Assessment of MTBE biodegradation in contaminated groundwater using C and C analysis: Field and laboratory microcosm studies     

Steven F. Thornton  Simon H. Bottrell  Keith H. Spence  Roger Pickup  Michael J. Spence  Nadeem Shah  Helen E.H. Mallinson  Hans H. Richnow 《Applied Geochemistry》2011,26(5):828-837

Radiolabelled assays and compound-specific stable isotope analysis (CSIA) were used to assess methyl tert-butyl ether (MTBE) biodegradation in an unleaded fuel plume in a UK chalk aquifer, both in the field and in laboratory microcosm experiments. The ¹⁴C-MTBE radiorespirometry studies demonstrated widespread potential for aerobic and anaerobic MTBE biodegradation in the aquifer. However, δ¹³C compositions of MTBE in groundwater samples from the plume showed no significant ¹³C enrichment that would indicate MTBE biodegradation at the field scale. Carbon isotope enrichment during MTBE biodegradation was assessed in the microcosms when dissolved O₂ was not limiting, compared with low in situ concentrations (2 mg/L) in the aquifer, and in the absence of O₂. The microcosm experiments showed ubiquitous potential for aerobic MTBE biodegradation in the aquifer within hundreds of days. Aerobic MTBE biodegradation in the microcosms produced an enrichment of 7‰ in the MTBE δ¹³C composition and an isotope enrichment factor (ε) of −1.53‰ when dissolved O₂ was not limiting. However, for the low dissolved O₂ concentration of up to 2 mg/L that characterizes most of the MTBE plume fringe, aerobic MTBE biodegradation produced an enrichment of 0.5-0.7‰, corresponding to an ε value of −0.22‰ to −0.24‰. No anaerobic MTBE biodegradation occurred under these experimental conditions. These results suggest the existence of a complex MTBE-biodegrading community in the aquifer, which may consist of different aerobic species competing for MTBE and dissolved O₂. Under low O₂ conditions, the lower fractionating species have been shown to govern overall MTBE C-isotope fractionation during biodegradation, confirming the results of previous laboratory experiments mixing pure cultures. This implies that significant aerobic MTBE biodegradation could occur under the low dissolved O₂ concentration that typifies the reactive fringe zone of MTBE plumes, without producing detectable changes in the MTBE δ¹³C composition. This observed insensitivity of C isotope enrichment to MTBE biodegradation could lead to significant underestimation of aerobic MTBE biodegradation at field scale, with an unnecessarily pessimistic performance assessment for natural attenuation. Site-specific C isotope enrichment factors are, therefore, required to reliably quantify MTBE biodegradation, which may limit CSIA as a tool for the in situ assessment of MTBE biodegradation in groundwater using only C isotopes.  相似文献   

A methodology to constrain the parameters of a hydrogeological discrete fracture network model for sparsely fractured crystalline rock,exemplified by data from the proposed high-level nuclear waste repository site at Forsmark,Sweden   总被引：3，自引：1，他引：2  

Sven Follin  Lee Hartley  Ingvar Rhén  Peter Jackson  Steven Joyce  David Roberts  Ben Swift 《Hydrogeology Journal》2014,22(2):313-331

The large-scale geological structure of the crystalline rock at the proposed high-level nuclear waste repository site at Forsmark, Sweden, has been classified in terms of deformation zones of elevated fracture frequency. The rock between deformation zones was divided into fracture domains according to fracture frequency. A methodology to constrain the geometric and hydraulic parameters that define a discrete fracture network (DFN) model for each fracture domain is presented. The methodology is based on flow logging and down-hole imaging in cored boreholes in combination with DFN realizations, fracture connectivity analysis and pumping test simulations. The simulations suggest that a good match could be obtained for a power law size distribution where the value of the location parameter equals the borehole radius but with different values for the shape parameter, depending on fracture domain and fracture set. Fractures around 10–100 m in size are the ones that typically form the connected network, giving inflows in the simulations. The report also addresses the issue of up-scaling of DFN properties to equivalent continuous porous medium (ECPM) bulk flow properties. Comparisons with double-packer injection tests provide confidence that the derived DFN formulation of detailed flows within individual fractures is also suited to simulating mean bulk flow properties and their spatial variability.  相似文献   

Petrochemistry and hydrothermal alteration within the Tyrone Igneous Complex,Northern Ireland: implications for VMS mineralization in the British and Irish Caledonides     

