Surface-structure-controlled sectoral zoning of the rare earth elements in fluorite from Long Lake, New York, and Bingham, New Mexico, USA   总被引：1，自引：0，他引：1  

Stephanie BoszeJohn Rakovan 《Geochimica et cosmochimica acta》2002,66(6):997-1009

The concentration and distribution of rare earth elements (REE) in sectorally zoned fluorite crystals from Long Lake, New York, and the Hansonburg Mining District, Bingham, New Mexico, have been studied using cathodoluminescence and synchrotron X-ray fluorescence microanalysis (SXRFMA). In cubo-octahedral samples from Long Lake, New York, Ce, Nd, Gd, Dy, Ho, Er, and Tm are preferentially partitioned into the |111| sector relative to the |100| sector. Partition coefficients (K_d = concentration in |111| sector/concentration in |100| sector) range between 3.5 for Ce, to 1.4 for Tm, with a general decrease in K_d as elements deviated from the ionic radius of Ca²⁺, for which REE substitute in fluorite. Diffusion of the REE has occurred, as evidenced by gradual changes in composition over distances of 0.2 to 0.3 mm at sector boundaries.In Bingham samples, three different partition coefficients were determined for Dy: K_d|100|/|111| = 2.83, K_{d |100|/|110|} = 1.77, and K_{d |110|/|111|} = 1.60. These are mean K_d values for a 95% confidence interval. In another sample from the same deposit, Dy, Er, and Gd were found to be preferentially incorporated into the |100| sector relative to the |210| sector with average K_{d |100|/|210|} of 3.1, 2.4, and 2.9, respectively. In a third sample, Nd was found to be preferentially incorporated into the |110| sector relative to the |321| sector with an average K_{d |110|/|321|} value of 2.3.Compositional heterogeneities in a given sector (concentric zoning) have been resolved using SXRFMA but are significantly less than the concentration difference across sector boundaries. Often fluorite exists in a wide variety of morphologies, as is the case in the Hansonburg Mining District of Bingham. We suggest caution when using the REE as petrogenetic indicators because fluorite trace element chemistry can vary greatly among crystals within a deposit depending on the internal morphology of a particular crystal.  相似文献   

Use of composite data sets for source-tracking enterococci in the water column and shoreline interstitial waters on Pensacola Beach, Florida     

Genthner FJ  James JB  Yates DF  Friedman SD 《Marine pollution bulletin》2005,50(7):724-732

Sources of Enterococcus faecalis isolates from Pensacola Beach, FL. were identified using a library-based approach by applying the statistical method of average similarity to single and composite data sets generated from separate analyses. Data sets included antibiotic resistance analysis (ARA), rep-fingerprints, and fatty acid methyl ester (FAME) profiles. Use of a composite data set composed of ARA and rep-fingerprints, added to the confidence of the identifications. The addition of FAME data to composite data sets did not add to the confidence of identifications. Source identification was performed to better understand risk associated with higher densities of enterococci found in swash zone interstitial water (SZIW) as compared to adjacent bathing water on Pensacola Beach, FL. The "swash zone" is that area of the beach continually washed over by waves. As the potential sources of enterococci were limited in this environment, only two library units, sea gull and human, were constructed. Identification of the beach isolates using a composite data set indicated a sea gull origin. The clonality of the beach isolates suggested that the beach environment selects certain subspecies of E. faecalis.  相似文献   

Evaluation of an ensemble of Arctic regional climate models: spatiotemporal fields during the SHEBA year   总被引：1，自引：1，他引：0  

A.?RinkeEmail author  K.?Dethloff  J.?J.?Cassano  J.?H.?Christensen  J.?A.?Curry  P.?Du  E.?Girard  J.-E.?Haugen  D.?Jacob  C.?G.?Jones  M.?K?ltzow  R.?Laprise  A.H.?Lynch  S.?Pfeifer  M.?C.?Serreze  M.?J.?Shaw  M.?Tjernstr?m  K.?Wyser  M.??agar 《Climate Dynamics》2006,26(5):459-472

