Flow,stress and sediment resuspension in a shallow tidal channel     

Steven traynum  Richard Styles 《Estuaries and Coasts》2007,30(1):94-101

In October of 2004, a 3-d observational program to measure flow and sediment resuspension within a coastal intertidal salt marsh was conducted in the North Inlet/Winyah Bay National Estuarine Research Reserve located near Georgetown, South Carolina. Current and acoustic backscatter profiles were obtained from a moored acoustic Doppler current profiler (ADCP) deployed in a shallow tidal channel during the spring phase of the tidal cycle under high discharge conditions. The channel serves as a conduit between Winyah Bay, a large brackish estuary, and North Inlet, a saline intertidal coastal salt marsh with little freshwater input. Salinity measurements indicate that the water column is vertically well mixed during flood, but becomes vertically stratified during early ebb. The stratification results from brackish (15 psu) Winyah Bay water entering North Inlet via the tidal channel, suggesting an exchange mechanism that permits North Inlet to receive a fraction of the poor water quality and high discharge flow from upland rivers. Although maximum flood currents exceed maximum ebb currents by 0.2 m s⁻¹, suspended sediment concentrations are highest during the latter ebb phase and persist for a longer fraction of the ebb cycle. Even though the channel is flood-dominated, the higher concentrations occurring over a longer fraction of the ebb phase indicate net particulate transport from Winyah Bay to North Inlet during spring tide accompanied by high discharge. Our evidence suggests that the higher concentrations during ebb result from increased bed friction caused by flow asymmetries and variations in water depth in which the highest stresses occur near the end of ebb near low water despite stronger maximum currents during flood.  相似文献   

Geochemical Evidence for Slab Melting in the Trans-Mexican Volcanic Belt   总被引：3，自引：0，他引：3  

Gomez-Tuena  Arturo; Langmuir  Charles H.; Goldstein  Steven L.; Straub  Susanne M.; Ortega-Gutierrez  Fernando 《Journal of Petrology》2007,48(3):537-562

Geochemical studies of Plio-Quaternary volcanic rocks from theValle de Bravo–Zitácuaro volcanic field (VBZ) incentral Mexico indicate that slab melting plays a key role inthe petrogenesis of the Trans-Mexican Volcanic Belt. Rocks fromthe VBZ are typical arc-related high-Mg andesites, but two differentrock suites with distinct trace element patterns and isotopiccompositions erupted concurrently in the area, with a traceelement character that is also distinct from that of other Mexicanvolcanoes. The geochemical differences between the VBZ suitescannot be explained by simple crystal fractionation and/or crustalassimilation of a common primitive magma, but can be reconciledby the participation of different proportions of melts derivedfrom the subducted basalt and sediments interacting with themantle wedge. Sr/Y and Sr/Pb ratios of the VBZ rocks correlateinversely with Pb and Sr isotopic compositions, indicating thatthe Sr and Pb budgets are strongly controlled by melt additionsfrom the subducted slab. In contrast, an inverse correlationbetween Pb(Th)/Nd and ¹⁴³Nd/¹⁴⁴Nd ratios, which extend to lowerisotopic values than those for Pacific mid-ocean ridge basalts,indicates the participation of an enriched mantle wedge thatis similar to the source of Mexican intraplate basalts. In addition,a systematic decrease in middle and heavy rare earth concentrationsand Nb/Ta ratios with increasing SiO₂ contents in the VBZ rocksis best explained if these elements are mobilized to some extentin the subduction flux, and suggests that slab partial fusionoccurred under garnet amphibolite-facies conditions. KEY WORDS: arcs; mantle; Mexico; sediment melting; slab melting  相似文献   

The energy balance experiment EBEX-2000. Part II: Intercomparison of eddy-covariance sensors and post-field data processing methods     

Matthias Mauder  Steven P. Oncley  Roland Vogt  Tamas Weidinger  Luis Ribeiro  Christian Bernhofer  Thomas Foken  Wim Kohsiek  Henk A. R. De Bruin  Heping Liu 《Boundary-Layer Meteorology》2007,123(1):29-54

