laug  Andreas  Haberzettl  Torsten  Pannes  Andre  Schwarz  Anja  Turner  Falko  Wang  Junbo  Engels  Stefan  Rigterink  Sonja  Börner  Nicole  Ahlborn  Marieke  Ju  Jianting  Schwalb  Antje 《Journal of Paleolimnology》2021,66(3):171-186

Journal of Paleolimnology - The Tibetan Plateau, also known as the “Water Tower of Asia” because of its function as a water storage and supply region, responds dramatically to modern...  相似文献   

Effect of sediment size on area of influence during groundwater remediation by air sparging: a laboratory approach   总被引：2，自引：0，他引：2  

J. W. Peterson  P. A. Lepczyk  K. L. Lake 《Environmental Geology》1999,38(1):1-6

 Air sparging is a groundwater remediation technique, in which organic contaminants volatilize into air as it rises from the saturated to vadose zone. An unknown has been the relationship between sediment size and area affected by air. Laboratory experiments were performed on sediments to determine the area affected by air as a function of grain size. For average grain sizes of 1.1 and 1.3-mm diameter, air flow occurs in discrete meandering channels, with a maximum area of sediment column affected of 13%/m² for 1.1-mm and 14%/m² for 1.3-mm sediments. For average grain sizes of 1.84, 2.61 and 4.38-mm diameter, air flow is pervasive, forming a symmetrical cone of influence around the injection point. Maximum areas affected are15%/m² for 1.84-mm, 25%/m² for 2.61-mm, and 9%/m² for 4.38-mm sediments. Optimal sites for air sparging, may be those with grain diameters between about 2–3 mm. Received: 26 June 1998 · Accepted: 27 July 1998  相似文献   

Hummock corridors in the south‐central sector of the Fennoscandian ice sheet,morphometry and pattern          下载免费PDF全文

Gustaf Peterson  Mark D. Johnson 《地球表面变化过程与地形》2018,43(4):919-929

Subglacial conditions strongly influence the flow of ice‐sheets, in part due to the availability of melt water. Contemporary ice sheets are retreating and are affected by increased melting as climate warms. The south Swedish uplands (SSU) were deglaciated during the relatively warm Bølling‐Allerød interval, and by studying the glacial landforms there it is possible to increase the understanding of the subglacial environment during this period of warming. Across the study area, vast tracts of hummocks have long been recognized. However, recent mapping shows a pattern of elongated zones of hummocks radially oriented, hereafter referred to as ‘hummock corridors’. Morphometric parameters were measured on the hummock corridors using a 2 m horizontal resolution digital elevation model. Corridor width varies between 0.2 and 4.9 km and their length between 1.5 and 11.8 km. A majority of hummock corridors are incised in drumlinised till surfaces. The pattern of hummock corridors shows a clear relation to the overall ice‐flow. Further, hummock corridors do not follow topographic gradients, and in at least one place an esker overlies hummocks on the corridor floor. The lateral spacing of hummock corridors and corridor morphology are similar to tunnel valleys, eskers and glaciofluvial corridors reported elsewhere. Such relationships support a subglacial genesis of the corridors in the SSU by water driven by the subglacial hydraulic gradient and that hummock corridors are forms that can be identified as tunnel valleys and glaciofluvial corridors (GFC). Ages were assigned to hummock‐corridor cross‐sections from a deglacial reconstruction of the Fennoscandian Ice Sheet. By comparing the frequency of corridors per age interval with climate variations from a Greenland ice core, we hypothesize that an increase in the number of corridors is related to the Bølling‐Allerød warming, indicating a higher rate of delivery of surface melt water to the bed at this time. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献