Simulations of eight different regional climate models (RCMs) have been performed for the period September 1997–September 1998, which coincides with the Surface Heat Budget of the Arctic Ocean (SHEBA) project period. Each of the models employed approximately the same domain covering the western Arctic, the same horizontal resolution of 50 km, and the same boundary forcing. The models differ in their vertical resolution as well as in the treatments of dynamics and physical parameterizations. Both the common features and differences of the simulated spatiotemporal patterns of geopotential, temperature, cloud cover, and long-/shortwave downward radiation between the individual model simulations are investigated. With this work, we quantify the scatter among the models and therefore the magnitude of disagreement and unreliability of current Arctic RCM simulations. Even with the relatively constrained experimental design we notice a considerable scatter among the different RCMs. We found the largest across-model scatter in the 2 m temperature over land, in the surface radiation fluxes, and in the cloud cover which implies a reduced confidence level for these variables. An erratum to this article can be found at  相似文献   

A case study of coping strategies and landslides in two villages of Central-Eastern Nepal     

Karen Sudmeier-Rieux  Stephanie Jaquet 《Applied geography (Sevenoaks, England)》2012,32(2):680-690

Landslides are an increasing problem in Nepal’s Middle Hills due to both natural and human phenomena: mainly increasingly intense monsoon rains and a boom in rural road construction. This problem has largely been neglected due to underreporting of losses and the dispersed nature of landslides. Understanding how populations cope with landslides is a first step toward developing more effective landslide risk management programs. The present research focuses on two villages in Central-Eastern Nepal, both affected by active landslides but with different coping strategies. Research methods are interdisciplinary, based on a geological assessment of landslide risk and a socio-economic study of the villages using household questionnaires, focus group discussions and transect walks. Community risk maps are compared with geological landslide risk maps to better understand and communicate community risk perceptions, priorities and coping strategies. A modified typology of coping strategies is presented, based on previous work by Burton, Kates, and White (1993) that is useful for decision-makers for designing more effective programs for landslide mitigation. Main findings underscore that coping strategies, mainly seeking external assistance and outmigration, are closely linked to access to resources, ethnicity/social status and levels of community organization. Conclusions include the importance of investing in organizational skills, while building on local knowledge about landslide mitigation for reducing landslide risk. There is great potential to increase coping strategies by incorporating skills training on landslide mitigation in existing agricultural outreach and community forest user group training.  相似文献   

Performance of a multi-RCM ensemble for South Eastern South America   总被引：1，自引：1，他引：0  

A. F. Carril  C. G. Menéndez  A. R. C. Remedio  F. Robledo  A. S?rensson  B. Tencer  J.-P. Boulanger  M. de Castro  D. Jacob  H. Le Treut  L. Z. X. Li  O. Penalba  S. Pfeifer  M. Rusticucci  P. Salio  P. Samuelsson  E. Sanchez  P. Zaninelli 《Climate Dynamics》2012,39(12):2747-2768

The ability of four regional climate models to reproduce the present-day South American climate is examined with emphasis on La Plata Basin. Models were integrated for the period 1991–2000 with initial and lateral boundary conditions from ERA-40 Reanalysis. The ensemble sea level pressure, maximum and minimum temperatures and precipitation are evaluated in terms of seasonal means and extreme indices based on a percentile approach. Dispersion among the individual models and uncertainties when comparing the ensemble mean with different climatologies are also discussed. The ensemble mean is warmer than the observations in South Eastern South America (SESA), especially for minimum winter temperatures with errors increasing in magnitude towards the tails of the distributions. The ensemble mean reproduces the broad spatial pattern of precipitation, but overestimates the convective precipitation in the tropics and the orographic precipitation along the Andes and over the Brazilian Highlands, and underestimates the precipitation near the monsoon core region. The models overestimate the number of wet days and underestimate the daily intensity of rainfall for both seasons suggesting a premature triggering of convection. The skill of models to simulate the intensity of convective precipitation in summer in SESA and the variability associated with heavy precipitation events (the upper quartile daily precipitation) is far from satisfactory. Owing to the sparseness of the observing network, ensemble and observations uncertainties in seasonal means are comparable for some regions and seasons.  相似文献   