The eddy-covariance method is the primary way of measuring turbulent fluxes directly. Many investigators have found that these flux measurements often do not satisfy a fundamental criterion—closure of the surface energy balance. This study investigates to what extent the eddy-covariance measurement technology can be made responsible for this deficiency, in particular the effects of instrumentation or of the post-field data processing. Therefore, current eddy-covariance sensors and several post-field data processing methods were compared. The differences in methodology resulted in deviations of 10% for the sensible heat flux and of 15% for the latent heat flux for an averaging time of 30 min. These disparities were mostly due to different sensor separation corrections and a linear detrending of the data. The impact of different instrumentation on the resulting heat flux estimates was significantly higher. Large deviations from the reference system of up to 50% were found for some sensor combinations. However, very good measurement quality was found for a CSAT3 sonic together with a KH20 krypton hygrometer and also for a UW sonic together with a KH20. If these systems are well calibrated and maintained, an accuracy of better than 5% can be achieved for 30-min values of sensible and latent heat flux measurements. The results from the sonic anemometers Gill Solent-HS, ATI-K, Metek USA-1, and R.M. Young 81000 showed more or less larger deviations from the reference system. The LI-COR LI-7500 open-path H₂O/CO₂ gas analyser in the test was one of the first serial numbers of this sensor type and had technical problems regarding direct solar radiation sensitivity and signal delay. These problems are known by the manufacturer and improvements of the sensor have since been made. The National Center for Atmospheric Research is supported by the National Science Foundation.  相似文献   

The Role of Residential Location in Conditioning the Effect of Metropolitan Economic Structure on Male Youth Employment     

Steven R. Holloway 《The Professional geographer》1998,50(1):31-45

Youths have increasingly experienced labor market problems over the last several decades. One fruitful line of explanation focuses on structural changes in the demand for labor stemming from deindustrialization, changing skill requirements for employees, and increasing supply competition from women and recent immigrants. While these explanations merit attention, they have not adequately considered facts that condition their impact. This paper considers the argument that intra-metropolitan residential location conditions the effects of metropolitan labor market structure on black and white male youths' employment probabilities. Using a sample of individual-level data drawn from the 1990 census combined with metropolitan-level indicators of economic structure, it was found that some structural effects varied between central-city and suburban male youths. The conditioning role of residential location, and the subsequent nature of the structural effects, varied considerably between black and white male youths. Interpretations of the conditioning role of residential location include a variety of social and institutional effects on individual residents and the stigmatizing effects of some neighborhoods, especially on black male youths.  相似文献   

Rock-weathering rates as functions of time   总被引：2，自引：0，他引：2  

Steven M. Colman 《Quaternary Research》1981,15(3):250-264

The scarcity of documented numerical relations between rock weathering and time has led to a common assumption that rates of weathering are linear. This assumption has been strengthened by studies that have calculated long-term average rates. However, little theoretical or empirical evidence exists to support linear rates for most chemical-weathering processes, with the exception of congruent dissolution processes. The few previous studies of rock-weathering rates that contain quantitative documentation of the relation between chemical weathering and time suggest that the rates of most weathering processes decrease with time. Recent studies of weathering rinds on basaltic and andesitic stones in glacial deposits in the western United States also clearly demonstrate that rock-weathering processes slow with time. Some weathering processes appear to conform to exponential functions of time, such as the square-root time function for hydration of volcanic glass, which conforms to the theoretical predictions of diffusion kinetics. However, weathering of mineralogically heterogeneous rocks involves complex physical and chemical processes that generally can be expressed only empirically, commonly by way of logarithmic time functions. Incongruent dissolution and other weathering processes produce residues, which are commonly used as measures of weathering. These residues appear to slow movement of water to unaltered material and impede chemical transport away from it. If weathering residues impede weathering processes then rates of weathering and rates of residue production are inversely proportional to some function of the residue thickness. This results in simple mathematical analogs for weathering that imply nonlinear time functions. The rate of weathering becomes constant only when an equilibrium thickness of the residue is reached. Because weathering residues are relatively stable chemically, and because physical removal of residues below the ground surface is slight, many weathering features require considerable time to reach constant rates of change. For weathering rinds on volcanic stones in the western United States, this time is at least 0.5 my.  相似文献   

