Magnetic behavior of trioctahedral micas with different octahedral Fe ordering     

Stefano Pini  Maria Franca Brigatti  Marco Affronte  Daniele Malferrari  Augusto Marcelli 《Physics and Chemistry of Minerals》2012,39(8):665-674

This contribution is finalized at the discussion of the magnetic structure of two samples, belonging to phlogopite–annite [sample TK, chemical composition ^IV(Si_2.76Al_1.24) ^VI(Al_0.64Mg_0.72 $ {\text{Fe}}_{1.45}^{2 + } $ Mn_0.03Ti_0.15) (K_0.96Na_0.05) O_10.67 (OH)_1.31 Cl_0.02] and polylithionite–siderophyllite joints [sample PPB, chemical composition ^IV(Si_3.14Al_0.86)^VI(Al_0.75Mg_0.01 $ {\text{Fe}}_{1.03}^{2 + } $ $ {\text{Fe}}_{1.03}^{3 + } $ Mn_0.01Ti_0.01Li_1.09) (K_0.99Na_0.01) O_10.00 (OH)_0.65F_1.35]. Samples differ for Fe ordering in octahedral sites, Fe²⁺/(Fe²⁺?+?Fe³⁺) ratio, octahedral composition, defining a different environment around Fe cations, and layer symmetry. Spin-glass behavior was detected for both samples, as evidenced by the dependency of the temperature giving the peak in the susceptibility curve from the frequency of the applied alternating current magnetic field. The crystal chemical features are associated to the different temperature at which the maximum in magnetic susceptibility is observed: 6?K in TK, where Fe is disordered in all octahedral sites, and 8?K in PPB sample, showing a smaller and more regular coordination polyhedron for Fe, which is ordered in the trans-site and in one of the two cis-sites.  相似文献   

Syn-thrust deformation across a transverse zone: the Grem–Vedra fault system (central Southern Alps, N Italy)     

Andrea Zanchi  Paolo D’Adda  Stefano Zanchetta  Fabrizio Berra 《Swiss Journal of Geoscience》2012,105(1):19-38

The lateral continuity of the E?CW trending thrust sheets developed within the Lower to Middle Triassic cover of the central Southern Alps (Orobic belt) is disturbed by the occurrence of several N?CS trending transverse zones, such as the poorly known Grem?CVedra Transverse Zone (GVTZ). The GVTZ developed during the emplacement of the up to six S-verging thrust sheets consisting of Lower to Middle Triassic units, occurring immediately south of the Orobic Anticlines. The transverse zone, active during thrust emplacement related to the early Alpine compressions which pre-date the Adamello intrusion, includes three major vertical shear zones, the Grem, Pezzel and Zuccone faults. The major structure of the transverse zone is the dextral Grem fault, forming a deep lateral ramp between thrust sheets 3 and 5. A similar evolution also occurred along the Zuccone and Pezzel faults, which show a left-lateral displacement of syn-thrust folds. The Grem fault was later reactivated as an oblique tear fault during the emplacement of the Orobic Anticlines, due to back-thrusting along out-of-sequence thrust surfaces (Clusone fault). Transpressional deformations along the fault zone are recorded by the rotation of major syn-thrust folds, which also suggest a horizontal offset close to 0.5?km. Records of the first stage of evolution of the Grem fault are better preserved along its northern segment, and structural relationships suggest that it propagated southward and downward in the growing thrust stack. The study of the meso and megascopic structures developed along the GVTZ constrains the evolution of the transverse zone, illustrating the complex deformational phenomena occurring in a transpressional regime. The GVTZ probably reflects the existence of pre-existing tectonic lineaments with a similar orientation. Evidence of pre-existing structures are not preserved in the exposed units, nevertheless the N?CS extensional fault systems that characterize the Norian to Jurassic rifting history of the Lombardian basin are valid candidates.  相似文献   

In Situ Determination of Au and Cu in Natural Pyrite by Near‐Infrared Femtosecond Laser Ablation‐Inductively Coupled Plasma‐Quadrupole Mass Spectrometry: No Evidence for Matrix Effects     

German Velásquez  Anastassia Y. Borisova  Stefano Salvi  Didier Béziat 《Geostandards and Geoanalytical Research》2012,36(3):315-324

Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for ⁵⁷Fe, ⁶³Cu and ¹⁹⁷Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator.  相似文献   

Modelling hydrostratigraphy and groundwater flow of a fractured and karst aquifer in a Mediterranean basin (Salento peninsula, southeastern Italy)   总被引：2，自引：0，他引：2  

Mauro Giudici  Stefano Margiotta  Fiorella Mazzone  Sergio Negri  Chiara Vassena 《Environmental Earth Sciences》2012,67(7):1891-1907

The control exerted by the hydrostratigraphic structure on aquifer recharge, groundwater flow and discharge along the coastal areas of a Mediterranean basin (Salento peninsula, about 5,000?km² wide, southern Italy) is assessed through the development and application of a groundwater flow model based on the reconstruction of the hydrostratigraphic architecture at the regional scale. The hydrostratigraphic model, obtained by processing surface and subsurface data, is applied to map the top of the main aquifer, which is hosted in the deep hydrostratigraphic unit corresponding to Cretaceous and Oligocene limestones with complex geometrical relationships with the sea. It is also used to estimate the aquifer recharge, which occurs by percolation through overlying younger sediments with low permeability. These data are completed with information about the soil use to estimate water abstraction for irrigation and with literature data to estimate the water abstraction for drinking and industrial purposes. The above-sketched conceptual model is the basis for a finite difference groundwater 2D pseudo-stationary flow model, which assumes the following fundamental approximations: the fractured and karst limestone hydrostratigraphic unit can be approximated, at the model scale, as a continuous medium for which the discrete Darcy??s law is valid; the transition zone between salt and fresh water is so small with respect to the grid spacing that the Ghyben?CHerzberg??s approximation for a sharp interface can be applied. Along the coastline different boundary conditions are assigned if the top of the limestone hydrostratigraphic unit lies either above the sea level (the aquifer has a free surface and fresh water is drained), or below the sea level (the aquifer is under pressure and the contact with sea occurs off-shore). The groundwater flow model correctly predicts the areas where the aquifer is fully saturated with salt water.  相似文献   

Analysis of a regional change in the sign of the SAM�Ctemperature relationship in Antarctica     

Gareth J. Marshall  Stefano Di Battista  Sushant S. Naik  Meloth Thamban 《Climate Dynamics》2011,36(1-2):277-287

This study examines regional atmospheric circulation changes associated with a reversal in the sign of the relationship between the Southern Annular Mode (SAM) and near-surface temperatures at Halley station, East Antarctica, during the 1980s. We show that the key factor affecting the regional SAM?Ctemperature relationship (STR) is the relative magnitude of two climatological low pressure centres to the west and east of the area, which determines the source region of air masses advected into the locality. The principal difference affecting the STR is shown to be a trend towards a significantly weaker climatological low (higher pressure) at ~20°E during a positive phase of the SAM. Specifically, it is variations in the phase and magnitude of the wave number three patterns of atmospheric circulation, the non-annular component of the SAM, which are the principal factors governing the regional STR. A similar reversal is observed in the sign of the correlation between the SAM and oxygen-isotope values from an ice core located some 1,200?km east of Halley. This relationship is examined throughout the 20th Century, by comparing the isotope data to SAM reconstructions, and demonstrates marked decadal variability. Thus, these data suggest that switches in the STR are more likely to reflect natural variability in the long-wave patterns over the Southern Ocean rather than the influence of an anthropogenic forcing. This finding is important when considering the potential utility of Antarctic isotope data as a proxy for the SAM.  相似文献   

Ostreopsis cf. ovata bloom in the northern Adriatic Sea during summer 2009: ecology, molecular characterization and toxin profile     

Accoroni S  Romagnoli T  Colombo F  Pennesi C  Di Camillo CG  Marini M  Battocchi C  Ciminiello P  Dell'Aversano C  Dello Iacovo E  Fattorusso E  Tartaglione L  Penna A  Totti C 《Marine pollution bulletin》2011,62(11):2512-2519

