Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site     

Thomas Pape  André Bahr  Janet Rethemeyer  John D. Kessler  Heiko Sahling  Kai-Uwe Hinrichs  Stephan A. Klapp  William S. Reeburgh  Gerhard Bohrmann 《Chemical Geology》2010,269(3-4):350-363

Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C₁–C₄, CO₂]). Molecular ratios of LMWHC (C₁/[C₂ + C₃] > 1000) and stable isotopic compositions of methane (δ¹³C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C₁/C₂₊ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C₁–C₄, CO₂]) relative to the other gas types and the virtual lack of ¹⁴C–CH₄ indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C₁–C₄, CO₂)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of ¹⁴C–CH₄ (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.  相似文献   

In situ U–Pb dating of micro-baddeleyite by secondary ion mass spectrometry     

Axel K. Schmitt  Kevin R. Chamberlain  Susan M. Swapp  T. Mark Harrison 《Chemical Geology》2010,269(3-4):386-395

We introduce a technique for U–Pb dating of baddeleyite using secondary ion mass spectrometry (SIMS) in situ analysis of ng-mass crystals that cannot be efficiently extracted by conventional mineral separation techniques. Average ²⁰⁷Pb/²⁰⁶Pb ages for Precambrian baddeleyite crystals are within < 0.3% of the respective isotope dilution thermal ionization mass spectrometry (ID-TIMS) ages. ²⁰⁶Pb/²³⁸U ratios are corrected for instrumental fractionation calibrated through linear regression in a Pb/U relative sensitivity vs. UO₂⁺/U⁺ calibration plot. Calibration is performed on separated baddeleyite crystals (～ 100–200 μm in maximum dimension) mounted in random crystallographic orientation. ²⁰⁶Pb/²³⁸U ages for baddeleyite from Duluth gabbro (FC4b) and Kovdor are accurate within 1–2% when averaging 15–30 individual spot analyses and relative sensitivities calibrated on Phalaborwa baddeleyite. The relative difference of ²⁰⁶Pb/²³⁸U between large crystals and micro-baddeleyite from FC4b is within ～ 1%. Comparison between silicate glass and baddeleyite, as well as replicate analysis of the same grains in different orientations relative to the incidence direction of the primary beam support previous evidence for bias in Pb/U sensitivity in baddeleyite due to variable crystal orientations. We successfully utilized oxygen flooding and a UO₂⁺/U⁺-based calibration to significantly reduce orientation dependent bias.  相似文献   

In situ U–Pb SIMS (IN-SIMS) micro-baddeleyite dating of mafic rocks: Method with examples     

Kevin R. Chamberlain  Axel K. Schmitt  Susan M. Swapp  T. Mark Harrison  Norbert Swoboda-Colberg  Wouter Bleeker  Tony D. Peterson  Charles W. Jefferson  Andrei K. Khudoley 《Precambrian Research》2010

An in situ U–Pb SIMS (IN-SIMS) method to date micro-baddeleyite crystals as small as 3 μm is presented with results from three samples that span a variety of ages and geologic settings. The method complements ID-TIMS geochronology by extending the range of dateable crystals to sizes smaller than can be recovered by physical separation. X-ray mapping and BSE imaging are used to locate target grains in thin section, followed by SIMS analysis on a CAMECA ims 1270, using the field aperture in the transfer column to screen out ions from host phases. Internal age precisions for the method are anticipated to range from 0.1% for Precambrian rocks to 3–7% for Phanerozoic rocks. Results establish a 2689 ± 5 Ma age for mafic dikes in the Wyoming craton, USA, a 1540 ± 30 Ma age for a subaerial lava flow from the Thelon Basin of northern Canada, and a 457 ± 34 Ma age for mafic dikes in the platform sequence of southeastern Siberia. The method is ideal for relatively non-destructive dating of small samples such as extraterrestrial rocks and precious terrestrial samples.  相似文献   

Pediment response to drainage basin evolution in south-central Arizona     

Phillip H. Larson  Ronald I. Dorn  R. Evan Palmer  Zack Bowles  Emma Harrison  Scott Kelley 《自然地理学》2014,35(5):369-389

The Sonoran Desert portion of the Basin and Range physiographic province contains a number of streams that now flow across once-closed basins. We explore here the research questions of if and how granitic rock pediments respond to the transition from rimming endorheic basins to bordering through-flowing streams. Granitic rock pediments of the northern Usery and eastern McDowell Mountains once graded to the closed Miocene–Pliocene Pemberton basin that occupied the present-day location of the confluence of the Salt and Verde Rivers. The process of lake overflow, which integrated these rivers, first aggraded fill terraces that, in turn, caused aggradation of a mantle of transported grus on bedrock pediments. Subsequent episodic incision of the Salt and Verde rivers lowered the base level; this led to the development of erosional features such as rolling topography of a degrading pediment mantle; exposure of the former piedmont angle and its associated zones of enhanced bedrock decay and regolith carbonate; and exposure of spheroidally weathered bedrock and emerging tors, some of which experienced 20^th century erosion. The granitic pediments of the former Pemberton Basin, which now transport grus to the Salt and Verde rivers, have actively adjusted to aggradational and degradational events associated with drainage integration and do not appear to be inherited from an ancient wet climatic interval.  相似文献   

Atlantic watermass and circulation response to persistent freshwater forcing in two coupled general circulation models     