Public policy, institutional investors and climate change: a UK case-study     

Stephanie Pfeifer  Rory Sullivan 《Climatic change》2008,89(3-4):245-262

Institutional investors have two important roles to play in encouraging companies to address the risks and take advantage of the opportunities presented by climate change. The first is through using their influence as shareholders to encourage companies to adopt more proactive approaches to managing the risks and opportunities presented by climate change. The second is through explicitly factoring climate change risks and opportunities into ‘mainstream’ investment analysis processes. While there is growing investor activity on the former, the integration of climate change into investment analysis remains confined to sectors where there are strong government incentives (e.g. for renewable energy) or where greenhouse gas emissions have a market price. This article reviews the evolution of UK institutional investor interest in climate change from 1990 to 2005, focusing in particular on the relative contributions of ‘soft’ policy measures such as information-disclosure and awareness raising, and ‘hard’ policy measures such as regulation and market-based instruments. The article concludes that, over this period, soft policy measures played an important role in encouraging investors to discuss climate change issues with companies, but had minimal influence on investment decisions. It was only with the introduction of hard policy measures that climate change started to be systematically factored into investment analysis. The article canvasses the implications of these findings for government efforts in the UK and elsewhere to encourage investors to play a more proactive role in the climate change debate. It also considers the role that institutional investors themselves can play in strengthening public policy measures to reduce greenhouse gas emissions.  相似文献   

Long-term hydrology and aquatic biogeochemistry data from H. J. Andrews Experimental Forest,Cascade Mountains,Oregon     

Sherri L. Johnson  Don Henshaw  Greg Downing  Steve Wondzell  Mark Schulze  Adam Kennedy  Greg Cohn  Stephanie A. Schmidt  Julia A. Jones 《水文研究》2021,35(5):e14187

The H. J. Andrews Experimental Forest (HJA) encompasses the 6400 ha Lookout Creek watershed in western Oregon, USA. Hydrologic, chemistry and precipitation data have been collected, curated, and archived for up to 70 years. The HJA was established in 1948 to study the effects of harvest of old-growth conifer forest and logging-road construction on water quality, quantity and vegetation succession. Over time, research questions have expanded to include terrestrial and aquatic species, communities and ecosystem dynamics. There are nine small experimental watersheds and 10 gaging stations in the HJA, including both reference and experimentally treated watersheds. Gaged watershed areas range from 8.5 to 6242 ha. All gaging stations record stage height, water conductivity, water temperature and above-stream air temperature. At nine of the gage sites, flow-proportional water samples are collected and composited over 3-week intervals for chemical analysis. Analysis of stream and precipitation chemistry began in 1968. Analytes include dissolved and particulate species of nitrogen and phosphorus, dissolved organic carbon, pH, specific conductance, suspended sediment, alkalinity, and major cations and anions. Supporting climate measurements began in the 1950s in association with the first small watershed experiments. Over time, and following the initiation of the Long Term Ecological Research (LTER) grant in 1980, infrastructure expanded to include a set of benchmark and secondary meteorological stations located in clearings spanning the elevation range within the Lookout Creek watershed, as well as a large number of forest understory temperature stations. Extensive metadata on sensor configurations, changes in methods over time, sensor accuracy and precision, and data quality control flags are associated with the HJA data.  相似文献   

Connectivity of post-fire runoff and sediment from nested hillslopes and watersheds     

Codie Wilson  Stephanie K. Kampf  Sandra Ryan  Tim Covino  Lee H. MacDonald  Hunter Gleason 《水文研究》2021,35(1):e13975