Intense blooms of the benthic dinoflagellate Ostreopsis cf. ovata have occurred in the northern Adriatic Sea since 2006. These blooms are associated with noxious effects on human health and with the mortality of benthic organisms because of the production of palytoxin-like compounds. The O. cf. ovata bloom and its relationships with nutrient concentrations at two stations on the Conero Riviera (northern Adriatic Sea) were investigated in the summer of 2009. O. cf. ovata developed from August to November, with the highest abundances in September (1.3 × 10⁶ cells g⁻¹ fw corresponding to 63.8 × 10³ cells cm⁻²). The presence of the single O. cf. ovata genotype was confirmed by a PCR assay. Bloom developed when the seawater temperature was decreasing. Nutrient concentrations did not seem to affect bloom dynamics. Toxin analysis performed by high resolution liquid chromatography-mass spectrometry revealed a high total toxin content (up to 75 pg cell⁻¹), including putative palytoxin and all the ovatoxins known so far.  相似文献   

The 29 September 2009 Samoa Islands Tsunami: Simulations Based on the First Focal Mechanism Solutions and Implications on Tsunami Early Warning Strategies     

Roberto Tonini  Alberto Armigliato  Stefano Tinti 《Pure and Applied Geophysics》2011,168(6-7):1113-1123

The tsunamigenic earthquake (Mw?=?8.1) that occurred on 29 September 2009 at 17:48 UTC offshore of the Samoa archipelago east of the Tonga trench represents an example of the so-called ??outer-rise?? earthquakes. The areas most affected were the south coasts of Western and American Samoa, where almost 200 people were killed and run-up heights were measured in excess of 5?m at several locations along the coast. Moreover, tide gauge records showed a maximum peak-to-peak height of about 3.5?m near Pago Pago (American Samoa) and of 1.5?m offshore of Apia (Western Samoa). In this work, different fault models based on the focal mechanism solutions proposed by Global CMT and by USGS immediately after the 2009 Samoan earthquake are tested by comparing the near-field recorded signals (three offshore DART buoys and two coastal tide gauges) and the synthetic signals provided by the numerical simulations. The analysis points out that there are lights and shadows, in the sense that none of the computed tsunamis agrees satisfactorily with all the considered signals, although some of them reproduce some of the records quite well. This ??partial agreement?? and ??partial disagreement?? are analysed in the perspective of tsunami forecast and of Tsunami Early Warning System strategy.  相似文献   

Long-term morphological river response to hydrological changes     

Stefano Tealdi  Carlo CamporealeLuca Ridolfi 《Advances in water resources》2011,34(12):1643-1655

Hydrologic changes have a great impact on the long-term river morphology. The most common anthropic cause is the construction of dams, which often reduces both the discharge regime and sediment transport, producing a narrowing and degradation of the river bed. In this study we propose a simple, lumped morphodynamic model that describes fluvial cross-section dynamics consequent to changes in discharge and sediment transport induced by external factors. The model provides the temporal dynamics of the river width and bed quote. These dynamics result not to be trivial and can exhibit non monotonic behavior, with aggradations and degradations, and narrowing and widening. The model has been tested on real rivers using data obtained from field studies. The agreement between the outcomes and the data measured in the field works is always satisfactory.  相似文献   

Introspection on improper seismic retrofit of Basilica Santa Maria di Collemaggio after 2009 Italian earthquake     

Gian Paolo Cimellaro  Andrei M. Reinhorn  Alessandro De Stefano 《地震工程与工程振动(英文版)》2011,10(1):153-161

The 2009 L’Aquila, Italy earthquake highlighted the seismic vulnerability of historic masonry building structures due to improper "strengthening" retrofit work that has been done in the last 50 years. Italian seismic standards recommend the use of traditional reinforcement techniques such as replacing the original wooden roof structure with new reinforced concrete (RC) or steel elements, inserting RC tie-beams in the masonry and new RC floors, and using RC jacketing on the shear walls. The L’Aquila earthquake revealed the numerous limitations of these interventions, because they led to increased seismic forces (due to greater additional weight) and to deformation incompatibilities of the incorporated elements with the existing masonry walls. This paper provides a discussion of technical issues pertaining to the seismic retrofit of the Santa Maria di Collemaggio Basilica and in particular, the limitations of the last (2000) retrofit intervention. Considerable damage was caused to the church because of questionable actions and incorrect and improper technical choices.  相似文献   

Modeling the impact of river damming on riparian vegetation     

Stefano Tealdi  Carlo Camporeale  Luca Ridolfi 《Journal of Hydrology》2011,396(3-4):302-312

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