Steven P. Hollis  Stephen Roberts  Garth Earls  Richard Herrington  Mark R. Cooper  Stephen J. Piercey  Sandy M. Archibald  Martin Moloney 《Mineralium Deposita》2014,49(5):575-593

Although volcanogenic massive sulfide (VMS) deposits can form within a wide variety of rift-related tectonic environments, most are preserved within suprasubduction affinity crust related to ocean closure. In stark contrast to the VMS-rich Appalachian sector of the Grampian-Taconic orogeny, VMS mineralization is rare in the peri-Laurentian British and Irish Caledonides. Economic peri-Gondwanan affinity deposits are limited to Avoca and Parys Mountain. The Tyrone Igneous Complex of Northern Ireland represents a ca. 484–464 Ma peri-Laurentian affinity arc–ophiolite complex and a possible broad correlative of the Buchans-Robert’s Arm belt of Newfoundland, host to some of the most metal-rich VMS deposits globally. Stratigraphic horizons prospective for VMS mineralization in the Tyrone Igneous Complex are associated with rift-related magmatism, hydrothermal alteration, synvolcanic faults, and high-level subvolcanic intrusions (gabbro, diorite, and/or tonalite). Locally intense hydrothermal alteration is characterized by Na-depletion, elevated SiO₂, MgO, Ba/Sr, Bi, Sb, chlorite–carbonate–pyrite alteration index (CCPI) and Hashimoto alteration index (AI) values. Rift-related mafic lavas typically occur in the hanging wall sequences to base and precious metal mineralization, closely associated with ironstones and/or argillaceous sedimentary rocks representing low temperature hydrothermal venting and volcanic quiescence. In the ca. 475 Ma pre-collisional, calc-alkaline lower Tyrone Volcanic Group rift-related magmatism is characterized by abundant non-arc type Fe-Ti-rich eMORB, island-arc tholeiite, and low-Zr tholeiitic rhyolite breccias. These petrochemical characteristics are typical of units associated with VMS mineralization in bimodal mafic, primitive post-Archean arc terranes. Following arc-accretion at ca. 470 Ma, late rifting in the ensialic upper Tyrone Volcanic Group is dominated by OIB-like, subalkaline to alkali basalt and A-type, high-Zr rhyolites. These units are petrochemically favorable for Kuroko-type VMS mineralization in bimodal-felsic evolved arc terranes. The scarcity of discovered peri-Laurentian VMS mineralization in the British and Irish Caledonides is due to a combination of minimal exploration, poor-preservation of upper ophiolite sequences, and limited rifting in the Lough Nafooey arc of western Ireland. The geological and geochemical characteristics of the Tyrone Volcanic Group of Northern Ireland and peri-Gondwanan affinity arc/backarc sequences of Ireland and northwest Wales represent the most prospective sequences in the British and Irish Caledonides for VMS mineralization.  相似文献   

Phase Mixing in Unperturbed and Perturbed Hamiltonian Systems     

Henry E. Kandrup  Steven J. Novotny 《Celestial Mechanics and Dynamical Astronomy》2004,88(1):1-35

This paper summarises a numerical investigation of phase mixing in time-independent Hamiltonian systems that admit a coexistence of regular and chaotic phase space regions, allowing also for low amplitude perturbations idealised as periodic driving, friction, and/or white and coloured noise. The evolution of initially localised ensembles of orbits was probed through lower order moments and coarse-grained distribution functions. In the absence of time-dependent perturbations, regular ensembles disperse initially as a power law in time and only exhibit a coarse-grained approach towards an invariant equilibrium over comparatively long times. Chaotic ensembles generally diverge exponentially fast on a time scale related to a typical finite time Lyapunov exponent, but can exhibit complex behaviour if they are impacted by the effects of cantori or the Arnold web. Viewed over somewhat longer times, chaotic ensembles typical converge exponentially towards an invariant or near-invariant equilibrium. This, however, need not correspond to a true equilibrium, which may only be approached over very long time scales. Time-dependent perturbations can dramatically increase the efficiency of phase mixing, both by accelerating the approach towards a near-equilibrium and by facilitating diffusion through cantori or along the Arnold web so as to accelerate the approach towards a true equilibrium. The efficacy of such perturbations typically scales logarithmically in amplitude, but is comparatively insensitive to most other details, a conclusion which reinforces the interpretation that the perturbations act via a resonant coupling.  相似文献   

Nutrient limitation,hydrology and watershed nitrogen loss     

Steven S. Perakis 《水文研究》2002,16(17):3507-3511

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Jobs in Geography?     