Wildfire increases the potential connectivity of runoff and sediment throughout watersheds due to greater bare soil, runoff and erosion as compared to pre-fire conditions. This research examines the connectivity of post-fire runoff and sediment from hillslopes (< 1.5 ha; n = 31) and catchments (< 1000 ha; n = 10) within two watersheds (< 1500 ha) burned by the 2012 High Park Fire in northcentral Colorado, USA. Our objectives were to: (1) identify sources and quantify magnitudes of post-fire runoff and erosion at nested hillslopes and watersheds for two rain storms with varied duration, intensity and antecedent precipitation; and (2) assess the factors affecting the magnitude and connectivity of runoff and sediment across spatial scales for these two rain storms. The two summer storms that are the focus of this research occurred during the third summer after burning. The first storm had low intensity rainfall over 11 hours (return interval <1–2 years), whereas the second event had high intensity rainfall over 1 hour (return interval <1–10 years). The lower intensity storm was preceded by high antecedent rainfall and led to low hillslope sediment yields and channel incision at most locations, whereas the high intensity storm led to infiltration-excess overland flow, high sediment yields, in-stream sediment deposition and channel substrate fining. For both storms, hillslope-to-stream sediment delivery ratios and area-normalised cross-sectional channel change increased with the percent of catchment that burned at high severity. For the high intensity storm, hillslope-to-stream sediment delivery ratios decreased with unconfined channel length (%). The findings quantify post-fire connectivity and sediment delivery from hillslopes and streams, and highlight how different types of storms can cause varying magnitues and spatial patterns of sediment transport and deposition from hillslopes through stream channel networks.  相似文献   

The limited role of aquifer heterogeneity on metal reduction in an Atlantic coastal plain determined by push-pull tests     

Brian J. Mailloux  Stephanie Devlin  Mark E. Fuller  T.C. Onstott  Mary F. DeFlaun  Keun-Hyung Choi  Maria Green-Blum  Donald J.P. Swift  John McCarthy  Hailiang Dong 《Applied Geochemistry》2007

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The effect of lithology on valley width,terrace distribution,and bedload provenance in a tectonically stable catchment with flat‐lying stratigraphy          下载免费PDF全文

Amanda Keen‐Zebert  Mark R. Hudson  Stephanie L. Shepherd  Evan A. Thaler 《地球表面变化过程与地形》2017,42(10):1573-1587

How rock resistance or erodibility affects fluvial landforms and processes is an outstanding question in geomorphology that has recently garnered attention owing to the recognition that the erosion rates of bedrock channels largely set the pace of landscape evolution. In this work, we evaluate valley width, terrace distribution, and bedload provenance in terms of reach scale variation in lithology in the study reach and discuss the implications for landscape evolution in a catchment with relatively flat‐lying stratigraphy and very little uplift. A reach of the Buffalo National River in Arkansas was partitioned into lithologic reaches and the mechanical and chemical resistance of the main lithologies making up the catchment was measured. Valley width and the spatial distribution of terraces were compared among the different lithologic reaches. The surface grain size and provenance of coarse (2–90 mm) sediment of both modern gravel bars and older terrace deposits that make up the former bedload were measured and defined. The results demonstrate a strong impact of lithology upon valley width, terrace distribution, and bedload provenance and therefore, upon landscape evolution processes. Channel down‐cutting through different lithologies creates variable patterns of resistance across catchments and continents. Particularly in post‐tectonic and non‐tectonic landscapes, the variation in resistance that arises from the exhumation of different rocks in channel longitudinal profiles can impact local base levels, initiating responses that can be propagated through channel networks. The rate at which that response is transmitted through channels is potentially amplified and/or mitigated by differences between the resistance of channel beds and bedload sediment loads. In the study reach, variation in lithologic resistance influences the prevalence of lateral and vertical processes, thus producing a spatial pattern of terraces that reflects rock type rather than climate, regional base level change, or hydrologic variability. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献