Age of amphibolites associated with alpine peridotites in the Dinaride ophiolite zone,Yugoslavia   总被引：1，自引：0，他引：1  

Marvin A. Lanphere  Robert G. Coleman  Steven Karamata  Jakob Pamić 《Earth and Planetary Science Letters》1975,26(3):271-276

Amphibolites associated with alpine peridotites in the Central Ophiolite zone in Yugoslavia have K-Ar ages of 160–170 m.y. These amphibolites and associated peridotites underwent deep-seated metamorphism prior to tectonic emplacement into the sedimentary-volcanic assemblage of the Dinarides. The alpine peridotites and associated local rocks of the ophiolite suite are interpreted as Jurassic oceanic crust and upper mantle.  相似文献   

Evaluation of biogeochemical prospecting methods in the search for sulfide deposits in the Appalachian piedmont, Virginia, U.S.A.     

Steven W. Leavitt  H.Grant Goodell 《Journal of Geochemical Exploration》1979,11(1):89-100

Soil and stream sediment sampling have been the primary geochemical exploration tools in the Appalachian piedmont to date. However, the great thicknesses of soil and saprolite found in the region coupled with the dense vegetation frequently encountered favor biogeochemistry as an alternative or supplemental method since deep-rooted plants sample closer to bedrock. To evaluate this method, an orientation survey was performed in which soils and vegetation at 17 sites north of Mineral, Virginia, were sampled and analyzed for Ag, Cd, Cu, Pb and Zn. The traverse included stations over the host rocks of massive sulfide mineralization, as well as over apparent “barren” country rock. Samples were analyzed by atomic absorption spectrophotometry using standard digestion and analytical techniques.Both A- and B-horizon soil metals generally appear to be reliable indicators of mineralization, with soils developed over sulfides showing up to three-fold enrichment in metal content relative to the average soils developed on the country rock. Correlation of metal concentrations in vegetation to soil metal concentrations reveal plant concentrations expressed on a dry-weight basis correlate stronger and more frequently to soil metals than do ash-weight concentrations. Copper shows some promise in selected organs and species, Ag appears fair but data are limited to one organ of one species, and plant Pb seems totally unresponsive to soil metal concentrations perhaps because foliar absorption is an important plant uptake mechanism here. However, Zn and Cd in organs of the oak group, especially mature leaves and twigs of the current year's growth show the greatest promise as prospecting tools. They correlate well with soil metals and when compared directly to the geology they reliably reflect mineralization. Although results using White oak were slightly less profound than those obtained from the Black-Red oak group, White oak may be preferred as it is a single, more widespread, easily-identifiable species. Copper and especially Zn although essential elements to plants, do not appear to be “difficult” elements for biogeochemical prospecting in the Appalachian piedmont.  相似文献   

Kepone®: Toxicity and bioaccumulation in blue crabs     

Steven C. Schimmel  James M. Patrick  Linda F. Faas  Jerry L. Oglesby  Alfred J. Wilson 《Estuaries and Coasts》1979,2(1):9-15

Two long-term studies were conducted to determine toxicity, uptake and depuration of Kepone in blue crabs (Callinectes sapidus). In the first, Kepone was administered to crabs in seawater (0.03 or 0.3 μg Kepone/I) or food (eastern oyster,Crassostrea virginica, containing 0.25 μg/g Kepone). Uptake of Kepone in 28 days was primarily through the contaminated oysters. When these crabs were held in Kepone-free seawater and fed Kepone-free oysters for 28 days, no loss of the insecticide was evident. There were adverse effects on molting and survival in crabs fed oysters that contained 0.25 μg/g Kepone. A second study was conducted to determine: (1) the depuration of Kepone over a 90-day period in blue crabs fed oysters from the James River, Virginia (containing 0.15 μg/g Kepone); and (2) the effects of Kepone on molting and survival of blue crabs fed James River oysters or laboratory-contaminated oysters that contained 0.15 or 1.9 μg/g Kepone. Crabs fed Kepone-contaminated oysters followed by a diet of Kepone-free oysters for 90 days had detectable concentrations of the insecticide in tissues. Also, blue crabs that ate oysters containing Kepone in concentrations similar to those found in oysters from the James River, died or molted less frequently than crabs fed Kepone-free oysters meats.  相似文献   