M. Harrison  A. Adcroft  R. Hallberg 《Climate Dynamics》2014,42(1-2):59-68

The sensitivity of the Atlantic circulation and watermasses to biases in the convergence of moisture into the basin is examined in this study using two different general circulation models. For a persistent positive moisture flux into the tropical Atlantic, the average salinity and temperature in the basin is reduced, mainly below mid-depths and in high latitudes. A transient reduction in the Atlantic overturning strength occurs in this case, with a recovery timescale of 1–2 centuries. In contrast, a similar amount of freshwater directed into the Subpolar North Atlantic results in a persistent reduction in overturning and an increase in basin heat and salt content. In the unperturbed pre-industrial simulations, the Atlantic is unambiguously warmer and saltier than historical observations below mid-depths and in the Nordic Seas. The models’ tropical freshwater flux sensitivities project strongly onto the spatial pattern of this bias, suggesting a common atmospheric deficiency. The integrated Atlantic plus Arctic surface freshwater flux in these models is between ?0.5 and ?0.6 Sv, compared with an observational estimate of ?0.28 Sv. Our results suggest that shortcomings in the models’ ability to reproduce realistic bulk watermass properties are due to an overestimation of the inter-basin moisture export from the tropical Atlantic.  相似文献   

Scientific uncertainty and climate change: Part II. Uncertainty and mitigation     

Stephan Lewandowsky  James S. Risbey  Michael Smithson  Ben R. Newell 《Climatic change》2014,124(1-2):39-52

In public debate surrounding climate change, scientific uncertainty is often cited in connection with arguments against mitigative action. This article examines the role of uncertainty about future climate change in determining the likely success or failure of mitigative action. We show by Monte Carlo simulation that greater uncertainty translates into a greater likelihood that mitigation efforts will fail to limit global warming to a target (e.g., 2 °C). The effect of uncertainty can be reduced by limiting greenhouse gas emissions. Taken together with the fact that greater uncertainty also increases the potential damages arising from unabated emissions (Lewandowsky et al. 2014), any appeal to uncertainty implies a stronger, rather than weaker, need to cut greenhouse gas emissions than in the absence of uncertainty.  相似文献   

Erratum to “The relationship between shrink–swell occurrence and climate in south-east England” [Proc. Geol. Assoc. 123 (2012) 556–575]     

A.M. Harrison  J.F.M. Plim  M. Harrison  L.D. Jones  M.G. Culshaw 《Proceedings of the Geologists' Association. Geologists' Association》2014

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A study of hybrid and chaotic long-range propagation in a doublesound channel environment     

Noel  C. Viala  C. Stephan  Y. 《Oceanic Engineering, IEEE Journal of》1999,24(4):447-457

This paper presents the results of the analysis of long range propagation (~200 km) in a range-dependent environment. The propagation medium is characterized by two deep sound channels. The range dependence enables energy transfer between the channels and leads to a mismatch between real data and ray predictions. To explain this mismatch, an analysis of hybrid ray propagation is presented. This analysis is completed by an interpretation in terms of chaos. This chaos is quantified in the particular case of the Bay of Biscay environment. This paper puts forward that mesoscale perturbations, such as the Mediterranean outflow in the North Atlantic, can affect long-range propagation. However, it shows that the ray theory remains reliable for a propagation range of several hundred kilometers  相似文献   

Response of precipitation over Greenland and the adjacent ocean to North Pacific warm spells during Dansgaard–Oeschger stadials     

Thorsten Kiefer  Stephan Lorenz  Michael Schulz  Gerrit Lohmann  Michael Sarnthein  Henry Elderfield 《地学学报》2002,14(4):295-300

ABSTRACT Palaeoceanographic reconstructions from the North Atlantic indicate massive ice breakouts from East Greenland near the onset of cold Dansgaard–Oeschger (D–O) stadials. In contrast to these coolings in the North Atlantic area, a new sea-surface temperature record reveals concomitant warm spells in the northern North Pacific. A sensitivity experiment with an atmospheric general circulation model is used to test the potential impact of sea-surface warmings by 3.5 °C in the North Pacific, on top of otherwise cold stadial climate conditions, on the precipitation regime over the Northern Hemisphere ice sheets. The model predicts a maximum response over East Greenland and the Greenland Sea, where a 40% increase in net annual snow accumulation occurs. This remote effect of North Pacific warm spells on the East Greenland snow-accumulation rate may play an important role in generating D–O cycles by rebuilding the ice lost during ice breakouts. In addition, the increased precipitation over the Greenland Sea may help to sustain the D–O stadial climate state.  相似文献   

First Observations of Coronal Hole Structure and Evolution Using Soho-Cds     

J. E . Insley  V. Moore  R. A. Harrison 《Solar physics》1997,175(2):437-456

We report on initial observations of coronal holestructure and evolution by the Coronal Diagnostic Spectrometer (CDS) instrument on board the Solar and Heliospheric Observatory (SOHO). The data show that there is coronal activity on time scales of tens of minutes, manifested as brightenings at chromospheric network cell junctions in extreme ultraviolet (EUV) wavelengths. There are also significant differences in structure seen in different wavelengths in coronal holes. Finally, we show coronal hole EUV spectra and compare them to quiet-Sun spectra, also taken by CDS.  相似文献