Steven K. Pontius 《The Professional geographer》1973,25(3):277-279

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The nature of the dwarf population in Abell 868     

Peter J. Boyce  Steven Phillipps  J. Bryn Jones  Simon P. Driver  Rodney M. Smith  Warrick J. Couch 《Monthly notices of the Royal Astronomical Society》2001,328(1):277-282

We present the results of a study of the morphology of the dwarf galaxy population in Abell 868, a rich, intermediate-redshift     cluster which has a galaxy luminosity function (LF) with a steep faint-end slope     . A statistical background subtraction method is employed to study the     colour distribution of the cluster galaxies. This distribution suggests that the galaxies contributing to the faint-end of the measured cluster LF can be split into three populations: dwarf irregular galaxies (dIrrs) with     dwarf elliptical galaxies (dEs) with     and contaminating background giant ellipticals (gEs) with     . The removal of the contribution of the background gEs from the counts only marginally lessens the faint-end slope     . However, the removal of the contribution of the dIrrs from the counts produces a flat LF     . The dEs and the dIrrs have similar spatial distributions within the cluster, except that the dIrrs appear to be totally absent within a central projected radius of about 0.2 Mpc     . The number densities of both dEs and dIrrs appear to fall off beyond a projected radius of ≃ 0.35 Mpc. We suggest that the dE and dIrr populations of A868 have been associated with the cluster for similar time-scales, but evolutionary processes such as 'galaxy harassment' tend to fade the dIrr galaxies while having a much smaller effect on the dE galaxies. The harassment would be expected to have the greatest effect on dwarfs residing in the central parts of the cluster.  相似文献   

Sand sheets and ventifacts: the legacy of aeolian action in west Norfolk, UK   总被引：2，自引：1，他引：1  

Peter G. HoareC. Robin Stevenson  Steven P. Godby 《Proceedings of the Geologists' Association. Geologists' Association》2002,113(4):301-317

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Calculating capillary pressures in frozen and ice-free soils below the melting temperature     

Steven A. Grant  Ronald S. Sletten 《Environmental Geology》2002,42(2-3):130-136

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Multiple generations of hibonite in spinel-hibonite inclusions from Murchison     

Steven B. SIMON  Lawrence GROSSMAN  Andrew M. DAVIS 《Meteoritics & planetary science》1997,32(2):259-269

Abstract— Through freeze-thaw disaggregation of the Murchison meteorite, we have recovered, in addition to many spinel-hibonite spherules, several hibonite-rich inclusion fragments in which the hibonite has wider ranges in TiO₂ contents (e.g., 0.07–8.6 wt% in one inclusion and 2–10 wt% in another) than previously observed within single inclusions. In these inclusions, there are sharp contacts between texturally early, Ti-poor hibonite and relatively late, Ti-rich hibonite, and the two types occur in complex intergrowth textures that are not consistent with crystallization from a melt in a single-stage cooling event. One inclusion has, in addition to relatively TiO₂-rich hibonite, some that is virtually TiO₂-free but contains ～1 wt% MgO and ～1.5 wt% SiO₂. Instead of the common substitution of Mg + Ti for 2Al, Mg coupled with Si in this case, probably reflecting crystallization from an unusual, Ti-free silicate liquid. Ion microprobe analyses of Ti-rich and Ti-poor hibonite from this inclusion yield quite similar trace-element patterns and Mg-isotopic compositions. The results are most consistent with formation of Ti-rich hibonite from Ti-poor hibonite by addition of Mg and Ti to the latter by exchange with a hot, Ti-rich liquid. That this occurred without a resolvable change in the Mg-isotopic composition requires that the Ti-rich, second generation of hibonite formed <2.5 times 10⁵ yr later than the Ti-poor hibonite. Observations of spinel-hibonite spherules and spherule fragments in our sample suite provide additional evidence that, despite the claims by Greenwood et al. (1994), spinel-hibonite spherules crystallized from individual, molten droplets, as earlier suggested by Macdougall (1981) and MacPherson et al. (1983).  相似文献