Silica in Lake Superior: mass balance considerations and a model for dynamic response to eutrophication     

Thomas C. Johnson  Steven J. Eisenreich 《Geochimica et cosmochimica acta》1979,43(1):77-92

The dissolved silica concentration in waters of Lake Superior probably is in a steady state because it is not influenced significantly by man, and the climate, topography and vegetation in the drainage area of the lake have been stable for the past 4000 years. Therefore the rate at which dissolved silica is introduced to the lake should equal the output rate.The primary inputs are: tributaries (4.1–4.6 × 10⁸kgSiO₂/yr), diffusion from sediment pore waters (0.21?0.78 × 10⁸kgSiO₂/yr) and atmospheric loading (0.26 × 10⁸kgSiO₂/yr). Silica is lost from the lake waters by: outflow through the St. Marys River, diatom deposition, adsorption onto particulates in the sediments, and authigenic formation of new silicate minerals. Tributary outflow accounts for less than one half the annual input of silica, and diatom deposition and silica adsorption withdraw less than 10% of the annual input. Therefore the formation of new silicate phases must be the dominant sink for dissolved silica in Lake Superior. The specific phases formed are not identified in the bottom sediments. X-ray diffraction studies suggest that smectite is one product, and amorphous ferroaluminum silicates may be another product.Mathematical modeling of the dissolved silica response to lake eutrophication suggests that the phosphate loading to Lake Superior would have to increase by about 250-fold to cause a silica depletion rate equal to that reported for Lake Michigan, assuming no change in the rate of upwelling of deep waters.  相似文献   

Carbon Dioxide in igneous petrogenesis: I     

Frank J. Spera  Steven C. Bergman 《Contributions to Mineralogy and Petrology》1980,74(1):55-66

A number of experimental CO₂ solubility data for silicate and aluminosilicate melts at a variety of P- T conditions are consistent with solution of CO₂ in the melt by polymer condensation reactions such as SiO _4(m ^4? +CO_2(v)+Si _n O _3n+1(m) ⁽²ⁿ⁺¹⁾ ?Si _n+1O _3n+4(m) ^(2n+4)? +CO _3(m ^)2? . For various metalsilicate systems the relative solubility of CO₂ should depend markedly on the relative Gibbs free change of reaction. Experimental solubility data for the systems Li₂O-SiO₂, Na₂O-SiO₂, K₂O-SiO₂, CaO-SiO₂, MgO-SiO₂ and other aluminosilicate melts are in complete accord with predictions based on Gibbs Free energies of model polycondesation reactions. A rigorous thermodynamic treatment of published P- T-wt.% CO₂ solubility data for a number of mineral and natural melts suggests that for the reaction CO_2(m) ? CO_2(v)

1. CO₂-melt mixing may be considered ideal (i.e., { \(a_{{\text{CO}}_{\text{2}} }^m = X_{{\text{CO}}_{\text{2}} }^m \) );
2. \(\bar V_{{\text{CO}}_{\text{2}} }^m \) , the partial molal volume of CO₂ in the melt, is approximately equal to 30 cm³ mole^?1 and independent of P and T;
3. Δ C _p ⁰ is approximately equal to zero in the T range 1,400° to 1,650 °C and
4. enthalpies and entropies of the dissolution reaction depend on the ratio of network modifiers to network builders in the melt. Analytic expressions which relate the CO₂ content of a melt to P, T, and \(f_{{\text{CO}}_{\text{2}} } \) for andesite, tholeiite and olivine melilite melts of the form

$$\ln X_{{\text{CO}}_{\text{2}} }^m = \ln f_{{\text{CO}}_{\text{2}} } - \frac{A}{T} - B - \frac{C}{T}(P - 1)$$ have been determined. Regression parameters are (A, B, C): andesite (3.419, 11.164, 0.408), tholeiite (14.040, 5.440,0.393), melilite (9.226, 7.860, 0.352). The solubility equations are believed to be accurate in the range 3<P<30 kbar and 1,100°<T<1,650 °C. A series of CO₂ isopleth diagrams for a wide range of T and P are drawn for andesitic, tholeiitic and alkalic melts.  相似文献